This is a modern-English version of The Art of Perfumery, and Methods of Obtaining the Odors of Plants: With Instructions for the Manufacture of Perfumes for the Handkerchief, Scented Powders, Odorous Vinegars, Dentifrices, Pomatums, Cosmetics, Perfumed Soap, Etc., to which is Added an Appendix on Preparing Artificial Fruit-Essences, Etc., originally written by Piesse, G. W. Septimus (George William Septimus).
It has been thoroughly updated, including changes to sentence structure, words, spelling,
and grammar—to ensure clarity for contemporary readers, while preserving the original spirit and nuance. If
you click on a paragraph, you will see the original text that we modified, and you can toggle between the two versions.
Scroll to the bottom of this page and you will find a free ePUB download link for this book.
The Art
OF
PERFUMERY,
AND METHOD OF OBTAINING
THE ODORS OF PLANTS.

From the rafters of the roof of the Drying House are suspended in bunches all the herbs that the grower cultivates. To accelerate the desiccation of rose leaves and other petals, the Drying House is fitted up with large cupboards, which are slightly warmed with a convolving flue, heated from a fire below.
From the rafters of the Drying House, all the herbs grown by the farmer hang in bunches. To speed up the drying of rose leaves and other petals, the Drying House is equipped with large cabinets that are gently warmed by a circulating flue heated by a fire below.
The flower buds are placed upon trays made of canvas stretched upon a frame rack, being not less than twelve feet long by four feet wide. When charged they are placed on shelves in the warm cupboards till dry.
The flower buds are placed on trays made of canvas stretched over a frame that measures at least twelve feet long and four feet wide. Once filled, they are placed on shelves in the warm cupboards until they are dry.
THE ART OF PERFUMERY,
AND METHOD OF OBTAINING THE ODORS OF PLANTS,
WITH INSTRUCTIONS FOR THE MANUFACTURE OF PERFUMES FOR THE HANDKERCHIEF, SCENTED POWDERS, ODOROUS VINEGARS, DENTIFRICES, POMATUMS, COSMETIQUES, PERFUMED SOAP, ETC.
WITH AN APPENDIX ON THE COLORS OF FLOWERS, ARTIFICIAL FRUIT ESSENCES, ETC. ETC.

BY G.W. SEPTIMUS PIESSE,
AUTHOR OF THE "ODORS OF FLOWERS," ETC. ETC.
Preface.
By universal consent, the physical faculties of man have been divided into five senses,—seeing, hearing, touching, tasting, and smelling. It is of matter pertaining to the faculty of Smelling that this book mainly treats. Of the five senses, that of smelling is the least valued, and, as a consequence, is the least tutored; but we must not conclude from this, our own act, that it is of insignificant importance to our welfare and happiness.
By general agreement, human abilities are categorized into five senses—sight, hearing, touch, taste, and smell. This book primarily focuses on the sense of smell. Of the five senses, smell is often underestimated and, as a result, is the least exercised; however, we shouldn’t assume from our actions that it isn't vital to our well-being and happiness.
By neglecting to tutor the olfactory nerve, we are constantly led to breathe impure air, and thus poison the body by neglecting the warning given at the gate of the lungs. Persons who use perfumes are more sensitive to the presence of a vitiated atmosphere than those who consider the faculty of smelling as an almost useless gift.
By ignoring the need to train our sense of smell, we constantly breathe in dirty air and, as a result, harm our bodies by ignoring the signals from our lungs. People who wear perfumes are more aware of a polluted environment than those who think of the sense of smell as nearly worthless.
In the early ages of the world the use of perfumes was in constant practice, and it had the high sanction of Scriptural authority.
In the early days of the world, the use of perfumes was a common practice, and it had strong support from Scriptural authority.
The patrons of perfumery have always been considered the most civilized and refined people of the earth. If refinement consists in knowing how to enjoy the faculties which we possess, then must we learn not only how to distinguish the harmony of color and form, in order to please the sight, the melody of sweet sounds to delight the ear; the comfort of appropriate fabrics to cover the body, and to please the touch, but the smelling faculty must be shown how to gratify itself with the odoriferous products of the garden and the forest.
The supporters of perfume have always been seen as the most cultured and sophisticated people on the planet. If sophistication means knowing how to enjoy our senses, then we need to understand not just how to appreciate the beauty of color and shape to please our eyes, the lovely sounds to delight our ears, the comfort of fitting fabrics for our bodies, and to satisfy our sense of touch, but we also have to train our sense of smell to enjoy the fragrant offerings of the garden and the forest.
Pathologically considered, the use of perfumes is in the highest degree prophylactic; the refreshing qualities of the citrine odors to an invalid is well known. Health has often been restored when life and death trembled in the balance, by the mere sprinkling of essence of cedrat in a sick chamber.
Pathologically speaking, using perfumes is extremely preventative; the refreshing qualities of citrus scents for someone who's unwell are well known. Health has often been restored when life and death were hanging in the balance, just by the simple act of sprinkling essence of citron in a sickroom.
The commercial value of flowers is of no mean importance to the wealth of nations. But, vast as is the consumption of perfumes by the people under the rule of the British Empire, little has been done in England towards the establishment of flower-farms, or the production of the raw odorous substances in demand by the manufacturing perfumers of Britain; consequently nearly the whole are the produce of foreign countries. However, I have every hope that ere long the subject will attract the attention of the Society of Arts, and favorable results will doubtless follow. Much of the waste land in England, and especially in Ireland, could be very profitably employed if cultivated with odor-bearing plants.
The commercial value of flowers is really important to the wealth of nations. But despite the high demand for perfumes among people in the British Empire, not much has been done in England to establish flower farms or produce the raw fragrant materials that British perfumers need; as a result, almost all of it is imported from other countries. However, I'm hopeful that soon this will get the attention of the Society of Arts, and positive outcomes will likely follow. A lot of wasteland in England, especially in Ireland, could be very profitably used if it were cultivated with scent-bearing plants.
The climate of some of the British colonies especially fits them for the production of odors from flowers that require elevated temperature to bring them to perfection.
The climate of certain British colonies is particularly suited for producing fragrant flowers that need warmer temperatures to fully bloom.
But for the lamented death of Mr. Charles Piesse,[A] Colonial Secretary for Western Australia, I have every reason to believe that flower-farms would have been established in that colony long ere the publication of this work. Though thus personally frustrated in adapting a new and useful description of labor to British enterprise, I am no less sanguine of the final result in other hands.
But for the sad passing of Mr. Charles Piesse,[A] Colonial Secretary for Western Australia, I believe that flower farms would have been set up in that colony long before this work was published. Even though I couldn't personally contribute to applying a new and valuable form of labor to British business, I remain optimistic about the final outcome in the hands of others.
Mr. Kemble, of Jamaica, has recently sent to England some fine samples of Oil of Behn. The Moringa, from which it is produced, has been successfully cultivated by him. The Oil of Behn, being a perfectly inodorous fat oil, is a valuable agent for extracting the odors of flowers by the maceration process.
Mr. Kemble, from Jamaica, has recently sent some excellent samples of Oil of Behn to England. He has successfully cultivated the Moringa tree, from which this oil is made. Oil of Behn, which is a completely odorless fatty oil, is a valuable resource for extracting the scents of flowers using the maceration process.
At no distant period I hope to see, either at the Crystal Palace, Sydenham, at the Royal Botanical Gardens, Kew, or elsewhere, a place to illustrate the commercial use of flowers—eye-lectures on the methods of obtaining the odors of plants and their various uses. The horticulturists of England, being generally unacquainted with the methods of economizing the scents from the flowers they cultivate, entirely lose what would be a very profitable source of income. For many ages copper ore was thrown over the cliffs into the sea by the Cornish miners working the tin streams; how much wealth was thus cast away by ignorance we know not, but there is a perfect parallel between the old miners and the modern gardeners.
I hope to see, soon, either at the Crystal Palace, Sydenham, at the Royal Botanical Gardens, Kew, or elsewhere, a place to showcase the commercial use of flowers—visual lectures on how to extract the scents of plants and their various applications. The horticulturists in England, being mostly unaware of how to make the most of the fragrances from the flowers they grow, completely miss out on what could be a very lucrative source of income. For many years, Cornish miners working in the tin streams tossed copper ore off the cliffs into the sea; we can only imagine how much wealth was wasted due to ignorance, which mirrors the situation between the old miners and today's gardeners.
Many readers of the "Gardeners' Chronicle" and of the "Annals of Pharmacy and Chemistry" will recognize in the following pages much matter that has already passed under their eyes.
Many readers of the "Gardeners' Chronicle" and the "Annals of Pharmacy and Chemistry" will recognize a lot of the content on the following pages that they've already seen.
To be of the service intended, such matter must however have a book form; I have therefore collected from the above-mentioned periodicals all that I considered might be useful to the reader.
To be of the intended service, this information must be in book form; therefore, I have gathered from the previously mentioned periodicals everything I thought might be useful to the reader.
To Sir Wm. Hooker, Dr. Lindley, Mr. W. Dickinson, and Mr. W. Bastick, I respectfully tender my thanks for the assistance they have so freely given whenever I have had occasion to seek their advice.
To Sir Wm. Hooker, Dr. Lindley, Mr. W. Dickinson, and Mr. W. Bastick, I sincerely thank you for the help you've given me whenever I've needed your advice.
Contents.
Preface
SECTION I.
INTRODUCTION AND HISTORY.
Perfumes in use from the Earliest Periods—Origin lost in the Depth of its Antiquity—Possibly derived from Religious Observances—Incense or Frankincense burned in Honor of the Divinities—Early Christians put to Death for refusing to offer Incense to Idols—Use of perfumes by the Greeks and Romans—Pliny and Seneca observe that some of the luxurious People scent themselves Three Times a Day—Use of Incense in the Romish Church—Scriptural Authority for the use of Perfume—Composition of the Holy Perfume—The Prophet's Simile—St. Ephræm's Will—Fragrant Tapers—Constantine provides fragrant Oil to burn at the Altars—Frangipanni—Trade in the East in Perfume Drugs—The Art of Perfumery of little Distinction in England—Solly's admirable Remarks on Trade Secrets—British Horticulturists neglect to collect the Fragrance of the Flowers they cultivate—The South of France the principal Seat of the Art—England noted for Lavender—Some Plants yield more than one Perfume—Odor of Plants owing to a peculiar Principle known as Essential Oil or Otto
Perfumes have been used since ancient times—its origins are lost in deep antiquity—possibly stemming from religious rituals—incense or frankincense was burned to honor the gods—early Christians were killed for refusing to offer incense to idols—Greeks and Romans used perfumes—Pliny and Seneca noted that some wealthy people would scent themselves three times a day—incense is used in the Catholic Church—there is biblical support for using perfumes—the composition of holy perfume—the prophet's metaphor—St. Ephraim's will—fragrant candles—Constantine provided scented oil to burn at altars—frangipani—trade in perfumes in the East—perfumery in England lacks distinction—Solly’s valuable insights on trade secrets—British horticulturists fail to gather the scents from the flowers they grow—southern France is the main center for this art—England is known for lavender—some plants produce more than one scent—the fragrance of plants comes from a unique compound known as essential oil or otto.
SECTION II.
Consumption of Perfumery—Methods of obtaining the Odors:—Expression, Distillation, Maceration, Absorption
Consumption of Perfume—Ways to Get the Scents:—Cold Pressing, Distillation, Soaking, Absorption
SECTION III.
Steam-Still—Macerating Pan—Ottos exhibited at the Crystal Palace of 1851—Simple Extracts:—Allspice, Almond, Artificial Otto of Almonds, Anise, Balm, Balsams, Bay, Bergamot, Benzoin, Caraway, Cascarilla, Cassia, Cassie, Cedar, Cedrat, Cinnamon, Citron, Citronella, Clove, Dill, Eglantine or Sweet Brier, Elder, Fennel, Flag, Geranium, Heliotrope, Honeysuckle, Hovenia, Jasmine, Jonquil, Laurel, Lavender, Lemon-grass, Lilac, Lily, Mace, Magnolia, Marjoram, Meadow-sweet, Melissa, Mignonette, Miribane, Mint, Myrtle, Neroli, Nutmeg, Olibanum, Orange, Orris, Palm, Patchouly, Sweet Pea (Theory of Odors), Pineapple, Pink, Rhodium (Rose yields two Odors), Rosemary, Sage, Santal, Sassafras, Spike, Storax, Syringa, Thyme, Tonquin, Tuberose, Vanilla, Verbena or Vervain, Violet, Vitivert, Volkameria, Wallflower, Winter-green—Duty on Essential Oils—Quantity imported—Statistics, &c.,
Steam-Still—Macerating Pan—Ottos shown at the Crystal Palace of 1851—Simple Extracts:—Allspice, Almond, Artificial Otto of Almonds, Anise, Balm, Balsams, Bay, Bergamot, Benzoin, Caraway, Cascarilla, Cassia, Cassie, Cedar, Cedrat, Cinnamon, Citron, Citronella, Clove, Dill, Eglantine or Sweet Brier, Elder, Fennel, Flag, Geranium, Heliotrope, Honeysuckle, Hovenia, Jasmine, Jonquil, Laurel, Lavender, Lemon-grass, Lilac, Lily, Mace, Magnolia, Marjoram, Meadow-sweet, Melissa, Mignonette, Miribane, Mint, Myrtle, Neroli, Nutmeg, Olibanum, Orange, Orris, Palm, Patchouly, Sweet Pea (Theory of Odors), Pineapple, Pink, Rhodium (Rose yields two Odors), Rosemary, Sage, Santal, Sassafras, Spike, Storax, Syringa, Thyme, Tonquin, Tuberose, Vanilla, Verbena or Vervain, Violet, Vitivert, Volkameria, Wallflower, Winter-green—Duty on Essential Oils—Quantity imported—Statistics, &c.,
SECTION IV.
ANIMAL PERFUMES.
Ambergris—Civet—Musk
Ambergris—Civet—Musk
SECTION V.
Smelling Salts:—Ammonia, Preston Salts, Inexhaustible Salts, Eau de Luce, Sal Volatile Acetic Acid and its Use in Perfumery.—Aromatic Vinegar, Henry's Vinegar, Vinaigre à la Rose, Four Thieves' Vinegar, Hygienic Vinegar, Violet Vinegar, Toilet Vinegar, Vinaigre de Cologne
Smelling Salts:—Ammonia, Preston Salts, Endless Salts, Eau de Luce, Sal Volatile Acetic Acid and its Use in Perfumery.—Aromatic Vinegar, Henry's Vinegar, Rose Vinegar, Four Thieves' Vinegar, Hygienic Vinegar, Violet Vinegar, Toilet Vinegar, Cologne Vinegar
SECTION VI.
BOUQUETS AND NOSEGAYS.
Proposed Use of the Term "Otto" to denote the odoriferous Principle of Plants
Proposed Use of the Term "Otto" to refer to the fragrant Principle of Plants
Compound Odors:—The Alhambra Perfume—The Bosphorus Bouquet—Bouquet d'Amour—Bouquet des Fleurs du Val d'Andorre—Buckingham Palace Bouquet—Délices—The Court Nosegay—Eau de Chypre—The Empress Eugenie's Nosegay—Esterhazy—Ess Bouquet—Eau de Cologne. (French and English Spirit.) Flowers of Erin—Royal Hunt Bouquet—Extract of Flowers—The Guards' Bouquet—Italian Nosegay—English Jockey Club—French Jockey Club. (Difference of the Odor of English and French Perfumes due to the Spirit of Grape and Corn Spirit.) A Japanese Perfume—The Kew Garden Nosegay—Millefleurs—Millefleurs et Lavender—Delcroix's Lavender—Marechale—Mousselaine—Bouquet de Montpellier—Caprice de la Mode—May Flowers—Neptune, or Naval Nosegay—Bouquet of all Nations—Isle of Wight Bouquet—Bouquet du Roi—Bouquet de la Reine Victoria—Rondeletia. (Odors properly blended produce new Fragrances.) Bouquet Royal—Suave—Spring Flowers—Tulip Nosegay—The Wood Violet—Windsor Castle Bouquet—Yacht Club Nosegay
Compound Odors:—The Alhambra Perfume—The Bosphorus Bouquet—Bouquet d'Amour—Bouquet of the Flowers from the Valley of Andorra—Buckingham Palace Bouquet—Delights—The Court Nosegay—Eau de Chypre—The Empress Eugenie's Nosegay—Esterhazy—Ess Bouquet—Eau de Cologne. (French and English Spirit.) Flowers of Erin—Royal Hunt Bouquet—Extract of Flowers—The Guards' Bouquet—Italian Nosegay—English Jockey Club—French Jockey Club. (Difference in the Scent of English and French Perfumes due to Grape Spirit and Corn Spirit.) A Japanese Perfume—The Kew Garden Nosegay—Millefleurs—Millefleurs and Lavender—Delcroix's Lavender—Marechale—Mousselaine—Bouquet de Montpellier—Caprice de la Mode—May Flowers—Neptune, or Naval Nosegay—Bouquet of all Nations—Isle of Wight Bouquet—Bouquet of the King—Bouquet of Queen Victoria—Rondeletia. (Properly blended scents create new Fragrances.) Bouquet Royal—Suave—Spring Flowers—Tulip Nosegay—The Wood Violet—Windsor Castle Bouquet—Yacht Club Nosegay
SECTION VII.
The ancient Perfumes were only odoriferous Gums—Abstaining from the Use of Perfumes a Sign of Humiliation—The Vase at Alnwick Castle—Sachet Powders—Sachet au Chypre—Sachet à la Frangipanne—Heliotrope Sachet—Lavender Sachet—Sachet à la Maréchale—Mousselaine—Millefleur—Portugal Sachet—Patchouly Sachet—Pot Pourri—Olla Podrida—Rose Sachet—Santal-wood Sachet—Sachet (without a name)—Vervain Sachet—Vitivert—Violet Sachet—Perfumed Leather—Russia Leather—Peau d'Espagne—Perfumed Letter Paper—Perfumed Book-markers—Cassolettes, and Printaniers
The ancient perfumes were just scented resins. Avoiding perfumes was a sign of humility. The vase at Alnwick Castle. Scented powders. Chypre sachet. Frangipani sachet. Heliotrope sachet. Lavender sachet. Maréchale sachet. Mousselaine. Millefleur. Portugal sachet. Patchouli sachet. Potpourri. Olla podrida. Rose sachet. Sandalwood sachet. Unscented sachet. Vervain sachet. Vetiver. Violet sachet. Scented leather. Russian leather. Spanish leather. Scented stationery. Scented bookmarks. Censer and springtime scents.
Pastils—The Censer—Vase in the British Museum—Method of using the Censer—Incense for Altar Service—Yellow Pastils—Dr. Paris's Pastils—Perfumer's Pastils—Piesse's Pastils—Fumigation—The Perfume Lamp—Incandescent Platinum—Eau à Bruler—Eau pour Bruler—Fumigating Paper—Perfuming Spills—Odoriferous Lighters
Pastilles—The Censer—Vase in the British Museum—How to use the Censer—Incense for Altar Service—Yellow Pastilles—Dr. Paris's Pastilles—Perfumer's Pastilles—Piesse's Pastilles—Fumigation—The Perfume Lamp—Incandescent Platinum—Burning Water—Water for Burning—Fumigating Paper—Perfuming Sticks—Scented Lighters
SECTION VIII.
PERFUMED SOAP.
Perfumed Soap—Ancient Origin of Soap—Early Records of the Soap Trade in England—Perfumers not Soap Makers—Remelting—Primary Soaps—Curd Soap—Oil Soap—Castile Soap—Marine Soap—Yellow Soap—Palm Soap—Excise Duty on Soap—Fig Soft Soap—Naples Soft Soap—The remelting Process—Soap cutting—Soap stamping—Scented Soaps
Perfumed Soap—Ancient Origins of Soap—Early Records of the Soap Trade in England—Perfumers vs. Soap Makers—Remelting—Basic Soaps—Curd Soap—Oil Soap—Castile Soap—Marine Soap—Yellow Soap—Palm Soap—Excise Tax on Soap—Fig Soft Soap—Naples Soft Soap—The Remelting Process—Soap Cutting—Soap Stamping—Scented Soaps
Almond Soap—Camphor Soap—Honey Soap—White Windsor Soap—Brown Windsor Soap—Sand Soap—Fuller's Earth Soap—Scenting Soaps Hot—Scenting Soaps Cold—Colored Soaps:—Red, Green, Blue, Brown Soaps—Otto of Rose Soap—Tonquin Musk Soap—Orange-Flower Soap—Santal-wood Soap—Spermaceti Soap—Citron Soap—Frangipanne Soap—Patchouly Soap—Soft or Potash Soaps—Saponaceous Cream of Almonds—Soap Powders—Rypophagon Soap—Ambrosial Cream—Transparent soft Soap—Transparent hard Soap—Medicated Soaps—Juniper Tar Soap—Iodine Soap—Sulphur Soap—Bromine Soap—Creosote Soap—Mercurial Soap—Croton Oil Soap—Their Use in Cutaneous Diseases
Almond Soap—Camphor Soap—Honey Soap—White Windsor Soap—Brown Windsor Soap—Sand Soap—Fuller’s Earth Soap—Hot Scented Soaps—Cold Scented Soaps—Colored Soaps:—Red, Green, Blue, Brown Soaps—Rose Otto Soap—Tonquin Musk Soap—Orange Blossom Soap—Sandalwood Soap—Spermaceti Soap—Citron Soap—Frangipani Soap—Patchouli Soap—Soft or Potash Soaps—Almond Cream Soap—Soap Powders—Rypophagon Soap—Ambrosial Cream—Transparent Soft Soap—Transparent Hard Soap—Medicated Soaps—Juniper Tar Soap—Iodine Soap—Sulfur Soap—Bromine Soap—Creosote Soap—Mercury Soap—Croton Oil Soap—Their Use in Skin Diseases
SECTION IX.
EMULSINES.
Form Emulsions or Milks when mixed with Water—Prone to Change—Amandine—Olivine—Honey and Almond Paste—Pure Almond Paste—Almond Meal—Pistachio Nut Meal—Jasmine Emulsion—Violet Emulsion
Form emulsions or milks when mixed with water—susceptible to change—amandine—olivine—honey and almond paste—pure almond paste—almond meal—pistachio nut meal—jasmine emulsion—violet emulsion
SECTION X.
MILKS OR EMULSIONS.
Liebig's notice of Almond Milk—Milk of Roses—Milk of Almonds—Milk of Elder—Milk of Dandelion—Milk of Cucumber—Essence of Cucumber—Milk of Pistachio Nuts—Lait Virginal—Extract of Elder Flowers
Liebig's mention of Almond Milk—Rose Milk—Almond Milk—Elder Milk—Dandelion Milk—Cucumber Milk—Cucumber Essence—Pistachio Milk—Virgin's Milk—Elder Flower Extract
SECTION XI.
COLD CREAM.
Manipulation—Cold Cream of Almonds—Violet Cold Cream—Imitation Violet Cold Cream—Cold Cream of various Flowers—Camphor Cold Cream—Cucumber Cold Cream—Piver's Pomade of Cucumber—Pomade Divine—Almond Balls—Camphor Balls—Camphor Paste—Glycerine Balsam—Rose Lip Salve—White Lip Salve—Common Lip Salve
Manipulation—Almond Cold Cream—Violet Cold Cream—Imitation Violet Cold Cream—Cold Cream of different Flowers—Camphor Cold Cream—Cucumber Cold Cream—Piver's Cucumber Pomade—Divine Pomade—Almond Balls—Camphor Balls—Camphor Paste—Glycerin Balm—Rose Lip Balm—White Lip Balm—Regular Lip Balm
SECTION XII.
POMADES AND OILS.
Pomatum, as its name implies, originally made with Apples—Scentless Grease—Enfleurage and Maceration process—Acacia, or Cassie Pomade—Benzoin Pomade and Oil—Vanilla Oil and Pomade—Pomade called Bear's Grease—Circassian Cream—Balsam of Flowers—Crystallized Oils—Castor Oil Pomatum—Balsam of Neroli—Marrow Cream—Marrow Pomatum—Violet Pomatum—Pomade Double, Millefleurs—Pomade à la Heliotrope—Huile Antique—Philocome—Pomade Hongroise—Hard or Stick Pomatums—Black and Brown Cosmetique
Pomade, as the name suggests, originally made with apples—scentless grease—using enfleurage and maceration processes—acacia or cassie pomade—benzoin pomade and oil—vanilla oil and pomade—pomade known as bear's grease—Circassian cream—balsam of flowers—crystallized oils—castor oil pomade—balsam of neroli—marrow cream—marrow pomade—violet pomade—double pomade, millefleurs—heliotrope pomade—antique oil—philocome—Hungarian pomade—hard or stick pomades—black and brown cosmetics.
SECTION XIII.
HAIR DYES AND DEPILATORIES.
Painting the Face universal among the Women of Egypt—Kohhl, the Smoke of Gum Labdanum, used by the Girls of Greece to color the Lashes and Sockets of the Eye—Turkish Hair Dye—Rastikopetra Dye—Litharge Dye—Silver Dye—Hair Dyes, with Mordant—Inodorous Dye—Brown and Black Hair Dye—Liquid Lead Dye—Depilatory, Rusma
Painting the face is common among women in Egypt—Kohl, the smoke from gum labdanum, is used by the girls of Greece to color their lashes and eyelids—Turkish hair dye—Rastikopetra dye—litharge dye—silver dye—hair dyes with mordant—odorless dye—brown and black hair dye—liquid lead dye—depilatory, Rusma.
SECTION XIV.
ABSORBENT POWDERS.
Violet Powder—Rose Face Powder—Perle Powder—Liquid Blanc for Theatrical Use—Calcined Talc—Rouge and Red Paints—Bloom of Roses—Carmine Toilet Rouge—Carthamus Flowers—Pink Saucers—Crépon Rouge
Violet Powder—Rose Face Powder—Perle Powder—Liquid Blanc for Theatrical Use—Calcined Talc—Rouge and Red Paints—Bloom of Roses—Carmine Toilet Rouge—Carthamus Flowers—Pink Saucers—Crépon Rouge
SECTION XV.
TOOTH POWDERS AND MOUTH WASHES.
Mialhi's Tooth Powder—Camphorated Chalk—Quinine Tooth Powder—Prepared Charcoal—Peruvian Bark Powder—Homœopathic Chalk—Cuttle-Fish Powder—Borax and Myrrh—Farina Piesse's Dentifrice—Rose Tooth Powder—Opiate Paste—Violet Mouth Wash—Eau Botot—Botanic Styptic—Tincture of Myrrh and Borax—Myrrh with Eau de Cologne—Camphorated Eau de Cologne
Mialhi's Tooth Powder—Camphorated Chalk—Quinine Tooth Powder—Prepared Charcoal—Peruvian Bark Powder—Homeopathic Chalk—Cuttlefish Powder—Borax and Myrrh—Farina Piesse's Dentifrice—Rose Tooth Powder—Opiate Paste—Violet Mouth Wash—Eau Botot—Botanic Styptic—Tincture of Myrrh and Borax—Myrrh with Cologne Water—Camphorated Cologne Water
SECTION XVI.
HAIR WASHES.
Rosemary Hair Wash—Athenian Water—Vegetable or Botanic Hair Wash—Astringent Extract of Roses and Rosemary—Saponaceous Wash—Egg Julep—Bandolines—Rose and Almond Bandoline
Rosemary Hair Wash—Athenian Water—Vegetable or Botanic Hair Wash—Astringent Extract of Roses and Rosemary—Soapy Wash—Egg Julep—Bandolines—Rose and Almond Bandoline
Contents of Appendix.
Page. | |
Manufacture of Glycerine, | 249 |
Test for Alcohol in Essential Oils, | 251 |
Detection of Poppy and other drying Oils in Almond and Olive Oil, | 252 |
Coloring matter of Volatile Oils, | 253 |
Artificial Preparation of Otto of Cinnamon, | 254 |
Detection of Spike Oil and Turpentine in Lavender Oil, | 255 |
The Orange Flower Waters of Commerce, | 255 |
Concentrated Elder Water, | 256 |
Arnall on Spirits of Wine, | 256 |
Purification of Spirits by Filtration, | 259 |
Cobb on Otto of Lemons, | 260 |
Bastick on Benzoic Acid, | 263 |
On the Coloring matters of Flowers, | 267 |
Bleaching Bees' Wax, | 274 |
Chemical Examination of Naples Soap, | 275 |
Manufacture of Soap, | 275 |
How to Ascertain the Commercial Value of Soap, | 277 |
On the Natural Fats, | 281 |
Perfumes as Preventives of Mouldiness, | 284 |
Bastick on Fusel Oil, | 285 |
Bastick's Pine Apple Flavor, | 286 |
Wagner's Essence of Quince, | 288 |
Preparation of Rum-ether, | 289 |
Artificial Fruit essences, | 289 |
Volatile Oil of Gaultheria, | 291 |
Application of Chemistry to Perfumery, | 293 |
Correspondence from the Journal of the Society of Arts, | 298 |
Quantities of Ottos yielded by various Plants, | 303 |
French and English Weights and Measures compared, | 304 |
Illustrations.
Page | |
Drying House, Mitcham, Surrey, | (Frontispiece.) |
Smelling, from the Dresden Gallery, | (Vignette.) |
Pipette, to draw off small Portions of Otto from Water, | 36 |
Tap Funnel for separating Ottos from Waters, and Spirits from Oil, | 37 |
The Almond, | 43 |
Styrax Benzoin, | 48 |
Cassie Buds, | 50 |
The Clove, | 55 |
The Jasmine, | 66 |
The Orange, | 78 |
The Patchouly Plant, | 83 |
Santal-Wood, | 96 |
Tonquin, | 101 |
Vanilla, | 103 |
Vitivert, | 109 |
Civet Cat, | 117 |
Musk Pod, | 120 |
Musk Deer, | 121 |
The Censer, | 166 |
Perfume Lamp, | 171 |
Slab Soap Gauge, | 180 |
Barring Gauge, | 180 |
Squaring Gauge, | 181 |
Soap Scoops, | 181 |
Soap Press, | 182 |
Moulds, | 182 |
Soap Plane, | 187 |
Oil Runner, | 196 |
THE ART OF PERFUMERY.
INTRODUCTION AND HISTORY.
SECTION I.
The garden shines and brightens the fresh air. With luxurious scents. Here, let me draw Ethereal soul, there drink refreshing breezes,
Breathing heavily from the spicy woods And valleys of fragrance."—Thomson.
Among the numerous gratifications derived from the cultivation of flowers, that of rearing them for the sake of their perfumes stands pre-eminent. It is proved from the oldest records, that perfumes have been in use from the earliest periods. The origin of this, like that of many other arts, is lost in the depth of its antiquity; though it had its rise, no doubt, in religious observances. Among the nations of antiquity, an offering of perfumes was regarded as a token of the most profound respect and homage. Incense, or Frankincense, which exudes by incision and dries as a gum, from Arbor-thurifera, was formerly burnt in the temples of all religions, in honor of the divinities that were there adored. Many of the primitive Christians were put to death because they would not offer incense to idols.
Among the many pleasures of growing flowers, enjoying their fragrances stands out the most. Historical records show that perfumes have been used since ancient times. The exact origin of this practice, like many other arts, is lost in the mists of history; however, it likely began with religious rituals. In ancient cultures, offering perfumes was seen as a sign of deep respect and reverence. Incense or frankincense, which oozes from cuts in the bark and dries into a gum from Arbor-thurifera, was traditionally burned in the temples of all religions to honor the deities worshipped there. Many early Christians were executed because they refused to burn incense to idols.
"Of the use of these luxuries by the Greeks, and afterwards by the Romans, Pliny and Seneca gives much information respecting perfume drugs, the method of collecting them, and the prices at which they sold. Oils and powder perfumery were most lavishly used, for even three times a day did some of the luxurious people anoint and scent themselves, carrying their precious perfumes with them to the baths in costly and elegant boxes called Narthecia."
"Pliny and Seneca provide a lot of information about how the Greeks and later the Romans used these luxuries, especially regarding perfume ingredients, how they were collected, and their selling prices. Oils and powdered perfumes were used extravagantly; some wealthy individuals would apply and scent themselves up to three times a day, carrying their beloved perfumes to the baths in expensive and stylish boxes called Narthecia."
In the Romish Church incense is used in many ceremonies, and particularly at the solemn funerals of the hierarchy, and other personages of exalted rank.
In the Catholic Church, incense is used in many ceremonies, especially during the formal funerals of high-ranking officials and other important figures.
Pliny makes a note of the tree from which frankincense is procured, and certain passages in his works indicate that dried flowers were used in his time by way of perfume, and that they were, as now, mixed with spices, a compound which the modern perfumer calls pot-pourri, used for scenting apartments, and generally placed in some ornamental Vase.
Pliny mentions the tree from which frankincense is obtained, and certain parts of his writings suggest that dried flowers were used as perfume in his time, mixed with spices—something today's perfumers refer to as pot-pourri. This was used to scent living spaces and was usually kept in some decorative vase.
It was not uncommon among the Egyptian ladies to carry about the person a little pouch of odoriferous gums, as is the case to the present day among the Chinese, and to wear beads made of scented wood. The "bdellium" mentioned by Moses in Genesis is a perfuming gum, resembling frankincense, if not identical with it.
It was common for Egyptian women to carry a small pouch of fragrant gums with them, similar to what people do today in China, and to wear beads made from scented wood. The "bdellium" mentioned by Moses in Genesis is a perfuming gum that looks like frankincense, if not the same as it.
Several passages in Exodus prove the use of perfumes at a very early period among the Hebrews. In the thirtieth chapter of Exodus the Lord said unto Moses: "1. And thou shalt make an altar to burn incense upon; of Shittim wood shalt thou make it." "7. And Aaron shall burn thereon sweet incense every morning; when he dresseth the lamps he shall burn incense upon it." "34. Take unto thee sweet spices, stacte, and onycha, and galbanum; these sweet spices with pure frankincense: of each shall there be a like weight." "35. And thou shalt make it a perfume, a confection after the art of the apothecary, tempered together pure and holy." "36. And thou shalt beat some of it very small, and put of it before the testimony in the tabernacle of the congregation, where I will meet with thee; it shall be unto you most holy." "37. And as for the perfume which thou shalt make, ye shall not make to yourselves according to the composition thereof; it shall be unto thee holy for the Lord." "38. Whosoever shall make like unto that to smell thereto, shall even be cut off from his people."
Several passages in Exodus show that perfumes were used at a very early period among the Hebrews. In the thirtieth chapter of Exodus, the Lord said to Moses: "1. You shall make an altar to burn incense on; use Shittim wood to make it." "7. Aaron is to burn sweet incense on it every morning; when he tends the lamps, he shall burn incense on it." "34. Take sweet spices: stacte, onycha, and galbanum; these sweet spices with pure frankincense: you should weigh each one equally." "35. You shall make it a perfume, a blend created by a skilled perfumer, mixed pure and holy." "36. You shall crush some of it into a fine powder and place it before the testimony in the tabernacle of the congregation, where I will meet with you; it shall be most holy to you." "37. And as for the perfume that you shall create, you must not make any for yourselves using its formula; it shall be holy to the Lord for you." "38. Anyone who makes something similar to smell it will be cut off from his people."
"It was from this religious custom, of employing incense in the ancient temples, that the royal prophet drew that beautiful simile of his, when he petitioned that his prayers might ascend before the Lord like incense, Luke 1:10. It was while all the multitude was praying without, at the hour of incense, that there appeared to Zachary an angel of the Lord, standing on the right side of the altar of incense. That the nations attached a meaning not only of personal reverence, but also of religious homage, to an offering of incense, is demonstrable from the instance of the Magi, who, having fallen down to adore the new-born Jesus, and recognized his Divinity, presented Him with gold, myrrh and frankincense. The primitive Christians imitated the example of the Jews, and adopted the use of incense at the celebration of the Liturgy. St. Ephræm, a father of the Syriac Church, directed in his will that no aromatic perfumes should be bestowed upon him at his funeral, but that the spices should rather be given to the sanctuary. The use of incense in all the Oriental churches is perpetual, and almost daily; nor do any of them ever celebrate their Liturgy without it, unless compelled by necessity. The Coptic, as well as other Eastern Christians, observe the same ceremonial as the Latin Church in incensing their altar, the sacred vessels, and ecclesiastical personages."—Dr. Rock's Hierurgia.
"It was from this religious tradition of using incense in the ancient temples that the royal prophet made that beautiful comparison when he asked for his prayers to rise before the Lord like incense, Luke 1:10. It was while the crowd was praying outside at the time of incense that the angel of the Lord appeared to Zachary, standing on the right side of the altar of incense. The fact that nations associated not just personal reverence but also religious homage with an offering of incense is evident from the example of the Magi, who, after worshiping the newborn Jesus and recognizing his Divinity, presented Him with gold, myrrh, and frankincense. The early Christians followed the example of the Jews and incorporated the use of incense into the celebration of the Liturgy. St. Ephræm, a leader of the Syriac Church, specified in his will that no aromatic perfumes should be given to him at his funeral, but rather that the spices should be offered to the sanctuary. The use of incense in all Oriental churches is continuous and almost daily; they rarely celebrate their Liturgy without it unless absolutely necessary. The Coptic and other Eastern Christians follow the same rituals as the Latin Church by incensing their altar, sacred vessels, and church leaders."—Dr. Rock's Hierurgia.
Perfumes were used in the Church service, not only under the form of incense, but also mixed in the oil and wax for the lamps and lights commanded to be burned in the house of the Lord. The brilliancy and fragrance which were often shed around a martyr's sepulchre, at the celebration of his festival, by multitudes of lamps and tapers, fed with aromatics, have been noticed by St. Paulinus:—
Perfumes were used in church services, not just in the form of incense, but also mixed into the oil and wax for the lamps and lights that were required to be burned in the house of the Lord. The brilliance and fragrance that frequently surrounded a martyr's tomb during the celebration of his feast, thanks to countless lamps and candles filled with aromatic substances, have been mentioned by St. Paulinus:—
And wax candles, releasing fragrance all around From fragrant wicks, a calm scented light shines, "To brighten the night and bring joy to the shining day."
Constantine the Great provided fragrant oils, to be burned at the altars of the greater churches in Rome; and St. Paulinus, of Nola, a writer of the end of the fourth and beginning of the fifth century, tells us how, in his times, wax tapers were made for church use, so as to shed fragrance as they burned:—
Constantine the Great provided scented oils to be burned at the altars of the major churches in Rome; and St. Paulinus of Nola, a writer from the late fourth and early fifth centuries, explains how, in his time, wax candles were made for church use to release a pleasant aroma as they burned:—
"Lumina cerates adolentur odora papyris."
"Lumina creates scented papers."
A perfume in common use, even to this day, was the invention of one of the earliest of the Roman nobles, named Frangipani, and still bears his name; it is a powder, or sachet, composed of every known spice, in equal proportions, to which is added ground iris or orris root, in weight equal to the whole, with one per cent. of musk or civet. A liquid of the same name, invented by his grandson Mercutio Frangipani, is also in common use, prepared by digesting the Frangipane powder in rectified spirits, which dissolves out the fragrant principles. This has the merit of being the most lasting perfume made.
A popular perfume, even today, was created by one of the earliest Roman nobles named Frangipani, and it still carries his name. It’s a powder, or sachet, made from equal parts of every known spice, with added ground iris or orris root equal to the total weight, along with one percent of musk or civet. A liquid version of the same name, invented by his grandson Mercutio Frangipani, is also commonly used. It’s made by soaking the Frangipani powder in purified spirits, which extracts the fragrant compounds. This version is known for being the most long-lasting perfume available.
"The trade for the East in perfume-drugs caused many a vessel to spread its sails to the Red Sea, and many a camel to plod over that tract which gave to Greece and Syria their importance as markets, and vitality to the rocky city of Petra. Southern Italy was not long ere it occupied itself in ministering to the luxury of the wealthy, by manufacturing scented unguents and perfumes. So numerous were the Unguentarii, or perfumers, that they are said to have filled the great street of ancient Capua."—Hofmann.
"The trade in perfume and drugs from the East led many ships to set sail for the Red Sea, and many camels to travel across the region that made Greece and Syria important markets, giving life to the rocky city of Petra. Southern Italy soon started catering to the luxury of the wealthy by producing scented oils and perfumes. There were so many Unguent makers, or perfumers, that they supposedly crowded the main street of ancient Capua."—Hofmann.
As an art, in England, perfumery has attained little or no distinction. This has arisen from those who follow it as a trade, maintaining a mysterious secrecy about their processes. No manufacture can ever become great or important to the community that is carried on under a veil of mystery.
As an art, perfumery in England has achieved little to no distinction. This is due to those who pursue it as a trade, keeping their processes shrouded in secrecy. No industry can ever become significant or valuable to the community when it's operated behind a curtain of mystery.
"On the subject of trade mystery I will only observe, that I am convinced that it would be far more to the interest of manufacturers if they were more willing to profit by the experience of others, and less fearful and jealous of the supposed secrets of their craft. It is a great mistake to think that a successful manufacturer is one who has carefully preserved the secrets of his trade, or that peculiar modes of effecting simple things, processes unknown in other factories, and mysteries beyond the comprehension of the vulgar, are in any way essential to skill as a manufacturer, or to success as a trader."—Professor Solly.
"Regarding the mystery of trade, I just want to say that I believe it would benefit manufacturers greatly if they were more open to learning from the experiences of others and less worried and envious about the supposed secrets of their craft. It's a big mistake to think that a successful manufacturer is someone who has kept their trade secrets closely guarded, or that unique ways of doing simple tasks, processes not known in other factories, and mysteries that are beyond the understanding of the average person are in any way crucial to being skilled as a manufacturer or successful as a trader." —Professor Solly.
If the horticulturists of England were instructed how to collect the odors of flowers, a new branch of manufacture would spring up to vie with our neighbors' skill in it across the Channel.
If the gardeners of England were taught how to capture the scents of flowers, a new industry would emerge to compete with our neighbors' expertise over the Channel.
Of our five senses, that of Smelling has been treated with comparative indifference. However, as knowledge progresses, the various faculties with which the Creator has thought proper in his wisdom to endow man will become developed, and the faculty of Smelling will meet with its share of tuition as well as Sight, Hearing, Touch, and Taste.
Of our five senses, the sense of Scent has been largely overlooked. However, as we learn more, the different abilities that the Creator has wisely given us will be further developed, and the sense of Smelling will receive just as much attention as Sight, Hearing, Touch, and Taste.
Flowers yield perfumes in all climates, but those growing in the warmer latitudes are most prolific in their odor, while those from the colder are the sweetest. Hooker, in his travels in Iceland, speaks of the delightful fragrance of the flowers in the valley of Skardsheidi; we know that winter-green, violets, and primroses are found here, and the wild thyme, in great abundance. Mr. Louis Piesse, in company with Captain Sturt, exploring the wild regions of South Australia, writes: "The rains have clothed the earth with a green as beautiful as a Shropshire meadow in May, and with flowers, too, as sweet as an English violet; the pure white anemone resembles it in scent. The Yellow Wattle, when in flower, is splendid, and emits a most fragrant odor."
Flowers produce scents in all climates, but those in warmer regions are the most fragrant, while those in colder areas have the sweetest scents. Hooker, during his travels in Iceland, mentions the lovely fragrance of the flowers in the valley of Skardsheidi; we know that wintergreen, violets, and primroses grow there, along with an abundance of wild thyme. Mr. Louis Piesse, alongside Captain Sturt while exploring the remote areas of South Australia, writes: "The rains have covered the land with a green as beautiful as a Shropshire meadow in May, and with flowers that are just as sweet as an English violet; the pure white anemone has a similar scent. The Yellow Wattle, when in bloom, is stunning and gives off a wonderfully fragrant scent."
Though many of the finest perfumes come from the East Indies, Ceylon, Mexico, and Peru, the South of Europe is the only real garden of utility to the perfumer. Grasse and Nice are the principal seats of the art; from their geographical position, the grower, within comparatively short distances, has at command that change of climate best fitted to bring to perfection the plants required for his trade. On the seacoast his Cassiæ grows without fear of frost, one night of which would destroy all the plants for a season; while, nearer the Alps, his violets are found sweeter than if grown in the warmer situations, where the orange tree and mignionette bloom to perfection. England can claim the superiority in the growth of lavender and peppermint; the essential oils extracted from these plants grown at Mitcham, in Surrey, realize eight times the price in the market of those produced in France or elsewhere, and are fully worth the difference for delicacy of odor.
Although many of the best perfumes come from the East Indies, Ceylon, Mexico, and Peru, the southern part of Europe is the real hub for perfumers. Grasse and Nice are the main centers of this craft; due to their location, growers can easily access varying climates that are ideal for perfecting the plants needed for their trade. On the coast, their cassia thrives without the threat of frost, which could wipe out all the plants for the season in just one night; meanwhile, closer to the Alps, the violets are sweeter than those grown in warmer areas, where orange trees and mignonette bloom beautifully. England is known for producing superior lavender and peppermint; the essential oils extracted from these plants grown in Mitcham, Surrey, sell for eight times the price of those from France or other places, and they are absolutely worth the difference for their delicate fragrance.
The odors of plants reside in different parts of them, sometimes in the roots, as in the iris and vitivert; the stem or wood, in cedar and sandal; the leaves, in mint, patchouly, and thyme; the flower, in the roses and violets; the seeds in the Tonquin bean and caraway; the bark, in cinnamon, &c.
The scents of plants are found in various parts of them, sometimes in the roots, like in iris and vetiver; in the stem or wood, like in cedar and sandalwood; in the leaves, like in mint, patchouli, and thyme; in the flowers, like in roses and violets; in the seeds, like in tonka bean and caraway; and in the bark, like in cinnamon, etc.
Some plants yield more than one odor, which are quite distinct and characteristic. The orange tree, for instance, gives three—from the leaves one called petit grain; from the flowers we procure neroli; and from the rind of the fruit, essential oil of orange, essence of Portugal. On this account, perhaps, this tree is the most valuable of all to the operative perfumer.
Some plants produce multiple scents that are quite distinct and unique. The orange tree, for example, offers three: from the leaves we get petit grain; from the flowers we obtain neroli; and from the peel of the fruit, we have essential oil of orange, essence of Portugal. This might be why this tree is considered the most valuable to the working perfumer.
The fragrance or odor of plants is owing, in nearly all cases, to a perfectly volatile oil, either contained in small vessels, or sacs within them, or generated from time to time, during their life, as when in blossom. Some few exude, by incision, odoriferous gums, as benzoin, olibanum, myrrh, &c.; others give, by the same act, what are called balsams, which appear to be mixtures of an odorous oil and an inodorous gum. Some of these balsams are procured in the country to which the plant is indigenous by boiling it in water for a time, straining, and then boiling again, or evaporating it down till it assumes the consistency of treacle. In this latter way is balsam of Peru procured from the Myroxylon peruiferum, and the balsam of Tolu from the Myroxylon toluiferum. Though their odors are agreeable, they are not much applied in perfumery for handkerchief use, but by some they are mixed with soap, and in England they are valued more for their medicinal properties than for their fragrance.
The scent of plants usually comes from a volatile oil found in small vessels or sacs within them, or it's produced at different times during their life, like when they're blossoming. A few release fragrant gums, like benzoin, frankincense, and myrrh, when cut. Others produce what are known as balsams, which seem to be a blend of fragrant oil and odorless gum. Some of these balsams are obtained in the plant's native region by boiling it in water for a while, straining it, and then boiling it again or evaporating it until it thickens like syrup. This is how balsam of Peru is collected from the Myroxylon peruiferum and balsam of Tolu from the Myroxylon toluiferum. While their scents are pleasant, they aren't commonly used in perfumes for handkerchiefs; some people mix them with soap, and in England, they're appreciated more for their medicinal benefits than for their fragrance.
SECTION II.
Beauty's impact was lost without beauty, Neither it nor any memory of what it was; But flowers extracted, even when they face winter,
"Enjoy their performance, but their essence still remains beautiful."
The extensive flower farms in the neighborhood of Nice, Grasse, Montpellier, and Cannes, in France, at Adrianople (Turkey in Asia), at Broussa and Uslak (Turkey in Asia), and at Mitcham, in England, in a measure indicate the commercial importance of that branch of chemistry called perfumery.
The large flower farms near Nice, Grasse, Montpellier, and Cannes in France, at Adrianople (Turkey in Asia), at Broussa and Uslak (Turkey in Asia), and at Mitcham in England, highlight the commercial significance of the chemistry field known as perfumery.
British India and Europe consume annually, at the very lowest estimate, 150,000 gallons of perfumed spirits, under various titles, such as eau de Cologne, essence of lavender, esprit de rose, &c. The art of perfumery does not, however, confine itself to the production of scents for the handkerchief and bath, but extends to imparting odor to inodorous bodies, such as soap, oil, starch, and grease, which are consumed at the toilette of fashion. Some idea of the commercial importance of this art may be formed, when we state that one of the large perfumers of Grasse and Paris employs annually 80,000 lbs. of orange flowers, 60,000 lbs. of cassia flowers, 54,000 lbs. of rose-leaves, 32,000 lbs. of jasmine blossoms, 32,000 lbs. of violets, 20,000 lbs. of tubereuse, 16,000 lbs. of lilac, besides rosemary, mint, lemon, citron, thyme, and other odorous plants in large proportion. In fact, the quantity of odoriferous substances used in this way is far beyond the conception of those even used to abstract statistics.
British India and Europe consume at least 150,000 gallons of scented liquids each year, known by various names like eau de Cologne, lavender essence, rose spirit, and more. The art of perfumery goes beyond just creating scents for handkerchiefs and baths; it also involves adding fragrance to odorless products like soap, oil, starch, and grease, which are used in beauty routines. To give an idea of how commercially significant this industry is, one of the large perfumers in Grasse and Paris uses 80,000 lbs. of orange blossoms, 60,000 lbs. of cassia flowers, 54,000 lbs. of rose petals, 32,000 lbs. of jasmine, 32,000 lbs. of violets, 20,000 lbs. of tuberose, and 16,000 lbs. of lilac each year, along with large amounts of rosemary, mint, lemon, citron, thyme, and other fragrant plants. In fact, the sheer volume of fragrant substances used in this manner is far beyond what even those familiar with abstract statistics can imagine.
To the chemical philosopher, the study of perfumery opens a book as yet unread; for the practical perfumer, on his laboratory shelves, exhibits many rare essential oils, such as essential oil of the flower of the Acacia farnesiana, essential oil of violets, tubereuse, jasmine, and others, the compositions of which have yet to be determined.
To the chemical philosopher, studying perfumery reveals an unread book; for the practical perfumer, their laboratory shelves display many rare essential oils, like the essential oil from the flower of the Acacia farnesiana, essential oil of violets, tuberose, jasmine, and others, whose compositions are still to be determined.
The exquisite pleasure derived from smelling fragrant flowers would almost instinctively induce man to attempt to separate the odoriferous principle from them, so as to have the perfume when the season denies the flowers. Thus we find the alchemists of old, torturing the plants in every way their invention could devise for this end; and it is on their experiments that the whole art of perfumery has been reared. Without recapitulating those facts which may be found diffused through nearly all the old authors on medical botany, chemistry, pharmacy, and works of this character, from the time of Paracelsus to Celnart, we may state at once the mode of operation adopted by the practical perfumer of the present day for preparing the various extracts or essences, waters, oils, pomades, &c., used in his calling.
The incredible joy from smelling beautiful flowers almost instinctively makes people want to extract the fragrant compounds from them so they can enjoy the scent even when the flowers aren't in season. That's why we see ancient alchemists experimenting in every way they could think of to achieve this; their trials laid the foundation for the entire art of perfumery. Without going over all the details found in nearly all the old texts on medical botany, chemistry, pharmacy, and similar works from Paracelsus to Celnart, we can directly explain how today's practical perfumers prepare various extracts, essences, waters, oils, pomades, and so on used in their craft.
The processes are divided into four distinct operations; viz.—
The processes are divided into four clear operations:—
1. Expression; 2. Distillation; 3. Maceration; 4. Absorption.
1. Expression is only adopted where the plant is very prolific in its volatile or essential oil,—i.e. its odor; such, for instance, as is found in the pellicle or outer peel of the orange, lemon, and citron, and a few others. In these cases, the parts of the plant containing the odoriferous principle are put sometimes in a cloth bag, and at others by themselves into a press, and by mere mechanical force it is squeezed out. The press is an iron vessel of immense strength, varying in size from six inches in diameter, and twelve deep, and upwards, to contain one hundred weight or more; it has a small aperture at the bottom to allow the expressed material to run for collection; in the interior is placed a perforated false bottom, and on this the substance to be squeezed is placed, covered with an iron plate fitting the interior; this is connected with a powerful screw, which, being turned, forces the substance so closely together, that the little vessels containing the essential oils are burst, and it thus escapes. The common tincture press is indeed a model of such an instrument. The oils which are thus collected are contaminated with watery extracts, which exudes at the same time, and from which it has to be separated; this it does by itself in a measure, by standing in a quiet place, and it is then poured off and strained.
1. Extraction is only used when the plant produces a lot of its volatile or essential oil—i.e. its fragrance; for example, this can be found in the peel of oranges, lemons, and citrons, among a few others. In these cases, the parts of the plant that contain the fragrant oils are sometimes put in a cloth bag, or sometimes pressed by themselves, and mechanical force is applied to extract the oil. The press is a strong iron vessel that varies in size from six inches in diameter and twelve deep, up to one hundred weight or more; it has a small opening at the bottom to let the extracted material flow for collection. Inside, there's a perforated false bottom, and the material to be pressed is placed on this, covered with an iron plate that fits the interior. This is connected to a powerful screw that, when turned, compresses the material so tightly that the small vessels holding the essential oils burst, allowing the oil to escape. The common tincture press is a good example of such a device. The oils collected are mixed with watery extracts that come out at the same time, and they need to be separated; this occurs somewhat naturally by letting the mixture sit undisturbed, and then it is poured off and strained.

2. Distillation.—The plant, or part of it, which contains the odoriferous principle, is placed in an iron, copper, or glass pan, varying in size from that capable of holding from one to twenty gallons, and covered with water; to the pan a dome-shaped lid is fitted, terminating with a pipe, which is twisted corkscrew fashion, and fixed in a bucket, with the end peeping out like a tap in a barrel. The water in the still—for such is the name of the apparatus—is made to boil; and having no other exit, the steam must pass through the coiled pipe; which, being surrounded with cold water in the bucket, condenses the vapor before it can arrive at the tap. With the steam, the volatile oils—i.e. perfume—rises, and is liquefied at the same time. The liquids which thus run over, on standing for a time, separate into two portions, and are finally divided with a funnel having a stopcock in the narrow part of it. By this process, the majority of the volatile or essential oils are procured. In some few instances alcohol—i.e. rectified spirit of wine—is placed upon the odorous materials in lieu of water, which, on being distilled, comes away with the perfuming substance dissolved in it. But this process is now nearly obsolete, as it is found more beneficial to draw the oil or essence first with water, and afterwards to dissolve it in the spirit. The low temperature at which spirit boils, compared with water, causes a great loss of essential oil, the heat not being sufficient to disengage it from the plant, especially where seeds such as cloves or caraway are employed. It so happens, however, that the finest odors, the recherché as the Parisians say, cannot be procured by this method; then recourse is had to the next process.
2. Distillation.—The part of the plant that contains the fragrant substance is put into an iron, copper, or glass pan that can hold anywhere from one to twenty gallons and is covered with water. A dome-shaped lid fits onto the pan, ending in a pipe that twists like a corkscrew and is attached to a bucket, with the tip sticking out like a tap on a barrel. The water in the still—this is what we call the apparatus—is brought to a boil; since there’s no other way for the steam to escape, it has to go through the coiled pipe, which is surrounded by cold water in the bucket, cooling the vapor before it reaches the tap. Along with the steam, the volatile oils—i.e. perfume—rise and condense at the same time. The liquids that accumulate separate into two layers after sitting for a while and are finally divided using a funnel with a stopcock at its narrow end. This process is how most of the volatile or essential oils are obtained. In some cases, alcohol—i.e. purified spirit of wine—is used instead of water on the fragrant materials, and when distilled, it carries the scent with it. However, this method is mostly outdated, as it's discovered to be more effective to extract the oil or essence first with water and then dissolve it in the spirit. The lower boiling point of alcohol compared to water leads to significant loss of essential oil, as the heat isn't enough to extract it from the plant, particularly when using seeds like cloves or caraway. However, it turns out that the most exquisite fragrances, the recherché as the Parisians say, cannot be obtained this way; in those cases, the next method is used.

3. Maceration.—Of all the processes for procuring the perfumes of flowers, this is the most important to the perfumer, and is the least understood in England; as this operation yields not only the most exquisite essences indirectly, but also nearly all those fine pomades known here as "French pomatums," so much admired for the strength of fragrance, together with "French oils" equally perfumed. The operation is conducted thus:—For what is called pomade, a certain quantity of purified mutton or deer suet is put into a clean metal or porcelain pan, this being melted by a steam heat; the kind of flowers required for the odor wanted are carefully picked and put into the liquid fat, and allowed to remain from twelve to forty-eight hours; the fat has a particular affinity or attraction for the oil of flowers, and thus, as it were, draws it out of them, and becomes itself, by their aid, highly perfumed; the fat is strained from the spent flowers, and fresh are added four or five times over, till the pomade is of the required strength; these various strengths of pomatums are noted by the French makers as Nos. 6, 12, 18, and 24, the higher numerals indicating the amount of fragrance in them. For perfumed oils the same operation is followed; but, in lieu of suet, fine olive oil or oil of ben, derived from the ben nuts of the Levant, is used, and the same results are obtained. These oils are called "Huile Antique" of such and such a flower.
3. Maceration.—Of all the methods for extracting the scents from flowers, this one is the most important for the perfumer and is the least understood in England. This process not only produces the most exquisite essences indirectly, but also nearly all those fine pomades known here as "French pomatums," which are highly admired for their strong fragrance, along with "French oils" that are equally scented. The procedure is as follows: For what is called pomade, a specific amount of purified mutton or deer suet is placed in a clean metal or porcelain pan and melted using steam heat. The flowers needed for the desired scent are carefully picked and added to the liquid fat, where they are left to steep for twelve to forty-eight hours. The fat has a unique affinity for the oil of the flowers, effectively drawing it out and thus becoming richly scented itself. Afterward, the fat is strained from the spent flowers, and fresh flowers are added four or five times until the pomade reaches the desired strength. French makers denote these various strengths of pomatums as Nos. 6, 12, 18, and 24, with the higher numbers indicating a stronger fragrance. The same method is used for perfumed oils, but instead of suet, fine olive oil or oil of ben, sourced from the ben nuts of the Levant, is used, resulting in the same outcomes. These oils are referred to as "Huile Antique" of specific flowers.
When neither of the foregoing processes gives satisfactory results, the method of procedure adopted is by,—
When neither of the above processes produces satisfactory results, the method used is by,—
4. Absorption, or Enfleurage.—The odors of some flowers are so delicate and volatile, that the heat required in the previously named processes would greatly modify, if not entirely spoil them; this process is, therefore, conducted cold, thus:—Square frames, about three inches deep, with a glass bottom, say two feet wide and three feet long, are procured; over the glass a layer of fat is spread, about half an inch thick, with a kind of plaster knife or spatula; into this the flower buds are stuck, cup downwards, and ranged completely over it, and there left from twelve to seventy-two hours.
4. Absorption, or Enfleurage.—The scents of some flowers are so delicate and volatile that the heat needed in the previously mentioned processes would greatly alter, if not completely ruin them; therefore, this process is done cold, as follows: Square frames, about three inches deep, with a glass bottom, roughly two feet wide and three feet long, are obtained; over the glass, a layer of fat is spread, about half an inch thick, using a kind of plaster knife or spatula; into this, the flower buds are placed, cup down, filling the entire surface, and left there for twelve to seventy-two hours.
Some houses, such as that of Messrs. Pilar and Sons; Pascal Brothers; H. Herman, and a few others, have 3000 such frames at work during the season; as they are filled, they are piled one over the other, the flowers are changed so long as the plants continue to bloom, which now and then exceeds two or three months.
Some houses, like Pilar and Sons, Pascal Brothers, H. Herman, and a few others, have 3000 of these frames in operation during the season. As they get filled, they’re stacked one on top of the other, and the flowers are replaced as long as the plants keep blooming, which sometimes lasts more than two or three months.
For oils of the same plants, coarse linen cloths are imbued with the finest olive oil or oil of ben, and stretched upon a frame made of iron; on these the flowers are laid and suffered to remain a few days. This operation is repeated several times, after which the cloths are subjected to great pressure, to remove the now perfumed oil.
For oils from the same plants, rough linen cloths are soaked in the best olive oil or ben oil, and stretched over an iron frame; the flowers are placed on these and left for a few days. This process is repeated several times, after which the cloths are pressed hard to extract the now-scented oil.
As we cannot give any general rule for working, without misleading the reader, we prefer explaining the process required for each when we come to speak of the individual flower or plant.
Since we can't provide any general guidelines for working without confusing the reader, we prefer to explain the process needed for each when we discuss the individual flower or plant.
SECTION III.
Whenever a Still is named, or an article is said to be distilled or "drawn," it must be understood to be done so by steam apparatus, as this is the only mode which can be adopted for obtaining anything like a delicate odor; the old plan of having the fire immediately under the still, conveying an empyreumatic or burnt smell to the result, has become obsolete in every well-regulated perfumatory.
Whenever a still is mentioned, or something is described as distilled or "drawn," it should be understood that this is accomplished using steam equipment, as this is the only method that can produce anything resembling a delicate scent. The old practice of placing the fire directly under the still, which would impart a burnt or charred smell to the product, is now outdated in any properly managed perfume workshop.
The steam-still differs from the one described only in the lower part, or pan, which is made double, so as to allow steam from a boiler to circulate round the pan for the purpose of boiling the contents, instead of the direct fire. In macerating, the heat is applied in the same way, or by a contrivance like the common glue-pot, as made use of nowadays.
The steam-still is different from the one described only in the lower part, or pan, which is double-layered. This design lets steam from a boiler circulate around the pan to boil the contents instead of using direct heat. When macerating, heat is applied in the same way or with a device similar to the common glue pot that's used today.
This description of apparatus will be found very useful for experiments which we will suggest by-and-by.
This description of equipment will be really helpful for the experiments we will suggest later.
The perfumes for the handkerchief, as found in the shops of Paris and London, are either simple or compound; the former are called extracts, extraits, esprits, or essences, and the latter bouquets and nosegays, which are mixtures of the extracts so compounded in quantity that no one flower or odor can be discovered as predominating over another; and when made of the delicate-scented flowers carefully blended, they produce an exquisite sensation on the olfactory nerve, and are therefore much prized by all who can afford to purchase them.
The perfumes for handkerchiefs, found in the shops of Paris and London, come in either simple or mixed varieties. The simple ones are known as extracts, extraits, esprits, or essences, while the mixed ones are called bouquets and nosegays. These are blends of extracts combined in such a way that no single flower or scent stands out more than the others. When made from delicately scented flowers carefully mixed, they create an exquisite experience for the sense of smell, making them highly valued by those who can afford to buy them.
We shall first explain the mode for obtaining the simple extracts of flowers. This will be followed by the process for preparing ambergris, musk, and civet, substances, which, though of animal origin, are of the utmost importance as forming a large part in the most approved bouquets; and we shall conclude this department of the art with recipes for all the fashionable bouquets and nosegays, the value of which, we doubt not, will be estimated according to the labor bestowed upon their analysis.
We will first explain how to get simple extracts from flowers. Next, we'll cover how to prepare ambergris, musk, and civet—substances that, despite being from animals, are extremely important for creating many popular bouquets. We'll wrap up this section of the craft with recipes for all the trendy bouquets and nosegays, which we believe will be valued based on the effort put into their creation.
In order to render the work more easy of consultation, we have adopted the alphabetical arrangement in preference to a more scientific classification.
To make the work easier to consult, we have chosen to use an alphabetical arrangement instead of a more scientific classification.
Among the collection of ottos of the East India Company at the Exhibition of 1851, were several hitherto unknown in this country, and possessing much interest.
Among the collection of items from the East India Company at the Exhibition of 1851, there were several that had not been seen before in this country and that were quite intriguing.
It is to be regretted, that no person having any practical knowledge of perfumery was placed on the jury of Class IV or XXIX. Had such been the case, the desires of the exhibitors would probably have been realized, and European perfumers benefited by the introduction of new odors from the East. Some of the ottos sent by a native perfumer of Benares were deemed worthy of honorable mention. Such as Chumeylee, Beyla, Begla, Moteya, and many others from the Moluccas, but without any information respecting them.
It’s unfortunate that no one with practical knowledge of perfumery was on the jury for Class IV or XXIX. If there had been, the exhibitors’ wishes might have been fulfilled, and European perfumers could have gained from the introduction of new scents from the East. Some of the oils sent by a local perfumer from Benares were considered worthy of honorable mention, such as Chumeylee, Beyla, Begla, Moteya, and many others from the Moluccas, but without any information about them.
We are not going to speak of, perhaps, more than a tithe of the plants that have a perfume—only those will be mentioned that are used by the operative perfumer, and such as are imitated by him in consequence of there being a demand for the article, which circumstances prevent him from obtaining in its genuine state. The first that comes under our notice is—
We’re not going to talk about, maybe, more than a small portion of the plants that have a scent—only those that are used by the working perfumer, and those that he replicates because there’s a demand for the product, but circumstances prevent him from getting it in its real form. The first one we’ll look at is—
Allspice.—The odoriferous principle of allspice, commonly called pimento, is obtained by distilling the dried fruit, before it is quite ripe, of the Eugenia pimenta and Myrtus pimenta with water. It is thus procured as an essential oil; it is but little used in perfumery, and when so, only in combination with other spice oils; for scenting soap it is, however, very agreeable, and much resembles the smell of cloves, and deserves more attention than it has hitherto received. Mixed in the proportion of two ounces of oil of allspice with one gallon of rectified spirit of wine, it forms what may be termed extract of allspice, which extract will be found very useful in the manufacture of low-priced bouquets.
Allspice.—The fragrant component of allspice, commonly known as pimento, is extracted by distilling the dried, slightly unripe fruit of the Eugenia pimenta and Myrtus pimenta with water. This process produces an essential oil; it is rarely used in perfumery except in combination with other spice oils. However, it is quite pleasant for scenting soap and closely resembles the fragrance of cloves, warranting more attention than it has previously received. When mixed in the proportion of two ounces of allspice oil to one gallon of rectified spirit of wine, it creates what can be called extract of allspice, which will be very useful for making inexpensive bouquets.
Almonds.
Almonds.
If fragrant flowers weigh down the branches, The land will respond to the forest's rule,
"Great heat waves will come, and there will be large harvests of grain."
This perfume has been much esteemed for many ages. It may be procured by distilling the leaves of any of the laurel tribe, and the kernels of stone fruit; for trade purposes, it is obtained from the bitter almonds, and exists in the skin or pellicle that covers the seed after it is shelled. In the ordinary way, the almonds are put into the press for the purpose of obtaining the mild or fat oil from the nut; the cake which is left after this process is then mixed with salt and water, and allowed to remain together for about twenty-four hours prior to distillation. The reason for moistening the cake is well understood to the practical chemist, and although we are not treating the subject of perfumery in a chemical sense, but only in a practical way, it may not be inappropriate here to observe, that the essential oil of almonds does not exist ready formed to any extent in the nut, but that it is produced by a species of fermentation, from the amygdalin and emulsine contained in the almonds, together with the water that is added. Analogous substances exist in laurel leaves, and hence the same course is to be pursued when they are distilled. Some manufacturers put the moistened cake into a bag of coarse cloth, or spread it upon a sieve, and then force the stream through it; in either case, the essential oil of the almond rises with the watery vapor, and is condensed in the still-worm. In this concentrated form, the odor of almonds is far from agreeable; but when diluted with spirit, in the proportion of about one and a half ounce of the oil to a gallon of spirit or alcohol, it is very pleasant.
This perfume has been highly valued for many years. It can be made by distilling the leaves of any laurel plants and the pits of stone fruits. For commercial purposes, it comes from bitter almonds, found in the skin or outer layer that covers the shell after it’s removed. Typically, the almonds are pressed to extract the mild or fatty oil from the nut; the leftover cake is then mixed with salt and water and left together for about twenty-four hours before distillation. Moistening the cake is well understood by practical chemists, and although we're not discussing perfumery from a chemical perspective but rather a practical one, it’s worth noting that the essential oil of almonds isn’t readily available in significant amounts in the nut itself; instead, it’s generated through a type of fermentation involving the amygdalin and emulsin found in the almonds, along with the added water. Similar substances are present in laurel leaves, so the same method should be applied when distilling them. Some manufacturers place the moistened cake in a bag made of coarse cloth or spread it out on a sieve and then push the liquid through it; in either case, the essential oil of the almond rises with the vapor and is condensed in the still. In this concentrated form, the almond scent is not very pleasant; however, when diluted with alcohol at a ratio of about one and a half ounces of oil to a gallon of alcohol, it becomes quite pleasant.

The essential oil of almonds, enters into combination with soap, cold cream, and many other materials prepared by the perfumer; for which see their respective titles.
The essential oil of almonds is mixed with soap, cold cream, and various other products made by the perfumer; for details, see their respective titles.
Fourteen pounds of the cake yield about one ounce of essential oil.
Fourteen pounds of the cake produce about one ounce of essential oil.
In experiments with this substance, it must be carefully remembered that it is exceedingly poisonous, and, therefore, great caution is necessary in its admixture with substances used as a cosmetic, otherwise dangerous results may ensue.
In experiments with this substance, it’s important to remember that it is extremely poisonous, and therefore, great caution is needed when mixing it with substances used as cosmetics; otherwise, dangerous results could occur.
Artificial Otto of Almonds.—Five or six years ago, Mr. Mansfield, of Weybridge, took out a patent for the manufacture of otto of almonds from benzole. (Benzole is obtained from tar oil.) His apparatus, according to the Report of the juries of the 1851 Exhibition, consists of a large glass tube in the form of a coil, which at the upper end divides into two tubes; each of which is provided with a funnel. A stream of nitric acid flows slowly into one of the funnels, and benzole into the other. The two substances meet at the point of union of the tubes, and a combination ensues with the evolution of heat. As the newly formed compound flows down through the coil it becomes cool, and is collected at the lower extremity; it then requires to be washed with water, and lastly with a dilute solution of carbonate of soda, to render it fit for use. Nitro-benzole, which is the chemical name for this artificial otto of almonds, has a different odor to the true otto of almonds, but it can nevertheless be used for perfuming soap. Mr. Mansfield writes to me under date of January 3d, 1855:—"In 1851, Messrs. Gosnell, of Three King Court, began to make this perfume under my license; latterly I withdrew the license from them by their consent, and since then it is not made that I am aware of." It is, however, quite common in Paris.
Artificial Otto of Almonds.—Five or six years ago, Mr. Mansfield, from Weybridge, got a patent for producing otto of almonds using benzole. (Benzole comes from tar oil.) His setup, according to the Report of the juries of the 1851 Exhibition, features a large glass tube coiled up, which splits into two tubes at the top; each has a funnel. A stream of nitric acid slowly pours into one funnel, while benzole goes into the other. The two substances meet at the junction of the tubes, creating a reaction that produces heat. As the newly formed compound flows down through the coil, it cools down and collects at the bottom; it then needs to be washed with water, and finally with a diluted solution of sodium carbonate to be ready for use. Nitro-benzole, the chemical name for this artificial otto of almonds, has a different scent than true otto of almonds, but it can still be used for scenting soap. Mr. Mansfield wrote to me on January 3rd, 1855:—"In 1851, Messrs. Gosnell, from Three King Court, started making this perfume under my license; I later withdrew the license with their consent, and since then, as far as I know, it hasn't been made." It is, however, quite common in Paris.
Anise.—The odorous principle is procured by distilling the seeds of the plant Pimpinella anisum; the product is the oil of aniseed of commerce. As it congeals at a temperature of about 50° Fahr., it is frequently adulterated with a little spermaceti, to give a certain solidity to it, whereby other cheaper essential oils can be added to it with less chance of detection. As the oil of aniseed is quite soluble in spirit, and the spermaceti insoluble, the fraud is easily detected.
Anise seed.—The aromatic compound is obtained by distilling the seeds of the plant Pimpinella anisum; the result is the oil of aniseed found in stores. Since it solidifies at around 50° Fahrenheit, it's often mixed with a bit of spermaceti to make it more solid, allowing less expensive essential oils to be added with a lower risk of being noticed. Because the oil of aniseed dissolves well in alcohol while spermaceti does not, this fraud is easy to spot.
This perfume is exceedingly strong, and is, therefore, well adapted for mixing with soap and for scenting pomatums, but does not do nicely in compounds for handkerchief use.
This perfume is really strong, so it's great for mixing with soap and for scenting creams, but it doesn't work well in products for handkerchiefs.
Balm, oil of Balm, called also oil of Melissa, is obtained by distilling the leaves of the Melissa officinalis with water; it comes from the still tap with the condensed steam or water, from which it is separated with the tap funnel. But it is very little used in perfumery, if we except its combination in Aqua di Argento.
Soothing ointment, oil of Balm, also known as oil of Melissa, is made by distilling the leaves of the Melissa officinalis with water. It comes from the still tap with the condensed steam or water, which is then separated using the tap funnel. However, it's not commonly used in perfumery, except in its combination in Aqua di Argento.
Balsam.—Under this title there are two or three substances used in perfumery, such as balsam of Peru, balsam of Tolu, and balsam of storax (also called liquid amber). The first-named, is procured from the Myroxylon peruiferum; it exudes from the tree when wounded, and is also obtained by boiling down the bark and branches in water. The latter is the most common method for procuring it. It has a strong odor, like benzoin.
Balsam.—This title refers to two or three substances used in fragrances, including balsam of Peru, balsam of Tolu, and balsam of storax (also known as liquid amber). The first one is sourced from the Myroxylon peruiferum; it seeps from the tree when it’s injured, and it can also be collected by boiling the bark and branches in water. Boiling is the most popular method for obtaining it. It has a strong scent, similar to benzoin.
Balsam of Tolu flows from the Toluifera balsammum. It resembles common resin (rosin); with the least warmth, however, it runs to a liquid, like brown treacle. The smell of it is particularly agreeable, and being soluble in alcohol makes a good basis for a bouquet, giving in this respect a permanence of odor to a perfume which the simple solution of an oil would not possess. For this purpose all these balsams are very useful, though not so much used as they might be.
Balsam of Tolu comes from the Toluifera balsammum. It looks like regular resin (rosin); with just a little heat, it turns into a liquid, similar to brown syrup. Its scent is especially pleasant, and because it's soluble in alcohol, it makes a great base for a fragrance, providing a lasting scent that a simple oil solution wouldn’t have. These balsams are really useful for this, but they're not used as much as they could be.
"Ulex has found that balsam of Tolu is frequently adulterated with common resin. To detect this adulteration he pours sulphuric acid on the balsam, and heats the mixture, when the balsam dissolves to a cherry-red fluid, without evolving sulphurous acid, but with the escape of benzoic or cinnamic acid, if no common resin is present. On the contrary, the balsam foams, blackens, and much sulphurous acid is set free, if it is adulterated with common resin."—Archives der Pharmacie.
"Ulex has discovered that balsam of Tolu is often mixed with common resin. To identify this mixture, he pours sulfuric acid on the balsam and heats it. The balsam dissolves into a cherry-red liquid without producing sulfurous acid, but it releases benzoic or cinnamic acid if there's no common resin. In contrast, if the balsam contains common resin, it will foam, turn black, and release a lot of sulfurous acid."—Archives der Pharmacie.
They are all imported from South America, Chili, and Mexico, where the trees that produce them are indigenous.
They all come from South America, Chile, and Mexico, where the trees that produce them are native.
Bay, oil of sweet Bay, also termed essential oil of laurel-berries, is a very fragrant substance, procured by distillation from the berries of the bay laurel. Though very pleasant, it is not much used.
Bay, sweet bay oil, also known as essential oil of laurel berries, is a highly fragrant substance obtained through distillation from the berries of the bay laurel. While it has a pleasant aroma, it's not commonly used.
Bergamot.—This most useful perfume is procured from the Citrus Bergamia, by expression from the peel of the fruit. It has a soft sweet odor, too well known to need description here. When new and good it has a greenish-yellow tint, but loses its greenness by age, especially if kept in imperfectly corked bottles. It then becomes cloudy from the deposit of resinous matter, produced by the contact of the air, and acquires a turpentine smell.
Bergamot.—This incredibly useful fragrance comes from the Citrus Bergamia, extracted by pressing the peel of the fruit. It has a sweet, soft scent that's too familiar to describe here. When it's fresh and of good quality, it has a greenish-yellow color, but it loses its green hue over time, especially if stored in poorly sealed bottles. It then becomes cloudy due to the buildup of resinous substances caused by exposure to air and starts to smell like turpentine.
It is best preserved in well-stoppered bottles, kept in a cool cellar, and in the dark; light, especially the direct sunshine, quickly deteriorates its odor. This observation may be applied, indeed, to all perfumes, except rose, which is not so spoiled.
It’s best stored in tightly sealed bottles, kept in a cool place, and out of the light; exposure to light, especially direct sunlight, quickly damages its scent. This applies to all perfumes, except for rose, which doesn’t get ruined as easily.
When bergamot is mixed with other essential oils it greatly adds to their richness, and gives a sweetness to spice oils attainable by no other means, and such compounds are much used in the most highly scented soaps. Mixed with rectified spirit in the proportions of about four ounces of bergamot to a gallon, it forms what is called "extract of bergamot," and in this state is used for the handkerchief. Though well covered with extract of orris and other matters, it is the leading ingredient in Bayley and Blew's Ess. Bouquet (see Bouquets).
When bergamot is combined with other essential oils, it greatly enhances their richness and adds a sweetness to spice oils that can't be achieved in any other way. These blends are often used in the most fragrant soaps. When mixed with rectified spirit in a ratio of about four ounces of bergamot per gallon, it creates what's known as "extract of bergamot," which is used for handkerchiefs. Although is well covered with extract of orris and other substances, it is the main ingredient in Bayley and Blew's Ess. Bouquet (see Flower arrangements).

Benzoin, also called Benjamin.—This is a very useful substance to perfumers. It exudes from the Styrax benzoin by wounding the tree, and drying, becomes a hard gum-resin. It is principally imported from Borneo, Java, Sumatra, and Siam. The best kind comes from the latter place, and used to be called Amygdaloides, because of its being interspersed with several white spots, which resemble broken almonds. When heated, these white specks rise as a smoke, which is easily condensed upon paper. The material thus separated from the benzoin is called flowers of benzoin in commerce, and by chemists is termed benzoic acid. It has all, or nearly all, the odor of the resin from which it is derived.
Benzoin resin, also known as Benjamin.—This is a very useful substance for perfumers. It comes from the Styrax benzoin tree; when the tree is wounded, the substance dries into a hard gum-resin. It is mainly imported from Borneo, Java, Sumatra, and Thailand. The best quality comes from Thailand and used to be called Amygdaloides due to its white spots that look like broken almonds. When heated, these white specks produce smoke that can easily be condensed onto paper. The material separated from the benzoin is commercially known as flowers of benzoin, while chemists refer to it as benzoic acid. It has all, or almost all, of the fragrance of the resin it comes from.
The extract, or tincture of benzoin, forms a good basis for a bouquet.[B] Like balsam of Tolu, it gives permanence and body to a perfume made with an essential oil in spirit.
The extract, or tincture of benzoin, makes a great foundation for a bouquet.[B] Like balsam of Tolu, it provides lasting quality and depth to a fragrance created with essential oil in alcohol.
The principal consumption of benzoin is in the manufacture of pastilles (see Pastilles), and for the preparation of fictitious vanilla pomade (see Pomatums).
The main use of benzoin is in making pastilles (see Candy tablets) and for creating fake vanilla pomade (see Pommies).
Caraway.—This odoriferous principle is drawn by distillation from the seeds of the Carum carui. It has a very pleasant smell, quite familiar enough without description. It is well adapted to perfume soap, for which it is much used in England, though rarely if ever on the continent; when dissolved in spirit it may be used in combination with oil of lavender and bergamot for the manufacture of cheap essences, in a similar way to cloves (see Cloves). If caraway seeds are ground, they are well adapted for mixing to form sachet powder (see Sachets).
Caraway seed.—This fragrant substance is extracted through distillation from the seeds of the Carum carui. It has a very pleasant aroma, easily recognizable without needing a description. It's great for perfuming soap, which is commonly done in England, but it's rarely used on the continent; when dissolved in alcohol, it can be combined with lavender and bergamot oil to create inexpensive fragrances, similar to how cloves are used (see Cloves). If caraway seeds are ground, they can be effectively mixed to create sachet powder (see Pouches).
Cascarilla.—The bark is used in the formation of pastilles, and also enters into the composition known as Eau à Bruler, for perfuming apartments, to which we refer.
Cascarilla.—The bark is used to make pastilles and is also part of the recipe for Eau à Bruler, which is used to scent rooms, as we mentioned.
The bark alone of this plant is used by the manufacturing perfumer, and that only in the fabrication of pastilles. The Cascarilla gratissimus is however so fragrant, that according to Burnett its leaves are gathered by the Koras of the Cape of Good Hope as a perfume, and both the C. fragrans and C. fragilis are odoriferous. It behooves perfumers, therefore, who are on the look out for novelties, to obtain these leaves and ascertain the result of their distillation.
The bark of this plant is used by perfumers, but only for making pastilles. The Cascarilla gratissimus is so aromatic that, according to Burnett, its leaves are collected by the Koras of the Cape of Good Hope as a fragrance, and both C. fragrans and C. fragilis have a pleasant scent. Therefore, it’s important for perfumers, who are seeking new ideas, to get these leaves and see what happens when they distill them.
Messrs. Herring and Co., some years ago, drew the oil of cascarilla, but it was only offered to the trade as a curiosity.
Messrs. Herring and Co. extracted cascarilla oil a few years back, but it was only presented to the market as a novelty.
Cassia.—The essential oil of cassia is procured by distilling the outer bark of the Cinnamomum cassia. 1 cwt. of bark yields rather more than three quarters of a pound of oil; it has a pale yellow color; in smell it much resembles cinnamon, although very inferior to it. It is principally used for perfuming soap, especially what is called "military soap," as it is more aromatic or spicy than flowery in odor; it therefore finds no place for handkerchief use.
Cassia.—The essential oil of cassia is obtained by distilling the outer bark of the Cinnamomum cassia. One hundredweight of bark produces just over three-quarters of a pound of oil; it has a pale yellow color. Its scent is similar to cinnamon, though it is of much lower quality. It's mainly used for scenting soap, especially what's known as "military soap," since it has a spicier aroma rather than a floral one; therefore, it isn't used for handkerchiefs.
Cassie.—
Cassie.
"Pansies to delight the eyes, and cassie sweet to enhance."
This is one of those fine odors which enters into the composition of the best handkerchief bouquets.
This is one of those lovely scents that contributes to the mix of the finest handkerchief bouquets.

When smelled at alone, it has an intense violet odor, and is rather sickly sweet.
When smelled alone, it has a strong violet scent and is quite sickly sweet.
It is procured by maceration from the Acacia farnesiana. The purified fat is melted, into which the flowers are thrown and left to digest for several hours; the spent flowers are removed, and fresh are added, eight or ten times, until sufficient richness of perfume is obtained. As many flowers are used as the grease will cover, when they are put into it, in a liquid state.
It is obtained by soaking the Acacia farnesiana. The purified fat is melted, and the flowers are added and left to steep for several hours; the used flowers are taken out, and fresh ones are added, eight or ten times, until the desired fragrance is achieved. As many flowers are used as the fat can cover when they are added in their liquid form.
After being strained, and the pomade has been kept at a heat sufficient only to retain its liquidity, all impurities will subside by standing for a few days. Finally cooled, it is the cassie pomade of commerce. The Huile de Cassie, or fat oil of cassie, is prepared in a similar manner, substituting the oil of Egyptian ben nut, olive oil, or almond oil, in place of suet. Both these preparations are obviously only a solution of the true essential oil of cassie flowers in the neutral fatty body. Europe may shortly be expecting to import a similar scented pomade from South Australia, derived from the Wattle, a plant that belongs to the same genus as the A. farnesiana, and which grows most luxuriantly in Australia. Mutton fat being cheap, and the wattle plentiful, a profitable trade may be anticipated in curing the flowers, &c.
After being strained, and with the pomade kept at a temperature just warm enough to stay liquid, all impurities will settle after a few days. Once it cools down, it becomes the commercial cassie pomade. The Huile de Cassie, or fat oil of cassie, is made in a similar way, using oil from Egyptian ben nut, olive oil, or almond oil instead of suet. Both of these preparations are essentially just a solution of the true essential oil from cassie flowers in a neutral fatty substance. Europe can soon expect to import a similarly scented pomade from South Australia, made from the Wattle, a plant in the same genus as the A. farnesiana, which grows abundantly in Australia. Since mutton fat is inexpensive and wattle is plentiful, a profitable trade in processing the flowers and such can be anticipated.
To prepare the extract of cassie, take six pounds of No. 24 (best quality) cassie pomade, and place upon it one gallon of the best rectified spirit, as sent out by Bowerbank, of Bishopsgate. After it has digested for three weeks or a month, at a summer heat, it is fit to draw from the pomatum, and, if good, has a beautiful green color and rich flowery smell of the cassie blossom. All extracts made by this process—maceration, or, as it may be called, cold infusion, give a more natural smell of the flowers to the result, than by merely dissolving the essential oil (procured by distillation) in the spirit; moreover, where the odor of the flower exists in only very minute quantities, as in the present instance, and with violet, jasmine, &c., it is the only practical mode of proceeding.
To make the cassie extract, take six pounds of No. 24 (top quality) cassie pomade and add one gallon of the best rectified spirit, as supplied by Bowerbank of Bishopsgate. Let it sit for three weeks to a month in warm weather, and it will be ready to strain from the pomatum. If done right, it will have a beautiful green color and a rich floral smell of the cassie blossom. All extracts made through this method—maceration, or what you might call cold infusion—produce a more natural floral scent than simply dissolving essential oil (obtained by distillation) in the spirit; additionally, when the flower's fragrance is present in only very small amounts, as in this case and with violet, jasmine, etc., this is the only practical approach.
In this, and all other similar cases, the pomatum must be cut up into very small pieces, after the domestic manner of "chopping suet," prior to its being infused in the alcohol. The action of the mixture is simply a change of place in the odoriferous matter, which leaves the fat body by the superior attraction, or affinity, as the chemists say, of the spirits of wine, in which it freely dissolves.
In this and all other similar situations, the pomatum should be chopped into very small pieces, just like how you would chop suet, before being mixed with the alcohol. The process is essentially just a shift of the fragrant substances, which leave the fatty base due to the stronger attraction, or affinity, as chemists put it, of the spirits of wine, in which it dissolves easily.
The major part of the extract can be poured or drawn off the pomatum without trouble, but it still retains a portion in the interstices, which requires time to drain away, and this must be assisted by placing the pomatum in a large funnel, supported by a bottle, in order to collect the remainder. Finally, all the pomatum, which is now called washed pomatum, is to be put into a tin, which tin must be set into hot water, for the purpose of melting its contents; when the pomatum thus becomes liquefied, any extract that is still in it rises to the surface, and can be skimmed off, or when the pomatum becomes cold it can be poured from it.
Most of the extract can be easily poured or drawn off from the pomatum, but some still gets stuck in the small spaces, which takes time to drain out. To speed this up, place the pomatum in a large funnel supported by a bottle to catch the leftover liquid. Finally, all the pomatum, now referred to as washed pomatum, should be put into a tin, which needs to be placed in hot water to melt its contents. When the pomatum is liquefied, any remaining extract will rise to the top and can be skimmed off, or when the pomatum cools down, it can be poured out.
The washed pomatum is preserved for use in the manufacture of dressing for the hair, for which purpose it is exceedingly well adapted, on account of the purity of the grease from which it was originally prepared, but more particularly on account of a certain portion of odor which it still retains; and were it not used up in this way, it would be advisable to put it for a second infusion in spirit, and thus a weaker extract could be made serviceable for lower priced articles.
The washed pomatum is kept for use in the production of hairdressing, which it is particularly suitable for due to the purity of the grease it was made from, and especially because of a specific scent it still carries. If it weren't used this way, it would be wise to infuse it a second time in alcohol, creating a weaker extract that could be used for less expensive products.
I cannot leave cassie without recommending it more especially to the notice of perfumers and druggists, as an article well adapted for the purpose of the manufacture of essences for the handkerchief and pomades for the hair. When diluted with other odors, it imparts to the whole such a true flowery fragrance, that it is the admiration of all who smell it, and has not a little contributed to the great sale which certain proprietary articles have attained.
I can't recommend cassie enough, especially for perfumers and druggists, as it's perfect for making scented handkerchiefs and hair pomades. When mixed with other fragrances, it gives off a genuinely floral scent that's admired by everyone who sniffs it, and it has definitely helped boost the sales of certain branded products.
We caution the inexperienced not to confound cassie with cassia, which has a totally different odor. See Acacia Pomade.
We warn those who are inexperienced not to mix up cassie with cassia, which has a completely different scent. See Acacia Hair Pomade.
Cedar Wood now and then finds a place in a perfumer's warehouse; when ground, it does well to form a body for sachet powder. Slips of cedar wood are sold as matches for lighting lamps, because while burning an agreeable odor is evolved; some people use it also, in this condition, distributed among clothes in drawers to "prevent moth." On distillation it yields an essential oil that is exceedingly fragrant.
Cedar Wood occasionally shows up in a perfumer's storage; when ground, it works well as a base for sachet powder. Pieces of cedar wood are sold as matches for lighting lamps since they release a pleasant scent when burned; some people also use them in this form, placed among clothes in drawers to "keep moths away." When distilled, it produces an essential oil that is highly fragrant.
Messrs. Rigge and Co., of London, use it extensively for scenting soap.
Messrs. Rigge and Co. from London use it a lot for adding fragrance to soap.
Cedar Wood from Lebanon. (For the Handkerchief.)
Otto of cedar, | 1 oz. |
Rectified spirit, | 1 pint. |
Esprit rose trip, | 1/4 pint. |
The tincture smells agreeably of the wood, from which it can readily be made. Its crimson color, however, prohibits it from being used for the handkerchief. It forms an excellent tincture for the teeth, and is the basis of the celebrated French dentifrice "eau Botot."
The tincture has a pleasant scent of the wood it's made from. However, its red color makes it unsuitable for use on a handkerchief. It's a great tincture for oral care and is the key ingredient in the famous French toothpaste "eau Botot."
Cedrat.—This perfume is procured from the rind of the citron fruit (Citrus medica), both by distillation and expression; it has a very beautiful lemony odor, and is much admired. It is principally used in the manufacture of essences for the handkerchief, being too expensive for perfuming grease or soap. What is called extract of cedrat is made by dissolving two ounces of the above essential oil of citron in one pint of spirits, to which some perfumers add half an ounce of bergamot.
Lemon zest.—This fragrance is derived from the peel of the citron fruit (Citrus medica), using both distillation and expression methods; it has a lovely lemony scent and is highly praised. It is mainly used to create essences for handkerchiefs, as it's too costly for scenting grease or soap. The product known as extract of cedrat is made by dissolving two ounces of this essential citron oil in one pint of alcohol, with some perfumers adding half an ounce of bergamot.
Cinnamon.—Several species of the plant Laurus cinnamomum yield the cinnamon and cassia of commerce. Its name is said to be derived from China Amomum, the bark being one of the most valued spices of the East. Perfumers use both the bark and the oil, which is obtained by distillation from it. The ground bark enters into the composition of some pastilles, tooth powders, and sachets. The essential oil of cinnamon is principally brought to this country from Ceylon; it is exceedingly powerful, and must be used sparingly. In such compounds as cloves answer, so will cinnamon.
Cinnamon Spice.—Several species of the plant Laurus cinnamomum produce the cinnamon and cassia that we find in stores. Its name is thought to come from China Amomum, as the bark is one of the most prized spices in the East. Perfumers use both the bark and the oil, which is extracted by distillation. Ground bark is included in some pastes, tooth powders, and sachets. The essential oil of cinnamon is mostly imported from Ceylon; it is extremely potent and must be used sparingly. In mixtures where cloves are suitable, cinnamon will also work.
Citron.—On distilling the flowers of the Citrus medica, a very fragrant oil is procured, which is a species of neroli, and is principally consumed by the manufacturers of eau de Cologne.
Lemon.—When the flowers of the Citrus medica are distilled, a highly fragrant oil is obtained, which is a type of neroli, and is mainly used by producers of eau de Cologne.
Citronella.—Under this name there is an oil in the market, chiefly derived from Ceylon and the East Indies; its true origin we are unable to decide; in odor it somewhat resembles citron fruit, but is very inferior. Probably it is procured from one of the grasses of the Andropogon genus. Being cheap, it is extensively used for perfuming soap. What is now extensively sold as "honey" soap, is a fine yellow soap slightly perfumed with this oil. Some few use it for scenting grease, but it is not much admired in that way.
Lemon grass.—This is the name of an oil available in the market, mainly sourced from Ceylon and the East Indies; we can’t definitively identify its true origin. Its scent is somewhat similar to citron fruit, though it is much less pleasing. It likely comes from one of the grasses in the Andropogon genus. Because it is inexpensive, it is widely used to scent soap. The "honey" soap that is commonly sold is a fine yellow soap that is lightly scented with this oil. A few people use it to scent grease, but it isn’t particularly popular for that purpose.
Cloves.—Every part of the clove plant (Caryophyllus aromaticus) abounds with aromatic oil, but it is most fragrant and plentiful in the unexpanded flower-bud, which are the cloves of commerce. Cloves have been brought into the European market for more than 2000 years. The plant is a native of the Moluccas and other islands in the China seas. "The average annual crop of cloves," says Burnett, "is, from each tree, 2 or 2-1/2 lbs., but a fine tree has been known to yield 125 lbs. of this spice in a single season, and as 5000 cloves only weigh one pound, there must have been at least 625,000 flowers upon this single tree."
Clove buds.—Every part of the clove plant (Caryophyllus aromaticus) is filled with aromatic oil, but it’s most fragrant and abundant in the unexpanded flower-bud, which are the cloves we use commercially. Cloves have been part of the European market for over 2000 years. The plant originally comes from the Moluccas and other islands in the China seas. "The average annual crop of cloves," says Burnett, "is about 2 to 2.5 lbs. from each tree, but a healthy tree has been known to produce 125 lbs. of this spice in a single season, and since 5000 cloves only weigh one pound, that means there must have been at least 625,000 flowers on that single tree."

The oil of cloves may be obtained by expression from the fresh flower-buds, but the usual method of procuring it is by distillation, which is carried on to a very great extent in this country. Few essential oils have a more extensive use in perfumery than that of cloves; it combines well with grease, soap, and spirit, and, as will be seen in the recipes for the various bouquets given hereafter, it forms a leading feature in some of the most popular handkerchief essences, Rondeletia, the Guard's Bouquet, &c., and will be found where least expected. For essence of cloves, dissolve oil of cloves in the proportion of two ounces of oil to one gallon of spirit.
The oil of cloves can be obtained by pressing fresh flower buds, but it's usually extracted through distillation, which is widely done in this country. Few essential oils are used more in perfumery than clove oil; it blends well with oils, soap, and alcohol, and, as will be shown in the recipes for various bouquets provided later, it's a key ingredient in some of the most popular handkerchief scents, like Rondeletia and the Guard's Bouquet, and can be found in unexpected places. To make clove essence, dissolve two ounces of clove oil in one gallon of alcohol.
Dill.—Perfumers are now and then asked for "dill water;" it is, however, more a druggist's article than a perfumer's, as it is more used for its medicinal qualities than for its odor, which by the way, is rather pleasant than otherwise. Some ladies use a mixture of half dill water and half rose water, as a simple cosmetic, "to clear the complexion."
Dill herb.—Perfumers occasionally get requests for "dill water;" however, it's more of a pharmacy product than a perfume one, as it's used more for its medical benefits than for its scent, which, by the way, is actually quite pleasant. Some women mix half dill water and half rose water as a simple cosmetic "to improve their complexion."
The oil of dill is procured by submitting the crushed fruit of dill (Anethum graveolens) with water to distillation. The oil floats on the surface of the distillate, from which it is separated by the funnel in the usual manner; after the separation of the oil, the "water" is fit for sale. Oil of dill may be used with advantage, if in small proportions, and mixed with other oils, for perfuming soap.
The oil of dill is obtained by distilling the crushed seeds of dill (Anethum graveolens) with water. The oil rises to the top of the distillate, from which it is separated using a funnel in the usual way; once the oil is separated, the "water" is ready for sale. Dill oil can be beneficial when used in small amounts and mixed with other oils for scenting soap.
Eglantine, or Sweet Briar, notwithstanding what the poet Robert Noyes says—
Eglantine, or Sweet Briar, despite what the poet Robert Noyes states—
"Going beyond lemon orchards or spicy fields,"
does not find a place in the perfumer's "scent-room" except in name. This, like many other sweet-scented plants, does not repay the labor of collecting its odor. The fragrant part of this plant is destroyed more or less under every treatment that it is put to, and hence it is discarded. As, however, the article is in demand by the public, a species of fraud is practised upon them, by imitating it thus:—
does not have a spot in the perfumer's "scent-room" other than its name. This, like many other sweet-smelling plants, doesn’t justify the effort needed to extract its scent. The fragrant part of this plant gets damaged in almost every process it undergoes, which is why it is neglected. However, since the public wants it, a kind of deception is used to imitate it like this:—
Imitation Eglantine, or Essence of Sweet Briar.
Spirituous extract of French rose pomatum, | 1 pint. |
" " cassie, | 1/4 " |
" " fleur d'orange, | 1/4 " |
Esprit de rose, | 1/4 " |
Oil of neroli, | 1/2 drachm. |
Oil of lemon grass (verbena oil), | 1/2 " |
Elder (Sambucus nigra).—The only preparation of this plant for its odorous quality used by the perfumer, is elder-flower water. To prepare it, take nine pounds of elder-flowers, free from stalk, and introduce it to the still with four gallons of water; the first three gallons that come over is all that need be preserved for use; one ounce of rectified spirit should be added to each gallon of "water" distilled, and when bottled it is ready for sale. Other preparations of elder flowers are made, such as milk of elder, extract of elder, &c., which will be found in their proper place under Cosmetics. Two or three new materials made from this flower will also be given hereafter, which are likely to meet with a very large sale on account of the reputed cooling qualities of the ingredients; of these we would call attention more particularly to cold cream of elder-flowers, and to elder oil for the hair.
Senior (Sambucus nigra).—The only way this plant is used for its fragrant quality by perfumers is through elder-flower water. To make it, take nine pounds of elder flowers, removing the stems, and add them to the still with four gallons of water; the first three gallons that distill are all you need to keep for use. You should add one ounce of rectified spirit to each gallon of the distilled "water," and once bottled, it’s ready for sale. Other preparations from elder flowers are made, like elder milk, elder extract, etc., which will be listed in the appropriate section under Cosmetics. We will also introduce two or three new products made from this flower, which are expected to sell well because of their rumored cooling properties; among these, we particularly highlight cold cream of elder flowers and elder oil for hair.
The preparations of elder-flowers, if made according to the Pharmacopœias, are perfectly useless, as the forms therein given show an utter want of knowledge of the properties of the materials employed.
The preparations of elder flowers, if made according to the pharmacopoeias, are completely useless, as the instructions provided show a total lack of understanding of the properties of the ingredients used.
Fennel (Fœniculum vulgare).—Dried fennel herb, when ground, enters into the composition of some sachet powders. The oil of fennel, in conjunction with other aromatic oils, may be used for perfuming soap. It is procurable by distillation.
Fennel bulb (Fœniculum vulgare).—Dried fennel herb, when ground, is part of some sachet powders. Fennel oil, combined with other fragrant oils, can be used to scent soap. It can be obtained through distillation.
Flag (Sweet) (Acorus calamus).—The roots, or rhizome, of the sweet flag, yield by distillation a pleasant-smelling oil; 1 cwt. of the rhizome will thus yield one pound of oil. It can be used according to the pleasure of the manufacturer in scenting grease, soap, or for extracts, but requires other sweet oils with it to hide its origin.
Flag (Cool) (Acorus calamus).—The roots, or rhizome, of sweet flag provide a pleasant-smelling oil when distilled; 1 cwt. of rhizome will produce one pound of oil. It can be used at the manufacturer's discretion for scenting grease, soap, or for extracts, but needs to be blended with other sweet oils to mask its fragrance.
Geranium (Pelargonium odoratissimum, rose-leaf geranium).—The leaves of this plant yield by distillation a very agreeable rosy-smelling oil, so much resembling real otto of rose, that it is used very extensively for the adulteration of that valuable oil, and is grown very largely for that express purpose. It is principally cultivated in the south of France, and in Turkey (by the rose-growers). In the department of Seine-et-Oise, at Montfort-Lamaury, in France, hundreds of acres of it may be seen growing. 1 cwt. of leaves will yield about two ounces of essential oil. Used to adulterate otto of rose, it is in its turn itself adulterated with ginger grass oil (Andropogon), and thus formerly was very difficult to procure genuine; on account of the increased cultivation of the plant, it is now, however, easily procured pure. Some samples are greenish-colored, others nearly white, but we prefer that of a brownish tint.
Geranium (Pelargonium odoratissimum, rose-leaf geranium).—The leaves of this plant can be distilled to produce a pleasantly fragrant oil that smells like roses. This oil is so similar to real rose oil that it's often used to mix with it, and it's grown extensively for this specific purpose. It is mainly cultivated in southern France and in Turkey (by rose growers). In the Seine-et-Oise department, particularly in Montfort-Lamaury, France, you can find hundreds of acres of it being cultivated. One hundred weight of leaves can produce about two ounces of essential oil. While it is used to cut rose oil, it has also been cut with ginger grass oil (Andropogon), making it challenging to find genuine products in the past. Due to the increased cultivation of this plant, pure oil is now relatively easy to obtain. Some samples are greenish, others almost white, but we prefer the brownish variety.
When dissolved in rectified spirit, in the proportion of about six ounces to the gallon, it forms the "extract of rose-leaf geranium" of the shops. A word or two is necessary about the oil of geranium, as much confusion is created respecting it, in consequence of there being an oil under the name of geranium, but which in reality is derived from the Andropogon nardus, cultivated in the Moluccas. This said andropogon (geranium!) oil can be used to adulterate the true geranium, and hence we suppose its nomenclature in the drug markets. The genuine rose-leaf geranium oil fetches about 6s. per ounce, while the andropogon oil is not worth more than that sum per pound. And we may observe here, that the perfuming essential oils are best purchased through the wholesale perfumers, as from the nature of their trade they have a better knowledge and means of obtaining the real article than the drug-broker. On account of the pleasing odor of the true oil of rose-leaf geranium, it is a valuable article for perfuming many materials, and appears to give the public great satisfaction.
When mixed with rectified spirit at about six ounces to the gallon, it creates the "extract of rose-leaf geranium" found in stores. It's important to clarify something about geranium oil, as there's a lot of confusion around it. There’s an oil called geranium that actually comes from the Andropogon nardus, which is grown in the Moluccas. This Andropogon (geranium!) oil can be used to dilute the real geranium oil, which is likely why it's sold under this name in drug markets. The authentic rose-leaf geranium oil costs about 6s. per ounce, while the Andropogon oil is worth no more than that amount per pound. It's worth noting that the best place to buy perfuming essential oils is through wholesale perfumers since they are more knowledgeable and have better access to the genuine products than drug brokers. Due to the pleasant scent of genuine rose-leaf geranium oil, it is highly valued for scenting various materials and seems to provide great satisfaction to the public.
Heliotrope.—Either by maceration or enfleurage with clarified fat, we may obtain this fine odor from the flowers of the Heliotrope Peruvianum or H. grandiflorum. Exquisite as the odor of this plant is, at present it is not applied to use by the manufacturing perfumer. This we think rather a singular fact, especially as the perfume is powerful and the flowers abundant. We should like to hear of some experiments being tried with this plant for procuring its odor in this country, and for that purpose now suggest the mode of operation which would most likely lead to successful results. For a small trial in the first instance, which can be managed by any person having the run of a garden, we will say, procure an ordinary glue-pot now in common use, which melts the material by the boiling of water; it is in fact a water-bath, in chemical parlance—one capable of holding a pound or more of melted fat. At the season when the flowers are in bloom, obtain half a pound of fine mutton suet, melt the suet and strain it through a close hair-sieve, allow the liquefied fat, as it falls from the sieve, to drop into cold spring water; this operation granulates and washes the blood and membrane from it. In order to start with a perfectly inodorous grease, the melting and granulation process may be repeated three or four times; finally, remelt the fat and cast it into a pan to free it from adhering water.
Heliotrope plant.—We can extract this lovely scent from the flowers of the Heliotrope Peruvianum or H. grandiflorum either by soaking or using the enfleurage method with clarified fat. Even though this plant has a beautiful fragrance, it’s not currently being utilized by commercial perfumers, which seems quite unusual since the scent is strong and the flowers are plentiful. We would love to see some experiments conducted with this plant to capture its fragrance here, so we suggest a method that is likely to yield good results. For a small experiment to start with, which anyone with access to a garden can do, you'll need a standard glue pot commonly used today that melts material by boiling water; this essentially acts as a water bath capable of holding a pound or more of melted fat. When the flowers are in bloom, get half a pound of good mutton suet, melt it, and strain it through a fine sieve. Let the melted fat drip into cold spring water; this will granulate and wash out any blood and membrane. To begin with a completely odorless fat, you can repeat the melting and granulation process three or four times; finally, remelt the fat and pour it into a pan to remove any remaining water.
Now put the clarified suet into the macerating pot, and place it in such a position near the fire of the greenhouse, or elsewhere that will keep it warm enough to be liquid; into the fat throw as many flowers as you can, and there let them remain for twenty-four hours; at this time strain the fat from the spent flowers and add fresh ones; repeat this operation for a week: we expect at the last straining the fat will have become very highly perfumed, and when cold may be justly termed Pomade à la Heliotrope.
Now put the clarified suet into the macerating pot and place it near the greenhouse fire, or somewhere it will stay warm enough to remain liquid. Add as many flowers as you can into the fat and let them sit for twenty-four hours. After that, strain the fat from the used flowers and add fresh ones. Repeat this process for a week. By the final straining, the fat should be very fragrant and, when cool, can rightfully be called Pomade à la Heliotrope.
The cold pomade being chopped up, like suet for a pudding, is now to be put into a wide-mouthed bottle, and covered with spirits as highly rectified as can be obtained, and left to digest for a week or more; the spirit then strained off will be highly perfumed; in reality it will be extract of Heliotrope, a delightful perfume for the handkerchief. The rationale of the operation is simple enough: the fat body has a strong affinity or attraction for the odorous body, or essential oil of the flowers, and it therefore absorbs it by contact, and becomes itself perfumed. In the second operation, the spirit has a much greater attraction for the fragrant principle than the fatty matter; the former, therefore, becomes perfumed at the expense of the latter. The same experiment may be repeated with almond oil substituted for the fat.
The cold pomade, chopped up like fat for a pudding, is now going to be placed in a wide-mouth bottle and covered with the highest purified spirits available, then left to steep for a week or more. The spirit that is strained off will be highly scented; in fact, it will be extract of Heliotrope, a lovely fragrance for handkerchiefs. The reason this works is pretty straightforward: the fatty substance has a strong attraction for the fragrant component, or essential oil of the flowers, so it absorbs it through contact and becomes scented itself. In the second step, the spirit is much more attracted to the fragrant compound than the fatty material; therefore, the spirit becomes scented at the expense of the fatty substance. You can run the same experiment using almond oil in place of the fat.
The experiment here hinted at, may be varied with any flowers that there are to spare; indeed, by having the macerating bath larger than was mentioned above, an excellent millefleur pomade and essence might be produced from every conservatory in the kingdom, and thus we may receive another enjoyment from the cultivation of flowers beyond their beauty of form and color.
The experiment suggested here can be done with any spare flowers you have. In fact, by using a larger macerating bath than the one mentioned above, you could create an amazing millefleur pomade and essence from every conservatory in the kingdom. This way, we can enjoy another benefit from growing flowers beyond just their beauty in shape and color.
We hope that those of our readers who feel inclined to try experiments of this nature will not be deterred by saying, "they are not worth the trouble." It must be remembered, that very fine essences realize in the London perfumery warehouses 16s. per pint of 16 ounces, and that fine flowery-scented pomades fetch the same sum per pound. If the experiments are successful they should be published, as then we may hope to establish a new and important manufacture in this country. But we are digressing.
We hope that those of our readers who are interested in trying out experiments like these won’t be discouraged by thinking, "it’s not worth the effort." It's important to remember that high-quality essences sell in London perfume shops for 16s. per pint of 16 ounces, and that premium floral-scented pomades go for the same price per pound. If the experiments are successful, they should be shared so we can potentially establish a new and significant industry in this country. But we’re getting off track.
The odor of heliotrope resembles a mixture of almonds and vanilla, and is well imitated thus:—
The smell of heliotrope is like a blend of almonds and vanilla, and can be imitated like this:—
Extract of Heliotrope.
Spirituous extract of vanilla, | 1/2 pint. |
" " French rose pomatum, | 1/4 " |
" " orange-flower pomatum, | 2 oz. |
" " ambergris, | 1 oz. |
Essential oil of almonds, | 5 drops. |
Honeysuckle or Woodbine:—
Honeysuckle or Woodbine:—
What the poet Cowper here says is quite true; nevertheless, it is a flower that is not used in practical perfumery, though there is no reason for abandoning it. The experiments suggested for obtaining the odor of Heliotrope and Millefleur (thousand flowers) are also applicable to this, as also to Hawthorn. A good Imitation of Honeysuckle is made thus:—
What the poet Cowper says here is absolutely true; however, it's a flower that isn't commonly used in practical perfumery, even though there's no reason to disregard it. The methods proposed for extracting the scent of Heliotrope and Millefleur (thousand flowers) can also be applied to this flower, as well as to Hawthorn. A good Honeysuckle Imitation is made this way:—
Spirituous extract of rose pomatum, | 1 pint. |
" " violet " | 1 " |
" " tubereuse " | 1 " |
Extract of vanilla, | 1/4 " |
" Tolu, | 1/4 " |
Otto neroli, | 10 drops. |
" almonds, | 5 " |
The prime cost of a perfume made in this manner would probably be too high to meet the demand of a retail druggist; in such cases it may be diluted with rectified spirit to the extent "to make it pay," and will yet be a nice perfume. The formula generally given herein for odors is in anticipation that when bottled they will retail for at least eighteen-pence the fluid ounce! which is the average price put on the finest perfumery by the manufacturers of London and Paris.
The base cost of a perfume made this way would likely be too high for a retail pharmacist; in those situations, it can be diluted with rectified spirit to make it profitable, while still being a nice fragrance. The formula generally provided here for scents is based on the expectation that when bottled, they will sell for at least eighteen pence per fluid ounce! This is the average price set for the finest perfumes by manufacturers in London and Paris.
Hovenia.—A perfume under this name is sold to a limited extent, but if it did not smell better than the plant Hovenia dulcis or H. inequalis, a native of Japan, it would not sell at all. The article in the market is made thus:—
Hovenia.—A perfume with this name is sold in limited quantities, but if it didn’t smell better than the plant Hovenia dulcis or H. inequalis, a native of Japan, it wouldn’t sell at all. The product available in the market is made as follows:—
Rectified spirit, | 1 quart. |
Rose-water, | 1/2 pint. |
Otto lemons, | 1/2 oz. |
Otto of rose, | 1 drachm. |
" cloves, | 1/2 " |
" neroli, | 10 drops. |
First dissolve the ottos in the spirit, then add the rose-water. After filtration it is ready for sale. When compounds of this kind do not become bright by passing through blotting-paper, the addition of a little carbonate of magnesia prior to filtering effectually clears them. The water in the above recipe is only added in order that the article produced may be retailed at a moderate price, and would, of course, be better without that "universal friend."
First, dissolve the oils in the alcohol, then add the rose water. After filtering, it’s ready for sale. When mixtures like this don't become clear after going through blotting paper, adding a little magnesium carbonate before filtering clears them up effectively. The water in the recipe is only added to keep the final product affordable, and it would, of course, be better without that "universal friend."
Jasmine.—
Jasmine.
The jasmine spreading her lovely fragrance.
This flower is one of the most prized by the perfumer. Its odor is delicate and sweet, and so peculiar that it is without comparison, and as such cannot be imitated. When the flowers of the Jasminum odoratissimum are distilled, repeatedly using the water of distillation over fresh flowers, the essential oil of jasmine may be procured. It is, however, exceedingly rare, on account of the enormous cost of production. There was a fine sample of six ounces exhibited in the Tunisian department of the Crystal Palace, the price of which was 9l. the fluid ounce! The plant is the Yasmyn of the Arabs, from which our name is derived.
This flower is one of the most valued by perfumers. Its scent is delicate and sweet, and so unique that it can't be compared to anything else, making it impossible to imitate. When the flowers of the Jasminum odoratissimum are distilled, using the distillation water repeatedly over fresh flowers, you can obtain jasmine essential oil. However, it's extremely rare due to the high production costs. There was a beautiful sample of six ounces displayed in the Tunisian section of the Crystal Palace, priced at 9l. per fluid ounce! The plant is known as Yasmyn among the Arabs, which is where our name comes from.
In the perfumer's laboratory, the method of obtaining the odor is by absorption, or, as the French term it, enfleurage; that is, by spreading a mixture of pure lard and suet on a glass tray, and sticking the fresh-gathered flowers all over it, leaving them to stand a day or so, and repeating the operation with fresh flowers—the grease absorbs the odor. Finally, the pomade is scraped off the glass or slate, melted at as low a temperature as possible, and strained.
In the perfumer's lab, the process of getting the scent is through absorption, or as the French call it, enfleurage; this involves spreading a mix of pure lard and suet on a glass tray and placing freshly picked flowers all over it, letting them sit for a day or so, and repeating the process with new flowers—the grease absorbs the scent. Finally, the pomade is scraped off the glass or slate, melted at the lowest temperature possible, and strained.
Oils strongly impregnated with the fragrance are also prepared much in the same way. Layers of cotton wool, previously steeped in oil of ben (obtained by pressure from the blanched nuts of the Moringa oleifera) are covered with jasmine flowers, which is repeated several times; finally, the cotton or linen cloths which some perfumers use, are squeezed under a press. The jasmine oil thus produced is the Huile antique au jasmin of the French houses.
Oils that are heavily infused with fragrance are made in a similar way. Layers of cotton wool, soaked in oil of ben (which is extracted by pressing the blanched nuts of the Moringa oleifera), are layered with jasmine flowers, and this process is repeated several times. Finally, the cotton or linen cloths that some perfumers use are pressed. The jasmine oil created from this is known as Huile antique au jasmin in French perfumeries.
The "extract of jasmine" is prepared by pouring rectified spirit on the jasmine pomade or oil, and allowing them to remain together for a fortnight at a summer heat. The best quality extract requires two pounds of pomatum to every quart of spirit. The same can be done with the oil of jasmine. If the pomade is used, it must be cut up fine previously to being put into the spirit; if the oil is used, it must be shaken well together every two or more hours, otherwise, on account of its specific gravity, the oil separates, and but little surface is exposed to the spirit. After the extract is strained off, the "washed" pomatum or oil is still useful, if remelted, in the composition of pomatum for the hair, and gives more satisfaction to a customer than any of the "creams and balms," &c. &c., made up and scented with essential oils; the one smells of the flower, the other "a nondescript."
The "jasmine extract" is made by pouring purified alcohol over jasmine pomade or oil and letting them sit together for two weeks in warm weather. The best quality extract requires two pounds of pomatum for each quart of alcohol. The same process can be used with jasmine oil. If using pomade, it should be chopped finely before adding it to the alcohol; if using oil, it needs to be shaken well every couple of hours, or else the oil will separate due to its density, limiting the surface area exposed to the alcohol. After straining the extract, the "washed" pomatum or oil can still be useful if remelted for hair pomatum, and it generally provides more satisfaction to customers than any of the "creams and balms," etc., that are made and scented with essential oils; one smells like the flower, while the other has a vague scent.

The extract of jasmine enters into the composition of a great many of the most approved handkerchief perfumes sold by the English and French perfumers. Extract of jasmine is sold for the handkerchief often pure, but is one of those scents which, though very gratifying at first, becomes what people call "sickly" after exposure to the oxidizing influence of the air, but if judiciously mixed with other perfumes of an opposite character is sure to please the most fastidious customer.
The jasmine extract is a key ingredient in many of the most popular handkerchief perfumes offered by English and French perfumers. Jasmine extract is often sold pure for handkerchiefs, but it's one of those scents that, while initially pleasing, can become what people refer to as "sickly" after being exposed to air. However, if it's carefully blended with other fragrances that have contrasting characteristics, it can definitely satisfy even the most particular customer.
Jonquil.—The scent of the jonquil is very beautiful; for perfumery purposes it is however but little cultivated in comparison with jasmine and tubereuse. It is prepared exactly as jasmine. The Parisian perfumers sell a mixture which they call "extract of jonquil." The plant, however, only plays the part of a godfather to the offspring, giving it its name. The so-called jonquil is made thus:—
Jonquil.—The fragrance of the jonquil is lovely; however, it is not grown much for perfumes compared to jasmine and tuberose. It is processed in the same way as jasmine. Parisian perfumers offer a blend they refer to as "extract of jonquil." The plant essentially takes on the role of a godparent for the product, lending its name. The so-called jonquil is made this way:—
Spirituous extract of jasmine pomade, | 1 pint. |
" " tubereuse " | 1 " |
" " fleur d'orange, | 1/2 " |
Extract of vanilla, | 2 fluid ounces. |
Laurel.—By distillation from the berries of the Laurus nobilis, and from the leaves of the Laurus cerasus, an oil and perfumed water are procurable of a very beautiful and fragrant character. Commercially, however, it is disregarded, as from the similarity of odor to the oil distilled from the bitter almond, it is rarely, if ever, used by the perfumer, the latter being more economical.
Laurel.—You can obtain a beautiful and fragrant oil and perfumed water by distilling the berries of the Laurus nobilis and the leaves of the Laurus cerasus. However, it’s largely ignored in commercial use because it smells similar to the oil extracted from bitter almonds, which is more cost-effective for perfumers.
Lavender.—The climate of England appears to be better adapted for the perfect development of this fine old favorite perfume than any other on the globe. "The ancients," says Burnett, "employed the flowers and the leaves to aromatize their baths, and to give a sweet scent to water in which they washed; hence the generic name of the plant, Lavandula."
Lavender.—The climate in England seems to be better suited for the ideal growth of this classic favorite scent than anywhere else in the world. "The ancient people," says Burnett, "used the flowers and leaves to fragrance their baths and to add a pleasant scent to the water they bathed in; that's why the plant is called Lavandula."
Lavender is grown to an enormous extent at Mitcham, in Surrey, which is the seat of its production, in a commercial point of view. Very large quantities are also grown in France, but the fine odor of the British produce realizes in the market four times the price of that of Continental growth. Burnett says that the oil of Lavandula spica is more pleasant than that derived from the other species, but this statement must not mislead the purchaser to buy the French spike lavender, as it is not worth a tenth of that derived from the Lavandulæ veræ. Half-a-hundred weight of good lavender flowers yield, by distillation, from 14 to 16 oz. of essential oil.
Lavender is grown on a large scale in Mitcham, Surrey, which is the center of its commercial production. Significant amounts are also cultivated in France, but the fragrant quality of British lavender commands four times the market price compared to that from the Continent. Burnett claims that the oil of Lavandula spica is more pleasant than that from other species, but this shouldn’t mislead buyers into choosing French spike lavender, as it’s worth less than a tenth of the value of oil from Lavandulæ veræ. Half a hundredweight of good lavender flowers produces 14 to 16 oz. of essential oil through distillation.
All the inferior descriptions of oil of lavender are used for perfuming soaps and greases; but the best, that obtained from the Mitcham lavender, is entirely used in the manufacture of what is called lavender water, but which, more properly, should be called essence or extract of lavender, to be in keeping with the nomenclature of other essences prepared with spirit.
All the lower-quality lavender oil is used to scent soaps and lotions, but the best oil, sourced from Mitcham lavender, is exclusively used to make what is known as lavender water. However, it would be more accurately referred to as lavender essence or extract to match the naming conventions of other essences made with alcohol.
The number of formulæ published for making a liquid perfume of lavender is almost endless, but the whole of them may be resolved into essence of lavender, simple; essence of lavender, compound; and lavender water.
The number of recipes available for creating a lavender liquid perfume is nearly limitless, but they can all be categorized into three types: simple lavender essence, compound lavender essence, and lavender water.
The first process yields the finest quality: it is that which is adopted by the firm of Smyth and Nephew, whose reputation for this article is such that it gives a good character in foreign markets, especially India, to all products of lavender of English manufacture. Lavender essence, that which is made by the still, is quite white, while that by mixture only always has a yellowish tint, which by age becomes darker and resinous.
The first process produces the highest quality: it's the one used by the company Smyth and Nephew, whose reputation for this product is so strong that it enhances the reputation of all English lavender goods in foreign markets, particularly in India. Lavender essence, made through distillation, is completely clear, whereas the one made by blending tends to have a yellowish hue that deepens and becomes more resinous over time.
Smyth's Lavender.
To produce a very fine distillate, take—
To create a really high-quality distillate, take—
Otto of English Lavender, | 4 oz. |
Rectified spirit (60 over proof), | 5 pints. |
Rose-water, | 1 pint. |
Mix and distil five pints for sale. Such essence of lavender is expensive, but at 10s. a pint of 14 oz! there is a margin for profit. It not being convenient to the general dealer to sell distilled lavender essence, the following form, by mixture, will produce a first-rate article, and nearly as white as the above.
Mix and distill five pints for sale. This lavender essence is pricey, but at 10s. a pint of 14 oz! there is a chance for profit. Since it's not practical for the average seller to offer distilled lavender essence, the following mixture will create a top-quality product that’s almost as white as the pure version.
Lavender Essence.
Otto of lavender, | 3-1/2 oz. |
Rectified spirit, | 2 quarts. |
The perfumer's retail price for such quality is 8s. per pint of 14 oz.
The retail price from the perfumer for this quality is 8s. per pint of 14 oz.
Lavender Mist.—Take:
English oil of lavender, | 4 oz. |
Spirit, | 3 quarts. |
Rose-water, | 1 pint. |
Filter as above, and it is ready for sale.
Filter as described above, and it’s ready to sell.
Common Lavender Water.—Same form as the above, substituting French lavender for the British.
Lavender Hydrosol.—Same recipe as above, but use French lavender instead of British.
Recipes for Rondeletia, Lavender Bouquet, and other lavender compounds, will be given when we come to speak of compound perfumes, which will be reserved until we have finished explaining the method of making the simple essences.
Recipes for Rondeletia, Lavender Bouquet, and other lavender mixtures will be provided when we discuss compound perfumes, which we'll cover after we've finished explaining how to make the simple essences.
Lemon.—This fine perfume is abstracted from the Citrus limonum, by expression, from the rind of the fruit. The otto of lemons in the market is principally from Messina, where there are hundreds of acres of "lemon groves." Otto of lemons, like all the ottos of the Citrus family, is rapidly prone to oxidation when in contact with air and exposure to light; a high temperature is also detrimental, and as such is the case it should be preserved in a cool cellar. Most of the samples from the gas-heated shelves of the druggists' shops, are as much like essence of turpentine, to the smell, as that of lemons; rancid oil of lemons may, in a great measure, be purified by agitation with warm water and final decantation. When new and good, lemon otto may be freely used in combination with rosemary, cloves, and caraway, for perfuming powders for the nursery. From its rapid oxidation, it should not be used for perfuming grease, as it assists rather than otherwise all fats to turn rancid; hence pomatums so perfumed will not keep well. In the manufacture of other compound perfumes, it should be dissolved in spirit, in the proportion of six to eight ounces of oil to one gallon of spirit. There is a large consumption of otto of lemons in the manufacture of Eau de Cologne; that Farina uses it is easily discovered by adding a few drops of Liq. Ammoniæ fort. to half an ounce of his Eau de Cologne, the smell of the lemon is thereby brought out in a remarkable manner.
Lemon.—This lovely fragrance is derived from the Citrus limonum by pressing the rind of the fruit. Most of the lemon oil available comes from Messina, where there are extensive "lemon groves." Lemon oil, like all the citrus oils, quickly oxidizes when exposed to air and light; high temperatures can also harm it, so it should be stored in a cool place. Many samples from drugstore shelves heated by gas smell more like turpentine than lemons. Rancid lemon oil can be mostly purified by mixing it with warm water and then decanting it. When fresh and of good quality, lemon oil can be mixed with rosemary, cloves, and caraway for nursery powders. Due to its tendency to oxidize quickly, it shouldn't be used to scent fats, as it can cause them to go rancid; thus, pomades with this fragrance won't last. In making other blended fragrances, it should be dissolved in alcohol at a ratio of six to eight ounces of oil to one gallon of alcohol. There is a high demand for lemon oil in the production of Eau de Cologne; it's easy to notice that Farina uses it by adding a few drops of concentrated ammonia to half an ounce of his Eau de Cologne, as this really enhances the lemon scent.
Perhaps it is not out of place here to remark, that in attempts to discover the composition of certain perfumes, we are greatly assisted by the use of strong Liq. Ammoniæ. Certain of the essential oils combining with the Ammonia, allow those which do not do so, if present in the compound, to be smelt.
Perhaps it's worth noting here that when trying to identify the ingredients of certain perfumes, we are greatly helped by using strong liquid ammonia. Some essential oils react with the ammonia, allowing us to smell those that don't react if they're also in the mixture.
Lemon Grass.—According to Pereira, the otto in the market under this name is derived from the Andropogon schœnanthus a species of grass which grows abundantly in India. It is cultivated to a large extent in Ceylon and in the Moluccas purposely for the otto, which from the plant is easily procured by distillation. Lemon grass otto, or, as it is sometimes called, oil of verbena, on account of its similarity of odor to that favorite plant, is imported into this country in old English porter and stout bottles. It is very powerful, well adapted for perfuming soaps and greases, but its principal consumption is in the manufacture of artificial essence of verbena. From its comparatively low price, great strength, and fine perfume (when diluted), the lemon grass otto may be much more used than at present, with considerable advantage to the retail shopkeeper.
Lemongrass.—According to Pereira, the otto sold under this name comes from the Andropogon schœnanthus, a type of grass that grows plentifully in India. It's widely cultivated in Sri Lanka and the Moluccas specifically for the otto, which is easily extracted from the plant through distillation. Lemon grass otto, or sometimes called oil of verbena due to its similar scent to that popular plant, is imported into this country in old English porter and stout bottles. It's very potent and well-suited for scenting soaps and oils, but it's mainly used in making artificial essence of verbena. Because of its relatively low price, high strength, and pleasant fragrance (when diluted), lemon grass otto could be used much more widely than it is now, benefiting retail shopkeepers considerably.
Lilac.—The fragrance of the flowers of this ornamental shrub is well known. The essence of lilac is obtained either by the process of maceration, or enfleurage with grease, and afterwards treating the pomatum thus formed with rectified spirit, in the same manner as previously described for cassie; the odor so much resembles tubereuse, as to be frequently used to adulterate the latter, the demand for tubereuse being at all times greater than the supply. A beautiful Imitation of Essence of White Lilac may be compounded thus:—
Lilac.—The scent of the flowers from this ornamental shrub is well-known. The essence of lilac is extracted either through maceration or by using a fat-based enfleurage method, followed by treating the resulting pomade with purified alcohol, similar to how it's done for cassie. The fragrance is so similar to tuberose that it's often used to mix with it, as the demand for tuberose always exceeds the supply. A lovely Imitation of the Essence of White Lilac can be created like this:—
Spirituous extract from tubereuse pomade, | 1 pint. |
" of orange-flower pomade, | 1/4 " |
Otto of almonds, | 3 drops. |
Extract of civet, | 1/2 oz. |
The civet is only used to give permanence to the perfume of the handkerchief.
The civet is just used to make the scent of the handkerchief last.
Lily.—The manufacturing perfumer rejects the advice of the inspired writer, to "consider the lilies of the field." Rich as they are in odor, they are not cultivated for their perfume. If lilies are thrown into oil of sweet almonds, or ben oil, they impart to it their sweet smell; but to obtain anything like fragrance, the infusion must be repeated a dozen times with the same oil, using fresh flowers for each infusion, after standing a day or so. The oil being shaken with an equal quantity of spirit for a week, gives up its odor to the alcohol, and thus extract of lilies may be made. But how it is made is thus:—
Lily.—The commercial perfumer ignores the advice of the creative writer to "consider the lilies of the field." As fragrant as they are, they aren’t grown for their scent. If lilies are added to oil of sweet almonds or ben oil, they will give it their pleasant aroma; but to capture anything resembling a fragrance, the process has to be repeated a dozen times with the same oil, using fresh flowers for each infusion and letting it sit for a day or so. After shaking the oil with an equal amount of alcohol for a week, it releases its scent into the alcohol, allowing for the creation of lily extract may be made. But how it is made is as follows:—
Imitation "Lily of the Valley."
Extract of tubereuse, | 1/2 pint. |
" jasmine, | 1 oz. |
" fleur d'orange, | 2 oz. |
" vanilla, | 3 oz. |
" cassie, | 1/4 pint. |
" rose, | 1/4 " |
Otto of almonds, | 3 drops. |
Keep this mixture together for a month, and then bottle it for sale. It is a perfume that is very much admired.
Keep this mixture together for a month, and then bottle it for sale. It's a perfume that is highly admired.
Mace.—Ground mace is used in the manufacture of some of those scented powders called Sachets. A strong-smelling essential oil may be procured from it by distillation, but it is rarely used.
Mace spray.—Ground mace is used to make some of those fragrant powders known as sachets. A strong-smelling essential oil can be extracted from it through distillation, but it's not commonly used.
Magnolia.—The perfume of this flower is superb; practically, however, it is of little use to the manufacturer, the large size of the blossoms and their comparative scarcity prevents their being used, but a very excellent imitation of its odor is made as under, and is that which is found in the perfumers' shops of London and Paris.
Magnolia.—The scent of this flower is amazing; however, it's not very practical for manufacturers since the blossoms are large and relatively rare, making them difficult to use. Instead, a high-quality imitation of its fragrance is created as described below, and that's what you’ll find in the perfume shops of London and Paris.
Imitation "Magnolia Essence."
Spirituous extract of orange-flower pomatum, | 1 pint. |
" " rose pomatum, | 2 pints. |
" " tubereuse pomatum, | 1/2 pint. |
" " violet pomatum, | 1/2 " |
Essential oil of citron, | 3 drs. |
" " almonds, | 10 drops. |
Marjoram.—The otto procured by distilling Origanum majorana, commonly called oil of oringeat by the French, is exceedingly powerful, and in this respect resembles all the ottos from the different species of thyme, of which the marjoram is one. One hundred weight of the dry herb yields about ten ounces of the otto. Oringeat oil is extensively used for perfuming soap, but more in France than in England. It is the chief ingredient used by Gelle Frères, of Paris, for scenting their "Tablet Monstre Soap," so common in the London shops.
Marjoram herb.—The essential oil obtained from distilling Origanum majorana, known as oil of oringeat in French, is extremely potent and shares this characteristic with essential oils from various thyme species, including marjoram. From one hundred pounds of dry herb, you can extract about ten ounces of essential oil. Oringeat oil is widely used for scenting soap, particularly in France rather than in England. It is the main ingredient used by Gelle Frères in Paris for their "Tablet Monstre Soap," which is quite popular in London shops.
Meadow Sweet.—A sweet-smelling otto can be produced by distilling the Spiræa ulmaria, but it is not used by perfumers.
Meadow Sweet.—A sweet-smelling oil can be made by distilling the Spiræa ulmaria, but perfumers don’t use it.
Melissa. See Balm.
Melissa. See Balm.
Mignonette.—But for the exquisite odor of this little flower, it would scarcely be known otherwise than as a weed. Sweet as it is in its natural state, and prolific in odor, we are not able to maintain its characteristic smell as an essence. Like many others, during separation from the plant, the fragrance is more or less modified; though not perfect, it still reminds the sense of the odor of the flowers. To give it that sweetness which it appears to want, a certain quantity of violet is added to bring it up to the market odor.
Mignonette sauce.—Without the beautiful scent of this little flower, it would hardly be recognized as anything more than a weed. While it’s sweet in its natural state and has a strong fragrance, we can’t preserve its distinctive smell as an essence. Like many other scents, the fragrance changes somewhat when separated from the plant; although it’s not perfect, it still evokes the scent of the flowers. To enhance the sweetness it seems to lack, a certain amount of violet is added to match the market scent.
As this plant is so very prolific in odor, we think something might be done with it in England, especially as it flourishes as well in this country as in France; and we desire to see Flower Farms and organized Perfumatories established in the British Isles, for the extraction of essences and the manufacture of pomade and oils, of such flowers as are indigenous, or that thrive in the open fields of our country. Besides opening up a new field of enterprise and good investment for capital, it would give healthy employment to many women and children. Open air employment for the young is of no little consideration to maintain the stamina of the future generation; for it cannot be denied that our factory system and confined cities are prejudicial to the physical condition of the human family.
Since this plant has such a strong smell, we believe something could be done with it in England, especially since it grows well here just like it does in France. We would like to see Flower Farms and organized Perfumatories set up in the British Isles for extracting essences and making pomade and oils from flowers that are native or that thrive in our open fields. In addition to creating a new business opportunity and a good investment for capital, it would provide healthy jobs for many women and children. Outdoor work for the young is important to ensure the stamina of future generations because it's undeniable that our factory system and crowded cities are harmful to the physical well-being of people.
To return from our digression. The essence of mignonette, or, as it is more often sold under the name of Extrait de Rézéda, is prepared by infusing the rézéda pomade in rectified spirit, in the proportion of one pound of pomade to one pint of spirit, allowing them to digest together for a fortnight, when the essence is filtered off the pomade. One ounce of extrait d'ambré is added to every pint. This is done to give permanence to the odor upon the handkerchief, and does not in any way alter its odor.
To get back to our topic. The essence of mignonette, or what is more commonly referred to as Extrait de Rézéda, is made by soaking the rézéda pomade in rectified spirit, using a ratio of one pound of pomade to one pint of spirit. They are allowed to steep together for two weeks, after which the essence is filtered from the pomade. One ounce of extrait d'ambré is added to each pint. This step is to ensure the scent lasts on the handkerchief without changing its original fragrance.
Miribane.—The French name for artificial essence of almond (see Almond).
Miribane.—The French term for synthetic almond flavoring (see Almonds).
Mint.—All the Menthidæ yield fragrant ottos by distillation. The otto of the spear-mint (M. viridis) is exceedingly powerful, and very valuable for perfuming soap, in conjunction with other perfumes. Perfumers use the ottos of the mint in the manufacture of mouth-washes and dental liquids. The leading ingredient in the celebrated "eau Botot" is oil of peppermint in alcohol. A good imitation may be made thus:—
Minty.—All the Menthidæ produce fragrant oils through distillation. The oil from spear-mint (M. viridis) is very strong and highly valued for adding scent to soap, especially when mixed with other fragrances. Perfumers incorporate mint oils in making mouthwashes and dental products. The main ingredient in the famous "eau Botot" is peppermint oil blended with alcohol. A good imitation can be made this way:—
Botot Fragrance.
Tincture of cedar wood, | 1 pint. |
" myrrh, | 1 oz. |
Oil of peppermint, | 1/2 dr. |
" spear mint, | 1/4 dr. |
" cloves, | 10 drops. |
" roses, | 10 " |
Modifications of this formula can be readily suggested, but the main object is to retain the mint ottos, as they have more power than any other aromatic to overcome the smell of tobacco. Mouth-washes, it must be remembered, are as much used for rinsing the mouth after smoking as for a dentifrice.
Modifications to this formula can be easily proposed, but the main goal is to keep the mint oils, as they are more effective than any other fragrance at masking the smell of tobacco. It's important to remember that mouthwashes are used just as much for rinsing the mouth after smoking as they are for cleaning teeth.
Myrtle.—A very fragrant otto may be procured by distilling both flowers and leaves of the common myrtle; one hundred-weight will yield about five ounces of the volatile oil. The demand for essence of myrtle being very limited, the odor as found in the perfumers' shops is very rarely a genuine article, but it is imitated thus:—
Myrtle.—You can get a highly fragrant oil by distilling the flowers and leaves of common myrtle; one hundred pounds will produce about five ounces of the essential oil. Since there's not much demand for myrtle essence, the scent available in perfume shops is hardly ever the real deal; it's usually made to imitate it like this:—
Myrtle Scent Oil.
Extract of vanilla, | 1/2 pint. |
" roses | 1 " |
Extract of fleur d'orange, | 1/2 pint. |
" tubereuse, | 1/2 " |
" jasmine, | 2 oz. |
Mix and allow to stand for a fortnight: it is then fit for bottling, and is a perfume that gives a great deal of satisfaction.
Mix and let it sit for two weeks: it will then be ready for bottling and will produce a fragrance that provides a lot of enjoyment.
Myrtle-flower water is sold in France under the name of eau d'ange, and may be prepared like rose, elder, or other flower waters.
Myrtle-flower water is sold in France as eau d'ange and can be made like rose, elder, or other floral waters.
Neroli, or Orange-flower.—Two distinct odors are procurable from the orange-blossom, varying according to the methods adopted for procuring them. This difference of perfume from the same flower is a great advantage to the manufacturer. This curious fact is worthy of inquiry by the chemical philosopher. It is not peculiar to the orange-flower, but applies to many others, especially rose—probably to all flowers.
Neroli, or orange blossom.—You can get two different scents from the orange blossom, depending on the methods used to extract them. This variation in fragrance from the same flower is a significant benefit for manufacturers. This interesting phenomenon deserves investigation by those in the field of chemistry. It's not unique to the orange blossom; it applies to many other flowers as well, especially roses—likely to all flowers.
When orange-flowers are treated by the maceration process, that is, by infusion in a fatty body, we procure orange-flower pomatum, its strength and quality being regulated by the number of infusions of the flower made in the same grease.
When orange flowers are processed through maceration, meaning they are steeped in a fatty substance, we create orange-flower pomade, with its potency and quality depending on how many times the flowers are infused into the same fat.
By digesting this orange-flower pomatum in rectified spirits in the proportions of from six pounds to eight pounds of pomade to a gallon of spirit, for about a fortnight at a summer heat, we obtain the extrait de fleur d'orange, or extract of orange-flowers, a handkerchief perfume surpassed by none. In this state its odor resembles the original so much, that with closed eyes the best judge could not distinguish the scent of the extract from that of the flower. The peculiar flowery odor of this extract renders it valuable to perfumers, not only to sell in a pure state, but slightly modified with other extraits passes for "sweet pea," "magnolia," &c., which it slightly resembles in fragrance.
By mixing this orange flower pomade with purified alcohol in proportions of six to eight pounds of pomade to a gallon of alcohol, and letting it sit for about two weeks in warm weather, we get the orange flower extract, a captivating handkerchief perfume that's second to none. At this stage, its scent is so close to the original that even the best judge, with their eyes closed, couldn't tell the difference between the extract and the flower. The unique floral scent of this extract makes it valuable to perfumers, not just for selling it on its own, but also for combining it with other extracts, allowing it to pass off as "sweet pea," "magnolia," etc., which it slightly resembles in fragrance.

Now, when orange-flowers are distilled with water, we procure the otto of the blossom, which is known commercially as oil of neroli. The neroli procured from the flowers of the Citrus aurantium is considered to be the finest quality, and is called "neroli petale." The next quality, "neroli bigarade," is derived from the blossoms of the Citrus bigaradia, or Seville orange. Another quality, which is considered inferior to the preceding, is the neroli petit grain, obtained by distilling the leaves and the young unripe fruit of the different species of the citrus.
Now, when orange blossoms are distilled with water, we obtain the essence of the flower, which is commercially known as neroli oil. The neroli from the flowers of the Citrus aurantium is regarded as the highest quality and is referred to as "neroli petale." The next quality, "neroli bigarade," comes from the blossoms of the Citrus bigaradia, or Seville orange. Another type, considered lower quality than the previous ones, is neroli petit grain, which is obtained by distilling the leaves and young unripe fruit of various citrus species.
The "petale" and "bigarade" neroli are used to an enormous extent in the manufacture of eau de Cologne and other handkerchief perfumes. The petit grain is mainly consumed for scenting soap. To form the esprit de neroli, dissolve 1-1/2 oz. of neroli petale in one gallon of rectified spirits. Although very agreeable, and extensively used in the manufacture of bouquets, it has no relation to the flowery odor of the extrait de fleur d'orange, as derived from the same flowers by maceration; in fact, it has as different an odor as though obtained from another plant, yet in theory both these extraits are but alcoholic solutions of the otto of the flower.
The "petale" and "bigarade" neroli are widely used in making eau de Cologne and other handkerchief perfumes. The petit grain is mostly used to scent soap. To create the esprit de neroli, dissolve 1.5 oz. of neroli petale in one gallon of rectified spirits. While it is very pleasant and commonly used in making bouquets, it doesn’t resemble the floral scent of the extrait de fleur d'orange, which is derived from the same flowers through maceration; in fact, it smells as different as if it came from another plant, although theoretically both of these extraits are just alcoholic solutions of the flower’s essence.
The water used for distillation in procuring the neroli, when well freed from the oil, is imported into this country under the name of eau de fleur d'orange, and may be used, like elder-flower and rose-water, for the skin, and as an eye lotion. It is remarkable for its fine fragrance, and it is astonishing that it is not more used, being moderate in price. (See Syringa.)
The water used for distilling neroli, once well separated from the oil, is imported to this country as eau de fleur d'orange. It can be used for the skin and as an eye wash, similar to elderflower and rose water. It's known for its lovely scent, and it's surprising that it isn't used more often since it's reasonably priced. (See Syringa.)
Nutmeg.—The beautiful odor of the nutmeg is familiar to all. Though an otto can be drawn from them of a very fragrant character, it is rarely used in perfumery. The ground nuts are, however, used advantageously in the combinations of scented powders used for scent bags.—See "Sachet's Powders."
Nutmeg spice.—The lovely smell of nutmeg is known to everyone. Although a fragrant oil can be extracted from them, it's rarely used in perfumes. However, the ground seeds are often used effectively in scented powders for scent bags.—See "Sachet's Powders."
Olibanum is a gum resin, used to a limited extent in this country, in the manufacture of incense and pastilles. It is chiefly interesting as being one of those odoriferous bodies of which frequent mention is made in the Holy volume.[C]
Frankincense is a gum resin, used to a limited extent in this country, in the making of incense and pastilles. It is mainly notable for being one of those fragrant substances that are often mentioned in the Holy book.[C]
"It is believed," says Burnett, "to have been one of the ingredients in the sweet incense of the Jews; and it is still burnt as incense in the Greek and Romish churches, where the diffusion of such odors round the altar forms a part of the prescribed religious service."
"It is believed," says Burnett, "that it was one of the ingredients in the sweet incense used by the Jews; and it is still burned as incense in the Greek and Roman churches, where the spread of such scents around the altar is part of the prescribed religious service."
Olibanum is partially soluble in alcohol, and, like most of the balsams, probably owes its perfume to a peculiar odoriferous body, associated with the benzoic acid it contains.
Olibanum is partly soluble in alcohol, and like most balsams, it likely gets its fragrance from a unique aromatic compound linked to the benzoic acid it has.
For making the tincture or extract of olibanum, take 1 pound of the gum to 1 gallon of the spirit.
To make the tincture or extract of frankincense, use 1 pound of the gum for every 1 gallon of the alcohol.
Orange.—Under the title "Neroli" we have already spoken of the odoriferous principle of the orange-blossom. We have now to speak of what is known in the market as Essence of Orange, or, as it is more frequently termed, Essence of Portugal,—a name, however, which we cannot admit in a classified list of the "odors of plants."
Orange.—We've already discussed the fragrant essence of orange blossoms under the title "Neroli." Now we need to talk about what's commonly known as Essence of Orange, or more often referred to as Essence of Portugal. However, we can't accept this name in a categorized list of the "scents of plants."
The otto of orange-peel, or odoriferous principle of the orange fruit, is procured by expression and by distillation. The peel is rasped in order to crush the little vessels or sacs that imprison the otto.
The oil from orange peel, or the fragrant essence of the orange fruit, is obtained through pressing and distillation. The peel is grated to break the small vessels or sacs that contain the oil.
Its abundance in the peel is shown by pinching a piece near the flame of a candle; the otto that spirts out ignites with a brilliant illumination.
Its richness in the peel is evident when you pinch a piece near a candle flame; the oil that squirts out ignites with a bright glow.
It has many uses in perfumery, and from its refreshing fragrance finds many admirers.
It has a lot of uses in fragrance-making, and its fresh scent attracts many fans.
Lisbon Water.
Rectified spirit (not less than 60 over proof), | 1 gallon. |
Otto of orange peel, | 3 oz. |
" lemon peel, | 3 oz. |
" rose | 1/4 oz. |
This is a form for
This is a form for
Portugal Cologne.
Rectified spirit (60 over proof), | 1 gallon. |
Essential oil of orange peel, | 6 oz. |
" lemon peel, | 1 oz. |
" lemon grass, | 1/4 oz. |
" bergamot, | 1 oz. |
" otto of rose, | 1/4 oz. |
It should be noted that these perfumes are never to be filled into wet bottles, for if in any way damp from water, a minute portion of the ottos are separated, which gives an opalescent appearance to the mixture. Indeed, all bottles should be spirit rinsed prior to being filled with any perfume, but especially with those containing essences of orange or lemon peel.
It’s important to remember that these perfumes should never be poured into wet bottles, because if they are at all damp from water, a tiny amount of the essential oils can separate, making the mixture look opalescent. In fact, all bottles should be spirit rinsed before being filled with any perfume, but this is especially true for those containing orange or lemon peel essences.
Orris, properly Iris.—The dried rhizome of Iris florentina has a very pleasant odor, which, for the want of a better comparison, is said to resemble the smell of violets; it is, however, exceedingly derogatory to the charming aroma of that modest flower when such invidious comparisons are made. Nevertheless the perfume of iris root is good, and well worthy of the place it has obtained as a perfuming substance. The powder of orris root is very extensively used in the manufacture of sachet powders, tooth-powder, &c. It fathers that celebrated "oriental herb" known as "Odonto." For tincture of orris, or, as the perfumers call it,
Orris, more accurately Iris.—The dried root of Iris florentina has a lovely scent that's often said to remind people of violets; however, it’s unfair to compare it to the delightful fragrance of that delicate flower. Still, the perfume from iris root is delightful and deserving of its reputation as a fragrance ingredient. The powder made from orris root is widely used in making sachets, tooth powders, and more. It produces the famous "oriental herb" referred to as "Odonto." For orris tincture, or as perfumers call it,
Orris extract,
Take orris root, crushed, | 7 lbs. |
Rectified spirits, | 1 gallon. |
After standing together for about a fortnight, the extract is fit to take off. It requires considerable time to drain away, and, to prevent loss, the remainder of the orris should be placed in the tincture press. This extract enters into the composition of many of the most celebrated bouquets, such as "Jockey Club," and others, but is never sold alone, because its odor, although grateful, is not sufficiently good to stand public opinion upon its own merits; but in combination its value is very great; possessing little aroma itself, yet it has the power of strengthening the odor of other fragrant bodies; like the flint and steel, which though comparatively incombustible, readily fire inflammable bodies.
After sitting together for about two weeks, the extract is ready to be removed. It takes a considerable amount of time to drain, and to avoid any loss, the leftover orris should be put in the tincture press. This extract is part of many well-known fragrances, like "Jockey Club" and others, but it’s never sold by itself because, while its scent is pleasant, it doesn't have a strong enough appeal to stand alone in public opinion. However, when combined, its value is significant; it has little aroma of its own, but it enhances the scent of other fragrant materials, similar to how flint and steel can spark a fire in flammable substances despite their own lack of combustibility.
Palm.—The odor of palm oil—the fat oil of commerce—is due to a fragrant principle which it contains. By infusion in alcohol, the odoriferous body is dissolved, and resembles, to a certain extent, the tincture of orris, or of extract of violet, but is very indifferent, and is not likely to be brought into use, though several attempts have been made to render it of service when the cultivation of the violets have failed from bad seasons.
Palm tree.—The smell of palm oil—the commercial fat oil—comes from a fragrant substance it has. When infused in alcohol, the fragrant compound dissolves and somewhat resembles violet extract or orris tincture, but it’s pretty lackluster and probably won’t be used, even though there have been multiple attempts to make it useful when violet crops have failed due to poor weather.
Patchouly.—Pogostemon patchouly (Lindley), Plectranthus crassifolius (Burnett), is an herb that grows extensively in India and China. It somewhat resembles our garden sage in its growth and form, but the leaves are not so fleshy.
Patchouli.—Pogostemon patchouly (Lindley), Plectranthus crassifolius (Burnett), is a herb that grows widely in India and China. It looks a bit like our garden sage in its growth and shape, but the leaves aren’t as thick.

The odor of patchouly is due to an otto contained in the leaves and stems, and is readily procured by distillation. 1 cwt. of good herb will yield about 28 oz. of the essential oil, which is of a dark brown color, and of a density about the same as that of oil of sandal wood, which it resembles in its physical character. Its odor is the most powerful of any derived from the botanic kingdom; hence, if mixed in the proportion of measure for measure, it completely covers the smell of all other bodies.
The scent of patchouli comes from an essential oil found in the leaves and stems, which can be easily obtained through distillation. One hundredweight of good herb will produce about 28 ounces of essential oil, which is a dark brown color and has a density similar to sandalwood oil, resembling it in its physical properties. Its fragrance is the strongest of any plant-based scent; therefore, if mixed in equal parts, it completely masks the smell of all other substances.
Patchouli Extract.
Rectified spirit, | 1 gallon. |
Otto of patchouly, | 1-1/4 oz. |
" rose, | 1/4 oz. |
The essence of patchouly thus made is that which is found in the perfumers' shops of Paris and London. Although few perfumes have had such a fashionable run, yet when smelled at in its pure state, it is far from agreeable, having a kind of mossy or musty odor, analogous to Lycopodium, or, as some say, it smells of "old coats."
The essence of patchouli made in this way is what you find in the perfumeries of Paris and London. Although few perfumes have been as trendy, when you smell it in its pure form, it’s not very pleasant, having a sort of mossy or musty scent, similar to Lycopodium, or as some say, it smells like "old coats."
The characteristic smell of Chinese or Indian ink is due to some admixture of this herb.
The distinct smell of Chinese or Indian ink comes from a blend of this herb.
The origin of the use of patchouly as a perfume in Europe is curious. A few years ago real Indian shawls bore an extravagant price, and purchasers could always distinguish them by their odor; in fact, they were perfumed with patchouly. The French manufacturers had for some time successfully imitated the Indian fabric, but could not impart the odor.
The origin of using patchouli as a perfume in Europe is interesting. A few years ago, genuine Indian shawls were very expensive, and buyers could always tell them apart by their scent; they were actually scented with patchouli. French manufacturers had been successfully copying the Indian fabric for a while, but they couldn’t replicate the scent.
At length they discovered the secret, and began to import the plant to perfume articles of their make, and thus palm off homespun shawls as real Indian! From this origin the perfumers have brought it into use. Patchouly herb is extensively used for scenting drawers in which linen is kept; for this purpose it is best to powder the leaves and put them into muslin sacks, covered with silk, after the manner of the old-fashioned lavender-bag. In this state it is very efficacious in preventing the clothes from being attacked by moths. Several combinations of patchouly will be given in the recipes for "bouquets and nosegays."
Eventually, they figured out the secret and started importing the plant to scent their own products, making their homemade shawls seem like real Indian ones! From this origin, perfumers began using it. Patchouli herb is widely used for freshening drawers where linen is stored; for this, it's best to grind the leaves and place them in muslin bags, covered with silk, similar to the old-fashioned lavender bags. In this form, it is very effective in keeping moths away from the clothes. Several patchouli combinations will be included in the recipes for "bouquets and nosegays."
Pea (Sweet).—A very fine odor may be abstracted from the flowers of the chick-vetch by maceration in any fatty body, and then digesting the pomade produced in spirit. It is, however, rarely manufactured, because a very close
Pea (Sweet).—A delightful scent can be extracted from the flowers of the chick-vetch by soaking them in any fatty substance, and then infusing the resulting pomade in alcohol. However, it is seldom produced because a very close
Imitation of Sweet Pea Essence.
can be prepared thus:—
can be prepared like this:—
Extract of tuberose, | 1/2 pint. |
" fleur d'orange, | 1/2 " |
" rose from pomatum, | 1/2 " |
" vanilla, | 1 oz. |
Scents, like sounds, appear to influence the olfactory nerve in certain definite degrees. There is, as it were, an octave of odors like an octave in music; certain odors coincide, like the keys of an instrument. Such as almond, heliotrope, vanilla, and orange-blossoms blend together, each producing different degrees of a nearly similar impression. Again, we have citron, lemon, orange-peel, and verbena, forming a higher octave of smells, which blend in a similar manner. The metaphor is completed by what we are pleased to call semi-odors, such as rose and rose geranium for the half note; petty grain, neroli, a black key, followed by fleur d'orange. Then we have patchouli, sandal-wood, and vitivert, and many others running into each other.
Scents, like sounds, seem to impact the olfactory nerve in specific ways. There’s a range of odors similar to an octave in music; certain scents match up, like the keys on an instrument. For example, almond, heliotrope, vanilla, and orange blossoms mix together, each creating different levels of a nearly similar effect. Then we have citron, lemon, orange peel, and verbena, forming a higher range of smells that blend in a similar way. The analogy continues with what we call semi-odors, like rose and rose geranium representing the half note; petit grain, neroli serving as a black key, followed by fleur d'orange. Lastly, there are patchouli, sandalwood, vitivert, and many others merging into one another.
The odor of some flowers resembles others so nearly that we are almost induced to believe them to be the same thing, or, at least, if not evolved from the plant as such, to become so by the action of the air-oxidation. It is known that some actually are identical in composition, although produced from totally different plants, such as camphor, turpentine, rosemary. Hence we may presume that chemistry will sooner or later produce one from the other, for with many it is merely an atom of water or an atom of oxygen that causes the difference. It would be a grand thing to produce otto of roses from oil of rosemary, or from the rose geranium oil, and theory indicates its possibility.
The smell of some flowers is so similar to others that we might almost believe they are the same or, at the very least, that they could become so through exposure to the air. It's known that some flowers actually have the same chemical makeup even though they come from completely different plants, like camphor, turpentine, and rosemary. Therefore, we can assume that chemistry will eventually make one from the other, as often it's just a water molecule or an oxygen atom that makes the difference. It would be amazing to create rose oil from rosemary oil or from rose geranium oil, and theories suggest that it's possible.
The essential oil of almonds in a bottle that contains a good deal of air-oxygen, and but a very little of the oil, spontaneously passes into another odoriferous body, benzoic acid; which is seen in crystals to form over the dry parts of the flask. This is a natural illustration of this idea. In giving the recipe for "sweet pea" as above, we form it with the impression that its odor resembles the orange-blossom, which similarity is approached nearer by the addition of the rose and tuberose.
The essential oil of almonds in a bottle that holds a lot of air and only a small amount of the oil naturally transforms into another fragrant substance, benzoic acid, which forms visible crystals on the dry parts of the flask. This is a natural illustration of this concept. When we provide the recipe for "sweet pea" as mentioned earlier, we do it with the idea that its scent is reminiscent of orange blossom, a similarity that is enhanced with the addition of rose and tuberose.
The vanilla is used merely to give permanence to the scent on the handkerchief, and this latter body is chosen in preference to extract of musk or ambergris, which would answer the same purpose of giving permanence to the more volatile ingredients; because the vanilla strikes the same key of the olfactory nerve as the orange-blossom, and thus no new idea of a different scent is brought about as the perfume dies off from the handkerchief. When perfumes are not mixed upon this principle, then we hear that such and such a perfume becomes "sickly" or "faint" after they have been on the handkerchief a short time.
The vanilla is used just to make the scent last longer on the handkerchief, which is preferred over musk or ambergris for the same purpose of prolonging the more volatile ingredients. This is because vanilla activates the same part of the olfactory nerve as orange blossom, so no new scent is introduced as the perfume fades from the handkerchief. When perfumes aren't blended this way, we often find that certain fragrances become "sickly" or "faint" after a short while on the handkerchief.
Pine-apple.—Both Dr. Hoffman and Dr. Lyon Playfair have fallen into some error in their inferences with regard to the application of this odor in perfumery. After various practical experiments conducted in a large perfumatory, we have come to the conclusion that it cannot be so applied, simply because when the essence of pine-apple is smelled at, the vapor produces an involuntary action of the larynx, producing cough, when exceedingly dilute. Even in the infinitesimal portions it still produces disagreeable irritation of the air-pipes, which, if prolonged, such as is expected if used upon a handkerchief, is followed by intense headache. It is obvious, therefore, that the legitimate use of the essence of pine-apple (butyric ether) cannot be adapted with benefit to the manufacturing perfumer, although invaluable to the confectioner as a flavoring material. What we have here said refers to the artificial essence of pine-apple, or butyrate of ethyloxide, which, if very much diluted with alcohol, resembles the smell of pine-apple, and hence its name; but how far the same observations are applicable to the true essential oil from the fruit or epidermis of the pine-apple, remains to be seen when we procure it. As the West Indian pine-apples are now coming freely into the market, the day is probably not distant when demonstrative experiments can be tried; but hitherto it must be remembered our experiments have only been performed with a body resembling in smell the true essential oil of the fruit. The physical action of all ethers upon the human body is quite sufficient to prevent their application in perfumery, however useful in confectionary, which it is understood has to deal with another of the senses,—not of smell, but of taste. The commercial "essence of pine-apple," or "pine-apple oil," and "jargonelle pear-oil," are admitted only to be labelled such, but really are certain organic acid ethers. For the present, then, perfumers must only look on these bodies as so many lines in the "Poetry of Science," which, for the present, are without practical application in his art.
Pineapple.—Both Dr. Hoffman and Dr. Lyon Playfair have made some mistakes in their conclusions about how this scent can be used in perfumes. After conducting various practical experiments in a large perfume factory, we concluded that it cannot be used that way, mainly because when the pineapple essence is inhaled, the vapor causes an involuntary reaction in the throat, leading to coughing, even when very diluted. Even in tiny amounts, it still irritates the airways, which, if prolonged, like when used on a handkerchief, can result in a severe headache. Therefore, it’s clear that the legitimate use of pineapple essence (butyric ether) cannot be beneficial for the perfumer, though it is invaluable to candy makers as a flavoring agent. What we’ve stated here refers to the artificial pineapple essence, or butyrate of ethyloxide, which, when significantly diluted with alcohol, mimics the scent of pineapple, hence its name; but it remains to be seen how far these observations apply to the true essential oil from the fruit or outer layer of the pineapple when we obtain it. As West Indian pineapples are now making their way into the market, it’s likely that soon we can conduct demonstrative experiments; but so far, we’ve only experimented with a substance that resembles the scent of the true essential oil of the fruit. The physical effects of all ethers on the human body are enough to prevent their use in perfumery, even though they are useful in candy making, which deals with a different sense—not smell, but taste. The commercial "essence of pineapple," or "pineapple oil," and "jargonelle pear oil," are only allowed to be labeled as such, but in reality, they are certain organic acid ethers. For now, perfumers should view these substances as mere lines in the "Poetry of Science," which, at this time, have no practical application in their craft.
Pink.—Dianthus Caryophyllus.—The clove pink emits a most fragrant odor, "especially at night," says Darwin.
Pink.—Dianthus Caryophyllus.—The clove pink has a really pleasant scent, "especially at night," according to Darwin.
is not, however, at present applied in perfumery, except in name.
is not, however, currently used in perfumery, except in name.
Imitation Clove Pink Fragrance.
Esprit rose, | 1/2 pint. |
" fleur d'orange, | 1/4 " |
" " de cassie, | 1/4 " |
" vanilla, | 2 oz. |
Oil of cloves, | 10 drops. |
Rhodium.—When rose-wood, the lignum of the Convolvulus scoparius, is distilled, a sweet-smelling oil is procured, resembling in some slight degree the fragrance of the rose, and hence its name. At one time, that is, prior to the cultivation of the rose-leaf geranium, the distillates from rose-wood and from the root of the Genista canariensis (Canary-rose-wood), were principally drawn for the adulteration of real otto of roses, but as the geranium oil answers so much better, the oil of rhodium has fallen into disuse, hence its comparative scarcity in the market at the present day, though our grandfathers knew it well. One cwt. of wood yields about three ounces of oil.
Rhodium.—When rosewood, the wood from the Convolvulus scoparius, is distilled, it produces a sweet-smelling oil that somewhat resembles the scent of roses, which is how it got its name. Back in the day, before people started growing rose-leaf geraniums, the oils extracted from rosewood and the root of the Genista canariensis (Canary rosewood) were mainly used to mix with real rose oil. But because geranium oil works so much better, rhodium oil has become less common and is relatively rare in today’s market, even though our grandparents were quite familiar with it. One hundredweight of wood yields about three ounces of oil.
Ground rose-wood is valuable as a basis in the manufacture of sachet powders for perfuming the wardrobe.
Ground rosewood is valuable for making sachet powders to perfume your wardrobe.
The French have given the name jacaranda to rose-wood, under the idea that the plant called jacaranda by the Brazilians yields it, which is not the case; "the same word has perhaps been the origin of palisander—palixander, badly written."—Burnett.
The French call rosewood "jacaranda," believing that the Brazilian plant of the same name produces it, which isn't true; "the same word may have possibly led to the term palisander—palixander, misspelled."—Burnett.
Rose.—
Rose.—
And spread its treasures, a sweet fragrance,
In incense to the skies.
This queen of the garden loses not its diadem in the perfuming world. The oil of roses, or, as it is commonly called, the otto, or attar, of roses, is procured (contrary to so many opposite statements) simply by distilling the roses with water.
This queen of the garden doesn't lose its crown in the fragrant world. The oil of roses, or what is commonly known as otto or attar of roses, is made (contrary to many contradictory claims) simply by distilling the roses with water.
The otto, or attar, of rose of commerce is derived from the Rosa centifolia provincialis. Very extensive rose farms exist at Adrianople (Turkey in Europe); at Broussa, now famous as the residence of Abd-el-Kader; and at Uslak (Turkey in Asia); also at Ghazepore, in India.
The rose oil, or attar, used in commerce comes from the Rosa centifolia provincialis. There are large rose farms located in Adrianople (European Turkey), Broussa, now well-known as the home of Abd-el-Kader, Uslak (Asian Turkey), and Ghazepore, in India.
The cultivators in Turkey are principally the Christian inhabitants of the low countries of the Balkan, between Selimno, and Carloya, as far as Philippopolis, in Bulgaria, about 200 miles from Constantinople. In good seasons, this district yields 75,000 ounces; but in bad seasons only 20,000 to 30,000 ounces of attar are obtained. It is estimated that it requires at least 2000 rose blooms to yield one drachm of otto.
The farmers in Turkey are mainly the Christian residents of the low-lying areas of the Balkans, between Selimno and Carloya, reaching up to Philippopolis in Bulgaria, about 200 miles from Istanbul. In good years, this region produces 75,000 ounces; but in bad years, only 20,000 to 30,000 ounces of attar are collected. It is estimated that at least 2,000 rose blooms are needed to produce one drachm of otto.
The otto slightly varies in odor from different districts; many places furnish an otto which solidifies more readily than others, and, therefore, this is not a sure guide of purity, though many consider it such. That which was exhibited in the Crystal Palace of 1851, as "from Ghazepore," in India, obtained the prize.
The otto has a slightly different smell depending on the region; some areas provide an otto that solidifies more easily than others, so this is not a reliable indicator of purity, even though many people think it is. The one that was showcased at the Crystal Palace in 1851, labeled "from Ghazepore," India, won the prize.
"Attar of roses, made in Cashmere, is considered superior to any other; a circumstance not surprising, as, according to Hugel, the flower is here produced of surpassing fragrance as well as beauty. A large quantity of rose-water twice distilled is allowed to run off into an open vessel, placed over night in a cool running stream, and in the morning the oil is found floating on the surface in minute specks, which are taken off very carefully by means of a blade of sword-lily. When cool it is of a dark green color, and as hard as resin, not becoming liquid at a temperature about that of boiling water. Between 500 and 600 pounds' weight of leaves is required to produce one ounce of the attar."—Indian Encyclopædia.
"Rose oil, made in Cashmere, is considered the best of all; this isn’t surprising, as Hugel notes that the flowers here have an incredible fragrance and beauty. A large amount of rose water is distilled twice and then allowed to flow into an open container, which is left overnight in a cool stream. In the morning, the oil is found floating on the surface in tiny specks, which are carefully collected using a blade of sword lily. When cooled, it turns dark green and is as hard as resin, not melting even at a temperature close to boiling water. It takes between 500 and 600 pounds of leaves to produce just one ounce of the oil."—Indian Encyclopædia.
Pure otto of roses, from its cloying sweetness, has not many admirers; when diluted, however, there is nothing to equal it in odor, especially if mixed in soap, to form rose soap, or in pure spirit, to form the esprit de rose. The soap not allowing the perfume to evaporate very fast, we cannot be surfeited with the smell of the otto.
Pure rose oil, because of its overwhelming sweetness, doesn't have many fans; however, when diluted, nothing compares to its scent, especially when mixed into soap to create rose soap, or in pure alcohol to make rose essence. The soap keeps the fragrance from evaporating quickly, so we aren't overwhelmed by the smell of the oil.
The finest preparation of rose as an odor is made at Grasse, in France. Here the flowers are not treated for the otto, but are subjected to the process of maceration in fat, or in oil, as described under jasmine, heliotrope, &c.
The best way to prepare rose fragrance is done in Grasse, France. Here, the flowers aren't processed for essential oil; instead, they're immersed in fat or oil, similar to the methods used for jasmine, heliotrope, and others.
The rose pomade thus made, if digested in alcohol, say 8 lbs. of No. 24 Pomade to one gallon of spirit, yields an esprit de rose of the first order, very superior to that which is made by the addition of otto to spirit. It is difficult to account for this difference, but it is sufficiently characteristic to form a distinct odor. See the article on fleur d'orange and neroli (pp. 77, 78), which have similar qualities, previously described. The esprit de rose made from the French rose pomade is never sold retail by the perfumer; he reserves this to form part of his recherche bouquets.
The rose pomade, when mixed with alcohol—about 8 lbs. of No. 24 Pomade to one gallon of spirit—produces a high-quality rose essence that's much better than what's made by adding otto to spirit. It's hard to explain this difference, but it's distinctive enough to create a unique scent. Check out the section on fleur d'orange and neroli (pp. 77, 78), which share similar qualities and were discussed earlier. The rose essence made from the French rose pomade is never sold directly to customers by the perfumer; he keeps it to use in his special bouquets.
Some wholesale druggists have, however, been selling it now for some time to country practitioners, for them to form extemporaneous rose-water, which it does to great perfection. Roses are cultivated to a large extent in England, near Mitcham, in Surrey, for perfumers' use, to make rose-water. In the season when successive crops can be got, which is about the end of June, or the early part of July, they are gathered as soon as the dew is off, and sent to town in sacks. When they arrive, they are immediately spread out upon a cool floor: otherwise, if left in a heap, they heat to such an extent, in two or three hours, as to be quite spoiled. There is no organic matter which so rapidly absorbs oxygen, and becomes heated spontaneously, as a mass of freshly gathered roses.
Some wholesale druggists have been selling it for a while now to rural practitioners, so they can make fresh rose water, which it does perfectly. Roses are widely grown in England, near Mitcham in Surrey, for use by perfumers to create rose water. During the season when multiple harvests are possible, which is around the end of June or early July, they are picked as soon as the dew is gone and sent to the city in sacks. Once they arrive, they are quickly spread out on a cool floor; if left in a pile, they can get so hot within two or three hours that they spoil completely. There's no organic material that absorbs oxygen and heats up spontaneously as quickly as a pile of freshly picked roses.
To preserve these roses, the London perfumers immediately pickle them; for this purpose, the leaves are separated from the stalks, and to every bushel of flowers, equal to about six pounds' weight, one pound of common salt is thoroughly rubbed in. The salt absorbs the water existing in the petals, and rapidly becomes brine, reducing the whole to a pasty mass, which is finally stowed away in casks. In this way they will keep almost any length of time, without the fragrance being seriously injured. A good rose-water can be prepared by distilling 12 lbs. of pickled roses, and 2-1/2 gallons of water. "Draw" off two gallons; the product will be the double-distilled rose-water of the shops. The rose-water that is imported from the South of France is, however, very superior in odor to any that can be produced here. As it is a residuary product of the distillation of roses for procuring the attar, it has a richness of aroma which appears to be inimitable with English-grown roses. There are four modifications of essence of rose for the handkerchief, which are the ne plus ultra of the perfumer's art. They are,—esprit de rose triple, essence of white of roses, essence of tea rose, and essence of moss rose. The following are the recipes for their formation:—
To preserve these roses, the London perfumers immediately pickle them; for this purpose, the leaves are separated from the stalks, and for every bushel of flowers, weighing about six pounds, one pound of common salt is thoroughly rubbed in. The salt absorbs the moisture in the petals, quickly turning into brine and reducing everything to a paste, which is then stored in barrels. This method allows them to last a long time without losing much of their fragrance. A good rose water can be made by distilling 12 lbs. of pickled roses with 2.5 gallons of water. "Draw" off two gallons; this will yield the double-distilled rose water found in stores. However, the rose water imported from the South of France is much better in scent than any produced here. As it is a byproduct of distilling roses to make attar, it has a rich aroma that seems impossible to replicate with English-grown roses. There are four types of rose essence for handkerchiefs, which represent the pinnacle of perfumer's craft. They are—esprit de rose triple, essence of white roses, essence of tea rose, and essence of moss rose. Here are the recipes for making them:—
Esprit de Rose Triple.
Rectified alcohol, | 1 gallon. |
Otto of rose, | 3 oz. |
Mix at a summer heat; in the course of a quarter of an hour the whole of the otto is dissolved, and is then ready for bottling and sale. In the winter season beautiful crystals of the otto—if it is good—appear disseminated through the esprit.
Mix in the summer heat; after about fifteen minutes, the entire otto is dissolved and is then ready for bottling and sale. In the winter, beautiful crystals of the otto—if it's good—emerge throughout the esprit.
Moss Rose Essence.
Spirituous extract from French Rose pomatum, | 1 quart. |
Esprit de rose triple, | 1 pint. |
Extracts fleur d'orange pomatum, | 1 " |
" of ambergris, | 1/2 " |
" musk, | 4 oz. |
Allow the ingredients to remain together for a fortnight; then filter, if requisite, and it is ready for sale.
Let the ingredients sit together for two weeks; then strain them if needed, and it's ready to sell.
Essence of White Rose.
Esprit de rose from pomatum, | 1 quart. |
" " triple, | 1 " |
" violette, | 1 " |
Extracts of jasmine | 1 pint. |
" patchouly, | 1/2 " |
Essence of Tea Rose.
Esprit de rose pomade, | 1 pint. |
" " triple, | 1 " |
Extract of rose-leaf geranium, | 1 " |
" sandal-wood, | 1/2 " |
" neroli, | 1/4 " |
" orris, | 1/4 " |
Rosemary.—
Rosemary.
By distilling the Rosmarinus officinalis a thin limpid otto is procured, having the characteristic odor of the plant, which is more aromatic than sweet. One cwt. of the fresh herb yields about twenty-four ounces of oil. Otto of rosemary is very extensively used in perfumery, especially in combination with other ottos for scenting soap. Eau de Cologne cannot be made without it, and in the once famous "Hungary water" it is the leading ingredient. The following is the composition of
By extracting the Rosmarinus officinalis, a clear and light oil is obtained, which has the distinctive scent of the plant, more fragrant than sweet. One hundred pounds of the fresh herb produces about twenty-four ounces of oil. Rosemary oil is commonly used in perfumery, especially when mixed with other oils for fragrancing soap. Eau de Cologne cannot be created without it, and it is the main ingredient in the once-popular "Hungary water." The following is the composition of
Hungarian water.
Rectified alcohol, | 1 gallon. |
Otto of English rosemary, | 2 oz. |
" lemon-peel, | 1 oz. |
" balm (Melissa), | 1 oz. |
" mint, | 1/2 drachm. |
Esprit de rose, | 1 pint. |
Extract of fleur d'orange, | 1 " |
It is put up for sale in a similar way to eau de Cologne, and is said to take its name from one of the queens of Hungary, who is reported to have derived great benefit from a bath containing it, at the age of seventy-five years. There is no doubt that clergymen and orators, while speaking for any time, would derive great benefit from perfuming their handkerchief with Hungary water or eau de Cologne, as the rosemary they contain excites the mind to vigorous action, sufficient of the stimulant being inhaled by occasionally wiping the face with the handkerchief wetted with these "waters." Shakspeare giving us the key, we can understand how it is that such perfumes containing rosemary are universally said to be "so refreshing!"
It’s sold in a way similar to eau de Cologne and is said to be named after one of the queens of Hungary, who reportedly greatly benefited from a bath with it at the age of seventy-five. There’s no doubt that clergymen and speakers would benefit from perfuming their handkerchiefs with Hungary water or eau de Cologne, as the rosemary in them stimulates the mind for active thinking. Just a bit of the fragrance is inhaled by occasionally wiping the face with the handkerchief dampened with these "waters." With Shakespeare giving us the clue, we can understand why such perfumes with rosemary are commonly said to be "so refreshing!"
Sage.—A powerful-scenting otto can be procured by distillation from any of the Salvieæ. It is rarely used, but is nevertheless very valuable in combination for scenting soap.
Sage.—You can get a strong-smelling essential oil through distillation from any of the Salvieæ. It's not commonly used, but it's still quite valuable when mixed in to scent soap.
Dried sage-leaves, ground, will compound well for sachets.
Dried sage leaves, when ground, will mix nicely for sachets.
Santal.—Santalum album.
Sandalwood.—Santalum album.
This is an old favorite with the lovers of scent; it is the wood that possesses the odor. The finest santal-wood grows in the island of Timor, and the Santal-wood Islands, where it is extensively cultivated for the Chinese market. In the religious ceremonies of the Brahmins, Hindoos, and Chinese, santal-wood is burned, by way of incense, to an extent almost beyond belief. The Santala grew plentifully in China, but the continued offerings to the Buddahs have almost exterminated the plant from the Celestial Empire; and such is the demand, that it is about to be cultivated in Western Australia, in the expectation of a profitable return, which we doubt not will be realized; England alone would consume tenfold the quantity it does were its price within the range of other perfuming substances. The otto which exists in the santal-wood is readily procured by distillation; 1 cwt. of good wood will yield about 30 ounces of otto.
This is an old favorite among scent lovers; it’s the wood that has the fragrance. The best sandalwood comes from the island of Timor and the Sandalwood Islands, where it is widely grown for the Chinese market. In religious ceremonies of the Brahmins, Hindus, and Chinese, sandalwood is burned as incense to an extent that’s hard to believe. The Santala used to grow abundantly in China, but continuous offerings to the Buddhas have nearly wiped out the plant from the Celestial Empire; and such is the demand that it’s about to be cultivated in Western Australia, with hopes for a profitable return, which we have no doubt will be achieved; England alone would consume ten times the current amount if the price were comparable to other fragrant substances. The essential oil found in sandalwood can be easily extracted through distillation; 1 cwt. of good wood will yield about 30 ounces of essential oil.

The white ant, which is so common in India and China, eating into every organic matter that it comes across, appears to have no relish for santal-wood; hence it is frequently made into caskets, jewel-boxes, deed-cases, &c. This quality, together with its fragrance, renders it a valuable article to the cabinet-makers of the East.
The white ant, which is very common in India and China, consumes all types of organic matter it encounters, but it seems to have no taste for sandalwood. As a result, sandalwood is often used to make caskets, jewelry boxes, deed cases, etc. This characteristic, along with its fragrance, makes it a valuable material for cabinet makers in the East.
The otto of santal is remarkably dense, and is above all others oleaginous in its appearance, and, when good, is of a dark straw color. When dissolved in spirit, it enters into the composition of a great many of the old-fashioned bouquets, such as "Marechale," and others, the formulæ of which will be given hereafter. Perfumers thus make what is called
The otto of sandalwood is incredibly thick and has a significantly oily look, and when it’s of high quality, it has a dark straw color. When mixed with alcohol, it becomes a key ingredient in many classic perfumes, like "Marechale," among others, the recipes for which will be provided later. Perfumers use this to create what is known as
Sandalwood extract.
Rectified spirits, | 7 pints. |
Esprit de rose, | 1 pint. |
Essential oil, i.e.otto, of santal, | 3 oz. |
All those Extracts, made by dissolving the otto in alcohol, are nearly white, or at least only slightly tinted by the color of the oil used. When a perfumer has to impart a delicate odeur to a lady's mouchoir, which in some instances costs "no end of money," and is an object, at any cost, to retain unsullied, it behooves his reputation to sell an article that will not stain a delicate white fabric. Now, when a perfume is made in a direct manner from any wood or herb, as tinctures are made, that is, by infusion in alcohol, there is obtained, besides the odoriferous substance, a solution of coloring and extractive matter, which is exceedingly detrimental to its fragrance, besides seriously staining any cambric handkerchief that it may be used upon; and for this reason this latter method should never be adopted, except for use upon silk handkerchiefs.
All those Extracts, created by dissolving the otto in alcohol, are nearly white or only slightly tinted by the color of the oil used. When a perfumer needs to give a delicate scent to a lady's mouchoir, which can sometimes cost "a fortune" and is something that must stay spotless at all costs, it's crucial for his reputation to sell a product that won't stain a delicate white fabric. However, when a perfume is made directly from any wood or herb, as tinctures are made—meaning by infusing in alcohol—it not only produces an aromatic substance but also a solution of coloring and extractive materials that can seriously affect its fragrance and stain any cambric handkerchief it’s used on. For this reason, this latter method should only be used on silk handkerchiefs.
The odor of santal assimilates well with rose; and hence, prior to the cultivation of rose-leaf geranium, it was used to adulterate otto of roses; but is now but seldom used for that purpose.
The scent of sandalwood mixes well with rose, so before rose-leaf geranium was cultivated, it was often used to dilute otto of roses; but now it's rarely used for that.
By a "phonetic" error, santal is often printed "sandal," and "sandel."
By a "phonetic" error, santal is often printed as "sandal" and "sandel."
Sassafras.—Some of the perfumers of Germany use a tincture of the wood of the Laurus sassafras in the manufacture of hair-washes and other nostrums; but as, in our opinion, it has rather a "physicky" smell than flowery, we cannot recommend the German recipes. The Eau Athenienne, notwithstanding, has some reputation as a hair-water, but is little else than a weak tincture of sassafras.
Sassafras.—Some perfumers in Germany use an extract from the wood of the Laurus sassafras to make hair washes and other remedies; however, we don't recommend the German recipes because we think it has more of a medicinal smell than a floral one. The Eau Athenienne does have some reputation as a hair product, but it's basically just a diluted extract of sassafras.
Spike.—French oil of lavender, which is procured from the Lavandula spica, is generally called oil of spike. (See Lavender.)
Spike.—French oil of lavender, obtained from the Lavandula spica, is commonly referred to as spike oil. (See Lavender.)
Storax and Tolu are used in perfumery in the same way as benzoin, namely, by solution in spirit as a tincture. An ounce of tincture of storax, tolu, or benzoin, being added to a pound of any very volatile perfume, gives a degree of permanence to it, and makes it last longer on the handkerchief than it otherwise would: thus, when any perfume is made by the solution of an otto in spirit, it is usual to add to it a small portion of a substance which is less volatile, such as extract of musk, extract of vanilla, ambergris, storax, tolu, orris, vitivert, or benzoin; the manufacturer using his judgment and discretion as to which of these materials are to be employed, choosing, of course, those which are most compatible with the odor he is making.
Storax and Tolu are used in perfumery just like benzoin, specifically by dissolving them in alcohol to create a tincture. Adding an ounce of tincture of storax, tolu, or benzoin to a pound of any very volatile perfume increases its lasting power, making it stay longer on a handkerchief than it normally would. Therefore, when a perfume is created by dissolving an essence in alcohol, it's common to add a small amount of a less volatile substance, such as musk extract, vanilla extract, ambergris, storax, tolu, orris, vitivert, or benzoin; the manufacturer exercises their judgment and discretion regarding which of these materials to use, selecting those that best match the fragrance they are creating.
The power which these bodies have of "fixing" a volatile substance, renders them valuable to the perfumer, independent of their aroma, which is due in many cases to benzoic acid, slightly modified by an esential oil peculiar to each substance, and which is taken up by the alcohol, together with a portion of resin. When the perfume is put upon a handkerchief, the most volatile bodies disappear first: thus, after the alcohol has evaporated, the odor of the ottos appear stronger; if it contains any resinous body, the ottos are held in solution, as it were, by the resin, and thus retained on the fabric. Supposing a perfume to be made of otto only, without any "fixing" substance, then, as the perfume "dies away," the olfactory nerve, if tutored, will detect its composition, for it spontaneously analyzes itself, no two ottos having the same volatility: thus, make a mixture of rose, jasmine, and patchouly; the jasmine predominates first, then the rose, and, lastly, the patchouly, which will be found hours after the others have disappeared.
The ability of these substances to “fix” a volatile compound makes them valuable to perfumers, regardless of their scent, which is often due to benzoic acid, slightly altered by a unique essential oil from each substance. This oil is absorbed by the alcohol along with some resin. When a perfume is applied to a handkerchief, the most volatile components evaporate first: after the alcohol evaporates, the scent of the pure oils becomes stronger; if it contains any resinous substances, the oils are effectively held in the resin and thus retained on the fabric. If a perfume consists purely of oils without any fixing agent, as the scent fades, a trained nose will be able to pick up on its composition because it naturally breaks down; no two oils have the same volatility. For example, if you mix rose, jasmine, and patchouli, the jasmine will be noticeable first, followed by the rose, and finally the patchouli, which will linger hours after the others have faded away.
Syringa.—The flowers of the Philadelphus coronarius, or common garden syringa, have an intense odor resembling the orange-blossom; so much so, that in America the plant is often termed "mock orange." A great deal of the pomatum sold as pommade surfin, à la fleur d'orange, by the manufacturers of Cannes, is nothing more than fine suet perfumed with syringa blossoms by the maceration process. Fine syringa pomade could be made in England at a quarter the cost of what is paid for the so-called orange pomatum.
Lilac.—The flowers of the Philadelphus coronarius, or common garden syringa, have a strong scent similar to orange blossoms; so much so that in America, this plant is often called "mock orange." A lot of the pomade sold as pommade surfin, à la fleur d'orange by manufacturers in Cannes is actually just fine suet scented with syringa blossoms through the maceration process. High-quality syringa pomade could be made in England for a quarter of the price of what people pay for the so-called orange pomatum.
Thyme.—All the different species of thyme, but more particularly the lemon thyme, the Thymus serpyllum, as well as the marjorams, origanum, &c., yield by distillation fragrant ottos, that are extensively used by manufacturing perfumers for scenting soaps; though well adapted for this purpose, they do not answer at all in any other combinations. Both in grease and in spirit all these ottos impart an herby smell (very naturally) rather than a flowery one, and, as a consequence, they are not considered recherché.
Thyme herb.—All the different types of thyme, especially lemon thyme, the Thymus serpyllum, along with marjorams, oreganos, and so on, produce fragrant oils through distillation. These oils are widely used by perfume manufacturers to scent soaps. Although they work well for this purpose, they don’t blend well in any other combinations. In both oil and alcohol, these oils give off a herbaceous scent (which makes sense) rather than a floral one, and because of that, they aren’t considered recherché.
When any of these herbs are dried and ground, they usefully enter into the composition of sachet powders.
When any of these herbs are dried and ground, they can be effectively used in making sachet powders.
Tonquin, or Tonka.—The seeds of the Dipterix odorata are the tonquin or coumarouma beans of commerce. When fresh they are exceedingly fragrant, having an intense odor of newly made hay. The Anthoxanthum odoratum, or sweet-smelling vernal grass, to which new hay owes its odor, probably yields identically the same fragrant principle, and it is remarkable that both tonquin beans and vernal grass, while actually growing, are nearly scentless, but become rapidly aromatic when severed from the parent stock.
Tonquin, or Tonka truck.—The seeds of the Dipterix odorata are the tonquin or coumarouma beans used in commerce. When fresh, they have a strong fragrance, resembling the smell of fresh hay. The Anthoxanthum odoratum, also known as sweet-scented vernal grass, is likely responsible for the same fragrant component that gives new hay its scent. Interestingly, both tonquin beans and vernal grass are nearly scentless while they are growing, but they quickly become aromatic once separated from the plant.
Chemically considered, tonquin beans are very interesting, containing, when fresh, a fragrant volatile otto (to which their odor is principally due), benzoic acid, a fat oil and a neutral principal—Coumarin. In perfumery they are valuable, as, when ground, they form with other bodies an excellent and permanent sachet, and by infusion in spirit, the tincture or extract of tonquin enters into a thousand of the compound essences; but on account of its great strength it must be used with caution, otherwise people say your perfume is "snuffy," owing to the predominance of the odor and its well-known use in the boxes of those who indulge in the titillating dust.
Tonquin beans are quite intriguing from a chemical perspective. When fresh, they contain a fragrant volatile otto (which is mainly responsible for their smell), benzoic acid, a fatty oil, and a neutral substance—Coumarin. In the world of perfumery, they are valuable because when ground, they create an excellent and lasting sachet with other ingredients. Additionally, when infused in alcohol, the tincture or extract of tonquin is used in countless compound essences. However, due to its intense strength, it must be used carefully; otherwise, people say your perfume smells "snuffy," as the strong odor can dominate, similar to what's found in the boxes of those who enjoy the stimulating powder.

Tonquin Extract.
Tonquin beans, | 1 lb. |
Rectified spirit, | 1 gallon. |
Digest for a month at a summer heat. Even after this maceration they are still useful when dried and ground in those compounds known as Pot Pourri, Olla Podria, &c. The extract of tonquin, like extract of orris and extract of vanilla, is never sold pure, but is only used in the manufacture of compound perfumes. It is the leading ingredient in Bouquet du Champ—The field Bouquet—the great resemblance of which to the odor of the hay-field, renders it a favorite to the lovers of the pastoral.
Soak for a month in the summer heat. Even after this soaking, they are still useful when dried and ground in mixtures known as Potpourri, Olla Podrida, etc. The extract of tonka bean, like orris and vanilla extracts, is never sold pure but is only used in making compound perfumes. It is the main ingredient in Bouquet du Champ—the Field Bouquet—which closely resembles the scent of a hayfield, making it a favorite among fans of pastoral fragrances.
Tuberose.—One of the most exquisite odors with which we are acquainted is obtained by enfleurage from the tuberose flower. It is, as it were, a nosegay in itself, and reminds one of that delightful perfume observed in a well-stocked flower-garden at evening close; consequently it is much in demand by the perfumers for compounding sweet essences.
Tuberose.—One of the most beautiful scents we know comes from extracting it from the tuberose flower using the method of enfleurage. It’s like a bouquet all on its own and brings to mind the lovely fragrance found in a well-kept flower garden at dusk; that’s why it’s highly sought after by perfumers for creating sweet fragrances.
Tuberose Extract.
Eight pounds of No. 24 tuberose pomatum, cut up very fine, is to be placed into 1 gallon of the best rectified spirit. After standing for three weeks or a month at summer heat, and with frequent agitation, it is fit to draw off, and being strained through cotton wool, is ready either for sale or use in the manufacture of bouquets.
Eight pounds of No. 24 tuberose pomade, finely chopped, should be mixed with 1 gallon of high-quality rectified spirit. After letting it sit for three weeks to a month in warm summer temperatures, with frequent shaking, it can be strained through cotton wool and is then ready for sale or for use in making bouquets.
This essence of tuberose, like that of jasmine, is exceedingly volatile, and if sold in its pure state quickly "flies off" the handkerchief; it is therefore necessary to add some fixing ingredient, and for this purpose it is best to use one ounce of extract of orris, or half an ounce of extract of vanilla, to every pint of tuberose.
The essence of tuberose, similar to jasmine, is very volatile, and when sold in its pure form, it quickly evaporates from a handkerchief. Therefore, it’s important to add a fixing agent, and for this, it’s best to use one ounce of orris extract or half an ounce of vanilla extract for every pint of tuberose.
Vanilla.—The pod or bean of the Vanilla planifolia yields a perfume of rare excellence. When good, and if kept for some time, it becomes covered with an efflorescence of needle crystals possessing properties similar to benzoic acid, but differing from it in composition. Few objects are more beautiful to look upon than this, when viewed by a microscope with the aid of polarized light.
Vanilla flavor.—The pod or bean of the Vanilla planifolia produces a fragrance of exceptional quality. When it’s good, and if stored for a while, it becomes coated with a crystalline powder that has properties similar to benzoic acid but is different in composition. Few things are more stunning to observe than this when seen through a microscope with polarized light.

Vanilla Extract.
Vanilla pods, | 1/2 lb. |
Rectified spirit, | 1 gallon. |
Slit the pods from end to end, so as to lay open the interior, then cut them up in lengths of about a quarter of an inch, macerate with occasional agitation for about a month; the tincture thus formed will only require straining through cotton to be ready for any use that is required. In this state it is rarely sold for a perfume, but is consumed in the manufacture of compound odors, bouquets, or nosegays, as they are called.
Cut the pods open from end to end to expose the inside, then slice them into pieces about a quarter of an inch long. Soak them with some stirring for about a month; the mixture created will just need to be strained through cotton to be ready for whatever use you need. At this stage, it’s rarely sold as a perfume but is used in making of blended scents, bouquets, or nosegays, as they’re called.
Extract of Vanilla is also used largely in the manufacture of hair-washes, which are readily made by mixing the extract of vanilla with either rose, orange, elder, or rosemary water, and afterwards filtering.
Extract of vanilla is also widely used in making hair washes, which are simply made by mixing vanilla extract with rose, orange, elder, or rosemary water, and then filtering it.
We need scarcely mention, that vanilla is greatly used by cooks and confectioners for flavoring.
We hardly need to point out that vanilla is widely used by chefs and bakers for flavoring.
Verbena, or Vervaine.—The scented species of this plant, the lemon verbena, Aloysia citriodora (Hooker), gives one of the finest perfumes with which we are acquainted; it is well known as yielding a delightful fragrance by merely drawing the hand over the plant; some of the little vessels or sacks containing the otto must be crushed in this act, as there is little or no odor by merely smelling at the plant.
Verbena, or Vervain.—The fragrant type of this plant, lemon verbena, Aloysia citriodora (Hooker), produces one of the best perfumes we know of. It’s famous for releasing a lovely scent just by rubbing your hand over the leaves; some of the tiny glands that hold the essential oils must be crushed during this process, as there is hardly any smell if you just sniff the plant.
The otto, which can be extracted from the leaves by distillation with water, on account of its high price, is scarcely, if ever, used by the manufacturing perfumer, but it is most successfully imitated by mixing the otto of lemon grass, Andropogon schœnanthus, with rectified spirit, the odor of which resembles the former to a nicety. The following is a good form for making the
The otto, which can be extracted from the leaves through water distillation, is rarely, if ever, used by commercial perfumers due to its high cost. Instead, it is often successfully replicated by blending lemon grass otto, Andropogon schœnanthus, with purified alcohol, which closely resembles the original scent. Here’s a good method for making the
Verbena extract.
Rectified spirit, | 1 pint. |
Otto of lemon grass, | 3 drachms. |
" lemon peel, | 2 oz. |
" orange peel, | 1/2 oz. |
Another mixture of this kind, presumed by the public to be made from the same plant, but of a finer quality, is composed thus—it is sold under the title
Another mix like this, which people think is made from the same plant but is of better quality, is made this way—it’s sold under the name
Verveine extract.
Rectified spirit, | 1 pint. |
Otto of orange peel, | 1 oz. |
" lemon peel, | 2 oz. |
" citron, | 1 drachm. |
" lemon grass, | 2-1/2 drachms. |
Extrait de fleur d'orange, | 7 oz. |
" " tubereuse, | 7 oz. |
Esprit de rose, | 1/2 pint. |
This mixture is exceedingly refreshing, and is one of the most elegant perfumes that is made. Being white, it does not stain the handkerchief. It is best when sold fresh made, as by age the citrine oils oxidize, and the perfume acquires an ethereal odor, and then customers say "it is sour." The vervaine thus prepared enters into the composition of a great many of the favorite bouquets that are sold under the title "Court Bouquet," and others which are mixtures of violet, rose, and jasmine, with verbena or vervaine in different proportions. In these preparations, as also in Eau de Portugal, and in fact where any of the citrine ottos are used, a much finer product is obtained by using grape spirit or brandy in preference to the English corn spirit as a solvent for them. Nor do they deteriorate so quickly in French spirit as in English. Whether this be due to the oil of wine (œanthic ether) or not we cannot say, but think it is so.
This mix is incredibly refreshing and is one of the most elegant perfumes out there. Being white, it won't stain your handkerchief. It's best when sold fresh, as over time the citrus oils oxidize and the perfume takes on an ethereal scent, leading customers to say "it smells sour." The prepared vervain is included in many popular bouquets sold under the name "Court Bouquet," along with others that mix violet, rose, and jasmine with verbena or vervain in different amounts. In these preparations, as well as in Eau de Portugal, and in fact whenever citrus oils are used, a much better product is achieved by using grape spirit or brandy instead of English corn spirit as a solvent. They also don't degrade as quickly in French spirit as they do in English. Whether this is due to the oil of wine (œanthic ether) or not, we can't say for sure, but we think it is.
Violet.—
Violet.
Sweet thief, where did you steal your sweet-smelling fragrance, "If not from the breath of my love?"
The perfume exhaled by the Viola odorata is so universally admired, that to speak in its favor would be more than superfluous. The demand for the "essence of violets" is far greater than the manufacturing perfumers are at present able to supply, and as a consequence, it is difficult to procure the genuine article through the ordinary sources of trade.
The fragrance released by the Viola odorata is so widely appreciated that it seems unnecessary to praise it. The demand for the "essence of violets" far exceeds what perfumers can currently produce, making it hard to find the real thing through normal retail channels.
Real violet is, however, sold by many of the retail perfumers of the West End of London, but at a price that prohibits its use except by the affluent or extravagant votaries of fashion. The violet farms from whence the flowers are procured to make this perfume are very extensive at Nice and Grasse, also in the neighborhood of Florence. The true smelling principle or otto of violets has never yet been isolated: a very concentrated solution in alcohol impresses the olfactory nerve with the idea of the presence of hydrocyanic acid, which is probably a true impression. Burnett says that the plant Viola tricolor (heart's ease), when bruised, smells like peach kernels, and doubtless, therefore, contains prussic acid.
Real violet is sold by many retail perfumers in London's West End, but it comes at a price that makes it accessible only to the wealthy or those who indulge in fashion. The violet farms that supply the flowers for this perfume are quite large, located in Nice and Grasse, as well as near Florence. The true fragrant compound or otto of violets has never been isolated; a highly concentrated solution in alcohol triggers the olfactory nerve to perceive a presence of hydrogen cyanide, which is likely an accurate impression. Burnett states that the plant Viola tricolor (heart's ease), when crushed, smells like peach pits and likely contains prussic acid.
For commercial purposes, the odor of the violet is procured in combination with spirit, oil, or suet, precisely according to the methods previously described for obtaining the aroma of some other flowers before mentioned, such as those for cassie, jasmine, orange-flower, namely, by maceration, or by enfleurage, the former method being principally adopted, followed by, when "essence" is required, digesting the pomade in rectified alcohol.
For commercial use, the scent of the violet is extracted using spirits, oils, or fats, just like the processes described earlier for other flowers like cassie, jasmine, and orange blossom. This is done through maceration or by enfleurage, with maceration being the main method used. When "essence" is needed, the pomade is then soaked in purified alcohol.
Good essence of violets, thus made, is of a beautiful green color, and, though of a rich deep tint, has no power to stain a white fabric, and its odor is perfectly natural.
Good violet essence, when made this way, is a lovely green color and, despite having a rich deep shade, won't stain white fabric, and its scent is completely natural.
The essence of violet, as prepared for retail sale, is thus made, according to the quality and strength of the pomade:—Take from six to eight pounds of the violet pomade, chop it up fine, and place it into one gallon of perfectly clean (free from fusel oil) rectified spirit, allow it to digest for three weeks or a month, then strain off the essence, and to every pint thereof add three ounces of tincture of orris root, and three ounces of esprit de cassie; it is then fit for sale.
The essence of violet, as prepared for sale, is made based on the quality and strength of the pomade:—Take six to eight pounds of violet pomade, chop it up finely, and put it into one gallon of completely clean (free from fusel oil) rectified spirit. Let it sit for three weeks to a month, then strain off the essence. To every pint, add three ounces of tincture of orris root and three ounces of esprit de cassie; it's then ready for sale.
We have often seen displayed for sale in druggists' shops plain tincture of orris root, done up in nice bottles, with labels upon them inferring the contents to be "Extract of Violet;" customers thus once "taken in" are not likely to be so a second time.
We often see plain tincture of orris root for sale in drugstores, packaged in nice bottles with labels suggesting the contents are “Extract of Violet.” Customers who have been misled like this once are unlikely to fall for it again.
A good Violet Scent Imitation is best prepared thus—
Spirituous extract of cassie pomade, | 1 pint. |
Esprit de rose, from pomade, | 1/2 " |
Tincture of orris, | 1/2 " |
Spirituous extract of tuberose pomade, | 1/2 " |
Otto of almonds, | 3 drops. |
After filtration it is fit for bottling. In this mixture, it is the extract of cassie which has the leading smell, but modified by the rose and tuberose becomes very much like the violet. Moreover, it has a green color, like the extract of violet; and as the eye influences the judgment by the sense of taste, so it does with the sense of smell. Extract of violet enters largely into the composition of several of the most popular bouquets, such as extract of spring flowers and many others.
After filtration, it's ready for bottling. In this mixture, the extract of cassie produces the dominant scent, but when combined with rose and tuberose, it resembles the smell of violet quite closely. Additionally, it has a green color, similar to the violet extract; and just as sight can influence our taste perception, it can also affect our sense of smell. The extract of violet is a key ingredient in several popular bouquets, including spring flower extract and many others.
Vitivert, or Kus-Kus, is the rhizome of an Indian grass. In the neighborhood of Calcutta, and in the city, this material has an extensive use by being manufactured into awnings, blinds, and sun-shades, called Tatty. During the hot seasons an attendant sprinkles water over them; this operation cools the apartment by the evaporation of the water, and, at the same time, perfumes the atmosphere, in a very agreeable manner, with the odoriferous principle of the vitivert. It has a smell between the aromatic or spicy odor and that of flowers—if such a distinction can be admitted. We classify it with orris root, not that it has any odor resembling it, but because it has a like effect in use in perfumery, and because it is prepared as a tincture for obtaining its odor.
Vitivert, or Kus-Kus, is the root of an Indian grass. Around Calcutta and in the city itself, this material is widely used to make awnings, blinds, and sun shades, known as Tatty. During the hot seasons, an attendant sprays water on them; this action cools the room through evaporation and also fills the air with a pleasant fragrance from the vitivert. It has a scent that is a mix between an aromatic or spicy smell and floral notes—if such a distinction makes sense. We categorize it with orris root, not because it smells similar, but due to its similar effects in perfumery and because it is prepared as a tincture to capture its fragrance.
Essence of Vitivert of the shops. In this state it is rarely used as a perfume, although it is occasionally asked for by those who, perhaps, have learnt to admire its odor by their previous residence in "the Eastern clime." The extract, essence, or tincture of vitivert, enters into the composition of several of the much-admired and old bouquets manufactured in the early days of perfumery in England, such as "Mousselaine des Indies," for which preparation M. Delcroix, in the zenith of his fame, created quite a furor in the fashionable world.
Vitivert essence from the stores. In this form, it's rarely used as a perfume, although some people occasionally request it, perhaps because they've come to appreciate its scent during their time living in "the Eastern region." The extract, essence, or tincture of vitivert is part of several well-liked and classic fragrances that were made during the early days of perfumery in England, like "Mousselaine des Indies," which M. Delcroix, at the peak of his popularity, created quite a furor in the fashion world.

Essence of vitivert is also made by dissolving 2 oz. of otto of vitivert in 1 gallon of spirit; this preparation is stronger than the tincture, as above.
Essence of vetiver is also made by dissolving 2 oz. of vetiver oil in 1 gallon of alcohol; this preparation is stronger than the tincture mentioned above.
Marechale and Bouquet du Roi, perfumes which have also "had their day," owe much of their peculiarity to the vitivert contained in them.
Marechal and King's Bouquet, perfumes that have also "had their moment," owe a lot of their uniqueness to the vetiver in them.
Bundles of vitivert are sold for perfuming linen and preventing moth, and, when ground, is used to manufacture certain sachet powders.
Bundles of vetiver are sold for scenting linens and keeping moths away, and when ground, it's used to make certain sachet powders.
Volkameria.—An exquisite perfume is sold under this name, presumed, of course, to be derived from the Volkameria inermis (Lindley). Whether it has a smell resembling the flower of that plant, or whether the plant blooms at all, we are unable to say. It is a native of India, and seems to be little known even in the botanic gardens of this country; however, the plant has a name, and that's enough for the versatile Parisian perfumer, and if the mixture he makes "takes" with the fashionable world—the plant which christens it has a fine perfume for a certainty!
Volkameria.—An exquisite perfume is marketed under this name, which is thought to be derived from the Volkameria inermis (Lindley). We can't say if it smells like the flower of that plant or if the plant even flowers at all. It's native to India and seems to be little known even in the botanical gardens in this country; however, the plant has a name, and that's enough for the versatile Parisian perfumer. If the blend he creates is popular in the fashion world, then the plant it’s named after must have a wonderful scent for sure!
Essence of Volkameria.
Esprit de violette, | 1 pint. |
" tubereuse, | 1 " |
" jasmine, | 1/4 " |
" rose, | 1/2 " |
Essence de muse, | 2 oz. |
Wallflower (Cherianthus).—Exquisite as is the odor of this flower, it is not used in perfumery, though no doubt it might be, and very successfully too, were the plant cultivated for that purpose. To this flower we would direct particular attention, as one well adapted for experiments to obtain its odoriferous principle in this country, our climate being good for its production. The mode for obtaining its odor has been indicated when we spoke of heliotrope, page 60. And if it answers on the small scale, there is little doubt of success in the large way, and there is no fear but that the scent of the old English wallflower will meet with a demand.
Shy person (Cherianthus).—As lovely as the fragrance of this flower is, it's not used in perfumes, though it definitely could be, and quite successfully, if the plant was grown for that purpose. We want to highlight this flower because it’s ideal for experiments to extract its fragrant oil in this country, as our climate is suitable for its growth. The method for extracting its scent has been mentioned in relation to heliotrope, page 60. If it works on a small scale, there's no doubt it will succeed on a larger scale, and there’s no concern that the scent of the traditional English wallflower will find a market.
An Wallflower Fragrance Имитация can be compounded thus:—
Extract fleur d'orange, | 1 pint. |
" vanilla, | 1/2 " |
Esprit de rose, | 1 " |
Extract of orris, | 1/2 " |
" cassie, | 1/2 " |
Essential oil of almonds, | 5 drops. |
Allow this mixture to be made up for two or three weeks prior to putting it up for sale.
Let this mixture sit for two or three weeks before putting it up for sale.
Winter Green (Trientalis Europœa).—A perfuming otto can be procured by distilling the leaves of this plant: it is principally consumed in the perfuming of soaps. Upon the strength of the name of this odorous plant a very nice handkerchief perfume is made.
Winter Green (Trientalis Europœa).—A fragrant oil can be extracted by distilling the leaves of this plant: it is mainly used to scent soaps. Based on the reputation of this aromatic plant, a lovely handkerchief perfume is created.
Iceland Winter Greenery.
Esprit de rose, | 1 pint. |
Essence of lavender, | 1/4 " |
Extract of neroli, | 1/2 " |
" vanilla, | 1/4 " |
" vitivert, | 1/4 " |
" cassie, | 1/2 " |
" ambergris, | 1/4 " |
We have now described all the important odoriferous bodies which are used by the manufacturing perfumer, as derived from the botanic kingdom; it may be understood that where an odoriferous material is unnoticed, it has no qualities peculiar enough to be remarked on, and that the methods adopted for preparing its essence, extract, water, or oil, are analogous to those that have been already noticed, that is, by the processes of maceration, absorption, or enfleurage for flowers, by tincturation for roots, and by distillation for seeds, modified under certain circumstances.
We have now covered all the significant fragrant substances used by the commercial perfumer that come from the plant kingdom. It should be understood that if a fragrant material is not mentioned, it doesn’t have distinctive qualities worth noting, and the methods used to prepare its essence, extract, water, or oil are similar to those we’ve already discussed. This includes processes like maceration, absorption, or enfleurage for flowers, tincturation for roots, and distillation for seeds, adjusted under specific circumstances.
There are, however, three other important derivative odors—ambergris, civet, and musk—which, being from the animal kingdom, are treated separately from plant odors, in order, it is considered, to render the whole matter less confused to manufacturers who may refer to them. Ammonia and acetic acid, holding an indefinite position in the order we have laid down, may also come in here without much criticism, being considered as primitive odors.
There are, however, three other significant derivative scents—ambergris, civet, and musk—which, because they come from animals, are treated separately from plant scents. This is thought to make it less confusing for manufacturers who might refer to them. Ammonia and acetic acid, which have a flexible position in the order we've established, can also be included here without much criticism, as they are regarded as basic scents.
On terminating our remarks relating to the simple preparations of the odors of plants, and before we speak of perfumes of an animal origin, or of those compound odors sold as bouquets, nosegays, &c., it may probably be interesting to give a few facts and statistics, showing the consumption, in England, of the several substances previously named.
On wrapping up our discussion about the basic preparations of plant scents, and before we talk about animal-derived perfumes or the mixed scents sold as bouquets, nosegays, etc., it might be interesting to share some facts and statistics regarding the consumption of the various substances mentioned earlier in England.
Quantities of Essential Oils, or Ottos, paying 1s. per pound in duty, imported for home consumption in the year 1852.
lbs. | ||
Otto of bergamot, | 28,574 | |
" caraway, | 3,602 | |
" cassia, | 6,163 | |
" cloves, | 595 | |
Otto of lavender, | 12,776 | |
" lemon, | 67,348 | |
" peppermint, | 16,059 | |
" roses, | 1,268 | |
" spearmint, | 163 | |
" thyme, | 11,418 | |
" lemon grass, | } | |
" citronella, | } | 47,380 |
And other ottos not otherwise described, | } | |
———— | ||
Total essential oils or ottos imported in one year, | 195,346 |
at the duty of 1s. per pound, yield a revenue annually of 9,766l. 16s.
at the duty of 1s. per pound, generate an annual revenue of 9,766l. 16s.
It would appear by the above return that our consumption of otto of cloves was exceedingly small; whereas it is probably ten times that amount. The fact is, several of the English wholesale druggists are very large distillers of this otto, leaving little or no room for the sale and importation of foreign distilled otto of cloves. Again, otto of caraway, the English production of that article is quite equal to the foreign; also, otto of lavender, which is drawn in this country probably to the extent of 6000 lbs. annually.
It seems from the information above that our use of clove oil is really low, even though it’s likely ten times that amount. The truth is, several large English wholesale druggists are major producers of this oil, leaving little room for the sale and import of foreign clove oil. Similarly, for caraway oil, the English production is about equal to the foreign supply; also, lavender oil is extracted in this country at a rate of around 6000 lbs. per year.
There were also passed through the Custom House for home consumption, in 1852—
There were also cleared through the Custom House for personal use in 1852—
Pomatums, procured by enfleurage, maceration, &c., commonly called "French Pomatums," | |
average value of 6s.per pound, and paying a duty of 1s.per pound, valued by the importers at | £1,306 |
Perfumery not otherwise described; value | £1,920 |
Number of bottles of eau de Cologne, paying a duty of 1s. each,[D] | 19,777 |
Revenue from eau de Cologne manufactured out of England, say 20,000 flacons at 8d. = 8,000l. annually.
Revenue from eau de Cologne made in England, let's say 20,000 bottles at 8d. = 8,000l. each year.
The total revenue derived from various sources, even upon this low scale of duties, from the substances with which "Britannia perfumes her pocket handkerchief," cannot be estimated at less than 40,000l. per annum. This, of course, includes the duty upon the spirits used in the home manufacture of perfumery.
The total revenue from various sources, even with these low duty rates, from the substances with which "Britannia perfumes her pocket handkerchief," can't be estimated to be less than £40,000 per year. This, of course, includes the duty on the spirits used in the domestic production of perfume.
SECTION IV.
PERFUMES OF ANIMAL ORIGIN.
In the previous articles we have only spoken of the odors of plants; we now enter upon those materials used in perfumery of an animal origin. The first under our notice is—
In the previous articles, we only talked about the scents of plants; now we will discuss the materials used in perfumery that come from animals. The first one to consider is—
Ambergris.—This substance is found in the sea, floating near the islands of Sumatra, Molucca, and Madagascar; also on the coasts of America, Brazil, China, Japan, and the Coromandel. The western coast of Ireland is often found to yield large pieces of this substance. The shores of the counties of Sligo, Mayo, Kerry, and the isles of Arran, are the principal places where it has been found. In the "Philosophical Transactions" there is an account of a lump found on the beach of the first-mentioned county, in the year 1691, which weighed 52 oz., and was bought on the spot for 20l., but which afterwards was sold in London for more than 100l. (Philos. Trans. No. 227, p. 509). We are quite within limit in stating that many volumes concerning the origin of ambergris have been written, but the question respecting it is still at issue. It is found in the stomachs of the most voracious fishes, these animals swallowing, at particular times, everything they happen to meet with. It has been particularly found in the intestines of the spermaceti whale, and most commonly in sickly fish, whence it is supposed to be the cause or effect of the disease.
Ambergris.—This substance is found in the sea, floating near the islands of Sumatra, Molucca, and Madagascar; as well as on the coasts of America, Brazil, China, Japan, and Coromandel. The western coast of Ireland often yields large pieces of this substance. The shores of Sligo, Mayo, Kerry, and the Isles of Arran are the main places where it has been discovered. In the "Philosophical Transactions," there's a report of a lump found on the beach in Sligo in 1691 that weighed 52 oz., which was bought for £20 but later sold in London for over £100 (Philos. Trans. No. 227, p. 509). It's fair to say that many books have been written about the origin of ambergris, but the question surrounding it remains unresolved. It’s found in the stomachs of the most voracious fish, which tend to swallow just about anything they come across at certain times. It has been particularly noted in the intestines of the sperm whale and is most commonly found in unhealthy fish, leading to the belief that it could be a cause or a result of the illness.
Some authors, and among them Robert Boyle, consider it to be of vegetable production, and analogous to amber; hence its name amber-gris (gray) gray amber. It is not, however, within the province of this work to discuss upon the various theories about its production, which could probably be satisfactorily explained if our modern appliances were brought to bear upon the subject. The field is open to any scientific enthusiast; all recent authors who mention it, merely quoting the facts known more than a century ago.
Some authors, including Robert Boyle, believe it's a vegetable product similar to amber, which is why it's called amber-gris (gray amber). However, this work doesn't aim to delve into the different theories about how it is produced, which could likely be better explained with today's technology. The topic is available for any science enthusiast to explore; all recent authors who mention it just refer to facts that have been known for over a century.
A modern compiler, speaking of ambergris, says, "It smells like dried cow-dung." Never having smelled this latter substance, we cannot say whether the simile be correct; but we certainly consider that its perfume is most incredibly overrated; nor can we forget that Homberg found that "a vessel in which he had made a long digestion of the human fæces had acquired a very strong and perfect smell of ambergris, insomuch that any one would have thought that a great quantity of essence of ambergris had been made in it. The perfume (odor!) was so strong that the vessel was obliged to be moved out of the laboratory." (Mem. Acad. Paris, 1711.)
A modern compiler, talking about ambergris, says, "It smells like dried cow dung." Since we’ve never smelled this latter substance, we can’t say if the comparison is accurate; however, we definitely think that its scent is incredibly overrated. We also can’t forget that Homberg discovered that "a container in which he had digested human feces for a long time had taken on a very strong and perfect smell of ambergris, so much so that anyone would have thought a large amount of ambergris essence had been produced in it. The scent (odor!) was so strong that the container had to be moved out of the laboratory." (Mem. Acad. Paris, 1711.)
Nevertheless, as ambergris is extensively used as a perfume, in deference to those who admire its odor, we presume that it has to many an agreeable smell.
Nevertheless, since ambergris is widely used in perfumes, respecting those who enjoy its scent, we assume that it has a pleasant smell for many.
Like bodies of this kind undergoing a slow decomposition and possessing little volatility, it, when mixed with other very fleeting scents, gives permanence to them on the handkerchief, and for this quality the perfumer esteems it much.
Like these kinds of substances that are slowly breaking down and have low volatility, when combined with other very fleeting scents, it makes them last on the handkerchief, and the perfumer values it highly for this quality.
Ambergris Essence
Is only kept for mixing; when retailed it has to be sweetened up to the public nose; it is then called after the Parisian name
Is only used for mixing; when sold to customers, it has to be sweetened to appeal to the public; it’s then referred to by the Parisian name.
Excerpt from Amber.
Esprit de rose triple, | 1/2 pint. |
Extract of ambergris, | 1 " |
Essence of musk, | 1/4 " |
Extract of vanilla, | 2 ounces. |
This perfume has such a lasting odor, that a handkerchief being well perfumed with it, will still retain an odor even after it has been washed.
This perfume has such a strong scent that a handkerchief that's been heavily scented with it will still smell even after it's been washed.
Powdered ambergris is used in the manufacture of cassolettes—little ivory or bone boxes perforated—which are made to contain a paste of strong-smelling substances, to carry in the pocket or reticule; also in the making of peau d'Espagne, or Spanish skin, used for perfuming writing paper and envelopes, and which will be described hereafter.
Powdered ambergris is used to make cassolettes—small ivory or bone boxes with holes—which are designed to hold a paste made of strong-smelling substances, to carry in your pocket or handbag; it's also used to create peau d'Espagne, or Spanish skin, for perfuming writing paper and envelopes, which will be described later.

Civet.—This substance is secreted by the Viverra civetta, or civet cat. It is formed in a large double glandular receptacle between the anus and the pudendum of the creature. Like many other substances of Oriental origin, it was first brought to this country by the Dutch.
Civet cat.—This substance is produced by the Viverra civetta, or civet cat. It is created in a large double glandular pouch located between the anus and the genitals of the animal. Similar to many other products from the East, it was initially introduced to this country by the Dutch.
When the civet cats are kept in a state of confinement, which at one time was common in Amsterdam, they are placed in strong cages, so constructed as to prevent the animal from turning round and biting the person employed in collecting the secreted substance. This operation is said to be performed twice a week, and is done by scraping out the civet with a small spoon: about a drachm at a time is thus obtained. A good deal of the civet now brought to European markets is from Calicut, capital of the province of Malabar, and from Bassora on the Euphrates.
When civet cats are kept in confinement, which was once common in Amsterdam, they are placed in strong cages designed to prevent them from turning around and biting the person who collects the secreted substance. This process is reportedly done twice a week, using a small spoon to scrape out the civet: about a drachm at a time is obtained this way. A significant amount of the civet now sold in European markets comes from Calicut, the capital of the Malabar province, and from Bassora on the Euphrates.
In its pure state, civet has, to nearly all persons, a most disgusting odor; but when diluted to an infinitesimal portion, its perfume is agreeable. It is difficult to ascertain the reason why the same substance, modified only by the quantity of matter presented to the nose, should produce an opposite effect on the olfactory nerve; but such is the case with nearly all odorous bodies, especially with ottos, which, if smelled at, are far from nice, and in some cases, positively nasty—such as otto of neroli, otto of thyme, otto of patchouly; but if diluted with a thousand times its volume of oil, spirit, &c., then their fragrance is delightful.
In its pure form, civet has a really unpleasant smell to almost everyone; however, when it's diluted to a tiny amount, its scent becomes quite pleasant. It's hard to understand why the same substance, changed only by the amount that's presented to the nose, can produce such different reactions in our sense of smell; but this happens with almost all fragrant substances, especially with essential oils. When smelled directly, they can be far from appealing and sometimes even downright offensive—like neroli oil, thyme oil, or patchouli oil. Yet when diluted with a thousand times their volume of oil, alcohol, etc., their fragrance becomes delightful.
Otto of rose to many has a sickly odor, but when eliminated in the homeopathic quantities as it rises from a single rose-bloom, who is it that will not admit that "the rose is sweet?" The odor of civet is best imparted, not by actual contact, but by being placed in the neighborhood of absorbent materials. Thus, when spread upon leather, which, being covered with silk and placed in a writing-desk, perfumes the paper and envelopes delightfully, and so much so, that they retain the odor after passing through the post.
Otto of rose may have a sickly smell to many, but when it's released in homeopathic amounts, like from a single rose bloom, who wouldn't agree that "the rose is sweet?" The scent of civet is best transferred, not through direct contact, but by being near absorbent materials. For instance, when it's applied to leather, which is then covered with silk and placed in a writing desk, it wonderfully scents the paper and envelopes, to the extent that they keep the fragrance even after going through the mail.
Extract of Civet is prepared by rubbing in a mortar one ounce of civet with an ounce of orris-root powder, or any other similar material that will assist to break up or divide the civet; and then placing the whole into a gallon of rectified spirits; after macerating for a month, it is fit to strain off. It is principally used as a "fixing" ingredient, in mixing essences of delicate odor. The French perfumers use the extract of civet more than English manufacturers, who seem to prefer extract of musk. From a quarter of a pint to half a pint is the utmost that ought to be mixed with a gallon of any other perfume.
Civet Extract is made by grinding one ounce of civet with one ounce of orris-root powder or another similar substance that helps break up the civet. Then, the mixture is added to a gallon of rectified spirits. After soaking for a month, it can be strained. This extract is mainly used as a "fixing" ingredient in blending fragrances with delicate scents. French perfumers use civet extract more than English manufacturers, who seem to favor musk extract. No more than a quarter to half a pint should be mixed with a gallon of any other perfume.
Castor is a secretion of the Castor fiber, or beaver, very similar to civet. Though we have often heard of its being used in perfumery, we do not personally know that such is the case.
Castor is a substance produced by the Castor fiber, or beaver, and is quite similar to civet. While we’ve often heard it mentioned in relation to perfumes, we can’t say we’ve seen it used ourselves.
Musk.—This extraordinary substance, like civet, is an animal secretion; it is contained in excretory follicles about the navel of the male animal. In the perfumery trade these little bags are called "pods," and as imported it is called "pod musk." When the musk is separated from the skin or sack in which it is contained, it is then called "grain musk."
Musk.—This amazing substance, similar to civet, comes from an animal secretion; it’s found in the excretory follicles near the navel of the male animal. In the perfume industry, these small bags are referred to as "pods," and when imported, it’s known as "pod musk." Once the musk is removed from the skin or pouch that holds it, it’s then referred to as "grain musk."
The musk deer (Moschus moschatus) is an inhabitant of the great mountain range which belts the north of India, and branches out into Siberia, Thibet, and China. And it is also found in the Altaic range, near Lake Baikal, and in some other mountain ranges, but always on the borders of the line of perpetual snow. It is from the male animal only that the musk is produced.
The musk deer (Moschus moschatus) lives in the vast mountain range that stretches across northern India and extends into Siberia, Tibet, and China. It's also found in the Altaic range near Lake Baikal and in a few other mountain ranges, but always near the edge of the snow line. Only the male deer produces musk.

It formerly was held in high repute as a medicine, and is still so among Eastern nations. The musk from Boutan, Tonquin, and Thibet, is most esteemed, that from Bengal is inferior, and from Russia is of still lower quality. The strength and the quantity produced by a single animal varies with the season of the year and the age of the animal. A single musk pod usually contains from two to three drachms of grain musk. Musk is imported into England from China, in caddies of from 50 to 100 ounces each. When adulterated with the animal's blood, which is often the case, it forms into lumps or clots; it is sometimes also mixed with a dark, friable earth. Those pods in which little pieces of lead are discovered, as a general rule, yield the finest quality of musk; upon this rule, we presume that the best musk is the most worthy of adulteration. Musk is remarkable for the diffusiveness and subtlety of its scent; everything in its vicinity soon becomes affected by it, and long retains its odor, although not in actual contact with it.
It was once highly regarded as a medicine and still is among Eastern nations. Musk from Bhutan, Tonkin, and Tibet is the most valued, while that from Bengal is of lower quality, and musk from Russia is even less esteemed. The strength and quantity produced by a single animal depend on the season of the year and the age of the animal. Typically, a single musk pod contains about two to three drachms of musk grain. Musk is imported into England from China in caddies containing 50 to 100 ounces each. When it's mixed with the animal's blood, which often happens, it clumps together; it's also sometimes combined with a dark, crumbly earth. Generally, those pods that have small pieces of lead are believed to produce the highest quality of musk; based on this, we assume that the best musk is the one most prone to adulteration. Musk is known for its pervasive and delicate scent; everything nearby quickly absorbs it and retains the odor for a long time, even without direct contact.
It is a fashion of the present day for people to say "that they do not like musk;" but, nevertheless, from great experience in one of the largest manufacturing perfumatories in Europe, we are of opinion that the public taste for musk is as great as any perfumer desires. Those substances containing it always take the preference in ready sale—so long as the vendor takes care to assure his customer "that there is no musk in it."
It’s a trend nowadays for people to claim they don’t like musk; however, from extensive experience at one of the biggest perfume factories in Europe, we believe that the public's interest in musk is as strong as any perfumer would want. Products containing musk consistently sell better—provided the seller makes sure to tell the customer “that there's no musk in it.”

The perfumer uses musk principally in the scenting of soap, sachet powder, and in mixing for liquid perfumery. The just reputation of Paris's original Windsor soap is due, in the main, to its delightful odor. The soap is, doubtless, of the finest quality, but its perfume stamps it among the élite—its fragrance it owes to musk.
The perfumer primarily uses musk to scent soap, sachet powder, and when blending for liquid fragrances. The strong reputation of Paris's original Windsor soap mainly comes from its pleasant scent. The soap is undoubtedly of the highest quality, but its fragrance places it among the élite—the scent comes from musk.
The alkaline reaction of soap is favorable to the development of the odoriferous principle of musk. If, however, a strong solution of potass be poured on to grain musk, ammonia is developed instead of the true musk smell.
The alkaline reaction of soap helps enhance the fragrant properties of musk. However, if a strong solution of potassium is poured onto grain musk, it produces ammonia instead of the authentic musk scent.
Musk extract.
Grain musk, | 2 oz. |
Rectified spirit, | 1 gallon. |
After standing for one month, at a summer temperature, it is fit to draw off. Such an extract is that which is used for mixing in other perfumes. That extract of musk which is prepared for retail sale, is prepared thus:—
After standing for one month at a summer temperature, it’s ready to be drawn off. This extract is what’s used for mixing into other perfumes. The extract of musk that’s made for retail sale is prepared this way:—
Musk excerpt.
Extract of musk (as above), | 1 pint. |
" ambergris, | 1/2 " |
" rose triple, | 1/4 " |
Mix and filter it; it is then fit for bottling.
Mix and filter it; then it's ready for bottling.
This preparation is sweeter than pure extract of musk made according to our first formula, and is also more profitable to the vendor. It will be seen hereafter that the original extract of musk is principally used for a fixing ingredient in other perfumes, to give permanence to a volatile odor; customers requiring, in a general way, that which is incompatible, namely, that a perfume shall be strong to smell, i.e. very volatile, and that it shall remain upon the handkerchief for a long period, ergo, not volatile! Small portions of extract of musk, mixed with esprit de rose, violet, tuberose, and others, do, in a measure, attain this object; that is, after the violet, &c., has evaporated, the handkerchief still retains an odor, which, although not that of the original smell, yet gives satisfaction, because it is pleasant to the nasal organ.
This preparation is sweeter than pure musk extract made using our first formula and is also more profitable for the seller. It will be shown later that the original musk extract is mainly used as a fixative in other perfumes to help a fleeting scent last longer; customers often want something that seems contradictory, meaning they want a perfume that has a strong smell, i.e. very volatile, yet also stays on the handkerchief for a long time, ergo, not volatile! Small amounts of musk extract mixed with rose, violet, tuberose, and other scents somewhat achieve this goal; that is, after the violet, etc., has evaporated, the handkerchief still holds a scent that, while different from the original, is still pleasing to the nose.
SECTION V.
Ammonia.—Under the various titles of "Smelling Salts," "Preston Salts," "Inexhaustible Salts," "Eau de Luce," "Sal Volatile," ammonia, mixed with other odoriferous bodies, has been very extensively consumed as material for gratifying the olfactory nerve.
Ammonia.—Known by various names like "Smelling Salts," "Preston Salts," "Inexhaustible Salts," "Eau de Luce," and "Sal Volatile," ammonia, combined with other fragrant substances, has been widely used as a way to stimulate the sense of smell.
The perfumer uses liq. amm. fortis, that is, strong liquid ammonia, and the sesqui-carbonate of ammonia, for preparing the various "salts" that he sells. These materials he does not attempt to make; in fact, it is quite out of his province so to do, but he procures them ready for his hand through some manufacturing chemist. The best preparation for smelling-bottles is what is termed Inexhaustible Salts, which is prepared thus:—
The perfumer uses strong liquid ammonia and sesqui-carbonate of ammonia to create the different "salts" he sells. He doesn’t try to make these materials himself; in fact, it's well beyond his expertise to do so, but he gets them ready-made from a manufacturing chemist. The best preparation for smelling bottles is what's called Endless Salts, which is made like this:—
Liquid ammonia, | 1 pint. |
Otto of rosemary, | 1 drachm. |
" English lavender, | 1 " |
" bergamot, | 1/2 " |
" cloves, | 1/2 " |
Mix the whole together with agitation in a very strong and well-stoppered bottle.
Combine everything in a sturdy, tightly sealed bottle and shake it well.
This mixture is used by filling the smelling-bottles with any porous absorbent material, such as asbestos, or, what is better, sponge cuttings, that have been well beaten, washed, and dried. These cuttings can be procured at a nominal price from any of the sponge-dealers, being the trimming or roots of the Turkey sponge, which are cut off before the merchants send it into the retail market. After the bottles are filled with the sponge, it is thoroughly saturated with the scented ammonia, but no more is poured in than the sponge will retain, when the bottles are inverted; as, if by any chance the ammonia runs out and is spilt over certain colored fabrics, it causes a stain. When such an accident happens, the person who sold it is invariably blamed.
This mixture is made by filling the smelling bottles with any porous absorbent material, like asbestos, or preferably, well-beaten, washed, and dried sponge cuttings. You can get these cuttings at a low cost from any sponge dealer; they are the trimmings or roots of the Turkey sponge, which are cut off before the merchants sell it in the retail market. After filling the bottles with the sponge, it's soaked with scented ammonia, but only as much as the sponge can hold when the bottles are turned upside down. If the ammonia spills out and gets on certain colored fabrics, it leaves a stain. When such accidents happen, the seller is usually the one who gets blamed.
When the sponge is saturated properly, it will retain the ammoniacal odor longer than any other material; hence, we presume, bottles filled in this way are called "inexhaustible," which name, however, they do not sustain more than two or three months with any credit; the warm hand soon dissipates the ammonia under any circumstances, and they require to be refilled.
When the sponge is properly soaked, it will hold onto the ammonia smell longer than anything else; that's why we assume bottles filled this way are called "inexhaustible." However, they only maintain that quality for about two or three months at best. The warmth from a hand quickly disperses the ammonia in any situation, so they need to be refilled.
For transparent colored bottles, instead of sponge, the perfumers use what they call insoluble crystal salts (sulphate of potass). The bottles being filled with crystals, are covered either with the liquid ammonia, scented as above, or with alcoholic ammonia. The necks of the bottles are filled with a piece of white cotton; otherwise, when inverted, from the non-absorbent quality of the crystals, the ammonia runs out, and causes complaints to be made. The crystals are prettier in colored bottles than the sponge; but in plain bottles the sponge appears quite as handsome, and, as before observed, it holds the ammonia better than any other material. Perfumers sell also what is called White Smelling Salts, and Preston Salts. The White Smelling Salt is the sesqui-carbonate of ammonia in powder, with which is mixed any perfuming otto that is thought fit,—lavender otto giving, as a general rule, the most satisfaction.
For clear colored bottles, instead of using a sponge, perfumers use what they refer to as insoluble crystal salts (sulfate of potassium). The bottles, filled with crystals, are either covered with the previously mentioned scented liquid ammonia or alcoholic ammonia. The necks of the bottles are packed with a piece of white cotton; otherwise, when turned upside down, the ammonia leaks out due to the non-absorbent nature of the crystals, leading to complaints. The crystals look nicer in colored bottles than the sponge, but in plain bottles, the sponge looks just as attractive, and, as mentioned earlier, it retains the ammonia better than any other material. Perfumers also sell what's known as White Aromatic Salts and Preston Salts. The White Smelling Salt is powdered sesquicarbonate of ammonia, mixed with any preferred perfuming oil, with lavender oil typically providing the most satisfaction.
Preston Salts, which is the cheapest of all the ammoniacal compounds, is composed of some easily decomposable salt of ammonia and lime, such as equal parts of muriate of ammonia, or of sesqui-carbonate of ammonia, and of fresh-slaked lime. When the bottles are filled with this compound, rammed in very hard, a drop or two of some cheap otto is poured on the top prior to corking. For this purpose otto of French lavender, or otto of bergamot, answers very well. We need scarcely mention that the corks are dipped into melted sealing-wax, or brushed over with liquid wax, that is, red or black wax dissolved in alcohol, to which a small portion of ether is added. The only other compound of ammonia that is sold in the perfumery trade is Eau de Luce, though properly it belongs to the druggist. When correctly made—which is very rarely the case—it retains the remarkable odor of oil of amber, which renders it characteristic.
Preston Salts, the cheapest of all ammoniacal compounds, is made from easily decomposed salt of ammonia and lime, like equal parts of ammonium chloride or ammonium sesquicarbonate and fresh-slaked lime. When the bottles are filled with this compound and packed tightly, a drop or two of a cheap essential oil is added on top before corking. For this, French lavender oil or bergamot oil works well. It's worth noting that the corks are dipped in melted sealing wax or brushed with liquid wax, which is red or black wax dissolved in alcohol with a bit of ether added. The only other ammonia compound sold in the fragrance industry is Eau de Luce, though it technically belongs to the pharmacy sector. When properly made—which is quite rare—it has the distinct scent of amber oil, which makes it unique.
Eau de Light.
Tincture of benzoin: or, | } | |
" balsam of Peru, | } | 1 oz. |
Otto of lavender, | 10 drops. | |
Oil of amber, | 5 " | |
Liquor ammonia, | 2 oz. |
Acetic Acid and its Use in Perfumery.—The pungency of the odor of vinegar naturally brought it into the earliest use in the art of perfumery.
Acetic Acid and Its Role in Fragrance Design.—The strong smell of vinegar naturally led to its early use in the art of perfumery.
The acetic acid, evolved by distilling acetate of copper (verdigris), is the true "aromatic" vinegar of the old alchemists.
The acetic acid produced by distilling copper acetate (verdigris) is the real "aromatic" vinegar of the ancient alchemists.
The modern aromatic vinegar is the concentrated acetic acid aromatized with various ottos, camphor, &c., thus—
The modern aromatic vinegar is concentrated acetic acid flavored with various essences, camphor, etc., thus—
Flavored Vinegar.
Concentrated acetic acid, | 8 oz. |
Otto of English lavender, | 2 drachms. |
" " rosemary, | 1 drachm. |
" cloves, | 1 " |
" camphor, | 1 oz. |
First dissolve the bruised camphor in the acetic acid, then add the perfumes; after remaining together for a few days, with occasional agitation, it is to be strained, and is then ready for use.
First, dissolve the crushed camphor in the vinegar, then add the scents; after staying mixed for a few days, with occasional stirring, it should be strained and is then ready for use.
Several forms for the preparation of this substance have been published, almost all of which, however, appear to complicate and mystify a process that is all simplicity.
Several methods for preparing this substance have been published, but almost all of them seem to complicate and confuse a process that is actually very simple.
The most popular article of this kind is—
The most popular article like this is—
Henry's Vinegar.
Dried leaves of rosemary, rue, wormwood, sage, mint, and lavender flowers, each, | 1/2 oz. |
Bruised nutmeg, cloves, angelica root, and camphor, each, | 1/4 oz. |
Alcohol (rectified), | 4 oz. |
Concentrated acetic acid, | 16 oz. |
As this mixture must not go into the ordinary metallic tincture press, for the obvious reason of the chemical action that would ensue, it is best to drain as much of the liquor away as we can, by means of a common funnel, and then to save the residue from the interstices of the herbs, by tying them up in a linen cloth, and subjecting them to pressure by means of an ordinary lemon-squeezer, or similar device.
Since this mixture shouldn't go into the regular metal tincture press because of the obvious chemical reactions that could happen, it's best to drain as much of the liquid as possible using a regular funnel. After that, we should collect the leftover substance from the spaces between the herbs by tying them up in a linen cloth and applying pressure using a standard lemon squeezer or a similar tool.
Rose Vinegar.
Concentrated acetic acid, | 1 oz. |
Otto of roses, | 1/2 drachm. |
Well shaken together.
Well mixed together.
It is obvious that vinegars differently perfumed may be made in a similar manner to the above, by using other ottos in place of the otto of roses. All these concentrated vinegars are used in the same way as perfumed ammonia, that is, by pouring three or four drachms into an ornamental "smelling" bottle, previously filled with crystals of sulphate of potash, which forms the "sel de vinaigre" of the shops; or upon sponge into little silver boxes, called vinaigrettes, from their French origin. The use of these vinegars had their origin in the presumption of keeping those who carried them from the effects of infectious disease, doubtless springing out of the story of the "four thieves' vinegar," which is thus rendered in Lewis's Dispensatory:
It's clear that vinegars with different scents can be made in a similar way to the one mentioned above, by using other essential oils instead of rose oil. All these concentrated vinegars are used similarly to perfumed ammonia, meaning you pour three or four drachms into a decorative "smelling" bottle, previously filled with crystals of potassium sulfate, which makes the "sel de vinaigre" sold in stores; or on a sponge inside little silver boxes, called vinaigrettes, due to their French origin. The use of these vinegars originated from the belief that carrying them could protect against infectious diseases, likely stemming from the legend of the "four thieves' vinegar," which is described in Lewis's Dispensatory:
"It is said that during the plague at Marseilles, four persons, by the use of this preservative, attended, unhurt, multitudes of those that were affected; that under the color of these services, they robbed both the sick and the dead; and that being afterwards apprehended, one of them saved himself from the gallows by disclosing the composition of the prophylactic (a very likely story!!), which was as follows:—
"It’s said that during the plague in Marseilles, four people used this protective method and were unharmed while attending to many who were infected. Under the guise of helping, they actually stole from both the sick and the dead. Later, when they were caught, one of them escaped the gallows by revealing the formula for the preventive measure (sounds like a tall tale!!), which was as follows:—
Four Thieves' Vinegar.
Take fresh tops of common wormwood, Roman wormwood, rosemary, sage, mint, and rue, of each, | 3/4 oz. |
Lavender flowers, | 1 oz. |
Garlic, calamus aromaticus, cinnamon, cloves, and nutmeg, each, | 1 drachm. |
Camphor, | 1/2 oz. |
Alcohol or brandy, | 1 oz. |
Strong vinegar, | 4 pints. |
Digest all the materials, except the camphor and spirit, in a closely covered vessel for a fortnight, at a summer heat; then express and filter the vinaigre produced, and add the camphor previously dissolved in the brandy or spirit."
Digest all the materials, except the camphor and spirit, in a tightly sealed container for two weeks at a warm temperature; then strain and filter the resulting vinegar, and add the camphor that was previously dissolved in the brandy or spirit.
A very similar and quite as effective a preparation may be made by dissolving the odorous principle of the plants indicated in a mixture of alcohol and acetic acid. Such preparations, however, are more within the province of the druggist than perfumer. There are, however, several preparations of vinegar which are sold to some extent for mixing with the water for lavatory purposes and the bath, their vendors endeavoring to place them in competition with Eau de Cologne, but with little avail. Among them may be enumerated—
A very similar and equally effective preparation can be made by dissolving the fragrant compounds of the specified plants in a mix of alcohol and vinegar. However, these types of preparations are more in the realm of pharmacists than perfumers. There are a few vinegar preparations that are sold to some degree for mixing with water for cleaning and bathing purposes, with sellers trying to market them as alternatives to Eau de Cologne, but with little success. Among these are—
Hygienic or Preventive Vinegar.
Brandy, | 1 pint. |
Otto of cloves, | 1 drachm. |
" lavender, | 1 " |
" marjoram, | 1/2 drachm. |
Gum benzoin, | 1 oz. |
Macerate these together for a few hours, then add— | |
Brown vinegar, | 2 pints. |
and strain or filter, if requisite, to be bright.
and strain or filter, if needed, to make it clear.
Toilet Cleaner Vinegar (à la Violette).
Extract of cassie, | 1/2 pint. |
" orris, | 1/4 " |
Esprit de rose, triple, | 1/4 " |
White wine vinegar, | 2 pints. |
Toilet cleaner vinegar (à la Rose).
Dried rose-leaves, | 4 oz. |
Esprit de rose, triple, | 1/2 pint. |
White wine vinegar, | 2 pints. |
Macerate in a close vessel for a fortnight, then filter and bottle for sale.
Soak in a sealed container for two weeks, then strain and bottle for sale.
Cologne vinegar.
To eau de Cologne, | 1 pint, |
Add, strong acetic acid, | 1/2 oz. |
Filter if necessary.
Understood! Please provide the text you would like me to modernize.
Without unnecessarily repeating similar formulæ, it will be obvious to the reader that vinegar of any flower may be prepared in a similar way to those above noticed; thus, for vinaigre à la jasmine, or for vinaigre à la fleur d'orange, we have only to substitute the esprit de jasmine, or the esprit de fleur d'orange, in place of the Eau de Cologne, to produce orange-flower or jasmine vinegars; however, these latter articles are not in demand, and our only reason for explaining how such preparations may be made, is in order to suggest the methods of procedure to any one desirous of making them leading articles in their trade.
Without going over the same formulas again, it's clear to the reader that vinegar can be made from any flower in a similar way to the ones mentioned above. For jasmine vinegar or orange flower vinegar, we just need to replace the Eau de Cologne with jasmine extract or orange flower extract to create those flavors. However, these products aren't very popular, and the only reason we explain how to make them is to provide methods for anyone interested in turning them into key items for their business.
We perhaps may observe, en passant, that where economy in the production of any of the toilet vinegars is a matter of consideration, they have only to be diluted with rose-water down to the profitable strength required.
We might note, en passant, that if cost is a concern in producing any of the toilet vinegars, they just need to be diluted with rose water to reach the desired strength for profitability.
Any of the perfumed vinegars that are required to produce opalescence, when mixed with water, must contain some gum-resin, like the hygienic vinegar, as above. Either myrrh, benzoin, storax, or tolu, answer equally well.
Any of the scented vinegars needed to create opalescence when mixed with water must have some gum-resin, like the hygienic vinegar mentioned above. Myrrh, benzoin, storax, or tolu all work just as well.
SECTION VI.
BOUQUETS AND NOSEGAYS.
In the previous articles we have endeavored to explain the mode of preparing the primitive perfumes—the original odors of plants. It will have been observed, that while the majority can be obtained under the form of otto or essential oil, there are others which hitherto have not been isolated, but exist only in solution in alcohol, or in a fatty body. Of the latter are included all that are most prized, with the exception of otto of rose—that diamond among the odoriferous gems. Practically, we have no essential oils or ottos of Jasmine, Vanilla, Acacia, Tuberose, Cassie, Syringa, Violets, and others. What we know of these odors is derived from esprits, obtained from oils or fats, in which the several flowers have been repeatedly infused, and afterwards infusing such fats or oils in alcohol. Undoubtedly, these odors are the most generally pleasing, while those made from the essential oils (i.e. otto), dissolved in spirit, are of a secondary character. The simple odors, when isolated, are called Essential Oils or Ottos; when dissolved or existing in solution in alcohol, by the English they are termed Essences, and by the French Extraits or Esprits; a few exceptions prove this rule. Essential oil of orange-peel, and of lemon-peel, are frequently termed in the trade "Essence" of orange and "Essence" of lemons, instead of essential oil or otto of lemons, &c. The sooner the correct nomenclature is used in perfumery, as well as in the allied arts, the better, and the fewer blunders will be made in the dispensatory. It appears to the writer, that if the nomenclature of these substances were revised, it would be serviceable; and he would suggest that, as a significant, brief, and comprehensive term, Otto be used as a prefix to denote that such and such a body is the odoriferous principle of the plant. We should then have otto of lavender instead of essential oil of lavender, &c. &c. In this work it will be seen that the writer has generally used the word otto in place of "essential oil," in accordance with his views. Where there exists a solution of an essential oil in a fat oil, the necessity of some such significant distinction is rendered obvious, for commercially such articles are still called "oils"—oil of jasmine, oil of roses, &c. It cannot be expected that the public will use the words "fat" oil and "essential" oil, to distinguish these differences of composition.
In the previous articles, we tried to explain how to prepare the basic perfumes—the original scents from plants. You may have noticed that while most can be obtained in the form of otto or essential oil, there are others that haven’t been isolated yet and only exist as a solution in alcohol or a fatty substance. This includes all the most sought-after scents, except for rose otto—that diamond among fragrant treasures. Practically, we don’t have essential oils or ottos for Jasmine, Vanilla, Acacia, Tuberose, Cassie, Syringa, Violets, and others. What we know about these scents comes from extracts obtained from oils or fats, where the various flowers have been repeatedly infused, and then those fats or oils are infused in alcohol. Undoubtedly, these scents are generally more enjoyable, while those made from essential oils (i.e., otto), dissolved in alcohol, are of a secondary nature. The pure scents, when isolated, are referred to as Essential oils or Otto's; when dissolved or existing in a solution in alcohol, the English call them Essences, and the French call them Excerpts or Spirits; a few exceptions prove this rule. Essential oil from orange peel and from lemon peel are often referred to in trade as "Essence" of orange and "Essence" of lemons, instead of essential oil or otto of lemons, etc. The sooner the correct terminology is used in perfumery, as well as in related arts, the better, and the fewer mistakes will be made in the dispensary. It seems to me that if the terminology of these substances were revised, it would be useful; and I would suggest that a clear, brief, and comprehensive term, Otto, be used as a prefix to indicate that a certain substance is the fragrant principle of the plant. We should then have otto of lavender instead of essential oil of lavender, etc. In this work, you will see that I have generally used the term otto instead of "essential oil," in line with my views. Where there is a solution of an essential oil in a fatty oil, the need for such a significant distinction is clear, as commercially these items are still called "oils"—oil of jasmine, oil of roses, etc. We can’t expect the public to use the terms "fat" oil and "essential" oil to distinguish these compositional differences.
There are several good reasons why the odoriferous principle of plants should not be denominated oils. In the first place, it is a bad principle to give any class of substances the same signification as those belonging to another. Surely, there are enough distinguishing qualities in their composition, their physical character, and chemical reaction, to warrant the application of a significant name to that large class of substances known as the aroma of plants!
There are several good reasons why the fragrant compounds in plants shouldn't be called oils. First and foremost, it's not a good idea to use the same term for different categories of substances. Clearly, there are enough distinguishing qualities in their composition, physical characteristics, and chemical reactions to justify giving a distinct name to the broad group of substances known as plant aromas!
When the chemical nomenclature was last revised, the organic bodies were little dealt with. We know that we owe this universal "oil" to the old alchemist, much in the same way as "spirit" has been used, but a little consideration quickly indicates the folly of its continued use. We can no longer call otto of rosemary, or otto of nutmegs, essential oil of rosemary or nutmegs, with any more propriety than we can term sulphuric acid "oil" of vitriol. All the chemical works speak of the odoriferous bodies as "essential" or "volatile" oils, and of the greasy bodies as "fat" or "unctuous" oils. Oils, properly so called, unite with salifiable bases and form soap; whereas the essential or volatile oils, i.e. what we would please to call the ottos, do no such thing. On the contrary, they unite with acids in the majority of instances.
When the chemical naming system was last updated, organic substances received little attention. We know that we owe this universal "oil" to the old alchemists, much like "spirit" has been used, but a bit of thought quickly shows how silly it is to keep using that term. We can no longer rightly refer to otto of rosemary or otto of nutmeg as the essential oil of rosemary or nutmeg, just as incorrectly as we can call sulfuric acid "oil" of vitriol. All chemical literature refers to fragrant substances as "essential" or "volatile" oils, and to greasy substances as "fat" or "unctuous" oils. Oils, in the proper sense, combine with basic substances to create soap; while essential or volatile oils, i.e., what we prefer to call the ottos, do not do that. On the contrary, in most cases, they combine with acids.
The word oil must hereafter be confined to those bodies to which its literal meaning refers—fat, unctuous, inodorous (when pure), greasy substances—and can no longer be applied to those odoriferous materials which possess qualities diametrically opposite to oil. We have grappled with "spirit," and fixed its meaning in a chemical sense; we have no longer "spirit" of salt, or "spirit" of hartshorn. Let us no longer have almond oil "essential," almond oil "unctuous," and the like.
The term oil should now be limited to those substances that it literally describes—fatty, smooth, odorless (when pure), greasy materials—and cannot be used for those fragrant substances that have qualities completely opposite to oil. We have worked on defining "spirit" in a chemical context; we no longer use "spirit" of salt or "spirit" of hartshorn. Let's stop referring to almond oil as "essential," "unctuous," and similar terms.
It remains only for us to complete the branch of perfumery which relates to odors for the handkerchief, by giving the formulæ for preparing the most favorite "bouquets" and "nosegays." These, as before stated, are but mixtures of the simple ottos in spirit, which, properly blended, produce an agreeable and characteristic odor,—an effect upon the smelling nerve similar to that which music or the mixture of harmonious sounds produces upon the nerve of hearing, that of pleasure.
It’s time for us to finish the section on fragrances for handkerchiefs by providing the recipes for creating the most popular "bouquets" and "nosegays." As mentioned before, these are just combinations of simple essential oils in alcohol, which, when blended properly, create a pleasant and distinctive scent—similarly affecting the sense of smell as music or harmonious sounds affect hearing, bringing a sense of enjoyment.
The Alhambra Fragrance.
Extract of tubereuse, | 1 pint. |
" geranium, | 1/2 " |
" acacia, | 1/4 " |
" fleur d'orange, | 1/4 " |
" civet, | 1/4 " |
The Bosphorus Flower Bouquet.
Extract of acacia, | 1 pint. | |
" jasmine, | } | |
" rose triple, | }of each, | 1/2 " |
" fleur d'orange, | } | |
" tubereuse, | } | |
" civet, | 1/4 " | |
Otto of almonds, | 10 drops. |
Bouquet of Love.
Esprit de rose, | } | ||
" jasmine, | }from pomade, of each, | 1 pint. | |
" violette, | } | ||
" cassie, | } | ||
Extract of musk, | } of each, | 1/2 " | |
" ambergris, | } |
Mix and filter.
Mix and filter.
Flower Bouquet from the Andorra Valley.
Extrait de jasmine, | } | |
" rose, | } from pomade, of each, | 1 pint. |
" violette, | } | |
" tuberose, | } | |
Extract of orris, | 1 " | |
Otto of geranium, | 1/4 oz. |
Buckingham Palace Flower Arrangement.
Extrait de fleur d'orange, | } | ||
" cassie, | } from pomade, of each, | 1 pint. | |
" jasmine, | } | ||
" rose, | } | ||
Extract of orris, | } of each, | 1/2 " | |
" ambergris, | } | ||
Otto of neroli, | 1/2 drachm. | ||
" lavender, | 1/2 " | ||
" rose, | 1 " |
Bouquet de Caroline; also known as Bouquet des Delices.
Extrait de rose, | } | ||
" violette, | } from pomade, of each, | 1 pint. | |
" tuberose,} | } | ||
Extract of orris, | } of each, | 1/2 " | |
" ambergris, | } | ||
Otto of bergamot, | } | ||
" Limette, | } of each, | 1/4 oz. | |
" cedret, | } |
The Court Bouquet.
Extrait de rose, | } | ||
" violette, | } of each, | 1 pint. | |
" jasmine, | } | ||
Esprit de rose triple, | 1 " | ||
Extract of musk, | } of each, | 1 oz. | |
" ambergris, | } | ||
Otto of lemon, | } of each, | 1/2 oz. | |
" bergamot, | } | ||
" neroli, | 1 drachm. |
Eau de Chypre.
This is an old-fashioned French perfume, presumed to be derived from the Cyperus esculentus by some, and by others to be so named after the Island of Cyprus; the article sold, however, is made thus—
This is an old-school French perfume, thought by some to come from the Cyperus esculentus and by others to be named after the Island of Cyprus; the product sold, however, is made this way—
Extract of musk, | 1 pint. | |
" ambergris, | } | |
" vanilla, | } of each, | 1/2 " |
" tonquin bean, | } | |
" orris, | } | |
Esprit de rose triple, | 2 pints. |
The mixture thus formed is one of the most lasting odors that can be made.
The mixture created is one of the most long-lasting scents you can make.
Empress Eugenie's Flower Bouquet.
Extract of musk, | } | ||
" vanilla, | } of each, | 1/4 pint. | |
" tonquin, | } | ||
" neroli, | } | ||
" geranium, | } | ||
" rose triple, | } of each, | 1/2 " | |
" santal, | } |
Esterhazy Cake.
Extrait de fleur d'orange (from pomade), | 1 pint. | |
Esprit de rose triple, | 1 " | |
Extract of vitivert, | } | |
" vanilla, | } of each, | 2 " |
" orris, | } | |
" tonquin, | } | |
Esprit de neroli, | 1 " | |
Extract of ambergris, | 1/2 " | |
Otto of santal, | 1/2 drachm. | |
" cloves, | 1/2 " |
Ess Bouquet.
The reputation of this perfume has given rise to numerous imitations of the original article, more particularly on the continent. In many of the shops in Germany and in France will be seen bottles labelled in close imitation of those sent out by Bayley and Co., Cockspur Street, London, who are, in truth, the original makers.
The reputation of this perfume has led to many fake versions of the original product, especially on the continent. In many shops in Germany and France, you can find bottles labeled to closely resemble those produced by Bayley and Co., Cockspur Street, London, who are, in fact, the original creators.
Esprit de rose triple, | 1 pint. |
Extract of ambergris, | 2 oz. |
" orris, | 8 " |
Otto of lemons, | 1/4 " |
" bergamot, | 1 " |
The name "Ess" bouquet, which appears to puzzle some folk, is but a mere contraction of "essence" of bouquet.
The name "Ess" bouquet, which seems to confuse some people, is simply a shortened form of "essence" of bouquet.
Cologne. (La première qualité.)
Spirit (from grape), 60 over proof, | 6 gallons. |
Otto of neroli, Petale, | 3 oz. |
" " Bigarade, | 1 " |
" rosemary, | 2 " |
" orange-peel, | 5 " |
" citron-peel, | 5 " |
" bergamot-peel, | 2 " |
Mix with agitation; then allow it to stand for a few days perfectly quiet, before bottling.
Mix vigorously; then let it sit undisturbed for a few days before bottling.
Cologne. (La deuxième qualité.)
Spirit (from corn), | 6 gallons. | |
Otto of neroli,Petit-grain, | 2 oz. | |
" " Petale, | 1/2 " | |
" rosemary, | 2 " | |
" orange-peel, | } | |
" lemon, | } of each, | 4 " |
" bergamot, | } |
Although Eau de Cologne was originally introduced to the public as a sort of "cure-all," a regular "elixir of life," it now takes its place, not as a pharmaceutical product, but among perfumery. Of its remedial qualities we can say nothing, such matter being irrelevant to the purpose of this book. Considered, however, as a perfume, with the public taste it ranks very high; and although it is exceedingly volatile and evanescent, yet it has that excellent quality which is called "refreshing." Whether this be due to the rosemary or to the spirit, we cannot say, but think something may be attributed to both. One important thing relating to Eau de Cologne must not, however, pass unnoticed, and that is, the quality of the spirit used in its manufacture. The utter impossibility of making brandy with English spirit in any way to resemble the real Cognac, is well known. It is equally impossible to make Eau de Cologne with English spirit, to resemble the original article. To speak of the "purity" of French spirit, or of the "impurity" of English spirit, is equally absurd. The fact is, that spirit derived from grapes, and spirit obtained from corn, have each so distinct and characteristic an aroma, that the one cannot be mistaken for the other. The odor of grape spirit is said to be due to the œanthic ether which it contains. The English spirit, on the other hand, owes its odor to fusel oil. So powerful is the œanthic ether in the French spirit, that notwithstanding the addition to it of such intensely odoriferous substances as the ottos of neroli, rosemary, and others, it still gives a characteristic perfume to the products made containing it, and hence the difficulty of preparing Eau de Cologne with any spirit destitute of this substance.
Although Eau de Cologne was originally marketed as a sort of "cure-all," a regular "elixir of life," it now holds its place not as a pharmaceutical product but as part of perfumery. We can't comment on its medicinal qualities since that isn't relevant to this book. However, when considered as a fragrance, it ranks very high with the public taste; and even though it's extremely volatile and fleeting, it possesses that excellent quality known as "refreshing." Whether this quality comes from the rosemary or the spirit, we can't say for sure, but we believe both play a role. One important thing about Eau de Cologne should not be overlooked, which is the quality of the spirit used in its creation. It's well known that it's impossible to make brandy from English spirit that resembles real Cognac. Similarly, it’s equally impossible to create Eau de Cologne from English spirit that resembles the original. Talking about the "purity" of French spirit or the "impurity" of English spirit is equally foolish. The truth is that spirit derived from grapes and spirit obtained from corn each have such distinct and characteristic aromas that they cannot be mistaken for one another. The scent of grape spirit is believed to be caused by the œanthic ether it contains. In contrast, the odor of English spirit comes from fusel oil. The œanthic ether in French spirit is so potent that, even with the addition of strongly aromatic substances such as the ottos of neroli, rosemary, and others, it still gives a distinctive perfume to the products made with it, which is why it’s challenging to create Eau de Cologne with any spirit lacking this substance.
Although very fine Eau de Cologne is often made by merely mixing the ingredients as indicated in the recipe as above, yet it is better, first, to mix all the citrine ottos with spirit, and then to distil the mixture, afterwards adding to the distillate the rosemary and nerolies, such process being the one adopted by the most popular house at Cologne.
Although high-quality Eau de Cologne is often produced by simply mixing the ingredients as outlined in the recipe above, it's better to first mix all the citrus essential oils with alcohol and then distill the mixture. Afterward, add the rosemary and neroli to the distillate. This method is used by the most renowned house in Cologne.
A great many forms for the manufacture of Eau de Cologne have been published, the authors of some of the recipes evidently having no knowledge, in a practical sense, of what they were putting by theory on paper; other venturers, to show their lore, have searched out all the aromatics of Lindley's Botany, and would persuade us to use absinthe, hyssop, anise, juniper, marjoram, caraway, fennel, cumin, cardamom, cinnamon, nutmeg, serpolet, angelica, cloves, lavender, camphor, balm, peppermint, galanga, lemon thyme, &c. &c. &c.
A lot of recipes for making Eau de Cologne have been published, with some authors clearly lacking practical knowledge of what they were theorizing on paper; other explorers, eager to showcase their expertise, have dug up all the aromatics from Lindley's Botany and tried to convince us to use absinthe, hyssop, anise, juniper, marjoram, caraway, fennel, cumin, cardamom, cinnamon, nutmeg, serpolet, angelica, cloves, lavender, camphor, balm, peppermint, galanga, lemon thyme, etc., etc., etc.
All these, however, are but hum—! Where it is a mere matter of profit, and the formula that we have given is too expensive to produce the article required, it is better to dilute the said Cologne with a weak spirit, or with rose-water, rather than otherwise alter its form; because, although weak, the true aroma of the original article is retained.
All of this, however, is just noise—! When it comes down to making a profit, and the formula we've provided is too costly to produce the required product, it's better to mix the Cologne with a weak alcohol or rose water, rather than change its form in other ways; because even though it's diluted, the genuine scent of the original product is still kept.
The recipe of the second quality of Eau de Cologne is given, to show that a very decent article can be produced with English spirit.
The recipe for the second quality of Eau de Cologne is provided to demonstrate that a very good product can be made with English spirit.
Erin's Flowers.
Extract of white rose (see White Rose), | 1 pint. |
" vanilla, | 1 oz. |
Royal Hunt Flower Arrangement.
Esprit de rose triple, | 1 pint. | ||
" neroli, | } | ||
" acacia, | } | ||
" fleur d'orange, | } | of each | 1/4 " |
" musk, | } | ||
" orris, | } | ||
" tonquin, | 1/2 " | ||
Otto of citron | 2 drachms. |
Bouquet of Flora; also known as Extract of Flowers.
Esprit de rose, | } | |
" tubereuse, | } from pomade, of each, | 1 pint. |
" violette, | } | |
Extract of benzoin, | 1-1/2 oz. | |
Otto of bergamot, | 2 " | |
" lemon, | } | |
" orange, | } of each, | 1/2 " |
The Guards' Bouquet.
Esprit de rose, | 2 pints. |
" neroli, | 1/2 pint. |
Extract of vanilla, | 2 oz. |
" orris, | 2 " |
" musk, | 1/4 pint. |
Otto of cloves, | 1/2 drachm. |
Italian Flower Bouquet.
Esprit de rose, from pomade, | 2 pints. | |
" rose triple, | 1 pint. | |
" jasmine, | } | |
" violette, | } from pomade, each, | 1 " |
Extract of cassie, | 1/2 " | |
" musk, | } | |
" ambergris, | } of each, | 2 oz. |
Jockey Club Flower Bouquet. (English formula.)
Extract of orris root, | 2 pints. | |
Esprit de rose, triple, | 1 pint. | |
" rose de pomade, | 1 " | |
Extrait de cassie, | } | |
" tubereuse, | } de pomade, of each | 1/2 " |
" ambergris, | } | 1/2 " |
Otto of bergamot, | 1/2 oz. |
Jockey Club Flower Arrangement. (French formula.)
Esprit de rose, de pomade, | 1 pint. |
" tubereuse, | 1 " |
" cassie, | 1/2 " |
" jasmine, | 1/4 " |
Extract of civet, | 3 oz. |
Independently of the materials employed being different to the original English recipe, it must be remembered that all the French perfumes are made of brandy, i.e. grape spirit; whereas the English perfumes are made with corn spirit, which alone modifies their odor. Though good for some mixtures, yet for others the grape spirit is very objectionable, on account of the predominance of its own aroma.
Regardless of the materials used being different from the original English recipe, it should be remembered that all French perfumes are made from brandy, i.e. grape spirit; while English perfumes are made with corn spirit, which alone changes their scent. Although it's good for some mixtures, grape spirit can be very undesirable for others because of its strong aroma.
We have spoken of the difference in the odor between the English and French spirit; the marked distinction of British and Parisian perfumes made according to the same recipes is entirely due to the different spirits employed. Owing to the strong "bouquet," as the French say, of their spirit in comparison with ours, the continental perfumers claim a superiority in the quality of their perfumes. Now, although we candidly admit that some odors are better when prepared with grape spirit than with that from corn spirit, yet there are others which are undoubtedly the best when prepared with spirit derived from the latter source. Musk, ambergris, civet, violet, tubereuse, and jasmine, if we require to retain their true aroma when in solution in alcohol, must be made with the British spirit.
We’ve talked about the difference in scent between English and French spirits; the clear distinction between British and Parisian perfumes made from the same recipes is entirely because of the different spirits used. Due to the strong “bouquet,” as the French say, of their spirit compared to ours, continental perfumers claim their perfumes are superior. While we honestly admit that some scents are better when made with grape spirit instead of corn spirit, there are others that are definitely best when made with the latter. Musk, ambergris, civet, violet, tuberose, and jasmine, if we want to keep their true aroma when dissolved in alcohol, must be made with British spirit.
All the citrine odors, verveine, vulnerary waters, Eau de Cologne, Eau de Portugal, Eau d'Arquebuzade, and lavender, can alone be brought to perfection by using the French spirit in their manufacture. If extract of jasmine, or extract of violet, &c., be made with the French or brandy spirit, the true characteristic odor of the flower is lost to the olfactory nerve—so completely does the œanthic ether of the grape spirit hide the flowery aroma of the otto of violet in solution with it. This solves the paradox that English extract of violet and its compounds, "spring flowers," &c., is at all times in demand on the Continent, although the very flowers with which we make it are grown there.
All the citrus scents, verbena, healing waters, Eau de Cologne, Eau de Portugal, Eau d'Arquebuzade, and lavender can only be perfected by using French spirits in their production. If jasmine or violet extracts, etc., are made with French or brandy spirits, the true distinctive scent of the flower is lost to the sense of smell—so completely does the fragrant ether of the grape spirit mask the floral aroma of violet oil mixed with it. This explains the puzzling fact that English violet extract and its various "spring flower" compounds are always in demand on the Continent, even though the very flowers we use to make them are grown there.
On the contrary, if an English perfumer attempts to make Eau de Portugal, &c., to bear any comparison as a fine odor to that made by Lubin, of Paris, without using grape spirit, his attempts will prove a failure. True, he makes Eau de Portugal even with English corn spirit, but judges of the article—and they alone can stamp its merit—discover instantly the same difference as the connoisseur finds out between "Patent British" and foreign brandy.
On the other hand, if an English perfumer tries to create Eau de Portugal, etc., that can compare as a fine scent to the one made by Lubin in Paris, without using grape spirit, their efforts will fail. It's true that he makes Eau de Portugal even with English corn spirit, but those who judge the product—and they alone can determine its quality—immediately notice the same difference that a connoisseur finds between "Patent British" and foreign brandy.
Perhaps it may not be out of place here to observe that what is sold in this country as British brandy is in truth grape spirit, that is, foreign brandy very largely diluted with English spirit! By this scheme, a real semblance to the foreign brandy flavor is maintained; the difference in duty upon English and foreign spirit enables the makers of the "capsuled" article to undersell those who vend the unsophisticated Cognac.
Perhaps it’s worth noting that what is sold in this country as British brandy is actually grape spirit, which is mostly foreign brandy that’s been heavily diluted with English spirit! This way, they keep a close resemblance to the flavor of genuine foreign brandy; the difference in tax between English and foreign spirits allows the producers of the "capsuled" product to sell it for less than those who sell the real Cognac.
Some chemists, not being very deep in the "tricks of trade," have thought that some flavoring, or that œanthic ether, was used to impart to British spirit the Cognac aroma. An article is even in the market called "Essence of Cognac," but which is nothing more than very badly made butyric ether.
Some chemists, not being very knowledgeable about the "tricks of the trade," have believed that some flavoring or that œanthic ether was used to give British spirits the Cognac smell. There's even a product available called "Essence of Cognac," which is really just poorly made butyric ether.
On the Continent a great deal of spirit is procured by the fermentation of the molasses from beet-root; this, of course, finds its way into the market, and is often mixed with the grape spirit; so, also, in England we have spirit from potatoes, which is mixed in the corn spirit. These adulterations, if we may so term it, modify the relative odors of the primitive alcohols.
On the Continent, a lot of alcohol is made by fermenting molasses from sugar beets; this, of course, ends up in the market and is often blended with grape alcohol. Similarly, in England, we have alcohol made from potatoes, which is mixed with the corn alcohol. These mixtures, if we can call them that, change the original scents of the base alcohols.
A Japanese fragrance.
Extract of rose triple, | } | |
" vitivert, | } | |
" patchouly, | } of each, | 1/2 pint. |
" cedar, | } | |
" santal, | } | |
" vervaine, | 1/4 " |
Kew Garden Bouquet.
Esprit de neroli (Petale), | 1 pint. | |
" cassie, | } | |
" tubereuse, | } from pomade, of each, | 1/2 " |
" jasmine, | } | |
" geranium, | 1/2 " | |
" musk, | } of each, | 3 oz. |
" ambergris, | } |
Thousand Flowers Water
Esprit de rose triple, | 1 pint. | ||
" rose de pomade, | } | ||
" tubereuse, | } | ||
" vjasmine, | } from pomade, of each, | 1/2 " | |
" fleur d'orange, | } | ||
" cassie, | } | ||
" violette, | } | ||
Extract of cedar, | 1/4 " | ||
Extract of vanilla, | } | ||
" ambergris, | } of each, | 2 oz. | |
" musk, | } | ||
Otto of almonds, | } | ||
" neroli, | } of each, | 10 drops. | |
" cloves, | } | ||
" bergamot, | 1 oz. |
Millefleurs and Lavender
Essence of lavender (Mitcham), | 1/2 pint. |
Eau des millefleurs, | 1 " |
Decroix's Milleflower Lavender.
Spirits from grape, | 1 pint. |
French otto of lavender, | 1 oz. |
Extract of ambergris, | 2 oz. |
The original "lavender aux millefleurs" is that of Delcroix; its peculiar odor is due to the French otto of lavender, which, although some folks like it, is very inferior to the English otto of lavender; hence the formula first given is far superior to that by the inventor, and has almost superseded the original preparations.
The original "lavender aux millefleurs" comes from Delcroix; its unique scent comes from the French lavender oil, which, while some people enjoy it, is much weaker than the English lavender oil. Therefore, the formula initially provided is much better than the one created by the inventor and has nearly replaced the original preparations.
There are several other compounds or bouquets of which lavender is the leading ingredient, and from which they take their name, such as lavender and ambergris, lavender and musk, lavender and maréchale, &c., all of which are composed of fine spirituous essences of lavender, with about 15 per cent. of any of the other ingredients.
There are several other combinations or blends where lavender is the main ingredient, and they are named after it, like lavender and ambergris, lavender and musk, lavender and maréchale, etc., all of which consist of high-quality lavender essences with about 15 percent of any of the other ingredients.
Bouquet of the Marshals.
Esprit de rose triple, | } of each, | 1 pint. | |
Extrait de fleur d'orange, | } | ||
" vitivert, | } | ||
" vanilla, | } | ||
" orris, | } of each, | 1/2 " | |
" tonquin, | } | ||
Esprit de neroli, | } | ||
Extract of musk, | } of each, | 1/4 pint. | |
" ambergris, | } | ||
Otto of cloves, | } of each, | 1/2 drachm. | |
" santal, | } |
Mousselaine fragrance.
Bouquet maréchale, | 1 pint. | |
Extrait de cassie, | } | |
" jasmine, | } from pomade, of each, | 1/2 " |
" tubereuse, | } | |
" rose, | } | |
Otto of santal, | 2 drachms. |
Montpellier Bouquet.
Extrait de tubereuse, | 1 pint. | |
" rose de pomade, | 1 " | |
" rose triple, | 1 " | |
Extract of musk, | } of each, | 1/4 " |
" ambergris, | } | |
Otto of cloves, | 1-1/2 drachm. | |
" bergarmot, | 1/2 oz. |
Fashion Whim.
Extrait de jasmine, | } | |
" tubereuse, | } of each, | 1/2 pint. |
" cassie, | } | |
" fleur d'orange, | } | |
Otto of almonds, | 10 drops. | |
" nutmegs, | 10 " | |
Extract of civet, | 1/4 pint. |
May Flowers.
Extract of rose (de pomade), | } | |
" jasmine, | } of each, | 1/2 pint. |
" fleur d'orange, | } | |
" cassie, | } | |
" vanilla, | 1 " | |
Otto of almonds, | 1/4 drachm. |
Neptune, or Navy Bouquet.
Extrait de rose, triple, | } | |
" santal, | } of each, | 1/2 pint. |
" vitivert, | } | |
" patchouly, | } | |
" verbena, | 1/8 " |
Bouquet of all Nations.
Countries wherein the Odors are produced.
Countries where the odors are produced.
Turkey, | Esprit de rose triple, | 1/2 pint. |
Africa, | Extract of jasmine, | 1/2 " |
England, | " lavender, | 1/4 " |
France, | " tubereuse, | 1/2 " |
South America, | " vanilla, | 1/4 " |
Timor, | " santal, | 1/4 " |
Italy, | " violet, | 1 " |
Hindoostan, | " patchouly, | 1/4 " |
Ceylon, | Otto of citronella, | 1 drachm. |
Sardinia, | " lemons, | 1/4 oz. |
Tonquin, | Extract of musk, | 1/4 pint. |
Isle of Wight Flower Bouquet.
Extract of orris, | 1/2 pint. |
" vitivert, | 1/4 " |
" santal, | 1 " |
" rose, | 1/2 " |
King's Bouquet.
Extract of jasmine, | } | ||
" violet, | } from pomade, of each, | 1 pint. | |
" rose | } | ||
" vanilla, | } of each, | 1/4 pint. | |
" vitivert, | } | ||
" musk, | } of each, | 1 oz. | |
" ambergris, | } | ||
Otto of bergamot, | 1 oz. | ||
" cloves, | 1 drachm. |
Queen's Bouquet.
Esprit de rose, | } from pomade, of each, | 1 pint. |
Extrait de violette, | } | |
" tubereuse, | 1/2 " | |
" fleur d'orange, | 1/4 " | |
Otto of bergamot, | 1/4 oz. |
Rondeletia.
The perfume bearing the above name is undoubtedly one of the most gratifying to the smelling nerve that has ever been made. Its inventors, Messrs. Hannay and Dietrichsen, have probably taken the name of this odor from the Rondeletia, the Chyn-len of the Chinese; or from the R. odorata of the West Indies, which has a sweet odor. We have before observed that there is a similarity of effect upon the olfactory nerve produced by certain odors, although derived from totally different sources: that, for instance, otto of almonds may be mixed with extract of violet in such proportion that, although the odor is increased, yet the character peculiar to the violet is not destroyed. Again: there are certain odors which, on being mixed in due proportion, produce a new aroma, perfectly distinct and peculiar to itself. This effect is exemplified by comparison with the influence of certain colors when mixed, upon the nerve of vision: such, for instance, as when yellow and blue are mixed, the result we call green; or when blue and red are united, the compound color is known as puce or violet.
The perfume mentioned above is definitely one of the most delightful scents ever created. Its creators, Messrs. Hannay and Dietrichsen, likely drew the name of this fragrance from the Rondeletia, known as the Chyn-len in China, or from the R. odorata of the West Indies, which has a sweet fragrance. We've previously noted that certain scents can have similar effects on the sense of smell, even if they come from completely different sources: for example, otto of almonds can be blended with violet extract in such a way that while the scent is intensified, the unique quality of the violet isn't lost. Moreover, there are certain fragrances that, when combined in the right ratios, create a completely new and distinct aroma. This is similar to how certain colors mix to affect our sense of sight: like when yellow and blue are combined, resulting in green; or when blue and red are mixed, producing the color puce or violet.
Now when the odor of lavender and odor of cloves are mixed, they produce a new fragrance, i.e. Rondeletia! It is such combinations that constitute in reality "a new perfume," which, though often advertised, is very rarely attained. Jasmine and patchouly produce a novel aroma, and many others in like manner; proportion and relative strength, when so mixed, must of course be studied, and the substances used accordingly. If the same quantity of any given otto be dissolved in a like proportion of spirit, and the solution be mixed in equal proportions, the strongest odor is instantly indicated by covering or hiding the presence of the other. In this way we discover that patchouly, lavender, neroli, and verbena are the most potent of the vegetable odors, and that violet, tubereuse, and jasmine are the most delicate.
Now, when the scent of lavender and the scent of cloves are combined, they create a new fragrance, namely Rondeletia! It's these combinations that truly make "a new perfume," which, although frequently promoted, is rarely achieved. Jasmine and patchouli also produce a unique aroma, as do many others in similar ways; the ratio and strength of the ingredients need to be carefully considered and mixed accordingly. If the same amount of any essential oil is dissolved in an equal amount of alcohol, and the solution is mixed in equal parts, the strongest scent will quickly mask the presence of the others. This method helps us determine that patchouli, lavender, neroli, and verbena are the strongest of the plant scents, while violet, tuberose, and jasmine are the most subtle.
Many persons will at first consider that we are asking too much, when we express a desire to have the same deference paid to the olfactory nerve, as to the other nerves that influence our physical pleasures and pains. By tutoring the olfactory nerve, it is capable of perceiving matter in the atmosphere of the most subtle nature: not only that which is pleasant, but also such as are unhealthful. If an unpleasant odor is a warning to seek a purer atmosphere, surely it is worth while to cultivate that power which enables us to act up to that warning for the general benefit of health.
Many people will initially think that we're asking for too much when we express a desire for the same respect given to our sense of smell as to the other senses that affect our physical pleasures and pains. By training our sense of smell, it can detect substances in the air that are incredibly subtle: not just those that are pleasant, but also those that are harmful. If an unpleasant smell serves as a signal to find cleaner air, then it’s definitely worthwhile to develop this ability, as it helps us act on that signal for the overall benefit of our health.
To return, however, to Rondeletia: it will be seen by the annexed formulæ, that, besides the main ingredients to which it owes its peculiar character—that is, cloves and lavender—it contains musk, vanilla, &c. These substances are used in these as in nearly all other bouquets for the sole purpose of fixing the more volatile odors to the handkerchief.
To get back to Rondeletia: as you can see from the attached formulas, in addition to the main ingredients that give it its unique character—cloves and lavender—it also includes musk, vanilla, etc. These substances are used in this and in nearly all other bouquets solely to help hold the more delicate scents on the handkerchief.
Essence of Rondeletia.
Spirit (brandy 60 o.p.), | 1 gallon. | |
Otto of lavender, | 2 oz. | |
" cloves, | 1 oz. | |
" roses, | 3 drachms. | |
" bergamot, | 1 oz. | |
Extract of musk, | } | |
" vanilla, | } each, | 1/4 pint. |
" ambergris, | } |
The mixture must be made at least a month before it is fit for sale. Very excellent Rondeletia may also be made with English spirit.
The mixture has to be prepared at least a month before it can be sold. You can also make very good Rondeletia using English spirit.
Royal Bouquet.
Extract of rose (from pomade), | 1 pint. | ||
Esprit de rose, triple, | 1/2 " | ||
Extract of jasmine, | } from pomade, each, | 1/2 " | |
" violet, | } | ||
" verbena, | } each, | 2-1/2 oz. | |
" cassie, | } | ||
Otto of lemons, | } each, | 1/4 oz. | |
" bergamot, | } | ||
Extract of musk, | } each, | 1 oz. | |
" ambergris, | } |
Smooth.
Extract of tubereuse, | } | |
" jasmine, | } from pomade, each, | 1 pint. |
" cassie, | } | |
" rose, | } | |
" vanilla, | 5 oz. | |
" musk, | } each, | 2 oz. |
" ambergris, | } | |
Otto of bergamot, | 1/4 oz. | |
" cloves, | 1 drachm. |
Spring Blooms.
Extract of rose, | } from pomade, each, | 1 pint. |
" violet, | } | |
" rose, triple, | 2-1/2 oz. | |
" cassie, | 2-1/2 oz. | |
Otto of bergamot, | 2 drachms. | |
Extract of ambergris, | 1 oz. |
The just reputation of this perfume places it in the first rank of the very best mixtures that have ever been made by any manufacturing perfumer. Its odor is truly flowery, but peculiar to itself. Being unlike any other aroma it cannot well be imitated, chiefly because there is nothing that we are acquainted with that at all resembles the odor of the esprit de rose, as derived from macerating rose pomade in spirit, to which, and to the extract of violet, nicely counterpoised, so that neither odor predominates, the peculiar character of "Spring Flowers" is due; the little ambergris that is present gives permanence to the odor upon the handkerchief, although from the very nature of the ingredients it may be said to be a fleeting odor. "Spring Flowers" is an Englishman's invention, but there is scarcely a perfumer in Europe that does not attempt an imitation.
The great reputation of this perfume puts it among the best blends ever created by any perfumer. Its scent is truly floral but unique to itself. Since it doesn’t resemble any other fragrance, it’s hard to replicate, mainly because there’s nothing we know of that even comes close to the scent of the esprit de rose, which comes from soaking rose pomade in alcohol. The combination of this and the violet extract, perfectly balanced so that neither scent overpowers the other, gives "Spring Flowers" its distinctive character. The small amount of ambergris included helps the scent last on a handkerchief, although it’s inherently a fleeting fragrance due to the nature of the ingredients. "Spring Flowers" is an English invention, yet nearly every perfumer in Europe tries to copy it.
Tulip Bouquet.
Nearly all the tulip tribe, although beautiful to the eye, are inodorous. The variety called the Duc Van Thol, however, yields an exquisite perfume, but it is not used by the manufacturer for the purpose of extracting its odor. He, however, borrows its poetical name, and makes an excellent imitation thus:—
Extract of tubereuse, | } from pomade each, | 1 pint. |
" violet, | } | |
" rose, | 1/2 " | |
" orris, | 3 oz. | |
Otto of almonds, | 3 drops. |
Wood Violet.
Under the head Violet, we have already explained the method of preparing the extract or essence of that modest flower. The Parisian perfumers sell a mixture of violet, which is very beautiful, under the title of the Violet des Bois, or the Wood Violet, which is made thus:—
Under the section on Violet, we've already explained how to prepare the extract or essence of that humble flower. Parisian perfumers sell a lovely blend of violet called the Violet des Bois, or the Wood Violet, which is made like this:—
Extract of violet, | 1 pint. |
" orris, | 3 oz. |
" cassie, | 3 oz. |
" rose (from pomade) | 3 oz. |
Otto of almonds, | 3 drops. |
This mixture, in a general way, gives more satisfaction to the customer than the pure violet.
This blend generally provides more satisfaction to the customer than the pure violet.
Windsor Castle Flower Arrangement.
Alcohol, | 1 pint. | ||
Otto of neroli, | } | ||
" rose, | } each, | 1/4 oz. | |
" lavender, | } | ||
" bergamot, | } | ||
" cloves, | 8 drops. | ||
Extract of orris, | 1 pint. | ||
" jasmine, | } each, | 1/4 " | |
" cassie, | } | ||
" musk, | } each, | 2-1/2 oz. | |
" ambergris, | } |
Yacht Club Bouquet.
Extract of santal, | 1 pint. | |
" neroli, | 1 " | |
" jasmine, | } each, | 1/2 " |
" rose triple, | } | |
" vanilla, | 1/4 " | |
Flowers of benzoin, | 1/4 oz. |
We have now completed the branch of the Art of Perfumery which relates to handkerchief perfumes, or wet perfumery. Although we have rather too much encroached upon the space of this work in giving the composition of so many bouquets, yet there are many left unnoticed which are popular. Those that are given are noted more particularly for the peculiar character of their odor, and are selected from more than a thousand recipes that have been practically tried.
We have now finished the section on the Art of Perfumery that focuses on handkerchief scents, or wet perfumery. Although we've spent quite a bit of space in this work discussing the composition of so many fragrance blends, there are still many popular ones we've left out. The ones we've included are highlighted particularly for their unique scents and are chosen from over a thousand recipes that have actually been tested.
Those readers who require to know anything about the simple extracts of flowers are referred to them under their respective alphabetical titles.
Readers who want to learn about the basic extracts of flowers can find them listed under their alphabetical titles.
SECTION VII.
The previous articles have exclusively treated of Wet Perfumes; the present matter relates, to Dry Perfumes,—sachet powders, tablets, pastilles, fumigation by the aid of heat of volatile odorous resins, &c. &c. The perfumes used by the ancients were, undoubtedly, nothing more than the odoriferous gums which naturally exude from various trees and shrubs indigenous to the Eastern hemisphere: that they were very extensively used and much valued, we have only to read the Scriptures for proofs:—"Who is this that cometh ... perfumed with myrrh and frankincense, with all the powders of the merchant?" (Song of Solomon, 3:6.) Abstaining from the use of perfume in Eastern countries is considered as a sign of humiliation:—"The Lord will take away the tablets, and it shall come to pass that instead of a sweet smell there shall be a stink." (Exod. 35:22; Isaiah 3:20, 24.) The word tablets in this passage means perfume boxes, curiously inlaid, made of metal, wood, and ivory. Some of these boxes may have been made in the shape of buildings, which would explain the word palaces, in Psalm 14:8:—"All thy garments smell of myrrh, and aloes, and cassia, out of the ivory palaces, whereby they have made thee glad." From what is said in Matt. 2:11, it would appear that perfumes were considered among the most valuable gifts which man could bestow;—"And when they (the wise men) had opened their treasures, they presented unto him (Christ) gifts; gold, and frankincense, and myrrh." As far as we are able to learn, all the perfumes used by the Egyptians and Persians during the early period of the world were dry perfumes, consisting of spikenard (Nardostachys jatamansi), myrrh, olibanum, and other gum-resins, nearly all of which are still in use by the manufacturers of odors. Among the curiosities shown at Alnwick Castle is a vase that was taken from an Egyptian catacomb. It is full of a mixture of gum-resin, &c., which evolve a pleasant odor to the present day, although probably 3000 years old. We have no doubt that the original use of this vase and its contents were for perfuming apartments, in the same way that pot pourri is now used.
The previous articles have focused solely on Wet Perfumes; the current topic is about Dry Perfumes—sachet powders, tablets, pastilles, fumigation using heated volatile fragrant resins, etc. The perfumes used by ancient peoples were likely just the fragrant gums that naturally come from various trees and shrubs found in the Eastern hemisphere. They were widely used and highly valued, as evidenced by references in the Scriptures: “Who is this coming ... perfumed with myrrh and frankincense, with all the powders of the merchant?” (Song of Solomon, 3:6.) Not using perfume in Eastern cultures is seen as a sign of dishonor: “The Lord will take away the tablets, and it shall come to pass that instead of a sweet smell there shall be a stink.” (Exod. 35:22; Isaiah 3:20, 24.) The term tablets in this context refers to decorative perfume boxes made from metal, wood, and ivory. Some of these boxes might have been designed in the shape of buildings, which could clarify the word palaces in Psalm 14:8: “All your garments smell of myrrh, aloes, and cassia, out of the ivory palaces, from which they have made you glad.” According to Matthew 2:11, it seems that perfumes were regarded as among the most valuable gifts one could offer: “And when they (the wise men) had opened their treasures, they presented to him (Christ) gifts; gold, frankincense, and myrrh.” From what we can gather, all the perfumes used by the Egyptians and Persians in the early world were dry perfumes, made from spikenard (Nardostachys jatamansi), myrrh, olibanum, and other gum-resins, most of which are still used by fragrance manufacturers today. Among the curiosities displayed at Alnwick Castle is a vase that was taken from an Egyptian catacomb. It is filled with a mixture of gum-resin, etc., which still has a pleasant aroma today, despite being around 3000 years old. We have no doubt that this vase and its contents were originally used to scent rooms, similar to how potpourri is used now.
Powdered Sachets.
The French and English perfumers concoct a great variety of these substances, which being put into silk bags, or ornamental envelopes, find a ready sale, being both good to smell and economical as a means of imparting an agreeable odor to linen and clothes as they lie in drawers. The following formula shows their composition. Every material is either to be ground in a mill, or powdered in a mortar, and afterwards sifted.
The French and English perfumers create a wide range of these substances, which are placed in silk bags or decorative envelopes and sell easily because they smell good and are an affordable way to add a pleasant scent to linens and clothes stored in drawers. The following formula shows how they are made. Each ingredient should either be ground in a mill or pulverized in a mortar and then sifted.
Cypress Sachet.
Ground rose-wood, | 1 lb. |
" cedar-wood, | 1 lb. |
" santal-wood, | 1 lb. |
Otto of rhodium, or otto of rose, | 3 drachms. |
Frangipane sachet.
Orris-root powder, | 3 lbs. | |
Vitivert powder, | 1/4 lb. | |
Santal-wood powder, | 1/4 lb. | |
Otto of neroli, | } | |
" rose, | } of each, | 1 drachm. |
" santal, | } | |
Musk-pods, ground, | 1 oz. |
The name of this sachet has been handed down to us as being derived from a Roman of the noble family of Frangipani. Mutio Frangipani was an alchemist, evidently of some repute, as we have another article called rosolis, or ros-solis, sun-dew, an aromatic spirituous liquor, used as a stomachic, of which he is said to be the inventor, composed of wine, in which is steeped coriander, fennel, anise, and musk.
The name of this sachet comes from a Roman noble family called Frangipani. Mutio Frangipani was an alchemist, clearly well-known, as we also have another product called rosolis, or ros-solis, sun-dew, an aromatic alcoholic drink used for digestion, which he is said to have invented, made from wine steeped with coriander, fennel, anise, and musk.
Heliotrope Scented Pouch.
Powdered orris, | 2 lbs. |
Rose leaves, ground, | 1 lb. |
Tonquin beans, ground, | 1/2 lb. |
Vanilla beans, | 1/4 lb. |
Grain musk, | 1/4 oz. |
Otto of almonds, | 5 drops. |
Well mixed by sifting in a coarse sieve, it is fit for sale.
Well mixed by sifting in a coarse sieve, it is ready for sale.
It is one of the best sachets made, and is so perfectly au naturel in its odor to the flower from which it derives its name, that no person unacquainted with its composition would, for an instant, believe it to be any other than the "real thing."
It’s one of the best sachets ever made, and it has such a natural scent, just like the flower it’s named after, that anyone who doesn't know what it's made of would instantly think it's the genuine article.
Lavender Sachet.
Lavender flowers, ground, | 1 lb. |
Gum benzoin, in powder, | 1/4 lb. |
Otto of lavender, | 1/4 oz. |
Sachet at the Marshals.
Powder of santal-wood, | 1/2 lb. |
" orris-root, | 1/2 lb. |
Rose-leaves, ground, | 1/4 lb. |
Cloves, ground, | 1/4 lb. |
Cassia-bark, | 1/4 lb. |
Grain musk, | 1/2 drachm. |
Sachet à la Mousselaine.
Vitivert, in powder, | 1 lb. | |
Santal-wood, | } | |
Orris, | } each, | 1/2 lb. |
Black-currant leaves (casse), | 1/2 lb. | |
Benzoin, in powder, | 1/4 lb. | |
Otto of thyme, | 5 drops. | |
" roses, | 1/2 drachm. |
Millefleur sachet.
Lavender-flowers, ground, | } | ||
Orris, | } each, | 1 lb. | |
Rose-leaves, | } | ||
Benzoin, | } | ||
Tonquin, | } | ||
Vanilla, | } each, | 1/4 lb. | |
Santal, | } | ||
Musk and civet, | 2 drachms. | ||
Cloves, ground, | 1/4 lb. | ||
Cinnamon, | } each, | 2 oz. | |
Allspice, | } |
Portugal sachet.
Dried orange-peel, | 1 lb. |
" lemon-peel, | 1/2 lb. |
" orris-root, | 1/2 lb. |
Otto of orange-peel, | 1 oz. |
" neroli, | 1/4 drachm. |
" lemon-grass, | 1/4 " |
Patchouli Sachet.
Patchouly herb, ground, | 1 lb. |
Otto of patchouly, | 1/4 drachm. |
Patchouly herb is often sold in its natural state, as imported, tied up in bundles of half a pound each.
Patchouly herb is usually sold in its natural form, imported, and bundled in half-pound packets.
Potpourri.
This is a mixture of dried flowers and spices not ground.
This is a mix of dried flowers and spices not ground.
Dried lavender, | 1 lb. | |
Whole rose-leaves, | 1 lb. | |
Crushed orris (coarse), | 1/2 lb. | |
Broken cloves, | } | |
" cinnamon, | } each, | 2 oz. |
" allspice, | } | |
Table salt, | 1 lb. |
We need scarcely observe that the salt is only used to increase the bulk and weight of the product, in order to sell it cheap.
We hardly need to mention that the salt is just used to add volume and weight to the product so it can be sold at a lower price.
Olla podrida.
This is a similar preparation to pot pourri. No regular form can be given for it, as it is generally made, or "knocked up," with the refuse and spent materials derived from other processes in the manufacture of perfumery; such as the spent vanilla after the manufacture of tincture or extract of vanilla, or of the grain musk from the extract of musk, orris from the tincture, tonquin beans, after tincturation, &c. &c., mixed up with rose-leaves, lavender, or any odoriferous herbs.
This preparation is similar to potpourri. There’s no standard recipe for it, as it’s typically made or “thrown together” with leftover and used materials from other perfume-making processes, like the leftover vanilla after making vanilla tincture or extract, the seed musk from the musk extract, or orris from the tincture, tonka beans after tincture, and so on, mixed with rose petals, lavender, or any fragrant herbs.
Rose Sachet.
Rose heels or leaves, | 1 lb. |
Santal-wood, ground, | 1/2 lb. |
Otto of roses, | 1/4 oz. |
Sandalwood Sachet.
This is a good and economical sachet, and simply consists of the ground wood. Santal-wood is to be purchased from some of the wholesale drysalters; the drug-grinders are the people to reduce it to powder for you—any attempt to do so at home will be found unavailable, on account of its toughness.
This is a practical and affordable sachet that just contains the ground wood. You can buy sandalwood from some wholesale drysalters; the drug grinders can turn it into powder for you—trying to do it at home will be ineffective because of its toughness.
Packet (without a name).
Dried thyme, | } | |
" lemon thyme, | } of each, | 1/4 lb. |
" mint, | } | |
" marjoram, | } | |
" lavender, | 1/2 lb. | |
" rose heels, | 1 lb. | |
Ground cloves, | 2 oz. | |
Allspice, | 2 oz. | |
Musk in grain, | 1 drachm. |
Vervain Sachet.
Lemon-peel, dried and ground, | 1 lb. |
" thyme, | 1/4 lb. |
Otto of lemon-grass, | 1 drachm. |
" " peel, | 1/2 oz. |
" bergamot, | 1 oz. |
Vitivert packet.
The fibrous roots of the Anthoxanthum muricatum being ground, constitute the sachet, bearing the name as above, derived from the Tamool name, vittie vayer, and by the Parisian vetiver. Its odor resembles myrrh. Vitivert is more often sold tied up in bunches, as imported from India, than ground, and is used for the prevention of moth, rather than as a perfume.
The fibrous roots of the Anthoxanthum muricatum are ground to create the sachet, which gets its name from the Tamool term vittie vayer, and by the Parisian term vetiver. Its scent is similar to myrrh. Vetiver is usually sold in tied bunches, imported from India, rather than being ground, and is primarily used to prevent moths instead of as a fragrance.
Violet Sachet.
Black-currant leaves (casse), | 1 lb. |
Rose heels or leaves, | 1 lb. |
Orris-root powder, | 2 lbs. |
Otto of almonds, | 1/4 drachm. |
Grain musk, | 1 " |
Gum benzoin, in powder, | 1/2 lb. |
Well mix the ingredients by sifting; keep them together for a week in a glass or porcelain jar before offering for sale.
Well mix the ingredients by sifting; keep them together for a week in a glass or porcelain jar before selling.
There are many other sachets manufactured besides those already given, but for actual trade purposes there is no advantage in keeping a greater variety than those named. There are, however, many other substances used in a similar way; the most popular is the
There are many other sachets made besides the ones already mentioned, but for actual trade purposes, there’s no benefit in having a wider variety than the ones listed. However, there are many other substances used in a similar way; the most popular is the
Spanish leather.
Peau d'Espagne, or Spanish skin, is nothing more than highly perfumed leather. Good sound pieces of wash leather are to be steeped in a mixture of ottos, in which are dissolved some odoriferous gum-resins, thus:—Otto of neroli, otto of rose, santal, of each half an ounce; otto of lavender, verbena, bergamot, of each a quarter of an ounce; otto of cloves and cinnamon, of each two drachms; with any others thought fit. In this mixture dissolve about two ounces of gum benzoin; now place the skin to steep in it for a day or so, then hang it over a line to dry. A paste is now to be made by rubbing in a mortar one drachm of civet with one drachm of grain musk, and enough solution of gum acacia or gum tragacantha to give it a spreading consistence; a little of any of the ottos that may be left from the steep stirred in with the civet, &c., greatly assists in making the whole of an equal body; the skin being cut up into pieces of about four inches square are then to be spread over, plaster fashion, with the last-named compost; two pieces being put together, having the civet plaster inside them, are then to be placed between sheets of paper, weighed or pressed, and left to dry thus for a week; finally, each double skin, now called peau d'Espagne, is to be enveloped in some pretty silk or satin, and finished off to the taste of the vender.
Peau d'Espagne, or Spanish skin, is simply highly scented leather. Good quality wash leather should be soaked in a mix of essential oils combined with some fragrant gum-resins, like this: Otto of neroli, otto of rose, and sandalwood, each half an ounce; otto of lavender, verbena, and bergamot, each a quarter of an ounce; otto of cloves and cinnamon, each two drams; along with any others that are suitable. In this mixture, dissolve about two ounces of gum benzoin; then place the leather in it to soak for a day or so, and hang it to dry. Next, make a paste by grinding one dram of civet with one dram of grain musk in a mortar, adding enough solution of gum acacia or gum tragacanth to achieve a spreadable consistency; mixing in a bit of any leftover essential oils from the soaking will help create a uniform blend. The leather, cut into pieces about four inches square, should then be coated like a plaster with this paste; two pieces are then placed together with the civet paste inside them, pressed between sheets of paper, and left to dry this way for a week. Finally, each double piece of leather, now called peau d'Espagne, is wrapped in nice silk or satin and finished to the seller's preference.
Skin or leather thus prepared evolves a pleasant odor for years, and hence they are frequently called "the inexhaustible sachet." Being flat, they are much used for perfuming writing-paper.
Skin or leather prepared this way develops a pleasant scent for years, which is why they are often referred to as "the endless sachet." Their flat shape makes them popular for scenting writing paper.
The lasting odor of Russia leather is familiar to all and pleasing to many; its perfume is due to the aromatic saunders-wood with which it is tanned, and to the empyreumatic oil of the bark of the birch tree, with which it is curried. The odor of Russia leather is, however, not recherché enough to be considered as a perfume; but, nevertheless, leather can be impregnated by steeping in the various ottos with any sweet scent, and which it retains to a remarkable degree, especially with otto of santal or lemon-grass (Verbena). In this manner the odor of the peau d'Espagne can be greatly varied, and gives great satisfaction, on account of the permanence of its perfume.
The lasting smell of Russia leather is familiar to everyone and enjoyed by many; its scent comes from the aromatic sandalwood used in tanning and the oily essence from birch tree bark used in curing. However, the scent of Russia leather isn't sophisticated enough to be considered a perfume; nonetheless, leather can be infused by soaking it in various oils with any sweet fragrance, which it holds onto remarkably well, especially sandalwood or lemon-grass oil (Verbena). This way, the scent of peau d'Espagne can be greatly varied, providing significant satisfaction due to the lasting quality of its fragrance.
Scented stationery.
If a piece of peau d'Espagne be placed in contact with paper, the latter absorbs sufficient odor to be considered as "perfumed;" it is obvious that paper for writing upon must not be touched with any of the odorous tinctures or ottos, on account of such matters interfering with the fluidity of the ink and action of the pen; therefore, by the process of infection, as it were, alone can writing paper be perfumed to advantage.
If a piece of peau d'Espagne comes into contact with paper, the paper absorbs enough scent to be considered "perfumed." It's clear that writing paper shouldn't be touched with any of the scented oils or extracts, since they would disrupt the flow of the ink and the pen's performance. So, the only way to effectively scent writing paper is through this process of infection, so to speak.
Besides the sachets mentioned there are many other substances applied as dry perfumes, such as scented wadding, used for quilting into all sorts of articles adapted for use in a lady's boudoir. Pincushions, jewel cases, and the like are lined with it. Cotton, so perfumed, is simply steeped in some strong essence of musk, &c.
Besides the sachets mentioned, there are many other substances used as dry perfumes, such as scented batting, which is quilted into various items made for a lady's bedroom. Pincushions, jewelry cases, and similar items are lined with it. Cotton, when perfumed, is simply soaked in a strong musk essence, etc.
Scented Bookmarks.
We have seen that leather can be impregnated with odoriferous substances, in the manufacture of peau d'Espagne; just so is card-board treated prior to being made up into book-marks. In finishing them for sale, taste alone dictates their design; some are ornamented with beads, others with embroidery.
We’ve seen that leather can be infused with fragrant substances during the production of peau d'Espagne; similarly, cardboard is treated before it's made into bookmarks. When finishing them for sale, design is dictated solely by taste; some are decorated with beads, while others have embroidery.
Casseroles and Spring Dishes.
Cassolettes and Printaniers are little ivory boxes, of various designs, perforated in order to allow the escape of the odors contained therein. The paste used for filling these "ivory palaces whereby we are made glad," is composed of equal parts of grain musk, ambergris, seeds of the vanilla-pod, otto of roses, and orris powder, with enough gum acacia, or gum tragacantha, to work the whole together into a paste. These things are now principally used for perfuming the pocket or reticule, much in the same way that ornamental silver and gold vinagrettes are used.
Cassolettes and Printaniers are small ivory boxes with different designs, featuring holes to let the scents inside escape. The mix used to fill these "ivory palaces that bring us joy" is made from equal parts of grain musk, ambergris, vanilla seeds, rose oil, and orris powder, combined with enough gum acacia or gum tragacanth to form a paste. Nowadays, these are mainly used to add fragrance to pockets or purses, much like decorative silver and gold vinaigrettes.
Pastilles.
There is no doubt whatever that the origin of the use of pastils, or pastilles, as they are more often called, from the French, has been derived from the use of incense at the altars of the temples during the religious services:—"According to the custom of the priest's office, his lot (Zacharias') was to burn incense when he went into the temple of the Lord." (Luke 1:9.) "And thou shalt make an altar to burn incense.... And Aaron shall burn thereon sweet incense every morning when he dresseth the lamps, and at even when he lighteth the lamps he shall burn incense upon it." (Exodus 30.)
There is no doubt that the use of pastils, or pastilles as they're more commonly known, comes from the practice of burning incense at temple altars during religious services: "According to the custom of the priest's office, his lot (Zacharias') was to burn incense when he went into the temple of the Lord." (Luke 1:9.) "And you shall make an altar to burn incense.... And Aaron shall burn sweet incense on it every morning when he prepares the lamps, and in the evening when he lights the lamps, he shall burn incense on it." (Exodus 30.)
An analogous practice is in use to the present day in the Roman Catholic churches, but, instead of being consumed upon an altar, the incense is burned in a censer, as doubtless many of our readers have seen. "As soon as the signal was given by the chief priest the incense was kindled, the holy place was filled with perfume, and the congregation without joined in prayers." (Carpenters Temple service of the Hebrews.)
An similar practice is still used today in Roman Catholic churches, but instead of being offered on an altar, the incense is burned in a censer, as many of our readers have likely seen. "As soon as the signal was given by the chief priest, the incense was lit, the holy place was filled with fragrance, and the congregation outside joined in prayers." (Carpenters Temple service of the Hebrews.)
The incense burner.
"On the walls of every temple in Egypt, from Meröe to Memphis, the censer is depicted smoking before the presiding deity of the place; on the walls of the tombs glow in bright colors the preparation of spices and perfumes." In the British Museum there is a vase (No. 2595) the body of which is intended to contain a lamp, the sides being perforated to admit the heat from the flame to act upon the projecting tubes; which are intended to contain ottos of flowers placed in the small vases at the end of the tubes; the heat volatilizes the ottos, and quickly perfumes an apartment. This vase or censer is from an Egyptian catacomb.
"On the walls of every temple in Egypt, from Meröe to Memphis, the censer is shown producing smoke in front of the main deity of the location; on the walls of the tombs, the preparation of spices and perfumes is depicted in bright colors." In the British Museum, there's a vase (No. 2595) designed to hold a lamp, with sides that have openings to allow the heat from the flame to work on the projecting tubes; these are meant to hold flower oils placed in the small vases at the ends of the tubes; the heat turns the oils into vapor, quickly filling a room with fragrance. This vase or censer comes from an Egyptian catacomb.

The Censer, as used in the "holy places," is made either of brass, German silver, or the precious metals; its form somewhat resembles a saucer and an inverted cup, which latter is perforated, to allow the escape of the perfume. In the outer saucer is placed an inner one of copper, which can be taken out and filled with ignited charcoal. When in use, the ignited carbon is placed in the censer, and is then covered with the incense; the heat rapidly volatilizes it in visible fumes. The effect is assisted by the incense-bearer swinging the censer, attached to three long chains, in the air. The manner of swinging the censer varies slightly in the churches in Rome, in France, and in England, some holding it above the head. At La Madeleine the method is always to give the censer a full swing at the greatest length of the chains with the right hand, and to catch it up short with the left hand.
The censer, used in the "holy places," is made of brass, German silver, or precious metals; its shape is similar to a saucer and an upside-down cup, which is perforated to let the perfume escape. Inside the outer saucer is a removable inner one made of copper that can be filled with burning charcoal. When it's in use, the burning carbon is placed in the censer and then topped with incense; the heat quickly turns it into visible smoke. The effect is enhanced by the incense-bearer swinging the censer, which is attached to three long chains, through the air. The way the censer is swung varies a bit among churches in Rome, France, and England, with some holding it above their heads. At La Madeleine, the method is always to give the censer a full swing at the fullest length of the chains with the right hand, then catch it with the left hand.
Several samples of "incense prepared for altar service," as sent out by Mr. Martin, of Liverpool, appear to be nothing more than gum olibanum, of indifferent quality, and not at all like the composition as especially commanded by God, the form for which is given in full in Exodus.
Several samples of "incense prepared for altar service," sent out by Mr. Martin from Liverpool, seem to be nothing more than low-quality gum olibanum, and they don't resemble the specific composition commanded by God, which is fully outlined in Exodus.
The pastils of the moderns are really but a very slight modification of the incense of the ancients. For many years they were called Osselets of Cyprus. In the old books on pharmacy a certain mixture of the then known gum-resins was called Suffitus, which being thrown upon hot ashes produced a vapor which was considered to be salutary in many diseases.
The pastilles of today are really just a very slight modification of the incense used in ancient times. For many years, they were called Osselets of Cyprus. In the old pharmacy books, a certain mixture of the known gum-resins was called Suffitus, which, when thrown on hot ashes, produced a vapor that was thought to be beneficial for many diseases.
It is under the same impression that pastils are now used, or at least to cover the mal odeur of the sick-chamber.
It is with the same idea in mind that pastilles are now used, or at least to mask the bad smell of the sickroom.
There is not much variety in the formula of the pastils that are now in use; we have first the
There is not much variety in the formula of the pastils that are now in use; we have first the
Indian or yellow pastilles.
Santal-wood, in powder, | 1 lb. | |
Gum benzoin, | 1-1/2 lb. | |
" Tolu, | 1/4 lb. | |
Otto of santal, | } | |
" cassia, | } each, | 3 drachms. |
" cloves, | } | |
Nitrate of potass, | 1-1/2 oz. | |
Mucilage of tragacantha, | q.s. to make the whole into a stiff paste. |
The benzoin, santal-wood, and Tolu, are to be powdered and mixed by sifting them, adding the ottos. The nitre being dissolved in the mucilage, is then added. After well beating in a mortar, the pastils are formed in shape with a pastil mould, and gradually dried.
The benzoin, sandalwood, and Tolu should be ground into a powder and mixed by sifting, then the essential oils are added. After dissolving the saltpeter in the mucilage, it’s added to the mixture. After thoroughly mixing in a mortar, the pastilles are shaped using a pastille mold and gradually dried.
The Chinese josticks are of a similar composition, but contain no Tolu. Josticks are burned as incense in the temples of the Buddahs in the Celestial Empire, and to such an extent as to greatly enhance the value of santal-wood.
The Chinese joss sticks are made from a similar mixture, but they don’t include Tolu. Joss sticks are burned as incense in the temples of the Buddhas in the Celestial Empire, which significantly increases the value of sandalwood.
Dr. Paris's Lozenges.
Benzoin, | } | |
Cascarilla, | } of each, | 1/4 lb. |
Myrrh, | 1-1/4 oz. | |
Charcoal, | 1-1/2 lb. | |
Otto of nutmegs, | } of each, | 3/4 oz. |
" cloves, | } | |
Nitre, | 2 oz. |
Mix as in the preceding.
Mix as in the above.
Scented Pastilles.
Well-burned charcoal, | 1 lb. | ||
Benzoin, | 3/4 lb. | ||
Tolu, | } | ||
Vanilla pods, | } of each, | 1/4 lb. | |
Cloves, | } | ||
Otto of santal, | } | ||
" neroli, | } of each, | 2 dr. | |
Nitre, | 1-1/2 oz. | ||
Mucilage tragacantha, | q.s. |
Piesse's Pastilles.
Willow charcoal, | 1/2 lb. | |
Benzoic acid, | 6 oz. | |
Otto of thyme, | } | |
" caraway, | } | |
" rose, | } of each, | 1/2 dr. |
" lavender, | } | |
" cloves, | } | |
" santal, | } |
Prior to mixing, dissolve 3/4 oz. nitre in half a pint of distilled or ordinary rose water; with this solution thoroughly wet the charcoal, and then allow it to dry in a warm place.
Before mixing, dissolve 3/4 oz. of nitre in half a pint of distilled or regular rose water; with this solution, thoroughly wet the charcoal, and then let it dry in a warm place.
When the thus nitrated charcoal is quite dry, pour over it the mixed ottos, and stir in the flowers of benzoin. When well mixed by sifting (the sieve is a better tool for mixing powders than the pestle and mortar), it is finally beaten up in a mortar, with enough mucilage to bind the whole together, and the less that is used the better.
When the nitrated charcoal is completely dry, pour the mixed essential oils over it and stir in the benzoin flowers. Once everything is well mixed by sifting (using a sieve is more effective for mixing powders than a mortar and pestle), it should be finally ground in a mortar with just enough mucilage to hold it all together, and the less you use, the better.
A great variety of formulæ have been published for the manufacture of pastils; nine-tenths of them contain some woods or bark, or aromatic seeds. Now, when such substances are burned, the chemist knows that if the ligneous fibre contained in them undergoes combustion—the slow combustion—materials are produced which have far from a pleasant odor; in fact, the smell of burning wood predominates over the volatilized aromatic ingredients; it is for this reason alone that charcoal is used in lieu of other substances. The use of charcoal in a pastil is merely for burning, producing, during its combustion, the heat required to quickly volatilize the perfuming material with which it is surrounded. The product of the combustion of charcoal is inodorous, and therefore does not in any way interfere with the fragrance of the pastil. Such is, however, not the case with any ingredients that may be used that are not in themselves perfectly volatile by the aid of a small increment of heat. If combustion takes place, which is always the case with all the aromatic woods that are introduced into pastils, we have, besides the volatilized otto which the wood contains, all the compounds naturally produced by the slow burning of ligneous matter, spoiling the true odor of the other ingredients volatilized.
A wide range of formulas has been published for making pastilles; most of them contain some type of wood, bark, or aromatic seeds. When these materials are burned, chemists understand that if the woody fiber in them undergoes slow combustion, it produces substances that do not smell good; in fact, the odor of burning wood dominates over the evaporated aromatic components. This is why charcoal is used instead of other materials. The role of charcoal in a pastille is just for burning, providing the heat needed to quickly vaporize the fragrance material surrounding it. The byproduct of burning charcoal is odorless, so it doesn't interfere with the pastille's fragrance. However, this is not true for any ingredients that are not perfectly volatile with a little added heat. If combustion occurs, as it does with all the aromatic woods used in pastilles, we end up with, in addition to the evaporated essence from the wood, all the compounds that naturally result from the slow burning of woody matter, which ruin the true smell of the other volatilized ingredients.
There are, it is true, certain kinds of fumigation adopted occasionally where these products are the materials sought. By such fumigation, as when brown paper is allowed to smoulder (undergo slow combustion) in a room for the purpose of covering bad smells. By the quick combustion of tobacco, that is, combustion with flame, there is no odor developed, but by its slow combustion, according to the method adopted by those who indulge in "the weed," the familiar aroma, "the cloud," is generated, and did not exist ready formed in the tobacco. Now a well-made pastil should not develope any odor of its own, but simply volatilize that fragrant matter, whatever it be, used in its manufacture. We think that the fourth formula given above carries out that object.
There are, it’s true, certain types of fumigation sometimes used when these products are the desired materials. This fumigation happens, for instance, when brown paper is allowed to smolder (burn slowly) in a room to mask unpleasant odors. With the quick burning of tobacco, which means burning with a flame, no smell is created, but its slow burning, as practiced by those who enjoy "the weed," produces the familiar aroma, "the cloud," which wasn’t already present in the tobacco. A well-made pastil shouldn’t produce any smell of its own but should just release whatever fragrant material was used to make it. We think the fourth formula mentioned above achieves that goal.
It does not follow that the formulæ that are here given produce at all times the odor that is most approved; it is evident that in pastils, as with other perfumes, a great deal depends upon taste. Many persons very much object to the aroma of benzoin, while they greatly admire the fumes of cascarilla.
The Fragrance Lamp.
Shortly after the discovery of the peculiar property of spongy platinum remaining incandescent in the vapor of alcohol, the late Mr. I. Deck, of Cambridge, made a very ingenious application of it for the purpose of perfuming apartments. An ordinary spirit lamp is filled with Eau de Cologne, and "trimmed" with a wick in the usual manner. Over the centre of the wick, and standing about the eighth of an inch above it, a small ball of spongy platinum is placed, maintained in its position by being fixed to a thin glass rod, which is inserted into the wick.
Shortly after discovering that spongy platinum stays glowing in alcohol vapor, the late Mr. I. Deck from Cambridge came up with a clever way to use it for scenting rooms. An ordinary spirit lamp is filled with Eau de Cologne and has a wick set up in the usual way. A small ball of spongy platinum is placed just above the center of the wick, held in place by being attached to a thin glass rod that goes into the wick.

Thus arranged, the lamp is to be lighted and allowed to burn until the platinum becomes red hot; the flame may then be blown out, nevertheless the platinum remains incandescent for an indefinite period. The proximity of a red-hot ball to a material of the physical quality of Eau de Cologne, diffused over a surface of cotton wick, as a matter of course causes its rapid evaporation, and as a consequence the diffusion of odor.
Thus set up, the lamp is to be lit and left burning until the platinum gets red hot; the flame can then be blown out, yet the platinum stays glowing for an indefinite period. Being close to a red-hot ball causes a material like Eau de Cologne, spread over cotton wick, to evaporate quickly, which in turn releases its scent.
Instead of the lamp being charged with Eau de Cologne, we may use Eau de Portugal, vervaine, or any other spirituous essence. Several perfumers make a particular mixture for this purpose, which is called
Instead of the lamp being filled with Eau de Cologne, we can use Eau de Portugal, vervain, or any other fragrant essence. Several perfumers create a specific blend for this purpose, which is called
Burning Water.
Eau de Cologne, | 1 pint. | |
Tincture of benzoin, | 2 oz. | |
" vanilla, | 1 oz. | |
Otto of thyme, | } | |
" mint, | } of each, | 1/2 drachm. |
" nutmeg, | } |
Another form, called
Another type, known as
Burning Water.
Rectified spirit, | 1 pint. | |
Benzoic acid, | 1/2 oz. | |
Otto of thyme, | } of each, | 1 drachm. |
" caraway, | } | |
" bergamot, | 2 oz. |
Persons who are in the habit of using the perfume lamps will, however frequently observe that, whatever difference there may be in the composition of the fluid introduced into the lamp, there is a degree of similarity in the odor of the result when the platinum is in action. This arises from the fact, that so long as there is the vapor of alcohol, mixed with oxygen-air, passing over red-hot platinum, certain definite products always result, namely, acetic acid, aldehyde, and acetal, which are formed more or less and impart a peculiar and rather agreeable fragrance to the vapor, but which overpowers any other odor that is present.
People who regularly use perfume lamps will often notice that, no matter how different the fluid used in the lamp may be, there is a certain similarity in the smell when the platinum is heated. This happens because as long as there is alcohol vapor mixed with oxygen-rich air flowing over the red-hot platinum, specific products are always produced—specifically, acetic acid, aldehyde, and acetal. These substances are created to varying degrees and give a unique and fairly pleasant scent to the vapor, which tends to dominate over any other odors present.
Fumigating Documents.
There are two modes of preparing this article:—
There are two ways to prepare this article:—
1. Take sheets of light cartridge paper, and dip them into a solution of alum—say, alum, one ounce; water, one pint. After they are thoroughly moistened, let them be well dried; upon one side of this paper spread a mixture of equal parts of gum benzoin, olibanum, and either balm of Tolu or Peruvian balsam, or the benzoin may be used alone. To spread the gum, &c., it is necessary that they be melted in an earthenware vessel and poured thinly over the paper, finally smoothing the surface with a hot spatula. When required for use, slips of this paper are held over a candle or lamp, in order to evaporate the odorous matter, but not to ignite it. The alum in the paper prevents it a to certain extent from burning.
1. Take sheets of light cartridge paper and dip them into a solution of alum—about one ounce of alum to one pint of water. Once they are fully moistened, let them dry completely. On one side of this paper, spread a mixture of equal parts of gum benzoin, olibanum, and either balm of Tolu or Peruvian balsam, or you can use only benzoin. To apply the gum, it's necessary to melt the ingredients in an earthenware container and pour them thinly over the paper, then smooth the surface with a hot spatula. When you need to use it, hold pieces of this paper over a candle or lamp to evaporate the fragrant substances, but be careful not to ignite it. The alum in the paper helps prevent it from burning to some extent.
2. Sheets of good light paper are to be steeped in a solution of saltpetre, in the proportions of two ounces of the salt to one pint of water, to be afterwards thoroughly dried.
2. Good quality light paper should be soaked in a solution of saltpeter, using two ounces of salt to one pint of water, and then thoroughly dried.
Slips of this paper are to be rolled up as spills, to be ignited, and then to be blown out.
Slips of this paper are to be rolled up as spills, ignited, and then blown out.
The nitre in the paper causes a continuance of slow combustion, diffusing during that time the agreeable perfume of the odoriferous gums. If two of these sheets of paper be pressed together before the surface is dry, they will join and become as one. When cut into slips, they form what are called Odoriferous Lighters, or Perfumed Spills.
The saltpeter in the paper leads to a slow, ongoing combustion, releasing the pleasant scent of fragrant gums during that process. If two of these sheets of paper are pressed together before the surface dries, they will stick and become one. When cut into strips, they create what are known as Perfumed Lighters, or Odoriferous Spills.
SECTION VIII.
PERFUMED SOAP.
The word soap, or sope, from the Greek sapo, first occurs in the works of Pliny and Galen. Pliny informs us that soap was first discovered by the Gauls, that it was composed of tallow and ashes, and that the German soap was reckoned the best. According to Sismondi, the French historian, a soapmaker was included in the retinue of Charlemagne.
The word soap, or sope, from the Greek sapo, first appears in the works of Pliny and Galen. Pliny tells us that soap was first discovered by the Gauls, made of tallow and ashes, and that the German soap was considered the best. According to Sismondi, the French historian, a soapmaker was part of Charlemagne's entourage.
At Pompeii (overwhelmed by an eruption of Vesuvius a.d. 79), a soap-boiler's shop with soap in it was discovered during some excavations made there not many years ago. (Starke's Letters from Italy.)
At Pompeii (overwhelmed by an eruption of Vesuvius A.D. 79), a soap-maker's shop containing soap was uncovered during excavations conducted there a few years ago. (Starke's Letters from Italy.)
From these statements it is evident that the manufacture of soap is of very ancient origin; indeed, Jeremiah figuratively mentions it—"For though thou wash thee with natron, and take thee much soap, yet thine iniquity is marked before me." (Jer. 2:22.)
From these statements, it's clear that soap making is really old; in fact, Jeremiah mentions it figuratively—"For though you wash yourself with natron and use a lot of soap, your sin is still before me." (Jer. 2:22.)
Mr. Wilson says that the earliest record of the soap trade in England is to be found in a pamphlet in the British Museum, printed in 1641, entitled "A short Account of the Soap Business." It speaks more particularly about the duty, which was then levied for the first time, and concerning certain patents which were granted to persons, chiefly Popish recusants, for some pretended new invention of white soap, "which in truth was not so." Sufficient is said here to prove that at that time soap-making was no inconsiderable art.
Mr. Wilson states that the earliest record of the soap trade in England can be found in a pamphlet at the British Museum, printed in 1641, titled "A Short Account of the Soap Business." It specifically discusses the duty that was imposed for the first time and certain patents that were granted to individuals, mainly Catholic recusants, for some supposed new invention of white soap, "which was actually not the case." It is clear from this that soap-making was an important craft at that time.
It would be out of place here to enter into the details of soap-making, because perfumers do not manufacture that substance, but are merely "remelters," to use a trade term. The dyer purchases his dye-stuffs from the drysalters already fabricated, and these are merely modified under his hands to the various purposes he requires; so with the perfumer, he purchases the various soaps in their raw state from the soap-makers, these he mixes by remelting, scents and colors according to the article to be produced.
It wouldn't be appropriate to go into the details of soap-making here, since perfumers don't actually make that substance but are just "remelters," as the trade puts it. The dyer buys his dye materials from drysalters who have already made them, and he just modifies them for his specific needs. Similarly, the perfumer buys different soaps in their raw form from soap-makers, and then he remelts, scents, and colors them based on the final product he wants to create.
The primary soaps are divided into hard and soft soaps: the hard soaps contain soda as the base; those which are soft are prepared with potash. These are again divisible into varieties, according to the fatty matter employed in their manufacture, also according to the proportion of alkali. The most important of these to the perfumer is what is termed curd soap, as it forms the basis of all the highly-scented soaps.
The main types of soaps are hard and soft soaps: hard soaps use soda as the base, while soft soaps are made with potash. These can also be divided into different types based on the fatty substances used in their production and the amount of alkali. The most significant type for perfumers is what's known as curd soap, as it serves as the foundation for all the highly scented soaps.
Curd Soap is a nearly neutral soap, of pure soda and fine tallow.
Curd soap is a soap that is almost neutral, made from pure soda and high-quality tallow.
Oil Soap, as made in England, is an uncolored combination of olive oil and soda, hard, close grain, and contains but little water in combination.
Oil Soap, made in England, is a colorless mix of olive oil and sodium, with a hard, tight grain, and contains very little water combined.
Castile Soap, as imported from Spain, is a similar combination, but is colored by protosulphate of iron. The solution of the salt being added to the soap after it is manufactured, from the presence of alkali, decomposition of the salt takes place, and protoxide of iron is diffused through the soap of its well-known black color, giving the familiar marbled appearance to it. When the soap is cut up into bars, and exposed to the air, the protoxide passes by absorption of oxygen into peroxide; hence, a section of a bar of Castile soap shows the outer edge red-marbled, while the interior is black-marbled. Some Castile soap is not artificially colored, but a similar appearance is produced by the use of a barilla or soda containing sulphuret of the alkaline base, and at other times from the presence of an iron salt.
Castile Soap, imported from Spain, is a similar mix but is dyed using protosulphate of iron. When the salt solution is added to the soap after it’s made, the presence of alkali causes the salt to break down, spreading protoxide of iron throughout the soap, which gives it its well-known black color and the familiar marbled look. When the soap is cut into bars and exposed to the air, the protoxide absorbs oxygen and transforms into peroxide; therefore, a cross-section of a bar of Castile soap reveals the outer edge as red-marbled while the inside remains black-marbled. Some Castile soap isn’t artificially colored, but a similar look is achieved by using a barilla or soda that contains sulphuret of the alkaline base, or sometimes from the presence of an iron salt.
Marine Soap is a cocoanut-oil soap, of soda containing a great excess of alkali, and much water combination.
Ocean Soap is a coconut oil soap with soda that contains a large amount of excess alkali and a lot of water.
Yellow Soap is a soda soap, of tallow, resin, of lard, &c. &c.
Yellow Soap is a soap made from soda, tallow, resin, lard, etc.
Palm Soap is a soda soap of palm oil, retaining the peculiar odor and color of the oil unchanged. The odoriferous principle of palm oil resembling that from orris-root, can be dissolved out of it by tincturation with alcohol; like ottos generally, it remains intact in the presence of an alkali, hence, soap made of palm oil retains the odor of the oil.
Palm Soap is a soda soap made from palm oil, keeping the unique smell and color of the oil unchanged. The fragrant component of palm oil, similar to that from orris root, can be extracted by soaking it in alcohol; like most essential oils, it stays intact when alkaline substances are present, which is why soap made from palm oil maintains the oil's scent.
The public require a soap that will not shrink and change shape after they purchase it. It must make a profuse lather during the act of washing. It must not leave the skin rough after using it. It must be either quite inodorous or have a pleasant aroma. None of the above soaps possess all these qualities in union, and, therefore, to produce such an article is the object of the perfumer in his remelting process.
The public needs a soap that won’t shrink or change shape after they buy it. It should lather up well while washing. It must not leave the skin feeling rough afterward. It should either be odorless or have a nice scent. None of the current soaps have all these qualities combined, and that’s why the perfumer aims to create such a product during his remelting process.
Prior to the removal of the excise duty upon soap, in 1853, it was a commercial impossibility for a perfumer to manufacture soap, because the law did not allow less than one ton of soap to be made at a time. This law, which, with certain modifications had been in force since the reign of Charles I, confined the actual manufacture of that article to the hands of a few capitalists. Such law, however, was but of little importance to the perfumer, as a soap-boiling plant and apparatus is not very compatible with a laboratory of flowers; yet, in some exceptional instances, these excise regulations interfered with him; such, for instance, as that in making soft soap of lard and potash, known, when perfumed, as Crême d'Amande; or unscented, as a Saponaceous Cream, which has, in consequence of that law, been entirely thrown into the hands of our continental neighbors.
Before the excise duty on soap was removed in 1853, it was virtually impossible for a perfumer to make soap, because the law required a minimum of one ton of soap to be produced at a time. This law, which had been in effect since the reign of Charles I with some modifications, limited the actual production of soap to a few wealthy individuals. However, this law didn’t matter much to perfumers, as soap-making equipment doesn’t really fit in with a flower lab. Still, in some rare cases, these excise rules did impact perfumers, like when producing soft soap from lard and potash, which is known as Crême d'Amande when scented or as a Saponaceous Cream when unscented. Because of that law, the production was primarily taken over by our continental neighbors.
Fig Soft Soap is a combination of oils, principally olive oil of the commonest kind, with potash.
Fig Liquid Soap is a mix of oils, mainly regular olive oil, with potash.
Naples Soft Soap is a fish oil (mixed with Lucca oil) and potash, colored brown for the London shavers, retaining, when pure, its unsophisticated "fishy" odor.
Naples Liquid Soap is made from fish oil (blended with Lucca oil) and potash, tinted brown for the London barbers, keeping its straightforward "fishy" smell when it's pure.
The above soaps constitute the real body or base of all the fancy scented soaps as made by the perfumers, which are mixed and remelted according to the following formula:—
The soaps mentioned above make up the actual body or base for all the fancy scented soaps made by perfumers, which are blended and remelted using the following formula:—
The remelting process is exceedingly simple. The bar soap is first cut up into thin slabs, by pressing them against a wire fixed upon the working bench. This cutting wire (piano wire is the kind) is made taut upon the bench, by being attached to two screws. These screws regulate the height of the wire from the bench, and hence the thickness of the slabs from the bars. The soap is cut up into thin slabs, because it would be next to impossible to melt a bar whole, on account of soap being one of the worst conductors of heat.
The remelting process is really straightforward. The bar soap is first sliced into thin slabs by pressing it against a wire fixed to the workbench. This cutting wire (usually piano wire) is made taut on the bench by being attached to two screws. These screws adjust the height of the wire from the bench, which determines the thickness of the slabs from the bars. The soap is cut into thin slabs because it would be nearly impossible to melt a whole bar, since soap is one of the worst conductors of heat.
The melting pan is an iron vessel, of various sizes, capable of holding from 28 lbs. to 3 cwt., heated by a steam jacket, or by a water-bath. The soap is put into the pan by degrees, or what is in the vernacular called "rounds," that is, the thin slabs are placed perpendicularly all round the side of the pan; a few ounces of water are at the same time introduced, the steam of which assists the melting. The pan being covered up, in about half an hour the soap will have "run down." Another round is then introduced, and so continued every half hour until the whole "melting" is finished. The more water a soap contains, the easier is it melted; hence a round of marine soap, or of new yellow soap, will run down in half the time that it requires for old soap.
The melting pan is an iron container of various sizes, holding anywhere from 28 lbs. to 3 cwt., heated by a steam jacket or a water bath. The soap is added to the pan gradually, or as we might say, in "rounds," which means the thin slabs are arranged vertically around the sides of the pan. At the same time, a few ounces of water are added, and the steam helps with the melting process. Once the pan is covered, the soap will have "run down" in about half an hour. Another round is then added, and this continues every half hour until the entire melting process is complete. The more water a soap has, the easier it melts; therefore, a round of marine soap or new yellow soap will melt in half the time it takes for old soap.
When different soaps are being remelted to form one kind when finished, the various sorts are to be inserted into the pan in alternate rounds, but each round must consist only of one kind, to insure uniformity of condition. As the soap melts, in order to mix it, and to break up lumps, &c., it is from time to time "crutched." The "crutch" is an instrument or tool for stirring up the soap; its name is indicative of its form, a long handle with a short cross—an inverted 'T', curved to fit the curve of the pan. When the soaps are all melted, it is then colored, if so required, and then the perfume is added, the whole being thoroughly incorporated with the crutch.
When different types of soap are melted down to create a single kind, they should be added to the pan in alternating layers, with each layer containing only one type to ensure consistent quality. As the soap melts, it is periodically stirred to mix it and break up any lumps, using a tool called a "crutch." The "crutch" is designed for this purpose, featuring a long handle with a short crossbar—essentially an inverted 'T'—curved to fit the shape of the pan. Once all the soaps are melted, color can be added if needed, followed by the perfume, and everything is thoroughly mixed with the crutch.

The soap is then turned into the "frame." The frame is a box made in sections, in order that it can be taken to pieces, so that the soap can be cut up when cold; the sections or "lifts" are frequently made of the width of the intended bar of soap.
The soap is then transformed into the "frame." The frame is a box built in sections so that it can be taken apart, allowing the soap to be cut into pieces when it's cool; the sections or "lifts" are often made to the width of the intended bar of soap.

Two or three days after the soap has been in the frame, it is cool enough to cut into slabs of the size of the lifts or sections of the frame; these slabs are set up edgeways to cool for a day or two more; it is then barred by means of a wire. The lifts of the frame regulate the widths of the bars; the gauge regulates their breadth. The density of the soap being pretty well known, the gauges are made so that the soap-cutter can cut up the bars either into fours, sixes, or eights; that is, either into squares of four, six, or eight to the pound weight. Latterly, various mechanical arrangements have been introduced for soap-cutting, which in very large establishments, such as those at Marseilles in France, are great economisers of labor; but in England the "wire" is still used.
Two or three days after the soap has been in the mold, it cools enough to be cut into slabs that match the size of the lifts or sections of the mold; these slabs are then stood up on their edges to cool for another day or two. It is then marked off using a wire. The lifts of the mold determine the widths of the bars, while the gauge controls their thickness. Knowing the density of the soap, the gauges are designed so the soap-cutter can slice the bars into groups of four, six, or eight; that is, into squares containing four, six, or eight to the pound weight. Recently, various mechanical systems have been introduced for cutting soap, which save a lot of labor in large factories, such as those in Marseille, France, but in England, the "wire" is still commonly used.


For making tablet shapes the soap is first cut into squares, and is then put into a mould, and finally under a press—a modification of an ordinary die or coin press. Balls are cut by hand, with the aid of a little tool called a "scoop," made of brass or ivory, being, in fact, a ring-shaped knife. Balls are also made in the press with a mould of appropriate form. The grotesque form and fruit shape are also obtained by the press and appropriate moulds. The fruit-shaped soaps, after leaving the mould, are dipped into melted wax, and are then colored according to artificial fruit-makers' rules.
To create tablet shapes, the soap is first cut into squares, then placed in a mold, and finally put under a press—a modified version of a regular die or coin press. Balls are shaped by hand using a small tool called a "scoop," which is made of brass or ivory and functions like a ring-shaped knife. Balls can also be produced in the press using a suitable mold. The unusual shapes and fruit designs are also formed using the press and the appropriate molds. After the fruit-shaped soaps come out of the mold, they are dipped into melted wax and then colored according to the guidelines used by artificial fruit makers.


The "variegated" colored soaps are produced by adding the various colors, such as smalt and vermilion, previously mixed with water, to the soap in a melted state; these colors are but slightly crutched in, hence the streaky appearance or party color of the soap; this kind is also termed "marbled" soap.
The "variegated" colored soaps are made by mixing different colors, like smalt and vermilion, with water and then adding them to the soap while it's melted; these colors are only minimally mixed in, which gives the soap its streaky or multi-colored look; this type is also called "marbled" soap.
Almond Soap.
This soap, by some persons "supposed" to be made of "sweet almond oil," and by others to be a mystic combination of sweet and bitter almonds, is in reality constituted thus:—
This soap is thought by some to be made from "sweet almond oil," and by others to be a mystical blend of sweet and bitter almonds, but in reality, it is made like this:—
Finest curd soap, | 1 cwt. |
" oil soap, | 14 lbs. |
" marine, | 14 lbs. |
Otto of almonds, | 1-1/2 lb. |
" cloves, | 1/4 lb. |
" caraway, | 1/2 lb. |
By the time that half the curd soap is melted, the marine soap is to be added; when this is well crutched, then add the oil soap, and finish with the remaining curd. When the whole is well melted, and just before turning it into the frame, crutch in the mixed perfume.
By the time half of the curd soap has melted, add the marine soap; once that’s mixed in well, add the oil soap, and finish with the rest of the curd. When everything is fully melted, just before pouring it into the mold, mix in the fragrance.
Some of the soap "houses" endeavored to use Mirabane or artificial essence of almonds (see Almond) for perfuming soap, it being far cheaper than the true otto of almonds; but the application has proved so unsatisfactory in practice, that it has been abandoned by Messrs. Gibbs, Pineau (of Paris), Gosnell, and others who used it.
Some of the soap "houses" tried to use Mirabane or synthetic almond essence (see Almonds) to scent their soap, since it was much cheaper than real almond oil. However, the results were so disappointing that it has been dropped by Messrs. Gibbs, Pineau (of Paris), Gosnell, and others who had used it.
Camphor soap.
Curd soap, | 28 lbs. |
Otto of rosemary, | 1-1/4 lb. |
Camphor, | 1-1/4 lb. |
Reduce the camphor to powder by rubbing it in a mortar with the addition of an ounce or more of almond oil, then sift it. When the soap is melted and ready to turn out, add the camphor and rosemary, using the crutch for mixing.
Reduce the camphor to a powder by grinding it in a mortar with an ounce or more of almond oil, then sift it. When the soap is melted and ready to be poured out, add the camphor and rosemary, using a stick to mix it.
Honey Soap.
Best yellow soap, | 1 cwt. |
Fig soft soap, | 14 lbs. |
Otto of citronella, | 1-1/2 lb. |
Windsor Soap in White.
Curd soap, | 1 cwt. | ||
Marine soap, | 21 lbs. | ||
Oil soap, | 14 lbs. | ||
Otto of caraway, | 1-1/2 lbs. | ||
" thyme, | } | ||
" rosemary, | } of each | 1/2 lb. | |
" cassia, | } | ||
" cloves, | } of each | 1/4 lb. |
Brown Windsor Soap.
Curd soap, | 3/4 cwt. | |
Marine soap, | 1/4 " | |
Yellow soap, | 1/4 " | |
Oil soap, | 1/4 " | |
Brown coloring (caramel), | 1/2 pint. | |
Otto of caraway, | } | |
" cloves, | } | |
" thyme, | } each, | 1/2 lb. |
" cassia, | } | |
" petit grain, | } | |
" French lavender, | } |
Sand Soap.
Curd soap, | 7 lbs. | |
Marine soap, | 7 lbs. | |
Sifted silver sand, | 28 lbs. | |
Otto of thyme, | } | |
" cassia, | } | |
" caraway, | } each, | 2 oz. |
" French lavender, | } |
Fuller's Earth Soap.
Curd soap, | 10-1/2 lbs. |
Marine soap, | 3-1/2 lbs. |
Fuller's earth (baked), | 14 lbs. |
Otto of French lavender, | 2 oz. |
" origanum, | 1 oz. |
The above forms are indicative of the method adopted for perfuming soaps while hot or melted.
The forms above show the method used for adding fragrance to soaps while they're hot or melted.
All the very highly scented soaps are, however, perfumed cold, in order to avoid the loss of scent, 20 per cent. of perfume being evaporated by the hot process.
All the highly scented soaps are, however, fragranced cold, to prevent losing the scent, as 20 percent of the fragrance would evaporate with the hot process.
The variously named soaps, from the sublime "Sultana" to the ridiculous "Turtle's Marrow," we cannot of course be expected to notice; the reader may, however, rest assured that he has lost nothing by their omission.
The different soaps, ranging from the fancy "Sultana" to the silly "Turtle's Marrow," aren't something we really need to pay attention to; however, the reader can be confident that he hasn't missed anything important by leaving them out.
The receipts given produce only the finest quality of the article named. Where cheap soaps are required, not much acumen is necessary to discern that by omitting the expensive perfumes, or lessening the quantity, the object desired is attained. Still lower qualities of scented soap are made by using greater proportions of yellow soap, and employing a very common curd, omitting the oil soap altogether.
The receipts provided yield only the highest quality of the specified item. When it comes to cheap soaps, it's pretty easy to see that by cutting out the expensive fragrances or reducing their amount, the desired outcome can be achieved. Even lower-quality scented soaps are created by using larger amounts of yellow soap and a very basic curd, completely leaving out the oil soap.
Scented soaps are hot.
In the previous remarks, the methods explained of scenting soap involved the necessity of melting it. The high temperature of the soap under these circumstances involves the obvious loss of a great deal of perfume by evaporation. With very highly scented soaps, and with perfume of an expensive character, the loss of ottos is too great to be borne in a commercial sense; hence the adoption of the plan of
In the earlier comments, the methods for adding fragrance to soap required melting it. The high temperature of the soap in this case leads to a significant loss of fragrance due to evaporation. With soaps that are heavily scented and with costly perfumes, the loss of essential oils is too substantial to be practical for business; therefore, the use of the approach of
Cold Scented Soaps.
This method is exceedingly convenient and economical for scenting small batches, involving merely mechanical labor, the tools required being simply an ordinary carpenter's plane, and a good marble mortar, and lignum vitæ pestle.
This method is very convenient and cost-effective for scenting small batches, involving only manual labor. The tools needed are just a regular carpenter's plane, a good marble mortar, and a lignum vitæ pestle.
The woodwork of the plane must be fashioned at each end, so that when placed over the mortar it remains firm and not easily moved by the parallel pressure of the soap against its projecting blade.
The woodwork of the plane needs to be shaped at each end so that when it’s set over the mortar, it stays sturdy and isn’t easily shifted by the even pressure of the soap against its protruding blade.
Things being thus arranged, the whole of the soap is to be pushed across the plane until it is all reduced into fine shavings. Like the French "Charbonnier," who does not saw the wood, but woods the saw, so it will be perceived that in this process we do not plane the soap, but that we soap the plane, the shavings of which fall lightly into the mortar as quickly as produced.
With everything set up, the entire bar of soap is pushed across the plane until it's all turned into fine shavings. Like the French "Charbonnier," who doesn't saw the wood but instead works the saw, it’s clear that in this process we’re not planing the soap, but rather we’re soaping the plane, with the shavings falling gently into the mortar as quickly as they’re made.

Soap, as generally received from the maker, is the proper condition for thus working; but if it has been in stock any time it becomes too hard, and must have from one to three ounces of distilled water sprinkled in the shaving for every pound of soap employed, and must lay for at least twenty-four hours to be absorbed before the perfume is added.
Soap, as it typically comes from the manufacturer, is the right consistency for this purpose; however, if it's been stored for a while, it gets too hard. You need to add one to three ounces of distilled water to the soap for every pound used, and it should sit for at least twenty-four hours to absorb the water before you add the fragrance.
When it is determined what size the cakes of soap are to be, what they are to sell for, and what it is intended they should cost, then the maker can measure out his perfume.
When the size of the soap bars is decided, the selling price is set, and the intended cost is established, then the maker can measure out the fragrance.
In a general way, soaps scented in this way retail from 4s. to 10s. per pound, bearing about 100 per cent. profit, which is not too much considering their limited sale. The soap being in a proper physical condition with regard to moisture, &c., is now to have the perfume well stirred into it. The pestle is then set to work for the process of incorporation. After a couple of hours of "warm exercise," the soap is generally expected to be free from streaks, and to be of one uniform consistency.
Generally, soaps with this scent sell for 4s. to 10s. per pound, yielding about 100 percent profit, which isn’t too high considering their limited market. Once the soap is in the right physical condition regarding moisture, etc., it’s time to mix in the fragrance thoroughly. The pestle is then used for the incorporation process. After a couple of hours of "warm exercise," the soap is typically expected to be streak-free and have a consistent texture.
For perfuming soap in large portions by the cold process, instead of using the pestle and mortar as an incorporator, it is more convenient and economical to employ a mill similar in construction to a cake chocolate-mill, or a flake cocoa-mill; any mechanical apparatus that answers for mixing paste and crushing lumps will serve pretty well for blending soap together.
To add fragrance to soap in large batches using the cold process, it's more practical and cost-effective to use a mill similar to a cake chocolate mill or a flake cocoa mill instead of a pestle and mortar. Any mechanical device that can mix paste and crush lumps will work quite well for blending soap.
Before going into the mill, the soap is to be reduced to shavings, and have the scent and color stirred in; after leaving it, the flakes or ribands of soap are to be finally bound together by the pestle and mortar into one solid mass; it is then weighed out in quantities for the tablets required, and moulded by the hand into egg-shaped masses; each piece being left in this condition, separately laid in rows on a sheet of white paper, dries sufficiently in a day or so to be fit for the press, which is the same as that previously mentioned. It is usual, before placing the cakes of soap in the press, to dust them over with a little starch-powder, or else to very slightly oil the mould; either of these plans prevents the soap from adhering to the letters or embossed work of the mould—a condition essential for turning out a clean well-struck tablet.
Before going into the mill, the soap needs to be shredded, and the scent and color mixed in; after leaving the mill, the flakes or strips of soap should be finally combined by hand in a pestle and mortar into one solid mass. Then, it's weighed out into portions for the required tablets and shaped by hand into egg-like pieces. Each piece is left as it is and laid out in rows on a sheet of white paper, where it dries enough in a day or so to be ready for the press, similar to what was mentioned earlier. Typically, before putting the soap cakes in the press, they are dusted with a bit of starch powder or very lightly oiled in the mold; either of these methods prevents the soap from sticking to the letters or designs in the mold, which is crucial for producing a clean, well-formed tablet.
The body of all the fine soaps mentioned below should consist of the finest and whitest curd soap, or of a soap previously melted and colored to the required shade, thus:—
The base of all the high-quality soaps listed below should be made from the best and whitest curd soap, or from soap that has been previously melted and colored to the desired shade, as follows:—
Rose-colored Soap is curd soap stained with vermilion, ground in water, thoroughly incorporated when the soap is melted, and not very hot.
Pink Soap is curd soap colored with vermilion, mixed in water, completely blended when the soap is melted, and not too hot.
Green Soap is a mixture of palm oil soap and curd soap, to which is added powdered smalt ground with water.
Green Soap is a combination of palm oil soap and curd soap, to which powdered smalt mixed with water is added.
Blue Soap, curd soap colored with smalt.
Blue Soap, a curd soap dyed with blue pigment.
Brown Soap, curd soap with caramel, i.e. burnt sugar.
Brown Soap, curd soap made with caramel, i.e. burnt sugar.
The intensity of color varies, of course, with the quantity of coloring.
The intensity of color changes, of course, with the amount of dye used.
Some kinds of soap become colored or tinted to a sufficient extent by the mere addition of the ottos used for scenting, such as "spermaceti soap," "lemon soap," &c., which become of a beautiful pale lemon color by the mere mixing of the perfume with the curd soap.
Some types of soap get colored just from adding the essential oils used for fragrance, like "spermaceti soap," "lemon soap," etc., which turn a lovely pale lemon color simply by mixing the scent with the soap base.
Otto of Rose Soap.
(To retail at 10s. per pound.)
Curd soap (previously colored with vermilion), | 4-1/2 lbs. |
Otto of rose, | 1 oz. |
Spirituous extract of musk, | 2 oz. |
Otto of santal, | 1/4 oz. |
" geranium, | 1/4 oz. |
Tonquin Musk Soap.
Pale brown-colored curd soap, | 5 lbs. |
Grain musk, | 1/4 oz. |
Otto of bergamot, | 1 oz. |
Rub the musk with the bergamot, then add it to the soap, and beat up.
Rub the musk with the bergamot, then mix it into the soap, and whip it well.
Orange Blossom Soap.
Curd soap, | 7 lbs. |
Otto of neroli, | 3-1/2 oz. |
Sandalwood Soap.
Curd soap, | 7 lbs. |
Otto of santal, | 7 oz. |
" bergamot, | 2 oz. |
Spermaceti Soap.
Curd soap, | 14 lbs. |
Otto of bergamot, | 2-1/2 lbs. |
" lemon, | 1/2 lb. |
Citron Body Wash.
Curd soap, | 6 lbs. |
Otto of citron, | 3/4 lb. |
" verbena (lemon-grass), | 1/2 oz. |
" bergamot, | 4 oz. |
" lemon, | 2 oz. |
One of the best of fancy soaps that is made.
One of the finest decorative soaps that is produced.
Frangipani Soap.
Curd soap (previously colored light brown), | 7 lbs. |
Civet, | 1/4 oz. |
Otto of neroli, | 1/2 oz. |
" santal, | 1-1/2 oz. |
" rose, | 1/4 oz. |
" vitivert, | 1/2 oz. |
Rub the civet with the various ottos, mix, and beat in the usual manner.
Rub the civet with the different essential oils, mix, and beat as you normally would.
Patchouli Soap.
Curd soap, | 4-1/2 lbs. | |
Otto of patchouly, | 1 oz. | |
" santal, | } | |
" vitivert, | } of each, | 1/4 oz. |
Almond Cream.
The preparation sold under this title is a potash soft soap of lard. It has a beautiful pearly appearance, and has met with extensive demand as a shaving soap. Being also used in the manufacture of Emulsines, it is an article of no inconsiderable consumption by the perfumer. It is made thus:—
The product sold under this name is a potash soft soap made from lard. It has a lovely pearly look and is very popular as a shaving soap. It’s also used in making Emulsifiers, so it has significant use in the perfume industry. Here’s how it's made:—
Clarified lard, | 7 lbs. |
Potash of lye (containing 26 per cent. of caustic potash), | 3-3/4 lbs. |
Rectified spirit, | 3 oz. |
Otto of almonds, | 2 drachms. |
Manipulation.—Melt the lard in a porcelain vessel by a salt-water bath, or by a steam heat under 15 lbs. pressure; then run in the lye, very slowly, agitating the whole time; when about half the lye is in, the mixture begins to curdle; it will, however, become so firm that it cannot be stirred. The crême is then finished, but is not pearly; it will, however, assume that appearance by long trituration in a mortar, gradually adding the alcohol, in which has been dissolved the perfume.
Manipulation.—Melt the lard in a porcelain container using a salt-water bath or by steam heat at 15 lbs. pressure; then slowly add the lye, stirring the whole time; when about half of the lye is added, the mixture will start to curdle; it will eventually become so thick that it can't be stirred. The cream is then complete, but it doesn't look pearly; however, it will take on that appearance with extended grinding in a mortar, gradually adding the alcohol that has dissolved the fragrance.
Laundry Detergents.
These preparations are sold sometimes as a dentifrice and at others for shaving; they are made by reducing the soap into shavings by a plane, then thoroughly drying them in a warm situation, afterwards grinding in a mill, then perfuming with any otto desired.
These products are sometimes sold as toothpaste and other times for shaving; they are made by shaving the soap into thin pieces with a planer, then drying them completely in a warm place, grinding them in a mill, and finally adding fragrance with any desired essential oil.
Rypophagon Soap.
Best yellow soap, | } |
Fig soft soap, | } equal parts melted together. |
Perfume with anise and citronella.
Anise and citronella fragrance.
Heavenly Cream.
Color the grease very strongly with alkanet root, then proceed as for the manufacture of saponaceous cream. The cream colored in this way has a blue tint; when it is required of a purple color we have merely to stain the white saponaceous cream with a mixture of vermilion and smalt to the shade desired. Perfume with otto of oringeat.
Color the grease intensely with alkanet root, then continue as you would for making soap cream. The cream colored this way has a blue tint; if a purple color is needed, just tint the white soap cream with a mixture of vermilion and smalt to achieve the desired shade. Add fragrance with orange flower oil.
Clear Liquid Soap.
Solution caustic potash (Lond. Ph.), | 6 lbs. |
Olive oil, | 1 lb. |
Perfume to taste. |
Clear Soap.
Reduce the soap to shavings, and dry them as much as possible, then dissolve in alcohol, using as little spirit as will effect the solution, then color and perfume as desired, and cast the product in appropriate moulds; finally dry in a warm situation.
Grate the soap into small pieces and dry them as much as you can, then dissolve in alcohol, using just enough spirits to dissolve it. After that, add color and fragrance as you like, and pour the mixture into suitable molds; finally, let it dry in a warm place.
Until the Legislature allows spirit to be used for manufacturing purposes, free of duty, we cannot compete with our neighbors in this article.
Until the Legislature permits spirit to be used for manufacturing purposes without duty, we can't compete with our neighbors in this area.
Juniper Tar Soap.
This soap is made from the tar of the wood of the Juniperus communis, by dissolving it in a fixed vegetable oil, such as almond or olive oil, or in fine tallow, and forming a soap by means of a weak soda lye, after the customary manner. This yields a moderately firm and clear soap, which may be readily used by application to parts affected with eruptions at night, mixed with a little water, and carefully washed off the following morning. This soap has lately been much used for eruptive disorders, particularly on the Continent, and with varying degrees of success. It is thought that the efficient element in its composition is a rather less impure hydrocarburet than that known in Paris under the name huile de cade. On account of its ready miscibility with water, it possesses great advantage over the common tar ointment.
This soap is made from the tar of the wood of the Juniperus communis by dissolving it in a fixed vegetable oil, like almond or olive oil, or in fine tallow, and creating a soap using a mild soda lye, as is typically done. This creates a moderately firm and clear soap that can be easily used by applying it to affected areas with eruptions at night, mixed with a little water, and carefully washed off the following morning. Recently, this soap has been widely used for eruptive skin conditions, especially in Europe, with varying levels of success. It's believed that the active ingredient in its formula is a slightly less impure hydrocarbon than what is referred to in Paris as huile de cade. Because it mixes well with water, it has a significant advantage over regular tar ointment.
Medicated Soaps.
Six years ago I began making a series of medicated soaps, such as Sulphur Soap, Iodine Soap, Bromine Soap, Creosote Soap, Mercurial Soap, Croton Oil Soap, and many others. These soaps are prepared by adding the medicant to curd soap, and then making in a tablet form for use. For sulphur soap, the curd soap may be melted, and flowers of sulphur added while the soap is in a soft condition. For antimony soap and mercurial soap, the low oxides of the metals employed may also be mixed in the curd soap in a melted state. Iodine, bromine, creosote soap, and others containing very volatile substances, are best prepared cold by shaving up the curd soap in a mortar, and mixing the medicant with it by long beating.
Six years ago, I started creating a series of medicated soaps, like Sulfur Soap, Iodine Soap, Bromine Soap, Creosote Soap, Mercurial Soap, Croton Oil Soap, and many more. These soaps are made by adding the medication to the curd soap and then shaping it into tablet form for use. For sulfur soap, the curd soap can be melted, and flowers of sulfur added while the soap is still soft. For antimony soap and mercurial soap, the low oxides of the used metals can also be mixed into the melted curd soap. Iodine, bromine, creosote soap, and others containing highly volatile substances are best prepared cold by shredding the curd soap in a mortar and mixing the medication in by thorough beating.
In certain cutaneous diseases the author has reason to believe that they will prove of infinite service as auxiliaries to the general treatment. It is obvious that the absorbent vessels of the skin are very active during the lavoratory process; such soap must not, therefore, be used except by the special advice of a medical man. Probably these soaps will be found useful for internal application. The precedent of the use of Castile soap (containing oxide of iron) renders it likely that when prejudice has passed away, such soaps will find a place in the pharmacopœias. The discovery of the solubility, under certain conditions, of the active alkaloids, quinine, morphia, &c., in oil, by Mr. W. Bastick, greatly favors the supposition of analogous compounds in soap.
In some skin diseases, the author believes these treatments could be extremely helpful as supplements to general care. It's clear that the absorbent vessels in the skin are very active during the cleaning process; therefore, such soap should only be used with special guidance from a doctor. These soaps might also be useful for internal use. The example of Castile soap (which contains iron oxide) suggests that once any bias is overcome, such soaps may be included in pharmacies. Mr. W. Bastick's discovery of the solubility of active alkaloids like quinine and morphine in oil under certain conditions supports the idea of similar compounds in soap.
SECTION IX.
EMULSINES.
From soaps proper we now pass to those compounds used as substitutes for soap, which are classed together under one general title as above, for the reason that all cosmetiques herein embraced have the property of forming emulsions with water.
From traditional soaps, we now move on to the compounds used as soap substitutes, which are grouped together under one general category as mentioned above, because all the cosmetics included here have the ability to create emulsions with water.
Chemically considered, they are an exceedingly interesting class of compounds, and are well worthy of study. Being prone to decomposition, as might be expected from their composition, they should be made only in small portions, or, at least, only in quantities to meet a ready sale.
Chemically speaking, they are a really fascinating group of compounds and deserve to be studied. Because they tend to break down, which is what you would expect from their makeup, they should be produced in small amounts or, at the very least, only in quantities that can be quickly sold.
While in stock they should be kept as cool as possible, and free from a damp atmosphere.
While in stock, they should be kept as cool as possible and in a dry environment.
Amandine.
Fine almond oil, | 7 lbs. |
Simple syrup,[E] | 4 oz. |
White soft soap, or saponaceous cream, i.e. Crême d'Amande, | 1 oz. |
Otto of almonds, | 1 oz. |
" bergamot, | 1 oz. |
" cloves, | 1/2 oz. |

In the manufacture of amandine (and olivine) the difficulty is to get in the quantity of oil indicated, without which it does not assume that transparent jelly appearance which good amandine should have. To attain this end, the oil is put into "a runner," that is, a tin or glass vessel, at the bottom of which is a small faucet and spigot, or tap. The oil being put into this vessel is allowed to run slowly into the mortar in which the amandine is being made, just as fast as the maker finds that he can incorporate it with the paste of soap and syrup; and so long as this takes place, the result will always have a jelly texture to the hand. If, however, the oil be put into the mortar quicker than the workman can blend it with the paste, then the paste becomes "oiled," and may be considered as "done for," unless, indeed, the whole process be gone through again, starting off with fresh syrup and soap, using up the greasy mass as if it were pure oil. This liability to "go off," increases as the amandine nears the finish; hence extra caution and plenty of "elbow grease" must be used during the addition of the last two pounds of oil. If the oil be not perfectly fresh, or if the temperature of the atmosphere be above the average of summer heat, it will be almost impossible to get the whole of the oil given in the formula into combination; when the mass becomes bright and of a crystalline lustre, it will be well to stop the further addition of oil to it.
In the production of amandine (and olivine), the challenge is to incorporate the specified amount of oil, without which it won’t take on the clear jelly-like appearance that quality amandine should have. To achieve this, the oil is placed in a "runner," which is a tin or glass container with a small faucet at the bottom. The oil is allowed to flow slowly into the mortar where the amandine is being made, at a pace that the maker can blend it with the soap and syrup mixture; as long as this is done, the result will always have a jelly-like texture. However, if the oil is added to the mortar faster than the worker can mix it in, the paste becomes "oiled" and is considered "done for," unless the entire process is restarted with fresh syrup and soap, using the greasy mixture as if it were pure oil. This risk of going wrong increases as the amandine nears completion; thus, extra care and significant effort must be applied during the addition of the last two pounds of oil. If the oil isn’t completely fresh, or if the temperature is above the typical summer heat, it will be nearly impossible to fully incorporate the oil specified in the formula. When the mixture becomes bright and has a crystalline shine, it’s advisable to stop adding more oil.
This and similar compounds should be potted as quickly as made, and the lids of the pots banded either with strips of tin-foil or paper, to exclude air. When the amandine is filled into the jars, the top or face of it is marked or ornamented with a tool made to the size of half the diameter of the interior of the jar, in a similar way to a saw; a piece of lead or tortoise-shell, being serrated with an angular file, or piece of an "old saw," will do very well; place the marker on the amandine, and turn the jar gently round.
This and similar mixtures should be jarred as soon as they're made, and the tops of the jars should be covered either with strips of tin foil or paper to keep out the air. When the amandine is put into the jars, the surface is decorated or marked with a tool that is half the diameter of the inside of the jar, similar to a saw; a piece of lead or tortoiseshell, which is jagged with a file or an "old saw," works quite well; place the marker on the amandine and gently turn the jar around.
Olivine.
Gum acacia, in powder, | 2 oz. |
Honey, | 6 oz. |
Yolk of eggs, in number, | 5. |
White soft soap, | 3 oz. |
Olive oil, | 2 lbs. |
Green oil, | 1 oz. |
Otto of bergamot, | 1 oz. |
" lemon, | 1 oz. |
" cloves, | 1/2 oz. |
" thyme and cassia, each, | 1/2 drachm. |
Honey Almond Spread. (Pâte d'Amande au Miel.)
Bitter almonds, blanched and ground, | 1/2 lb. |
Honey, | 1 lb. |
Yolk of eggs, in number, | 8. |
Almond oil, | 1 lb. |
Otto of bergamot, | 1/4 oz. |
" cloves, | 1/4 oz. |
Rub the eggs and honey together first, then gradually add the oil, and finally the ground almonds and the perfume.
Mix the eggs and honey together first, then slowly add the oil, and finally the ground almonds and the fragrance.
Almond Paste.
Bitter almonds, blanched and ground, | 1-1/2 lb. |
Rose-water, | 1-1/2 pint. |
Alcohol (60 o.p.), | 16 oz. |
Otto of bergamot, | 3 oz. |
Place the ground almonds and one pint of the rose-water into a stewpan; with a slow and steady heat, cook the almonds until their granular texture assumes a pasty form, constantly stirring the mixture during the whole time, otherwise the almonds quickly burn to the bottom of the pan, and impart to the whole an empyreumatic odor.
Put the ground almonds and one pint of rose water into a saucepan; over low and steady heat, cook the almonds until their grainy texture turns into a paste, stirring the mixture constantly the entire time, or the almonds will quickly burn to the bottom of the pan and give it a burnt smell.
When the almonds are nearly cooked, the remaining water is to be added; finally the paste is put into a mortar, and well rubbed with the pestle; then the perfume and spirit are added. Before potting this paste, as well as honey paste, it should be passed through a medium fine sieve, to insure uniformity of texture, especially as almonds do not grind kindly.
When the almonds are almost done cooking, add the remaining water; then put the mixture into a mortar and grind it well with a pestle; finally, add the perfume and spirit. Before putting this paste into jars, along with the honey paste, it should be strained through a medium-fine sieve to ensure a consistent texture, especially since almonds don’t grind easily.
Other pastes, such as Pâte de Pistache, Pâte de Cocos, Pâte de Guimauve, are prepared in so similar a manner to the above that it is unnecessary to say more about them here, than that they must not be confounded with preparations bearing a similar name made by confectioners.
Other pastes, like Pâte de Pistache, Pâte de Cocos, and Pâte de Guimauve, are made in such a similar way to the ones mentioned above that it’s not necessary to elaborate further here, except to note that they shouldn’t be confused with similarly named products created by confectioners.
Almond Flour.
Ground almonds, | 1 lb. |
Wheat flour, | 1 lb. |
Orris-root powder, | 1/4 lb. |
Otto of lemon, | 1/2 oz. |
" almonds, | 1/4 drachm. |
Pistachio Nut Meal, or any other nut.
Pistachio nuts (decorticated as almonds are bleached), | 1 lb. |
Orris powder, | 1 lb. |
Otto of neroli, | 1 drachm. |
" lemons, | 1/2 oz. |
Other meals, such as perfumed oatmeal, perfumed bran, &c., are occasionally in demand, and are prepared as the foregoing.
Other meals, like scented oatmeal, scented bran, etc., are sometimes sought after and are prepared just like the previous ones.
Jasmine Emulsin.
Saponaceous cream, | 1 oz. |
Simple syrup, | 1-1/2 oz. |
Almond oil, | 1 lb. |
Best jasmine oil, | 1/2 lb. |
Emulsin the Violette.
Saponaceous cream, | 1 oz. |
Syrup of violets, | 1-1/2 oz. |
Best violet oil, | 1-1/2 lb. |
Emulsin of other odors can be prepared with tubereuse, rose, or cassie (acacia) oil (prepared by enfleurage or maceration).
Emulsin of other scents can be made with tuberose, rose, or cassie (acacia) oil (made through enfleurage or maceration).
For the methods of mixing the ingredients, see "Amandine," p. 195.
For how to mix the ingredients, see "Amandine," p. 195.
On account of the high price of the French oils, these preparations are expensive, but they are undoubtedly the most exquisite of cosmetiques.
Due to the high cost of French oils, these products are pricey, but they are definitely the most luxurious cosmetics.
SECTION X.
MILK, OR EMULSIONS.
In the perfumery trade, few articles meet with a more ready sale than that class of cosmetiques denominated milks. It has long been known that nearly all the seeds of plants which are called nuts, when decorticated and freed from their pellicle, on being reduced to a pulpy mass, and rubbed with about four times their weight of water, produce fluid which has every analogy to cow's milk. The milky appearance of these emulsions is due to the minute mechanical division of the oil derived from the nuts being diffused through the water. All these emulsions possess great chemical interest on account of their rapid decomposition, and the products emanating from their fermentation, especially that made with sweet almonds and pistachios (Pistachia vera).
In the perfume industry, few products sell as quickly as what we call milks. It's been known for a long time that almost all seeds from plants known as nuts, when shelled and stripped of their skin, can be turned into a pulpy mixture. When this mass is mixed with about four times its weight in water, it creates a liquid that closely resembles cow's milk. The milky look of these mixtures comes from the tiny oil particles from the nuts spreading throughout the water. All these mixtures are of significant chemical interest because they decompose quickly, and the byproducts from their fermentation, especially those made with sweet almonds and pistachios (Pistachia vera), are particularly noteworthy.
In the manufacture of various milks for sale, careful manipulation is of the utmost importance, otherwise these emulsions "will not keep;" hence more loss than profit.
In making different types of milk for sale, careful handling is really important; otherwise, these mixtures "won't last," leading to more losses than gains.
"Transformation takes place in the elements of vegetable caseine (existing in seeds) from the very moment that sweet almonds are converted into almond-milk."—Liebig. This accounts for the difficulty many persons find in making milk of almonds that does not spontaneously divide, a day or so after its manufacture.
"Transformation occurs in the components of vegetable casein (found in seeds) from the very moment sweet almonds are turned into almond milk."—Liebig. This explains why many people struggle to make almond milk that doesn't separate within a day or so after it's made.
Rose Water.
Valencia almonds (blanched), | 1/2 lb. |
Rose-water, | 1 quart. |
Alcohol (60 o.p.), | 1/4 pint. |
Otto of rose, | 1 drachm. |
White wax, spermaceti, oil soap, each, | 1/2 oz. |
Manipulation.—Shave up the soap, and place it in a vessel that can be heated by steam or water-bath; add to it two or three ounces of rose-water. When the soap is perfectly melted, add the wax and spermaceti, without dividing them more than is necessary to obtain the correct weight; this insures their melting slowly, and allows time for their partial saponification by the fluid soap; occasional stirring is necessary. While this is going on, blanch the almonds, carefully excluding every particle that is in the least way damaged. Now proceed to beat up the almonds in a scrupulously clean mortar, allowing the rose-water to trickle into the mass by degrees; the runner, as used for the oil in the manufacture of olivine, is very convenient for this purpose. When the emulsion of almonds is thus finished, it is to be strained, without pressure, through clean washed muslin (new muslin often contains starch, flour, gum, or dextrine).
Manipulation.—Grate the soap and put it in a container that can be heated with steam or in a water bath; add two or three ounces of rose water. Once the soap is completely melted, add the wax and spermaceti, making sure not to break them down more than necessary to achieve the correct weight; this ensures they melt slowly and allows time for them to partially saponify with the liquid soap; stirring occasionally is important. While that’s happening, blanch the almonds, making sure to remove any damaged ones. Next, crush the almonds in a very clean mortar, gradually adding the rose water into the mixture; using a runner, like the one used for oil in making olivine, is very helpful for this. When the almond emulsion is ready, strain it without pressure through clean washed muslin (new muslin often has starch, flour, gum, or dextrin in it).
The previously-formed saponaceous mixture is now to be placed in the mortar, and the ready-formed emulsion in the runner; the soapy compound and the emulsion is then carefully blended together. As the last of the emulsion runs into the mortar, the spirit, in which the otto of roses has been dissolved, is to take its place, and to be gradually trickled into the other ingredients. A too sudden addition of the spirit frequently coagulates the milk and causes it to be curdled; as it is, the temperature of the mixture rises, and every means must be taken to keep it down; the constant agitation and cold mortar effecting that object pretty well. Finally, the now formed milk of roses is to be strained.
The previously mixed soapy mixture should now be placed in the mortar, and the prepared emulsion in the runner; then the soapy mixture and the emulsion are carefully blended together. As the last of the emulsion flows into the mortar, the spirit, in which the otto of roses has been dissolved, is to take its place and be gradually drizzled into the other ingredients. Adding the spirit too quickly often causes the milk to coagulate and curdle; as it is, the temperature of the mixture rises, and every effort must be made to keep it down; the constant stirring and cool mortar help with that quite well. Finally, the now created milk of roses should be strained.
The almond residue may be washed with a few ounces of fresh rose-water, in order to prevent any loss in bulk to the whole given quantity. The newly-formed milk should be placed into a bottle having a tap in it about a quarter of an inch from the bottom. After standing perfectly quiet for twenty-four hours it is fit to bottle. All the above precautions being taken, the milk of roses will keep any time without precipitate or creamy supernatation. These directions apply to all the other forms of milk now given.
The almond leftover can be rinsed with a few ounces of fresh rosewater to avoid losing any bulk from the total amount. The newly made milk should be put into a bottle with a tap about a quarter of an inch from the bottom. After sitting still for twenty-four hours, it's ready to be bottled. If all these precautions are followed, the rose milk can be stored indefinitely without any sediment or creamy layer forming on top. These instructions apply to all the other types of milk mentioned later.
Almond Milk.
Bitter almonds (blanched), | 10 oz. | |
Distilled (or rose) water, | 1 quart. | |
Alcohol (60 o.p.), | 3/4 pint.[F] | |
Otto of almonds, | 1/2 drachm. | |
" bergamot, | 2 drachms. | |
Wax, spermaceti, | } | |
Almond oil, curd soap, | } each, | 1/2 oz. |
Elderberry milk.
Sweet almonds, | 4 oz. |
Elder-flower water, | 1 pint. |
Alcohol (60 o.p.), | 8 oz. |
Oil of elder flowers, prepared by maceration, | 1/2 oz. |
Wax, sperm, soap, each, | 1/2 oz. |
Dandelion Milk.
Sweet almonds, | 4 oz. | |
Rose-water, | 1 pint. | |
Expressed juice of dandelion root, | 1 oz. | |
Esprit tubereuse, | 8 oz. | |
Green oil, wax, | } | |
Curd soap, | } each | 1/2 oz. |
Let the juice of the dandelion be perfectly fresh pressed; as it is in itself an emulsion, it may be put into the mortar after the almonds are broken up, and stirred with the water and spirit in the usual manner.
Let the juice of the dandelion be freshly pressed; since it’s an emulsion, it can be added to the mortar after the almonds are crushed, and mixed with the water and spirit as usual.
Cucumber Milk.
Sweet almonds, | 4 oz. | |
Expressed juice of cucumbers, | 1 pint. | |
Spirit (60 o.p.), | 8 oz. | |
Essence of cucumbers, | 1/4 pint. | |
Green oil, wax, | } | |
Curd soap, | } each | 1/2 oz. |
Raise the juice of the cucumbers to the boiling point for half a minute, cool it as quickly as possible, then strain through fine muslin; proceed to manipulate in the usual manner.
Bring the cucumber juice to a boil for half a minute, cool it down as quickly as you can, then strain it through fine muslin; then continue to work with it as usual.
Cucumber Essence.
Break up in a mortar 28 lbs. of good fresh cucumbers; with the pulp produced mix 2 pints rectified spirit (sp. gr. .837), and allow the mixture to stand for a day and night; then distil the whole, and draw off a pint and a half. The distillation may be continued so as to obtain another pint fit for ulterior purposes.
Break up 28 lbs. of fresh, good cucumbers in a mortar; mix the pulp with 2 pints of rectified spirit (specific gravity .837), and let the mixture sit for a day and a night. Then distill the entire mixture and collect a pint and a half. You can continue the distillation to get another pint for later use.
Pistachio Cream. (Milk of Pistachio Nuts.)
Pistachio nuts, | 3 oz. | |
Orange-flower water, | 3-1/4 pints. | |
Esprit neroli, | 3/4 pint. | |
Palm soap, | } | |
Green oil, wax, | } each, | 1 oz. |
Spermaceti, | } |
Virginal Milk.
Rose-water, | 1 quart. |
Tincture benzoin, | 1/2 oz. |
Add the water very slowly to the tincture; by so doing an opalescent milky fluid is produced, which will retain its consistency for many years; by reversing this operation, pouring the tincture into the water, a cloudy precipitate of the resinous matter ensues, which does not again become readily suspended in the water.
Add the water very slowly to the tincture; doing this creates a milky, opalescent liquid that will keep its consistency for many years. If you reverse this process and pour the tincture into the water, a cloudy residue of the resinous matter forms, which doesn’t easily mix back into the water.
Elderflower Extract.
Elder-flower water, | 1 quart. |
Tincture benzoin, | 1 oz. |
Manipulate as for virgin's milk.
Manipulate like for breast milk.
Similar compounds may, of course, be made with orange-flower and other waters.
Similar compounds can, of course, be made with orange flower water and other floral waters.
SECTION XI.
COLD CREAM.
Galen, the celebrated physician of Pergamos, in Asia, but who distinguished himself at Athens, Alexandria, and Rome, about 1700 years ago, was the inventor of that peculiar unguent, a mixture of grease and water, which is now distinguished as cold cream in perfumery, and as Ceratum Galeni in Pharmacy.
Galen, the famous physician from Pergamos in Asia, who made a name for himself in Athens, Alexandria, and Rome around 1700 years ago, was the creator of a unique ointment, a blend of grease and water, which is now known as cold cream in cosmetics and as Ceratum Galeni in pharmacy.
The modern formula for cold cream is, however, quite a different thing to that given in the works of Galen in point of odor and quality, although substantially the same—grease and water. In perfumery there are several kinds of cold cream, distinguished by their odor, such as that of camphor, almond, violet, roses, &c. Cold cream, as made by English perfumers, bears a high reputation, not only at home, but throughout Europe; the quantity exported, and which can only be reckoned by jars in hundreds of dozens, and the repeated announcements that may be seen in the shops on the Continent, in Germany, France, and Italy, of "Cold Crême Anglaise," is good proof of the estimation in which it is held.
The modern cold cream formula is quite different from what Galen described in terms of scent and quality, even though it's basically the same—grease and water. In the world of perfumery, there are several types of cold cream, each distinguished by its scent, like camphor, almond, violet, roses, etc. Cold cream made by English perfumers is highly regarded, not just in Britain but all across Europe; the amount exported can only be counted in jars by the hundreds, and the frequent advertisements in shops in Germany, France, and Italy for "Cold Crême Anglaise" clearly show how valued it is.
Rose Cold Cream.
Almond oil, | 1 lb. |
Rose-water, | 1 lb. |
White wax, } | |
spermaceti, } each, | 1 oz. |
Otto of roses, | 1/2 drachm. |
Manipulation.—Into a well-glazed thick porcelain vessel, which should be deep in preference to shallow, and capable of holding twice the quantity of cream that is to be made, place the wax and sperm; now put the jar into a boiling bath of water; when these materials are melted, add the oil, and again subject the whole to heat until the flocks of wax and sperm are liquefied; now remove the jar and contents, and set it under a runner containing the rose-water: the runner may be a tin can, with a small tap at the bottom, the same as used for the manufacture of milk of roses. A stirrer must be provided, made of lancewood, flat, and perforated with holes the size of a sixpence, resembling in form a large palette-knife. As soon as the rose-water is set running, the cream must be kept agitated until the whole of the water has passed into it; now and then the flow of water must be stopped, and the cream which sets at the sides of the jar scraped down, and incorporated with that which remains fluid. When the whole of the water has been incorporated, the cream will be cool enough to pour into the jars for sale; at that time the otto of rose is to be added. The reason for the perfume being put in at the last moment is obvious—the heat and subsequent agitation would cause unnecessary loss by evaporation. Cold cream made in this way sets quite firmly in the jars into which it is poured, and retains "a face" resembling pure wax, although one-half is water retained in the interstices of the cream. When the pots are well glazed, it will keep good for one or two years. If desired for exportation to the East or West Indies, it should always be sent out in stoppered bottles.
Manipulation.—In a well-glazed, thick porcelain container that’s deep rather than shallow and holds twice the amount of cream you want to make, add the wax and sperm. Place the jar in a boiling water bath. Once these materials have melted, stir in the oil and heat the mixture again until the wax and sperm are fully liquefied. Remove the jar and its contents, and position it under a runner that holds the rose-water. The runner can be a tin can with a small tap at the bottom, similar to what’s used for making rose milk. You’ll need a stirrer made from lancewood, which should be flat and have holes the size of a sixpence, resembling a large palette knife. As soon as the rose-water starts to flow, keep stirring the cream until all of the water has been absorbed. Occasionally, stop the water flow and scrape down the cream that settles on the sides of the jar, mixing it back into the fluid part. When all the water has been mixed in, the cream will be cool enough to pour into jars for sale; at this point, add the otto of rose. The reason for adding the perfume last is clear—the heat and constant stirring would cause it to evaporate unnecessarily. Cream made in this way sets firmly in the jars and has a surface that looks like pure wax, even though half of it is water trapped in the cream's structure. When the pots are well glazed, they can last for one or two years. If you plan to export it to the East or West Indies, always send it in stoppered bottles.
Almond Cold Cream
Is prepared precisely as the above; but in place of otto of roses otto of almonds is used.
Is prepared exactly as mentioned above; but instead of rose oil, almond oil is used.
Violet Cold Cream.
Huile violette, | 1 lb. |
Rose-water, | 1 lb. |
Wax and spermaceti, each, | 1 oz. |
Otto of almonds, | 5 drops. |
Violet Cold Cream. Knockoff.
Almond oil, | 3/4 lb. |
Huile cassie, | 1/4 lb. |
Rose-water, | 1 lb. |
Sperm and wax, | 1 oz. |
Otto of almonds, | 1/4 drachm. |
This is an elegant and economical preparation, generally admired.
This is a stylish and cost-effective dish, widely appreciated.
Tuberose, Jasmine, and Orange Blossom Cold Creams.
Are prepared in similar manner to violet (first form); they are all very exquisite preparations, but as they cost more than rose cold cream, perfumers are not much inclined to introduce them in lieu of the latter.
Are prepared in a similar way to violet (first form); they are all very delicate preparations, but since they cost more than rose cold cream, perfumers aren't very eager to use them instead of the latter.
Camphor Cold Cream. (Otherwise Camphor Ice.)
Almond oil, | 1 lb. |
Rose-water, | 1 lb. |
Wax and Spermaceti, | 1 oz. |
Camphor, | 2 oz. |
Otto of rosemary, | 1 drachm. |
Cucumber Chill Cream. (Crême de Concombre.)
Almond oil, | 1 lb. |
Green oil, | 1 oz. |
Juice of cucumber, | 1 lb. |
Wax and sperm, each, | 1 oz. |
Otto of neroli, | 1/4 drachm. |
The cucumber juice is readily obtained by subjecting the fruit to pressure in the ordinary tincture press. It must be raised to a temperature high enough to coagulate the small portion of albumen which it contains, and then strained through fine linen, as the heat is detrimental to the odor on account of the great volatility of the otto of cucumber. The following method may be adopted with advantage:—Slice the fruit very fine with a cucumber-cutter, and place them in the oil; after remaining together for twenty-four hours, repeat the operation, using fresh fruit in the strained oil; no warmth is necessary, or at most, not more than a summer heat; then proceed to make the cold cream in the usual manner, using the almond oil thus odorized, the rose-water, and other ingredients in the regular way, perfuming, if necessary, with a little neroli.
You can easily get cucumber juice by pressing the fruit in a regular tincture press. It needs to be heated enough to coagulate the small amount of albumen it contains, and then it should be strained through fine linen, as the heat can harm the scent due to the highly volatile cucumber oil. A beneficial method you can try is: slice the fruit very thin with a cucumber cutter and soak them in oil. After letting them sit together for twenty-four hours, repeat the process using fresh fruit in the strained oil; no heat is needed, or just a light summer warmth at most. Then, proceed to make the cold cream as usual, using the scented almond oil, rose water, and other regular ingredients, and add a little neroli for fragrance if needed.
Another and commoner preparation of cucumber is found among the Parisians, which is lard simply scented with the juice from the fruit, thus:—The lard is liquefied by heat in a vessel subject to a water-bath; the cucumber juice is then stirred well into it; the vessel containing the ingredients is now placed in a quiet situation to cool. The lard will rise to the surface, and when cold must be removed from the fluid juice; the same manipulation being repeated as often as required, according to the strength of odor of the fruit desired in the grease.
Another common way to prepare cucumber among Parisians is to infuse lard with the juice of the fruit. Here’s how: the lard is melted using a double boiler; then, the cucumber juice is mixed in thoroughly. The container with the mixture is set aside to cool in a stable place. Once it cools, the lard will float to the top, and when it's cold, it should be separated from the cucumber juice. This process can be repeated as many times as needed to achieve the desired scent intensity in the lard.
Pivers' Cucumber Pomade.
Benzoinated lard, | 6 lbs. |
Spermaceti, | 2 lbs. |
Essence of cucumbers, | 1 lb. |
Melt the stearine with the lard, then keep it constantly in motion while it cools, now beat the grease in a mortar, gradually adding the essence of cucumbers; continue to beat the whole until the spirit is evaporated, and the pomade is beautifully white.
Melt the stearine with the lard, then keep it moving the whole time as it cools. Next, mash the grease in a mortar, slowly mixing in the cucumber essence. Keep mixing until the alcohol evaporates and the pomade turns a nice white color.
Melons and other similar fruit will scent grease treated in the same way. (See "Essence of Cucumbers," p. 204.)
Melons and other similar fruits will give off a scent when grease is treated the same way. (See "Essence of Cucumbers," p. 204.)
Divine Pomade.
Among the thousand and one quack nostrums, pomade divine, like James's powder, has obtained a reputation far above the most sanguine expectations of its concoctors. This article strictly belongs to the druggist, being sold as a remedial agent; nevertheless, what is sold is almost always vended by the perfumer. It is prepared thus:—
Among the countless fake remedies, pomade divine, like James's powder, has gained a reputation that exceeds the highest hopes of its creators. This product is technically a pharmacy item, marketed as a healing agent; however, what’s actually sold is usually offered by the perfumer. It is made like this:—
Spermaceti, | 1/4 lb. |
Lard, | 1/2 lb. |
Almond oil, | 3/4 lb. |
Gum benzoin, | 1/4 lb. |
Vanilla beans, | 1-1/2 oz. |
Digest the whole in a vessel heated by a water-bath at a temperature not exceeding 90° C. After five or six hours it is fit to strain, and may be poured into the bottles for sale. (Must be stamped if its medicinal qualities are stated.)
Heat the entire mixture in a water bath at a temperature no higher than 90° C. After five to six hours, it's ready to strain and can be poured into bottles for sale. (It must be stamped if its medicinal benefits are mentioned.)
Almond Bites.
Purified suet, | 1 lb. |
White wax, | 1/2 lb. |
Otto of almonds, | 1 drachm. |
" cloves, | 1/4 drachm. |
Camphor Balls.
Purified suet, | 1 lb. |
White wax, | 1/2 lb. |
Camphor, | 1/4 lb. |
Otto of French lavender or rosemary, | 1/2 oz. |
Both the above articles are sold either white or colored with alkanet root. When thoroughly melted, the material is cast in a mould; ounce gallipots with smooth bottoms answer very well for casting in. Some venders use only large pill-boxes.
Both of the articles mentioned above are available in either white or colored with alkanet root. When fully melted, the material is poured into a mold; ounce gallipots with smooth bottoms work really well for this. Some sellers only use large pill-boxes.
Camphor Balm.
Sweet almond oil, | 1/2 lb. | |
Purified lard, | 1/4 lb. | |
Wax and spermaceti, | } | |
Camphor, | } each, | 1 oz. |
Glycerin Balm.
White wax, | } | |
Spermaceti, | } each, | 1 oz. |
Almond oil, | 1/2 lb. | |
Glycerine, | 2 oz. | |
Otto of roses, | 1/4 drachm. |
Of the remedial action of any of the above preparations we cannot here discuss; in giving the formulæ, it is enough for us that they are sold by perfumers.
Of the corrective effects of any of the above products, we can't discuss here; when providing the formulas, it’s sufficient for us to know that they are sold by perfumers.
Rose Lip Balm.
Almond oil, | 1/2 lb. |
Spermaceti and wax, each, | 2 oz. |
Alkanet root, | 2 oz. |
Otto of roses, | 1/4 drachm. |
Place the wax, sperm, and oil on to the alkanet root in a vessel heated by steam or water-bath; after the materials are melted, they must digest on the alkanet to extract its color for at least four or five hours; finally, strain through fine muslin, then add the perfume just before it cools.
Place the wax, sperm, and oil onto the alkanet root in a container heated by steam or a water bath; after the materials melt, they should steep on the alkanet to extract its color for at least four or five hours; finally, strain through fine muslin, then add the fragrance just before it cools.
White Lip Balm.
Almond oil, | 1/4 lb. |
Wax and Spermaceti, each, | 1 oz. |
Otto of almonds, | 1/2 drachm. |
" geranium, | 1/4 " |
After lip salve is poured into the pots and got cold, a red-hot iron must be held over them for a minute or so, in order that the heat radiated from the irons may melt the surface of the salve and give it an even face.
After the lip balm is poured into the containers and has cooled, a heated iron needs to be held over them for about a minute to let the heat from the iron melt the surface of the balm and create a smooth finish.
Lip Balm
Is made simply of equal parts of lard and suet, colored with alkanet root, and perfumed with an ounce of bergamot to every pound of salve.
Is made simply of equal parts of lard and suet, colored with alkanet root, and scented with an ounce of bergamot for every pound of salve.
SECTION XII.
POMADES AND OILS.
The name of pomatum is derived from pomum, an apple, because it was originally made by macerating over-ripe apples in grease.
The term pomatum comes from pomum, which means apple, because it was first created by soaking overripe apples in fat.
If an apple be stuck all over with spice, such as cloves, then exposed to the air for a few days, and afterwards macerated in purified melted lard, or any other fatty matter, the grease will become perfumed. Repeating the operation with the same grease several times, produces real "pomatum."
If you cover an apple completely with spices like cloves, let it sit in the air for a few days, and then soak it in purified melted lard or any other fatty substance, the fat will absorb the fragrance. Doing this a few times with the same fat will create actual "pomatum."
According to a recipe published more than a century ago the form given is:—"Kid's grease, an orange sliced, pippins, a glass of rose-water, and half a glass of white wine, boiled and strained, and at last sprinkled with oil of sweet almonds." The author, Dr. Quincy, observes, that "the apple is of no significance at all in the recipe," and, like many authors of the present day, concludes that the reader is as well acquainted with the subject as the writer, and therefore considers that the weights or bulk of the materials in his recipe are, likewise, of no significance. According to ancient writers, unguent, pomatum, ointment, are synonymous titles for medicated and perfumed greases. Among biblical interpreters, the significant word is mostly rendered "ointment;" thus we have in Prov. 27:9, "Ointment and perfume rejoice the heart;" in Eccles. 9:8, "Let thy head lack no ointment."
According to a recipe published over a hundred years ago, the ingredients are: “kid's grease, an orange sliced, pippins, a glass of rose-water, and half a glass of white wine, boiled and strained, and finally sprinkled with sweet almond oil.” The author, Dr. Quincy, notes that “the apple is not important at all in the recipe,” and like many contemporary authors, assumes that the reader knows as much about the topic as he does, so he thinks that the amounts or sizes of the ingredients in his recipe are also unimportant. According to ancient writers, unguent, pomatum, and ointment are all terms for medicated and scented greases. Among biblical scholars, the important word is usually translated as “ointment;” for instance, in Prov. 27:9, “Ointment and perfume rejoice the heart;” and in Eccles. 9:8, “Let thy head lack no ointment.”
Perfumers, acting upon their own or Dr. Quincy's advice, pay no regard to the apples in the preparation of pomatum, but make it by perfuming lard or suet, or a mixture of wax, spermaceti, and oil, or some of them or all blended, to produce a particular result, according to the name that it bears.
Perfumers, following their own ideas or Dr. Quincy's recommendations, ignore the apples when making pomade. Instead, they create it by scenting lard or suet, or by mixing wax, spermaceti, and oil, whether individually or combined, to achieve a specific outcome based on its name.
The most important thing to consider in the manufacture of pomatum, &c., is to start off with a perfectly inodorous grease, whatever that grease may be.
The most important thing to consider in making pomatum, etc., is to start with a completely odorless grease, whatever that grease may be.
Inodorous lard is obtained thus:—Take, say 28 lbs. of perfectly fresh lard, place it in a well-glazed vessel, that can be submitted to the heat of a boiling salt-water bath, or by steam under a slight pressure; when the lard is melted, add to it one ounce of powdered alum and two ounces of table salt; maintain the heat for some time, in fact till a scum rises, consisting in a great measure of coagulated proteine compounds, membrane, &c., which must be skimmed off; when the liquid grease appears of a uniform nature it is allowed to grow cold.
Inodorous lard is made like this: Take about 28 lbs. of perfectly fresh lard and put it in a well-glazed container that can handle the heat of a boiling salt-water bath or steam under slight pressure. Once the lard is melted, add one ounce of powdered alum and two ounces of table salt. Keep the heat on for a while, until a scum forms, mostly made up of coagulated protein compounds, membranes, etc., which should be skimmed off. When the liquid grease looks uniform, let it cool down.
The lard is now to be washed. This is done in small portions at a time, and is a work of much labor, which, however, is amply repaid by the result. About a pound of the grease is now placed on a slate slab a little on the incline, a supply of good water being set to trickle over it; the surface of the grease is then constantly renewed by an operative working a muller over it, precisely as a color-maker grinds paints in oil. In this way the water removes any traces of alum or salt, also the last traces of nitrogenous matter. Finally, the grease, when the whole is washed in this way, is remelted, the heat being maintained enough to drive off any adhering water. When cold it is finished.
The lard is now ready to be washed. This is done in small batches and is quite labor-intensive, but the end result is well worth the effort. About a pound of the grease is placed on a slightly sloped slate slab, with a steady trickle of clean water flowing over it; the surface of the grease is constantly renewed by a worker using a muller, just like a pigment maker grinds paints in oil. This process allows the water to remove any remaining traces of alum or salt, as well as any last bits of nitrogenous matter. Ultimately, after washing, the grease is remelted, with the heat kept high enough to evaporate any remaining water. Once cooled, it's ready for use.
Although purifying grease in this way is troublesome, and takes a good deal of time, yet unless done so, it is totally unfit for perfuming with flowers, because a bad grease will cost more in perfume to cover its mal odeur than the expense of thus deodorizing it. Moreover, if lard be used that "smells of the pig," it is next to impossible to impart to it any delicate odor; and if strongly perfumed by the addition of ottos, the unpurified grease will not keep, but quickly becomes rancid. Under any circumstances, therefore, grease that is not perfectly inodorous is a very expensive material to use in the manufacture of pomades.
Although purifying grease this way is a hassle and takes a lot of time, if it’s not done, it’s completely unsuitable for perfume with flowers, because poor-quality grease will require more perfume to mask its bad smell than the cost of deodorizing it. Additionally, if lard is used that “smells like pork,” it’s almost impossible to give it any subtle scent; and if it’s heavily perfumed with essences, the unpurified grease won’t last and will quickly go rancid. So, under any circumstances, grease that isn’t perfectly odorless is a very costly material for making pomades.
In the South and flower-growing countries, where the fine pomades are made by Enfleurage, or by Maceration[G] (see pp. 37, 38), the purification of grease for the purpose of these manufactures is of sufficient importance to become a separate trade.
In the southern regions and flower-growing countries, where high-quality pomades are produced through Enfleurage or Soaking[G] (see pp. 37, 38), the process of purifying grease for these products is significant enough to be recognized as its own trade.
The purification of beef and mutton suet is in a great measure the same as that for lard: the greater solidity of suets requires a mechanical arrangement for washing them of a more powerful nature than can be applied by hand labor. Mr. Ewen, who is undoubtedly the best fat-purifier in London, employs a stone roller rotating upon a circular slab; motion is given to the roller by an axle which passes through the centre of the slab, or rather stone bed, upon which the suet is placed; being higher in the centre than at the sides, the stream of water flows away after it has once passed over the suet; in other respects the treatment is the same as for lard. These greases used by perfumers have a general title of "body," tantamount to the French nomenclature of corps; thus we have pomades of hard corps (suet), pomades of soft corps (lard). For making extraits, such as extrait de violette, jasmin, the pomades of hard corps are to be preferred; but when scented pomade is to be used in fabrication of unguents for the hair, pomades of soft corps are the most useful.
The process for purifying beef and mutton fat is mostly the same as that for lard: the firmer texture of the fats requires a more powerful mechanical method for cleaning them than what can be achieved by hand. Mr. Ewen, who is definitely the best fat purifier in London, uses a stone roller that spins on a circular slab; the roller is turned by an axle that runs through the center of the slab, or stone bed, where the fat is placed. The slab is higher in the center than at the sides, allowing the water to drain away after flowing over the fat; otherwise, the process is the same as it is for lard. The fats used by perfumers are generally referred to as "body," similar to the French term corps; so we have hard body pomades (suet) and soft body pomades (lard). For making extraits, like extrait de violette and jasmin, hard body pomades are preferred; however, when scented pomade is needed for making hair ointments, soft body pomades are more useful.
The method of perfuming grease by the direct process with flowers having already been described under the respective names of the flowers that impart the odor thereto, it remains now only to describe those compounds that are made from them, together with such incidental matter connected with this branch of perfumery as has not been previously mentioned.
The process of adding fragrance to grease directly using flowers, which has already been detailed under the specific names of the flowers that provide the scent, now just leaves us to discuss the products made from them, along with any related topics in this area of perfumery that haven't been covered before.
Acacia Pomade, commonly called Cassie Pomatum, is made with a purified body-grease, by maceration with the little round yellow buds of the Acacia Farnesiana.
Acacia Pomade, often referred to as Cassie Pomatum, is created using a refined body grease, by soaking it with the small round yellow buds of the Acacia Farnesiana.
Black currant leaves, and which the French term cassie, have an odor very much resembling cassie (acacia), and are used extensively for adulterating the true acacia pomades and oils. The near similarity of name, their analogous odor (although the plants have no botanical connection), together with the word cassia, a familiar perfume in England, has produced generally confused ideas in this country as to the true origin of the odor now under discussion. Cassie, casse, cassia, it will be understood now, are three distinct substances; and in order to render the matter more perspicuous in future, the materials will always be denominated Acacia, if prepared from the Acacia Farnesiana; Casse, when from black currant; and Cassia, if derived from the bark of the Cinnamomum Cassia.
Black currant leaves, which the French call cassie, have a scent that closely resembles cassie (acacia) and are widely used to adulterate genuine acacia pomades and oils. The similar names and comparable scents (even though the plants aren't botanically related), along with the word cassia, a well-known perfume in England, have led to a lot of confusion in this country about the true source of the scent being discussed. To clarify this in the future, we will always refer to these materials as Acacia when made from Acacia Farnesiana; Casse when from black currant; and Cassia when derived from the bark of Cinnamomum Cassia.
Benzoin Pomade & Oil.
Benzoic acid is perfectly soluble in hot grease. Half an ounce of benzoic acid being dissolved in half a pint of hot olive or almond oil, deposits on cooling beautiful acicular crystals, similar to the crystals that effloresce from vanilla beans; a portion of the acid, however, remains dissolved in the oil at the ordinary temperature, and imparts to it the peculiar aroma of benzoin; upon this idea is based the principle of perfuming grease with gum benzoin by the direct process, that is, by macerating powdered gum benzoin in melted suet or lard for a few hours, at a temperature of about 80° C. to 90° C. Nearly all the gum-resins give up their odoriferous principle to fatty bodies, when treated in the same way; this fact becoming generally known, will probably give rise to the preparation of some new remedial ointments, such as Unguentum myrrhæ, Unguentum assafœtida, and the like.
Benzoic acid dissolves easily in hot grease. When you dissolve half an ounce of benzoic acid in half a pint of hot olive or almond oil, it forms beautiful needle-like crystals as it cools, similar to the ones that appear from vanilla beans. However, some of the acid stays dissolved in the oil at room temperature, giving it the unique scent of benzoin. This concept is the basis for perfuming grease with gum benzoin using the direct method, which involves soaking powdered gum benzoin in melted suet or lard for a few hours at a temperature between 80° C and 90° C. Almost all gum-resins release their fragrant compounds into fatty substances when treated in this way; as this fact becomes more widely known, it will likely lead to the creation of new medicinal ointments, such as Unguentum myrrhæ, Unguentum assafœtida, and others like them.
Tonquin beans, | 1/2 lb. |
Fat or oil, | 4 lbs. |
Strain through fine muslin; when cold, the grease will have a fine odor of the beans.
Strain it through fine muslin; once it’s cool, the grease will have a pleasant scent of the beans.
Vanilla Oil and Hair Pomade.
Vanilla pods, | 1/4 lb. |
Fat or oil, | 4 lbs. |
Macerate at a temperature of 25° C. for three or four days; finally strain.
Soak at a temperature of 25° C. for three or four days; then strain.
These pomatums and oils, together with the French pomades and huiles already described, constitute the foundation of the preparations of all the best hair greases sold by perfumers. Inferior scented pomatums and oils are prepared by perfuming lard, suet, wax, oil, &c., with various ottos; the results, however, in many instances more expensive than the foregoing, are actually inferior in their odor or bouquet—for grease, however slightly perfumed by maceration or enfleurage with flowers, is far more agreeable to the olfactory nerve than when scented by ottos.
These pomatums and oils, along with the French pomades and oils already mentioned, form the basis of the top hair greases sold by perfumers. Lower quality scented pomatums and oils are made by adding fragrances to lard, suet, wax, oil, etc., using various essential oils; however, in many cases, these are actually pricier than the better options but turn out to have a worse scent or aroma—because grease, even when just lightly scented by soaking or extracting with flowers, is much more pleasant to the nose than when it's artificially scented with essential oils.
The undermentioned greases have obtained great popularity, mainly because their perfume is lasting and flowery.
The following greases have become very popular, mainly because their scent is long-lasting and floral.
Bear's Grease pomade.
The most popular and "original" bears' grease is made thus:—
The most popular and "original" bear grease is made like this:—
Huile de rose, | } | |
" fleur d'orange, | } | |
" acacia, | } of each, | 1/2 lb. |
" tubereuse and jasmin, | } | |
Almond oil, | 10 lbs. | |
Lard, | 12 lbs. | |
Acacia pomade, | 2 lbs. | |
Otto of bergamot, | 4 oz. | |
" cloves, | 2 oz. |
Melt the solid greases and oils together by a water-bath, then add the ottos.
Melt the solid fats and oils together using a water bath, then add the ottos.
Bears' grease thus prepared is just hard enough to "set" in the pots at a summer heat. In very warm weather, or if required for exportation to the East or West Indies, it is necessary to use in part French pomatums instead of oils, or more lard and less almond oil.
Bears' grease, when prepared, is just firm enough to "set" in the containers during summer heat. In very hot weather, or if it needs to be shipped to the East or West Indies, it's necessary to use some French pomades instead of oils, or to use more lard and less almond oil.
Circassian Cream.
Purified lard, | 1 lb. |
Benzoin suet, | 1 lb. |
French rose pomatum, | 1/2 lb. |
Almond oil, colored with alkanet, | 2 lbs. |
Otto of rose, | 1/4 oz. |
Flower Balm.
French rose pomatum, | 12 oz. |
" violet pomatum, | 12 oz. |
Almond oil, | 2 lbs. |
Otto of bergamot, | 1/4 oz. |
Crystallized oil. (First quality).
Huile de rose, | 1 lb. |
" tubereuse, | 1 lb. |
" fleur d'orange, | 1/2 lb. |
Spermaceti, | 8 oz. |
Crystallized Oil. (Second quality.)
Almond, | 2-1/2 lbs. |
Spermaceti, | 1/2 lb. |
Otto of lemon, | 3 oz. |
Melt the spermaceti in a vessel heated by a water-bath, then add the oils; continue the heat until all flocks disappear; let the jars into which it is poured be warm; cool as slowly as possible, to insure good crystals; if cooled rapidly, the mass congeals without the appearance of crystals. This preparation has a very nice appearance, and so far sells well; but its continued use for anointing the hair renders the head scurfy; indeed, the crystals of sperm may be combed out of the hair in flakes after it has been used a week or two.
Melt the spermaceti in a container heated with a water bath, then add the oils; keep heating until all lumps disappear. Make sure the jars you pour it into are warm. Allow it to cool as slowly as possible to ensure good crystals form; if it cools too quickly, it will harden without forming crystals. This preparation looks very nice and sells well; however, using it regularly for hair treatment can make the scalp flaky. In fact, after using it for a week or two, you can comb out flakes of sperm crystals from the hair.
Castor Oil Ointment.
Tubereuse pomatum, | 1 lb. |
Castor oil, | 1/2 lb. |
Almond oil, | 1/2 lb. |
Otto of bergamot, | 1 oz. |
Neroli Balsam.
French rose pomatum, | 1/2 lb. |
" jasmine pomatum, | 1/2 lb. |
Almond oil, | 3/4 lb. |
Otto of neroli, | 1 drachm. |
Bone Marrow Cream.
Purified lard, | 1 lb. |
Almond oil, | 1 lb. |
Palm oil, | 1 oz. |
Otto of cloves, | 1/2 drachm. |
" bergamot, | 1/2 oz. |
" lemon, | 1-1/2 oz. |
Marrow Pomade.
Purified lard, | 4 lbs. |
" suet, | 2 lbs. |
Otto of lemon, | 1 oz. |
" bergamot, | 1/2 oz. |
" cloves, | 3 drachms. |
Melt the greases, then beat them up with a whisk or flat wooden spatula for half an hour or more; as the grease cools, minute vesicles of air are inclosed by the pomatum, which not only increase the bulk of the mixtures, but impart a peculiar mechanical aggregation, rendering the pomatum light and spongy; in this state it is obvious that it fills out more profitably than otherwise.
Melt the fats, then whisk them vigorously with a whisk or flat wooden spatula for half an hour or longer; as the fats cool, tiny air bubbles get trapped in the pomade, which not only increases the volume of the mixture but also gives it a unique texture, making the pomade light and fluffy; in this state, it’s clear that it’s more effective than if it weren't.
Common Violet Balm.
Purified lard, | 1 lb. |
Washed acacia pomatum, | 6 oz. |
" rose pomatum, | 4 oz. |
Manipulate as for marrow pomatum.
Manipulate like for hair pomade.
In all the cheap preparations for the hair, the manufacturing perfumers used the washed French pomatums and the washed French oils for making their greases. Washed pomatums and washed oils are those greases that originally have been the best pomatums and huiles prepared by enfleurage and by maceration with the flowers; which pomades and huiles have been subject to digestion in alcohol for the manufacture of essences for the handkerchief. After the spirit has been on the pomatums, &c., it is poured off; the residue is then called washed pomatum, and still retain an odor strong enough for the manufacture of most hair greases.
In all the cheap hair products, manufacturers used washed French pomades and washed French oils to create their greases. Washed pomades and oils are those greases that were originally the best pomades and oils made by enfleurage and maceration with flowers; these pomades and oils have been processed in alcohol to make essences for handkerchiefs. After the alcohol has been applied to the pomades, etc., it's poured off; the leftover material is then called washed pomade, and still retains a scent strong enough for most hair greases.
For pomatums of other odors it is only necessary to substitute rose, jasmine, tubereuse, and others, in place of the acacia pomatum in the above formulæ.
For pomatums with different scents, you just need to replace the acacia pomatum in the formulas above with rose, jasmine, tuberose, and others.
Millefleurs Double Pomade.
Rose, jasmine, fleur d'orange, violet, tubereuse, &c., are all made in winter, with two-thirds best French pomatum, one-third best French oils; in summer, equal parts.
Rose, jasmine, orange blossom, violet, tuberose, etc., are all made in winter using two-thirds of the best French pomade and one-third of the best French oils; in summer, mix equal parts.
Heliotrope Pomade.
French rose pomade, | 1 lb. |
Vanilla oil, | 1/2 lb. |
Huile de jasmine, | 4 oz. |
" tubereuse, | 2 oz. |
" fleur d'orange, | 2 oz. |
Otto of almonds, | 6 drops. |
" cloves, | 3 drops. |
Antique Oil. (A la Heliotrope.)
Same as the above, substituting rose oil for the pomade.
Same as above, replacing pomade with rose oil.
Philocome.
The name of this preparation, which is a compound of Greek and Latin, signifying "a friend to the hair," was first introduced by the Parisian perfumers; and a very good name it is, for Philocome is undoubtedly one of the best unguents for the hair that is made.
The name of this product, which combines Greek and Latin and means "a friend to the hair," was first used by Parisian perfumers; and it's a great name because Philocome is definitely one of the best hair ointments made.
Philocome. (First quality.)
White wax, | 10 oz. |
Fresh rose-oil, | 1 lb. |
" acacia oil, | 1/2 lb. |
" jasmine oil, | 1/2 lb. |
" fleur d'orange oil, | 1 lb. |
" tubereuse oil, | 1 lb. |
Melt the wax in the huiles by a water-bath, at the lowest possible temperature. Stir the mixture as it cools; do not pour out the Philocome until it is nearly cool enough to set; let the jars, bottles, or pots into which it is filled for sale be slightly warmed, or at least of the same temperature as the Philocome, otherwise the bottles chill the material as it is poured in, and make it appear of an uneven texture.
Melt the wax in the oils using a water bath, keeping the temperature as low as possible. Stir the mixture as it cools; don’t pour out the Philocome until it's almost cool enough to set. Make sure the jars, bottles, or pots you’re filling for sale are slightly warmed or at least at the same temperature as the Philocome; otherwise, the bottles will cool down the mixture as it's poured in, causing it to look uneven in texture.
Philocome. (Second quality.)
White wax, | 5 oz. |
Almond oil, | 2 lbs. |
Otto of bergamot, | 1 oz. |
" lemon, | 1/2 oz. |
" lavender, | 2 drachms. |
" cloves, | 1 drachm. |
Fluid Philocome.
Take 1 ounce of wax to 1 pound of oil.
Take 1 ounce of wax for every 1 pound of oil.
Hungarian Ointment. (For the Moustache.)
Lead plaster, | 1 lb. |
Acacia huile, | 2 oz. |
Otto of roses, | 2 drachms. |
" cloves, | 1 drachm. |
" almonds, | 1 drachm. |
Hard or Stick Pomades.
Purified suet, | 1 lb. |
White wax, | 1 lb. |
Jasmine pomatum, | 1/2 lb. |
Tubereuse pomatum, | 1/2 lb. |
Otto of rose, | 1 drachm. |
Another Format,—cheaper.
Suet, | 1 lb. |
Wax, | 1/2 lb. |
Otto of bergamot, | 1 oz. |
" cassia, | 1 drachm. |
The above recipes produce White Batons. Brown and Black Batons are also in demand. They are made in the same way as the above, but colored with lamp-black or umber ground in oil. Such colors are best purchased ready ground at an artist's colorman's.
The recipes above make White Batons. There is also a demand for Brown and Black Batons. They are made the same way as the ones above but are colored with lamp-black or umber mixed in oil. It's best to buy these colors pre-ground from an artist's supplier.
Black and Brown Beauty.
Such as is sold by Rimmel, is prepared with a nicely-scented soap strongly colored with lamp-black or with umber. The soap is melted, and the coloring added while the soap is soft; when cold it is cut up in oblong pieces.
Such as is sold by Rimmel London is made with a pleasantly scented soap that’s heavily pigmented with lamp-black or umber. The soap is melted, and the dye is mixed in while it's still soft; once it cools, it’s cut into rectangular pieces.
It is used as a temporary dye for the moustache, applied with a small brush and water.
It’s used as a temporary dye for the mustache, applied with a small brush and water.
SECTION XIII.
HAIR DYES AND DEPILATORY.
By way of personal adornment, few practices are of more ancient origin than that of painting the face, dyeing the hair, and blackening the eyebrows and eyelashes.
When it comes to personal decoration, few practices are older than painting the face, dyeing the hair, and darkening the eyebrows and eyelashes.
It is a practice universal among the women of the higher and middle classes in Egypt, and very common among those of the lower orders, to blacken the edge of the eyelids, both above and below the eye, with a black powder, which they term kohhl. The kohhl is applied with a small probe of wood, ivory, or silver, tapering towards the end, but blunt. This is moistened sometimes with rose-water, then dipped in the powder, and drawn along the edges of the eyelids. It is thought to give a very soft expression to the eye, the size of which, in appearance, it enlarges; to which circumstances probably Jeremiah refers when he writes, "Though thou rentest thy face (or thine eyes) with painting, in vain shalt thou make thyself fair."—Jer. 4:30. See also Lane's Modern Egyptians, vol. i, p. 41, et seq.
It is a common practice among women of the upper and middle classes in Egypt, and fairly typical among those from lower classes, to line the edges of their eyelids, both above and below the eye, with a black powder they call kohhl. The kohhl is applied using a small probe made of wood, ivory, or silver, which tapers at the end but is blunt. Sometimes, this probe is moistened with rose water, dipped in the powder, and then drawn along the edges of the eyelids. It is believed to create a very soft expression in the eyes and makes them appear larger, which may be what Jeremiah is referring to when he says, "Though you decorate your face (or your eyes) with makeup, in vain shall you make yourself beautiful."—Jer. 4:30. See also Lane's Modern Egyptians, vol. i, p. 41, et seq.
A singular custom is observable both among Moorish and Arab females—that of ornamenting the face between the eyes with clusters of bluish spots or other small devices, and which, being stained, become permanent. The chin is also spotted in a similar manner, and a narrow blue line extends from the point of it, and is continued down the throat. The eyelashes, eyebrows, and also the tips and extremities of the eyelids, are colored black. The soles, and sometimes other parts of the feet, as high as the ankles, the palms of the hands, and the nails, are dyed with a yellowish-red, with the leaves of a plant called Henna (Lawsonia inermis), the leaf of which somewhat resembles the myrtle, and is dried for the purposes above mentioned. The back of the hand is also often colored and ornamented in this way with different devices. On holidays they paint their cheeks of a red brick color, a narrow red line being also drawn down the temples.
A unique tradition can be seen among both Moorish and Arab women—they decorate their faces between the eyes with clusters of bluish spots or other small designs, which, once stained, become permanent. The chin is also marked in a similar way, and a narrow blue line runs from the tip of it down the throat. The eyelashes, eyebrows, and the edges of the eyelids are painted black. The soles of the feet, and sometimes higher parts up to the ankles, the palms of the hands, and the nails are dyed a yellowish-red using leaves from a plant called Henna (Lawsonia inermis), which resembles myrtle and is dried for these purposes. The back of the hand is often decorated in the same way with various designs. On holidays, they paint their cheeks a brick-red color, and a narrow red line is drawn down the temples.
In Greece, "for coloring the lashes and sockets of the eye they throw incense or gum labdanum on some coals of fire, intercept the smoke which ascends with a plate, and collect the soot. This I saw applied. A girl, sitting cross-legged as usual on a sofa, and closing one of her eyes, took the two lashes between the forefinger and thumb of her left hand, pulled them forward, and then, thrusting in at the external corner a sort of bodkin or probe which had been immersed in the soot, and withdrawing it, the particles previously adhering to the probe remained within the eyelashes."—Chandler's Travels in Greece.
In Greece, "to darken the eyelashes and the eye area, they put incense or gum labdanum on some hot coals, catch the smoke rising with a plate, and gather the soot. I witnessed this firsthand. A girl, sitting cross-legged as usual on a sofa and closing one eye, took the two eyelashes between her left hand's forefinger and thumb, pulled them forward, and then, inserting a kind of bodkin or probe that had been dipped in the soot into the outer corner, pulled it out, leaving the particles that had stuck to the probe on her eyelashes."—Chandler's Travels in Greece.
Dr. Shaw states that among other curiosities that were taken out of the tombs at Sahara relating to Egyptian women, he saw a joint of the common reeds, which contained one of these bodkins and an ounce or more of this powder.
Dr. Shaw says that among other interesting finds taken from the tombs at Sahara related to Egyptian women, he saw a piece of common reeds that held one of these bodkins and an ounce or more of this powder.
Turkish Hair Color.
In Constantinople there are some persons, particularly Armenians, who devote themselves to the preparation of cosmetics, and obtain large sums of money from those desirous of learning this art. Amongst these cosmetics is a black dye for the hair, which, according to Landerer, is prepared in the following manner:—
In Constantinople, there are some people, especially Armenians, who focus on making cosmetics and make a lot of money from those interested in learning this skill. One of these cosmetics is a black hair dye, which, according to Landerer, is made in the following way:—
Finely pulverized galls are kneaded with a little oil to a paste, which is roasted in an iron pan until the oil vapors cease to evolve, upon which the residue is triturated with water into a paste, and heated again to dryness. At the same time a metallic mixture, which is brought from Egypt to the commercial marts of the East, and which is termed in Turkish Rastiko-petra, or Rastik-Yuzi, is employed for this purpose. This metal, which looks like dross, is by some Armenians intentionally fused, and consists of iron and copper. It obtains its name from its use for the coloration of the hair, and particularly the eyebrows—for rastik means eyebrows, and yuzi stone. The fine powder of this metal is as intimately mixed as possible with the moistened gall-mass into a paste, which is preserved in a damp place, by which it acquires the blackening property. In some cases this mass is mixed with, the powder of odorous substances which are used in the seraglio as perfumes, and called harsi, that is, pleasant odor; and of these the principal ingredient is ambergris. To blacken the hair a little of this dye is triturated in the hand or between the fingers, with which the hair or beard is well rubbed. After a few days the hair becomes very beautifully black, and it is a real pleasure to see such fine black beards as are met with in the East among the Turks who use this black dye. Another and important advantage in the use of this dye consists therein, that the hair remains soft, pliant, and for a long time black, when it has been once dyed with this substance. That the coloring properties of this dye are to be chiefly ascribed to the pyrogallic acid, which can be found by treating the mass with water, may be with certainty assumed.
Finely ground galls are mixed with a bit of oil to form a paste, which is then roasted in an iron pan until the oil vapors stop emitting. After that, the residue is ground with water into a paste and heated again until dry. At the same time, a metallic mixture, brought from Egypt to the trading centers in the East, called in Turkish Rastiko-petra or Rastik-Yuzi, is used for this purpose. This metal, resembling dross, is intentionally fused by some Armenians and consists of iron and copper. It gets its name from its use in dyeing hair, especially eyebrows—rastik means eyebrows, and yuzi means stone. The fine powder of this metal is thoroughly mixed with the moistened gall mass into a paste, which is stored in a damp place to acquire the blackening quality. In some cases, this mass is mixed with the powder of fragrant substances used in the seraglio as perfumes, called harsi, meaning pleasant odor; the main ingredient being ambergris. To dye the hair, a little of this dye is rubbed in the hand or between the fingers, then thoroughly applied to the hair or beard. After a few days, the hair turns a beautifully rich black, and it’s truly a pleasure to see such fine black beards among the Turks in the East who use this dye. Another significant advantage of this dye is that the hair remains soft, flexible, and retains its black color for a long time after being dyed. It's safe to assume that the coloring properties of this dye are primarily due to the pyrogallic acid, which can be isolated by treating the mass with water.
Litharge Hair Color.
Powdered litharge, | 2 lbs. |
Quicklime, | 1/2 lb. |
Calcined magnesia, | 1/2 lb. |
Slake the lime, using as little water as possible to make it disintegrate, then mix the whole by a sieve.
Slake the lime, using as little water as you can to break it down, then mix everything through a sieve.
Another Way.
Slaked lime, | 3 lbs. |
White lead in powder, | 2 lbs. |
Litharge, | 1 lb. |
Mix by sifting, bottle, and well cork.
Mix by sifting, bottle, and tightly cork.
Directions to be sold with the above.—"Mix the powder with enough water to form a thick creamy fluid; with the aid of a small brush; completely cover the hair to be dyed with this mixture; to dye a light brown, allow it to remain on the hair four hours; dark brown, eight hours; black, twelve hours. As the dye does not act unless it is moist, it is necessary to keep it so by wearing an oiled silk, india-rubber, or other waterproof cap.
Directions to be sold with the above.—"Mix the powder with enough water to create a thick, creamy mixture; using a small brush, completely cover the hair you want to dye with this blend; for light brown, leave it on for four hours; for dark brown, eight hours; for black, twelve hours. Since the dye won't work unless it's wet, it's important to keep it moist by wearing an oiled silk, rubber, or other waterproof cap.
"After the hair is dyed, the refuse must be thoroughly washed from the head with plain water; when dry, the hair must be oiled."
"After dyeing the hair, you must wash out all the residue from your head with plain water; once dry, you should oil the hair."
Simple Silver Hair Dye. (Otherwise "Vegetable Dye.")
Nitrate of silver, | 1 oz. |
Rose-water, | 1 pint. |
Before using this dye it is necessary to free the hair from grease by washing it with soda or pearlash and water. The hair must be quite dry prior to applying the dye, which is best laid on with an old tooth-brush. This dye does not "strike" for several hours. It needs scarcely be observed that its effects are more rapidly produced by exposing the hair to sunshine and air.
Before using this dye, you need to remove any grease from your hair by washing it with soda or pearlash and water. The hair should be completely dry before applying the dye, which is best done with an old toothbrush. This dye doesn’t take effect for several hours. It’s worth noting that its effects happen much faster if you expose your hair to sunlight and air.
Hair Dye with Fixative. (Brown.)
Nitrate of silver, | 1 oz., blue bottles. |
Rose-water, | 9 oz. " |
The mordant.—Sulphuret of potassium, | 1 oz., white bottles. |
" Water, | 8 oz. " |
Hair Dye with Mordant. (Black.)
Nitrate of silver, | 1 oz., blue bottles. |
Water, | 6 oz. " |
The mordant.—Sulphuret of potassium, | 1 oz., white bottles. |
" Water, | 6 oz. " |
Great care must be taken that the sulphuret is fresh made, or at least, well preserved in closed bottles, otherwise, instead of the mordant acting to make to make the hair black, it will tend to impart a yellow hue. When the mordant is good, it has a very disagreeable odor, and although this is the quickest and best dye, its unpleasant smell has given rise to the
Great care must be taken to ensure that the sulfide is freshly made or, at the very least, well-preserved in sealed bottles; otherwise, instead of the mordant helping to dye the hair black, it will add a yellow tint. When the mordant is effective, it has a very unpleasant odor, and although this is the fastest and best dye, its foul smell has led to the
Odorless Dye.
Blue bottles.—Dissolve the nitrate of silver in the water as in the above, then add liquid ammonia by degrees until the mixture becomes cloudy from the precipitate of the oxide of silver, continue to add ammonia in small portions until the fluid again becomes bright from the oxide of silver being redissolved.
Blue bottles.—Dissolve silver nitrate in water as described above, then gradually add liquid ammonia until the mixture becomes cloudy due to the silver oxide precipitate. Keep adding ammonia in small amounts until the solution clears up again because the silver oxide has redissolved.
White bottles.—Pour half a pint of boiling rose-water upon three ounces of powdered gall-nuts; when cold, strain and bottle. This forms the mordant, and is used in the same way as the first-named dye, like the sulphuret mordant. It is not so good a dye as the previous one.
White bottles.—Pour half a pint of boiling rose-water over three ounces of powdered gall-nuts; when it cools, strain it and bottle it. This creates the mordant and is used in the same way as the first dye, similar to the sulphuret mordant. It’s not as good a dye as the one mentioned before.
French Brown Hair Dye.
Blue Bottles.—Saturated solution of sulphate of copper; to this add ammonia enough to precipitate the oxide of copper and redissolve it (as with the silver in the above), producing the azure liquid.
Blue Bottles.—A saturated solution of copper sulfate; then add enough ammonia to precipitate the copper oxide and redissolve it (like with the silver mentioned above), resulting in the blue liquid.
Artificial hair, for the manufacture of perukes, is dyed in the same manner as wool.
Artificial hair, used for making wigs, is dyed in the same way as wool.
There are in the market several other hair dyes, but all of them are but modifications of the above, possessing no marked advantage.
There are several other hair dyes on the market, but they are all just variations of the ones mentioned above, offering no significant benefits.
Lead Paint.
Liquid hair dye, not to blacken the skin, may be thus prepared:—Dissolve in one ounce of liquor potassæ as much freshly-precipitated oxide of lead as it will take up, and dilute the resulting clear solution with three ounces of distilled water. Care must be taken not to wet the skin unnecessarily with it.
Liquid hair dye, which shouldn't stain the skin, can be made like this: Dissolve as much freshly-precipitated lead oxide as possible in one ounce of potash liquor, and then dilute the clear solution with three ounces of distilled water. Be careful not to get it on the skin unnecessarily.
Quick Hair Removal or Rusma. (For removing hair.)
As the ladies of this country consider the growth of hair upon the upper lip, upon the arms, and on the back of the neck, to be detrimental to beauty, those who are troubled with such physical indications of good health and vital stamina have long had recourse to rusma or depilatory for removing it.
As the women in this country view hair on the upper lip, arms, and back of the neck as a flaw in beauty, those who have these physical signs of good health and vitality have often turned to rusma or hair removal products to get rid of it.
This or analogous preparations were introduced into this country from the East, rusma having been in use in the harems of Asia for many ages.
This or similar preparations were brought to this country from the East, with rusma having been used in the harems of Asia for many ages.
Best lime slaked, | 3 lb. |
Orpiment, in powder, | 1/2 lbs. |
Directions to be sold with the above. Mix the depilatory powder with enough water to render it of a creamy consistency; lay it upon the hair for about five minutes, or until its caustic action upon the skin renders it necessary to be removed; a similar process to shaving is then to be gone through, but instead of using a razor, operate with an ivory or bone paper-knife; then wash the part with plenty of water, and apply a little cold cream.
Directions to be sold with the above. Mix the depilatory powder with enough water to make it creamy; apply it to the hair for about five minutes, or until it starts to irritate the skin and needs to be removed; then follow a process similar to shaving, but instead of using a razor, use an ivory or bone paper knife; afterward, rinse the area with plenty of water and apply a little cold cream.
The precise time to leave depilatory upon the part to be depilated cannot be given, because there is a physical difference in the nature of hair. "Raven tresses" require more time than "flaxen locks;" the sensitiveness of the skin has also to be considered. A small feather is a very good test for its action.
The exact time to leave hair removal cream on the area being treated can’t be specified, as there are physical differences in hair types. Dark hair takes longer than light hair; the sensitivity of the skin also needs to be taken into account. A small feather is a good way to test its effects.
A few readers will, perhaps, be disappointed in finding that I have only given one formula for depilatory. The receipts might easily have been increased in number, but not in quality. The use of arsenical compounds is objectionable, but it undoubtedly increases the depilating action of the compounds. A few compilers of "Receipt Books," "Supplements to Pharmacopœias," and others, add to the lime "charcoal powder," "carbonate of potass," "starch," &c.; but what action have these materials—chemically—upon hair? The simplest depilatory is moistened quicklime, but it is less energetic than the mixture recommended above; it answers very well for tanners and fellmongers, with whom time is no object.
A few readers might feel let down to find that I've only provided one formula for a hair removal product. I could have easily added more recipes, but they wouldn't have been better. The use of arsenic compounds is not ideal, but it definitely boosts the hair removal effectiveness of the products. Some authors of "Recipe Books," "Supplements to Pharmacopeias," and others add things like "charcoal powder," "potassium carbonate," "starch," etc., to the lime; but what do these materials actually do—chemically—to hair? The simplest hair remover is damp quicklime, but it isn't as effective as the mixture I suggested earlier; it works fine for tanners and those dealing with skins, where time isn't an issue.
SECTION XIV.
ABSORBENT POWDERS.
A lady's toilet-table is incomplete without a box of some absorbent powder; indeed, from our earliest infancy, powder is used for drying the skin with the greatest benefit; no wonder that its use is continued in advanced years, if, by slight modifications in its composition, it can be employed not only as an absorbent, but as a means of "personal adornment." We are quite within limits in stating that many ton-weights of such powders are used in this country annually. They are principally composed of various starches, prepared from wheat, potatoes, and various nuts, mixed more or less with powdered talc—of Haüy, steatite (soap-stone), French chalk, oxide of bismuth, and oxide of zinc, &c. The most popular is what is termed
A woman's vanity table isn't complete without a box of absorbent powder; in fact, from our earliest days, powder has been used to dry the skin with great benefits. It's no surprise that its use continues into later years, especially since slight changes in its formula allow it to function not just as an absorbent, but also as a form of "personal enhancement." It's fair to say that many tons of these powders are used in this country every year. They mainly consist of various starches made from wheat, potatoes, and different nuts, often blended with powdered talc, soapstone, French chalk, bismuth oxide, zinc oxide, and so on. The most popular is what's called
Violet Powder.
Wheat starch, | 12 lbs. |
Orris-root powder, | 2 lbs. |
Otto of lemon, | 1/2 oz. |
" bergamot, | 3/4 oz. |
" cloves, | 2 drachms. |
Rose Face Powder.
Wheat starch, | 7 lbs. |
Rose Pink, | 1/2 drachm. |
Otto of rose, | 2 drachms. |
" santal, | 2 " |
Plain or Unscented Hair Powder
Is pure wheat starch. |
Face Powder.
Starch, | 1 lb. |
Oxide of Bismuth, | 4 oz. |
Pearl Powder.
French chalk, | 1 lb. |
Oxide of bismuth, | 1 oz. |
Oxide of zinc, | 1 oz. |
Pearl White
Is pure oxide of bismuth in powder. |
French White
Is levigated talc passed through a silk sieve. |
This is the best face powder made, particularly as it does not discolor from emanation of the skin or impure atmosphere.
This is the best face powder ever made, especially since it doesn't change color due to skin oils or a polluted environment.
Liquid White (for theatrical use).
The use of a white paint by actresses and dancers, is absolutely necessary; great exertion produces a florid complexion, which is incompatible with certain scenic effects, and requires a cosmetic to subdue it.
The use of white paint by actresses and dancers is absolutely necessary; intense effort creates a flushed complexion, which doesn't work well with certain visual effects, and needs makeup to tone it down.
Madame V——, during her stage career, has probably consumed more than half a hundredweight of oxide of bismuth, prepared thus:—
Madame V——, during her time on stage, has probably used more than fifty pounds of bismuth oxide, prepared like this:—
Rose or orange-flower water, | 1 pint. |
Oxide of bismuth, | 4 oz. |
Mixed by long trituration.
Mixed by extensive grinding.
Calcined Talc
Is also extensively used as a toilet powder, and is sold under various names; it is not so unctuous as the ordinary kind.
Is also widely used as a toilet powder and is sold under different names; it isn't as greasy as the regular kind.
Red Paints.
These preparations are in demand, not only for theatrical use, but by private individuals. Various shades of color are made, to suit the complexions of the blonde and brunette. One of the best kind is that termed
These preparations are sought after, not just for theater use, but also by private individuals. Different shades are created to match the complexions of blondes and brunettes. One of the best types is called
Rose Bloom.
Strong liquid ammonia, | 1/2 oz. |
Finest carmine, | 1/4 oz. |
Rose-water, | 1 pint. |
Esprit de rose (triple), | 1/2 oz. |
Place the carmine into a pint bottle, and pour on it the ammonia; allow them to remain together, with occasional agitation, for two days; then add the rose-water and esprit, and well mix. Place the bottle in a quiet situation for a week; any precipitate of impurities from the carmine will subside; the supernatant "Bloom of Roses" is then to be bottled for sale. If the carmine was perfectly pure there would be no precipitate; nearly all the carmine purchased from the makers is more or less sophisticated, its enormous price being a premium to its adulteration.
Put the carmine into a pint bottle and pour the ammonia over it; let them mix together, shaking occasionally, for two days. Then, add the rose water and esprit, and mix well. Leave the bottle in a quiet place for a week; any impurities from the carmine will settle at the bottom, and the clear "Bloom of Roses" can then be bottled for sale. If the carmine was completely pure, there would be no sediment; however, most carmine bought from suppliers is somewhat adulterated, with its high price reflecting this contamination.
Carmine cannot be manufactured profitably on a small scale for commercial purposes; four or five manufacturers supply the whole of Europe! M. Titard, Rue Grenier St. Lazare, Paris, produces, without doubt, the finest article; singular enough, however, the principal operative in the establishment is an old Englishman.
"The preparation of the finest carmine is still a mystery, because, on the one hand, its consumption being very limited, few persons are engaged in its manufacture, and, upon the other, the raw material being costly, extensive experiments on it cannot be conveniently made."—Dr. Ure.
"The process of making the best carmine is still a mystery because, on one hand, its use is very limited, so few people are involved in making it, and on the other hand, the raw material is expensive, making it impractical to conduct extensive experiments."—Dr. Ure.
In the Encyclopédie Roret will be found no less than a dozen recipes for preparing carmine; the number of formulæ will convince the most superficial reader that the true form is yet withheld.
In the Encyclopédie Roret, you'll find at least a dozen recipes for making carmine; the variety of formulas will convince even the most casual reader that the real method is still undisclosed.
Analysis has taught us its exact composition; but a certain dexterity of manipulation and proper temperature are indispensable to complete success.
Analysis has shown us its exact makeup, but a certain skill in handling it and the right temperature are essential for total success.
Most of the recipes given by Dr. Ure, and others, are from this source; but as they possess no practical value we refrain from reprinting them.
Most of the recipes provided by Dr. Ure and others come from this source; however, since they have no practical value, we won't reprint them.
Toilet Lipsticks.
Are prepared of different shades by mixing fine carmine with talc powder, in different proportions, say, one drachm of carmine to two ounces of talc, or one of carmine to three of talc, and so on. These rouges are sold in powder, and also in cake or china pots; for the latter the rouge is mixed with a minute portion of solution of gum tragacanth. M. Titard prepares a great variety of rouges. In some instances the coloring-matter of the cochineal is spread upon thick paper and dried very gradually; it then assumes a beautiful green tint. This curious optical effect is also observed in "pink saucers." What is known as Chinese book rouge is evidently made in the same way, and has been imported into this country for many years.
Rouges are made in different shades by mixing fine carmine with talc powder in various proportions, like one drachm of carmine to two ounces of talc, or one part carmine to three parts talc, and so on. These rouges are available in powder form as well as in cake or china pots; for the latter, the rouge is combined with a small amount of gum tragacanth solution. M. Titard offers a wide range of rouges. In some cases, the coloring matter from cochineal is applied to thick paper and dried very slowly, resulting in a beautiful green tint. This interesting optical effect is also seen in "pink saucers." What we call Chinese book rouge is clearly made the same way and has been imported to this country for many years.
When the bronze green cards are moistened with a piece of damp cotton wool, and applied to the lips or cheeks, the color assumes a beautiful rosy hue. Common sorts of rouge, called "theatre rouge," are made from the Brazil-wood lake; another kind is derived from the safflower (Carthamus tinctorius); from this plant also is made
When the bronze green cards are dampened with a piece of wet cotton wool and pressed against the lips or cheeks, the color takes on a lovely rosy shade. Ordinary types of blush, known as "theatre rouge," are made from Brazil-wood lake; another type comes from safflower (Carthamus tinctorius); this plant is also used to make
Pink Plates.
The safflower is washed in water until the yellow coloring-matter is removed; the carthamine or color principle is then dissolved out by a weak solution of carbonate of soda; the coloring is then precipitated into the saucers by the addition of sulphuric acid to the solution.
The safflower is rinsed in water until the yellow dye is completely removed; then, a mild solution of baking soda is used to dissolve the carthamine, or color component; afterward, the dye is precipitated into dishes by adding sulfuric acid to the solution.
Cotton wool and crape being colored in the same way are used for the same purpose, the former being sold as Spanish wool, the latter as Crépon rouge.
Cotton wool and crape, being dyed the same way, are used for the same purpose, with the former sold as Spanish wool and the latter as Crépon rouge.
SECTION XV.
TOOTH POWDERS AND MOUTH WASHES.
Tooth powders, regarded as a means merely of cleansing the teeth, are most commonly placed among cosmetics; but this should not be, as they assist greatly in preserving a healthy and regular condition of the dental machinery, and so aid in perfecting as much as possible the act of mastication. In this manner, they may be considered as most useful, although it is true, subordinate medicinal agents. By a careful and prudent use of them, some of the most frequent causes of early loss of the teeth may be prevented; these are, the deposition of tartar, the swelling of the gums, and an undue acidity of the saliva. The effect resulting from accumulation of the tartar is well known to most persons, and it has been distinctly shown that swelling of the substance of the gums will hasten the expulsion of the teeth from their sockets; and the action of the saliva, if unduly acid, is known to be at least injurious, if not destructive. Now, the daily employment of a tooth powder sufficiently hard, so as to exert a tolerable degree of friction upon the teeth, without, at the same time, injuring the enamel of the teeth, will, in most cases, almost always prevent the tartar accumulating in such a degree as to cause subsequent injury to the teeth; and a flaccid, spongy, relaxed condition of the gums may be prevented or overcome by adding to such a tooth powder, some tonic and astringent ingredient. A tooth powder containing charcoal and cinchona bark, will accomplish these results in most cases, and therefore dentists generally recommend such. Still, there are objections to the use of charcoal; it is too hard and resisting, its color is objectionable, and it is perfectly insoluble by the saliva, it is apt to become lodged between the teeth, and there to collect decomposing animal and vegetable matter around such particles as may be fixed in this position. Cinchona bark, too, is often stringy, and has a bitter, disagreeable taste. M. Mialhe highly recommends the following formula:—
Tooth powders, often seen just as a way to clean teeth, are usually categorized with cosmetics; however, this should change, as they play a significant role in maintaining a healthy and regular state of dental health, which helps improve chewing. In this regard, they can be viewed as very useful, though it's true they serve as secondary medicinal aids. By using them carefully and wisely, many common reasons for early tooth loss can be avoided, including tartar buildup, swollen gums, and overly acidic saliva. Most people are familiar with the effects of tartar accumulation. It's well established that swollen gums can lead to teeth being pushed out of their sockets, and if saliva is too acidic, it can be harmful, if not destructive, to the teeth. Daily use of a tooth powder that is hard enough to provide a reasonable level of friction on the teeth, without damaging the enamel, will usually prevent tartar buildup that could later harm the teeth. Additionally, a loose, spongy condition of the gums can be prevented or treated by adding some toning and astringent ingredients to the tooth powder. A formulation with charcoal and cinchona bark can achieve these results in most cases, which is why dentists often recommend them. However, there are some downsides to using charcoal; it is too hard and abrasive, its color is unattractive, and since it’s completely insoluble in saliva, it can easily get trapped between teeth, collecting decomposing food particles. Cinchona bark can also be stringy and has an unpleasant, bitter taste. M. Mialhe highly recommends the following formula:—
Mialhe's Toothpaste.
Sugar of milk, one thousand parts; lake, ten parts; pure tannin, fifteen parts; oil of mint, oil of aniseed, and oil of orange flowers, so much as to impart an agreeable flavor to the composition.
Sugar of milk, 1,000 parts; lake, 10 parts; pure tannin, 15 parts; oil of mint, oil of anise, and oil of orange blossom, enough to give a pleasant flavor to the mixture.
His directions for the preparation of this tooth powder, are, to rub well the lake with the tannin, and gradually add the sugar of milk, previously powdered and sifted; and lastly, the essential oils are to be carefully mixed with the powdered substances. Experience has convinced him of the efficacy of this tooth powder, the habitual employment of which, will suffice to preserve the gums and teeth in a healthy state. For those who are troubled with excessive relaxation and sponginess of the gums, he recommends the following astringent preparation:—
His instructions for making this tooth powder are to thoroughly mix the lake with the tannin, then gradually add the powdered and sifted milk sugar, and finally, carefully combine the essential oils with the powdered ingredients. He’s convinced by experience that this tooth powder is effective, and regular use will keep the gums and teeth healthy. For those who suffer from overly loose and spongy gums, he recommends the following astringent preparation:—
Mialhe's Toothpaste.
Alcohol, one thousand parts; genuine kino, one hundred parts; rhatany root, one hundred parts; tincture of balsam of tolu, two parts; tincture of gum benzoin, two parts; essential oil of canella, two parts; essential oil of mint, two parts; essential oil of aniseed, one part.
Alcohol, 1,000 parts; genuine kino, 100 parts; rhatany root, 100 parts; tincture of balsam of tolu, 2 parts; tincture of gum benzoin, 2 parts; essential oil of canella, 2 parts; essential oil of mint, 2 parts; essential oil of aniseed, 1 part.
The kino and the rhatany root are to be macerated in the alcohol for seven or eight days; and after filtration, the other articles are to be added. A teaspoonful of this preparation mixed in three or four spoonfuls of water, should be used to rinse the mouth, after the use of the tooth powder.
The kino and the rhatany root should be soaked in alcohol for seven or eight days; after filtering, the other ingredients should be added. A teaspoon of this mixture, combined with three or four spoonfuls of water, should be used as a mouth rinse after using the tooth powder.
Camphor Chalk.
Precipitated chalk, | 1 lb. |
Powdered orris-root, | 1/2 lb. |
Powdered camphor, | 1/4 lb. |
Reduce the camphor to powder by rubbing it in a mortar with a little spirit, then sift the whole well together. On account of the volatility of camphor, the powder should always be sold in bottles, or at least in boxes lined with tinfoil.
Reduce the camphor to powder by grinding it in a mortar with a bit of alcohol, then sift everything together thoroughly. Because camphor is volatile, the powder should always be sold in bottles or, at the very least, in boxes lined with aluminum foil.
Quinine Toothpaste.
Precipitated chalk, | 1 lb. |
Starch Powder, | 1/2 lb. |
Orris powder, | 1/2 lb. |
Sulphate of quinine, | 1 drachm. |
After sifting, it is ready for sale.
After sifting, it's ready to be sold.
Ready Charcoal.
Fresh-made charcoal in fine powder, | 7 lbs. |
Prepared chalk, | 1 lb. |
Orris-root, | 1 lb. |
Catechu, | 1/2 lb. |
Cassia bark, | 1/2 lb. |
Myrrh, | 1/4 lb. |
Sift.
Filter.
Peruvian Bark Powder.
Peruvian bark in powder, | 1/2 lb. |
Bole Ammoniac, | 1 lb. |
Orris powder, | 1 lb. |
Cassia bark, | 1/2 lb. |
Powdered myrrh, | 1/2 lb. |
Precipitated chalk, | 1/2 lb. |
Otto of cloves, | 3/4 oz. |
Homeopathic Chalk.
Precipitated chalk, | 1 lb. |
Powder orris, | 1 oz. |
" starch, | 1 oz. |
Cuttlefish Powder.
Powdered cuttle-fish, | 1/2 lb. |
Precipitated chalk, | 1 lb. |
Powder orris, | 1/2 lb. |
Otto of lemons, | 1 oz. |
" neroli, | 1/2 drachm. |
Borax and Myrrh Toothpaste.
Precipitated chalk, | 1 lb. |
Borax powder, | 1/2 lb. |
Myrrh powder, | 1/4 lb. |
Orris, | 1/4 lb. |
Farina Piesse Powder.
Precipitated chalk, | 2 lbs. |
Orris-root, | 2 lbs. |
Rose pink, | 1 drachm. |
Very fine powdered sugar, | 1/2 lb. |
Otto of neroli, | 1/2 drachm. |
" lemons, | 1/4 oz. |
" bergamot, | 1/4 oz. |
" orange-peel, | 1/4 oz. |
" rosemary, | 1 drachm. |
Rose Tooth Powder.
Precipitated chalk, | 1 lb. |
Orris, | 1/2 lb. |
Rose pink, | 2 drachms. |
Otto of rose, | 1 drachm. |
" santal, | 1/4 drachm. |
Opiate Toothpaste.
Honey, | 1/2 lb. | |
Chalk, | 1/2 lb. | |
Orris, | 1/2 lb. | |
Rose Pink, | 2 drachms. | |
Otto of cloves, | } | |
" nutmeg, | } each, | 1/2 drachm. |
" rose, | } | |
Simple syrup, | enough to form a paste. |
MOUTH WASHES.
Violet Mouthwash.
Tincture of orris, | 1/2 pint. |
Esprit de rose, | 1/2 pint. |
Spirit, | 1/2 pint. |
Otto of almonds, | 5 drops. |
Eau Botot.
Tincture of cedar wood, | 1 pint. |
" myrrh, | 1/4 pint. |
" rhatany, | 1/4 pint. |
Otto of peppermint, | 5 drops. |
All these tinctures should be made with grape spirit, or at least with pale unsweetened brandy.
All these tinctures should be made with grape alcohol, or at least with light unsweetened brandy.
Botanical Styptic.
Rectified spirit, | 1 quart. |
Rhatany root, } | |
Gum myrrh, } of each, | 2 oz. |
Whole cloves, } |
Macerate for fourteen days, and strain.
Macerate for two weeks, and then strain.
Myrrh and Borax tincture.
Spirits of wine, | 1 quart. | |
Borax, | } | |
Honey, | } of each, | 1 oz. |
Gum myrrh, | 1 oz. | |
Red sanders wood, | 1 oz. |
Rub the honey and borax well together in a mortar, then gradually add the spirit, which should not be stronger than .920, i.e. proof spirit, the myrrh, and sanders wood, and macerate for fourteen days.
Mix the honey and borax thoroughly in a mortar, then slowly add the spirit, which should not be stronger than .920, i.e. proof spirit, along with the myrrh and sandalwood, and let it soak for fourteen days.
Myrrh tincture with Eau de Cologne.
Eau de Cologne, | 1 quart. |
Gum myrrh, | 1 oz. |
Macerate for fourteen days, and filter.
Macerate for fourteen days, then filter.
Camphor Cologne.
Eau de Cologne, | 1 quart. |
Camphor, | 5 oz. |
SECTION XVI.
HAIR WASHES.
Rosemary Water.
Rosemary free from stalk, | 10 lbs. |
Water, | 12 gallons. |
Draw off by distillation ten gallons for use in perfumery manufacture.
Distill ten gallons for use in making perfume.
Rosemary Shampoo.
Rosemary water, | 1 gallon. |
Rectified spirit, | 1/2 pint. |
Pearlash, | 1 oz. |
Tinted with brown coloring.
Brown-tinted.
Athenian Water.
Rose-water, | 1 gallon. |
Alcohol, | 1 pint. |
Sassafras wood, | 1/4 lb. |
Pearlash, | 1 oz. |
Boil the wood in the rose-water in a glass vessel; then, when cold, add the pearlash and spirit.
Boil the wood in rosewater in a glass container; then, when it’s cool, add the pearlash and spirit.
Plant Extract.
Rose-water, | } | ||
Rectified spirits, | } of each, | 2 quarts. | |
Extrait de fleur d'orange, | } | ||
" jasmin, | } | ||
" acacia, | } of each, | 1/4 pint. | |
" rose, | } | ||
" tubereuse, | } | ||
Extract of vanilla, | 1/2 pint. |
This is a very beautifully-scented hair wash. It retails at a price commensurate with its cost.
This is a really nicely-scented hair wash. It sells for a price that matches its quality.
Astringent Extract of Roses and Rosemary.
Rosemary water, | 2 quarts. |
Esprit de rose, | 1/2 pint. |
Rectified spirit, | 1-1/2 pint. |
Extract of vanilla, | 1 quart. |
Magnesia to clear it, | 2 oz. |
Filter through paper.
Filter through the paperwork.
Soapy Wash.
Rectified spirit, | 1 pint. |
Rose-water, | 1 gallon. |
Extract of rondeletia, | 1/2 pint. |
Transparent soap, | 1/2 oz. |
Hay saffron, | 1/2 drachm. |
Shave up the soap very fine; boil it and the saffron in a quart of the rose-water; when dissolved, add the remainder of the water, then the spirit, finally the rondeletia, which is used by way of perfume. After standing for two or three days, it is fit for bottling. By transmitted light it is transparent, but by reflected light the liquid has a pearly and singular wavy appearance when shaken. A similar preparation is called Egg Julep.
Shave the soap into very fine pieces; boil it together with the saffron in a quart of rose water. Once it’s dissolved, add the rest of the water, then the spirit, and finally the rondeletia, which is used for fragrance. After letting it sit for two or three days, it’s ready to be bottled. By transmitted light, it’s clear, but when reflected, the liquid appears pearly and has a unique wavy look when shaken. A similar mixture is known as Egg Julep.
Bandolins.
Various preparations are used to assist in dressing the hair in any particular form. Some persons use for that purpose a hard pomatum containing wax, made up into rolls, called thence Baton Fixeteur. The little "feathers" of hair, with which some ladies are troubled, are by the aid of these batons made to lie down smooth. For their formula, see p. 224, 225.
Various products are used to help style the hair in a specific way. Some people use a firm pomade that contains wax, shaped into rolls, called Baton Fixeteur. The little "feathers" of hair that some women struggle with can be tamed and smoothed down with these batons. For their formula, see p. 224, 225.
The liquid bandolines are principally of a gummy nature, being made either with Iceland moss, or linseed and water variously perfumed, also by boiling quince-seed with water. Perfumers, however, chiefly make bandoline from gum tragacanth, which exudes from a shrub of that name which grows plentifully in Greece and Turkey.
The liquid bandolines are mainly sticky, made either from Iceland moss or linseed mixed with water and different scents, or by boiling quince seeds in water. However, perfumers mostly create bandoline using gum tragacanth, which comes from a shrub of the same name that grows abundantly in Greece and Turkey.
Rose Bandoline.
Gum tragacanth, | 6 oz. |
Rose-water, | 1 gallon. |
Otto of roses, | 1/2 oz. |
Steep the gum in the water for a day or so. As it swells and forms a thick gelatinous mass, it must from time to time be well agitated. After about forty-eight hours' maceration it is then to be squeezed through a coarse clean linen cloth, and again left to stand for a few days, and passed through a linen cloth a second time, to insure uniformity of consistency; when this is the case, the otto of rose is to be thoroughly incorporated. The cheap bandoline is made without the otto; for colored bandoline, it is to be tinted with ammoniacal solution of carmine, i.e. Bloom of Roses. See p. 236.
Soak the gum in water for about a day. As it expands and turns into a thick jelly-like mass, stir it occasionally. After around forty-eight hours, squeeze it through a clean, coarse linen cloth, then let it sit for a few days. Pass it through the linen cloth again to ensure a consistent texture. Once this is done, mix in the rose oil thoroughly. The budget version of bandoline doesn’t include the rose oil; for colored bandoline, add an ammoniacal solution of carmine, also known as Bloom of Roses. See p. 236.
Almond Hair Gel
Is made precisely as the above, scenting with a quarter of an ounce of otto of almonds in place of the roses.
Is made exactly like the one above, using a quarter of an ounce of almond oil instead of the roses.
Of various flowers in scent and color "Can you make me a longer story?"

APPENDIX.
MANUFACTURE OF GLYCERINE.
Glycerine is generally made on the large scale, on the one hand, by directly saponifying oil with the oxide of lead, or, on the other, from the "waste liquor" of soap manufacturers. To obtain glycerine by means of the first of these methods is the reverse of simple, and at the same time somewhat expensive; and by means of the second process, the difficulty of entirely separating the saline matters of the waste liquor renders it next to impossible to procure a perfectly pure result. To meet both these difficulties, and to meet the steadily increasing demand for glycerine, Dr. Campbell Morfit recommends the following process, which, he asserts, he has found, by experience, to combine the desirable advantages of economy as regards time, trouble, and expense. One hundred pounds of oil, tallow, lard, or stearin are to be placed in a clean iron-bound barrel, and melted by the direct application of a current of steam. Whilst still fluid and warm, add to it fifteen pounds of lime, previously slaked, and made into a milky mixture with two and a half gallons of water; then cover the vessel, and continue the steaming for several hours, or until the saponification shall be completed. This may be known when a sample of the soap when cold gives a smooth and bright surface on being scraped with the finger-nail, and at the same time, breaks with a crackling noise. By this process the fat or oil is decomposed, its acids uniting with the lime to form insoluble lime-soap, while the eliminated glycerine remains in solution in the water along with the excess of the lime. After it has been sufficiently boiled, it is allowed to cool and to settle, and it is then to be strained.
Glycerin is typically produced on a large scale in two ways: either by directly saponifying oil with lead oxide or by using the "waste liquor" from soap manufacturers. The first method is quite complicated and somewhat costly, while the second method faces challenges in completely separating the saline substances from the waste liquor, making it nearly impossible to get a perfectly pure product. To address these issues and meet the growing demand for glycerin, Dr. Campbell Morfit suggests a process that he claims is efficient in terms of time, effort, and cost. Start with one hundred pounds of oil, tallow, lard, or stearin placed in a clean, iron-bound barrel, and melt it using direct steam. While it's still liquid and warm, add fifteen pounds of slaked lime mixed with two and a half gallons of water to create a milky solution; then cover the barrel and keep steaming for several hours, or until the saponification is complete. You can tell it's done when a sample of the soap, when cold, has a smooth and shiny surface when scraped with a fingernail and gives a crackling sound. Through this process, the fat or oil breaks down, with its acids combining with the lime to create insoluble lime-soap, while the glycerin is left dissolved in the water along with the excess lime. After boiling for a sufficient time, allow the mixture to cool and settle, then strain it.
The strained liquid contains only the glycerine and excess of lime, and requires to be carefully concentrated by heated steam. During evaporation, a portion of the lime is deposited, on account of its lesser solubility in hot than in cold water. The residue is removed by treating the evaporated liquid with a current of carbonic acid gas, boiling by heated steam to convert a soluble bicarbonate of lime that may have been formed into insoluble neutral carbonate, decanting or straining off the clear supernatant liquid from the precipitated carbonate of lime, and evaporating still further, as before, if necessary, so as to drive off any excess of water. As nothing fixed or injurious is employed in this process, glycerine, prepared in this manner, may be depended upon for its almost absolute purity.
The strained liquid contains only glycerin and excess lime, and needs to be carefully concentrated using heated steam. During evaporation, some of the lime settles out because it is less soluble in hot water than in cold. The residue is removed by treating the evaporated liquid with a stream of carbon dioxide gas, boiling with heated steam to change any soluble lime bicarbonate that may have formed into insoluble neutral carbonate, decanting or filtering off the clear liquid on top from the precipitated lime carbonate, and evaporating further if necessary to remove any excess water. Since nothing fixed or harmful is used in this process, glycerin made this way can be trusted for its almost complete purity.
M. Jahn's process is as follows:—
M. Jahn's process is as follows:—
Take of finely-powdered litharge five pounds, and olive oil nine pounds. Boil them together over a gentle fire, constantly stirring, with the addition occasionally of a small quantity of warm water, until the compound has the consistence of plaster. Jahn boils this plaster for half an hour with an equal weight of water, keeping it at the same time constantly stirred. When cold, he pours off the supernatant fluid, and repeats the boiling three times at least with a fresh portion of water. The sweet fluids which result are mixed, and evaporated to six pounds, and sulphuretted hydrogen conducted through them as long as sulphuret of lead is precipitated. The liquid filtered from the sulphuret of lead is to be reduced to a thin syrupy consistence by evaporation. To remove the brown coloring matter, it must be treated with purified animal charcoal. However, this agent does not prevent the glycerine becoming slightly colored upon further evaporation. It possesses also still a slight smell and taste of lead plaster, which may be removed by diluting it with water, and by digestion with animal charcoal, and some fresh burnt-wood charcoal. After filtration, this liquid must be evaporated until it has acquired a specific gravity of 1.21, when it will be found to be free from smell, and of a pale yellow color. For the preparation of glycerine, distilled water is necessary, to prevent it being contaminated with the impurities of common water. Jahn obtained, by this method, from the above quantity of lead plaster, upwards of seven ounces of glycerine.—Archives der Pharmacie.
Take five pounds of finely powdered litharge and nine pounds of olive oil. Boil them together over a gentle flame, stirring constantly, and occasionally adding a small amount of warm water, until the mixture has the consistency of plaster. Jahn boils this plaster for half an hour with an equal weight of water, continuously stirring it. When it cools, he pours off the liquid on top and repeats the boiling at least three times with fresh water. The resulting sweet liquids are combined and evaporated down to six pounds, and hydrogen sulfide is bubbled through them until lead sulfide is precipitated. The liquid filtered from the lead sulfide is then reduced to a thin syrupy consistency by evaporation. To remove the brown coloring matter, it should be treated with purified animal charcoal. However, this does not stop the glycerin from becoming slightly colored with further evaporation. It still has a slight smell and taste of lead plaster, which can be removed by diluting it with water and digesting it with animal charcoal and some fresh burnt wood charcoal. After filtering, this liquid must be evaporated until it reaches a specific gravity of 1.21, at which point it will be free of odor and have a pale yellow color. For preparing glycerin, distilled water is necessary to avoid contamination from impurities in regular water. Jahn obtained over seven ounces of glycerin from the aforementioned amount of lead plaster by this method.—Archives der Pharmacie.
TEST FOR ALCOHOL IN ESSENTIAL OILS.
J.J. Bernoulli recommends for this purpose acetate of potash. When to an ethereal oil, contaminated with alcohol, dry acetate of potash is added, this salt dissolves in the alcohol, and forms a solution from which the volatile oil separates. If the oil be free from alcohol, this salt remains dry therein.
J.J. Bernoulli suggests using potassium acetate for this purpose. When dry potassium acetate is added to an ethereal oil that contains alcohol, this salt dissolves in the alcohol, creating a solution from which the volatile oil separates. If the oil is free of alcohol, this salt stays dry in it.
Wittstein, who speaks highly of this test, has suggested the following method of applying it as the best:—In a dry test-tube, about half an inch in diameter, and five or six inches long, put no more than eight grains of powdered dry acetate of potash; then fill the tube two-thirds full with the essential oil to be examined. The contents of the tube must be well stirred with a glass rod, taking care not to allow the salt to rise above the oil; afterwards set aside for a short time. If the salt be found at the bottom of the tube dry, it is evident that the oil contains no spirit. Oftentimes, instead of the dry salt, beneath the oil is found a clear syrupy fluid, which is a solution of the salt in the spirit, with which the oil was mixed. When the oil contains only a little spirit, a small portion of the solid salt will be found under the syrupy solution. Many essential oils frequently contain a trace of water, which does not materially interfere with this test, because, although the acetate of potash becomes moist thereby, it still retains its pulverent form.
Wittstein, who speaks highly of this test, has suggested the following method of applying it as the best: In a dry test tube, about half an inch in diameter and five or six inches long, put no more than eight grains of powdered dry acetate of potash; then fill the tube two-thirds full with the essential oil you want to examine. The contents of the tube must be stirred well with a glass rod, making sure not to let the salt rise above the oil; then set it aside for a short time. If the salt at the bottom of the tube is dry, it’s clear that the oil contains no spirit. Often, instead of dry salt, you might find a clear syrupy fluid beneath the oil, which is a solution of the salt in the spirit that mixed with the oil. When the oil contains only a small amount of spirit, a little solid salt will be found beneath the syrupy solution. Many essential oils often contain a bit of water, which doesn’t significantly affect this test because, although the acetate of potash becomes moist, it still stays in its powdered form.
A still more certain result may be obtained by distillation in a water-bath. All the essential oils which have a higher boiling-point than spirit, remain in the retort, whilst the spirit passes into the receiver with only a trace of the oil, where the alcohol may be recognized by the smell and taste. Should, however, a doubt exist, add to the distillate a little acetate of potash and strong sulphuric acid, and heat the mixture in a test-tube to the boiling-point, when the characteristic odor of acetic ether will be manifest, if any alcohol be present.
A more reliable outcome can be achieved by distilling in a water bath. All the essential oils with a higher boiling point than alcohol will stay in the retort, while the alcohol passes into the receiver with just a hint of the oil, which can be identified by its smell and taste. If there's any uncertainty, add a bit of potassium acetate and strong sulfuric acid to the distillate, then heat the mixture in a test tube to the boiling point. If any alcohol is present, you'll notice the distinct smell of acetic ether.
DETECTION OF POPPY AND OTHER DRYING OILS IN ALMOND AND OLIVE OILS.
It is known that the olein of the drying oils may be distinguished from the olein of those oils which remain greasy in the air by the first not being convertible into elaidic acid, consequently it does not become solid. Professor Wimmer has recently proposed a convenient method for the formation of elaidin, which is applicable for the purpose of detecting the adulteration of almond and olive oils with drying oils. He produces nitrous acid by treating iron filings in a glass bottle with nitric acid. The vapor of nitrous acid is conducted through a glass tube into water, upon which the oil to be tested is placed. If the oil of almonds or olives contains only a small quantity of poppy oil when thus treated, it is entirely converted into crystallized elaidin, whilst the poppy oil swims on the top in drops.
It is known that the olein from drying oils can be distinguished from the olein of oils that stay greasy in the air because the former can’t be converted into elaidic acid, meaning it doesn’t solidify. Professor Wimmer has recently proposed a simple method to form elaidin, which can be used to detect the adulteration of almond and olive oils with drying oils. He generates nitrous acid by mixing iron filings with nitric acid in a glass bottle. The vapor of nitrous acid is then passed through a glass tube into water, where the oil to be tested is placed. If almond or olive oil contains only a small amount of poppy oil, it will completely turn into crystallized elaidin, while the poppy oil will float on top in drops.
COLORING MATTER OF VOLATILE OILS.
BY G.E. SACHSSE.
It is well known that most ethereal oils are colorless; however, there are a great number colored, some of which are blue, some green, and some yellow. Up to the present time the question has not been decided, whether it is the necessary property of ethereal oils to have a color, or whether their color is not due to the presence of some coloring matter which can be removed. It is most probable that their color arises from the presence of a foreign substance, as the colored ethereal oils can at first, by careful distillation, be obtained colorless, whilst later the colored portion passes over. Subsequent appearances lead to the solution of the question, and are certain evidence that ethereal oils, when they are colored, owe their color to peculiar substances which, by certain conditions, may be communicated from one oil to another. When a mixture of oils of wormwood, lemons, and cloves is subjected to distillation, the previously green-colored oil of wormwood passes over, at the commencement, colorless, while, towards the end of the distillation, after the receiver has been frequently charged, the oil of cloves distils over in very dense drops of a dark green color. It therefore appears that the green coloring matter of the oil of wormwood has been transferred to the oil of cloves.—Zeitschrift für Pharmacie.
It’s well known that most essential oils are colorless; however, there are quite a few that are colored, some blue, some green, and some yellow. So far, it hasn't been decided whether it's a necessary feature of essential oils to have color or if their color comes from some coloring substance that can be removed. It’s most likely that their color results from a foreign substance, as the colored essential oils can initially be distilled to become colorless, while later the colored part is collected. Further observations provide clarity on this issue and confirm that when essential oils are colored, they owe their color to specific substances that, under certain conditions, can be transferred from one oil to another. When a mixture of oils from wormwood, lemons, and cloves is distilled, the initially green-colored oil from wormwood first distills colorless, while toward the end of the process, after the receiver has filled up multiple times, the oil of cloves distills over in heavy drops of dark green. This suggests that the green coloring of the wormwood oil has been transferred to the oil of cloves.—Zeitschrift für Pharmacie.
ARTIFICIAL PREPARATION OF OIL OF CINNAMON.
BY A. STRECKER.
Some years since, Strecker has shown that styrone, which is obtained when styracine is treated with potash, is the alcohol of cinnamic acid. Wolff has converted this alcohol by oxidizing agents into cinnamic acid. The author has now proved that under the same conditions by which ordinary alcohol affords aldehyde, styrone affords the aldehyde of cinnamic acid, that is, oil of cinnamon. It is only necessary to moisten platinum black with styrone, and let it remain in the air some days, when by means of the bisulphite of potash the aldehyde double compound may be obtained in crystals, which should be washed in ether. By the addition of diluted sulphuric acid, the aldehyde of cinnamic acid is afterwards procured pure. These crystals also dissolve in nitric acid, and then form after a few moments crystals of the nitrate of the hyduret of cinnamyle. The conversion of styrone into the hyduret of cinnamyle by the action of the platinum black is shown by the following equation:
A few years ago, Strecker demonstrated that styrone, which is produced when styracine is treated with potash, is the alcohol derived from cinnamic acid. Wolff has transformed this alcohol into cinnamic acid using oxidizing agents. The author has now proven that under the same conditions in which regular alcohol produces aldehyde, styrone produces the aldehyde of cinnamic acid, known as oil of cinnamon. To achieve this, it’s enough to moisten platinum black with styrone and leave it exposed to air for a few days; then, by using bisulphite of potash, the aldehyde double compound can be crystallized and should be washed with ether. By adding diluted sulphuric acid, the pure aldehyde of cinnamic acid can then be obtained. These crystals also dissolve in nitric acid, subsequently forming crystals of the nitrate of the hyduret of cinnamyle after a few moments. The transformation of styrone into the hyduret of cinnamyle through the action of platinum black can be represented by the following equation:
DETECTION OF SPIKE OIL AND TURPENTINE IN LAVENDER OIL
BY DR. J. GASTELL.
There are two kinds of lavender oil known in commerce; one, which is very dear, and is obtained from the flowers of the Lavandula vera; the other is much cheaper, and is prepared from the flowers of the Lavandula spica. The latter is generally termed oil of spike. In the south of France, whether the oil be distilled from the flowers of the Lavandula vera or Lavandula spica, it is named oil of lavender.
There are two types of lavender oil available on the market; one is quite expensive and comes from the flowers of the Lavandula vera; the other is much cheaper and is made from the flowers of the Lavandula spica. The latter is usually called oil of spike. In the south of France, regardless of whether the oil is distilled from the flowers of Lavandula vera or Lavandula spica, it is referred to as oil of lavender.
By the distillation of the whole plant or only the stalk and the leaves, a small quantity of oil is obtained, which is rich in camphor, and is there called oil of spike. Pure oil of lavender should have a specific gravity from .876 to .880, and be completely soluble in five parts of alcohol of a specific gravity of .894. A greater specific gravity shows that it is mixed with oil of spike; and a less solubility, that it contains oil of turpentine.
By distilling the entire plant or just the stalk and leaves, a small amount of oil is produced that is rich in camphor, known there as oil of spike. Pure lavender oil should have a specific gravity of .876 to .880 and be fully soluble in five parts of alcohol with a specific gravity of .894. A higher specific gravity indicates it’s mixed with oil of spike; and lower solubility suggests it contains oil of turpentine.
DIFFERENT ORANGE-FLOWER WATERS FOUND IN COMMERCE
BY M. LEGUAY.
There are three sorts of orange-flower waters found in commerce. The first is distilled from the flowers; the second is made with distilled water and neroli; and the third is distilled from the leaves, the stems, and the young unripe fruit of the orange tree. The first may be easily distinguished by the addition of a few drops of sulphuric acid to some of the water in a tube; a fine rose color is almost immediately produced. The second also gives the same color when it is freshly prepared; but after a certain time, two or three months at the farthest, this color is no longer produced, and the aroma disappears completely. The third is not discolored by the addition of the sulphuric acid; it has scarcely any odor, and that rather an odor of the lemon plant than of orange-flowers.—Bulletin de la Société Pharmaceutique d'Indre et Loire.
There are three types of orange blossom waters available commercially. The first is distilled from the flowers; the second is made with distilled water and neroli; and the third is distilled from the leaves, stems, and immature fruit of the orange tree. You can easily tell the first type by adding a few drops of sulfuric acid to some of the water in a tube; a beautiful rose color will appear almost immediately. The second type also produces the same color when freshly prepared, but after a while, usually two or three months at most, this color fades and the scent completely disappears. The third type remains unchanged by the addition of sulfuric acid; it has very little odor, which is more reminiscent of the lemon plant than of orange blossoms.—Bulletin de la Société Pharmaceutique d'Indre et Loire.
A FORMULA FOR CONCENTRATED ELDER-FLOWER WATER.
Krembs recommends the following process for making a concentrated elder-flower water, from which he states the ordinary water can be extemporaneously prepared, of excellent quality, and of uniform strength:—2 lbs. of the flowers are to be distilled with water until that which passes into the receiver has lost nearly all perfume. This will generally happen when from 15 to 18 pounds have passed over. To the distillate, 2 lbs. of alcohol are to be added, and the mixture distilled until about 5 lbs. are collected. This liquor contains all the odor of the flowers. To make the ordinary water, 2 ounces of the concentrated water are to be added to 10 ounces of distilled water.—Buchner's Report.
Krembs suggests the following method for making concentrated elderflower water, which he says can be easily turned into high-quality, consistent ordinary water: Distill 2 lbs. of the flowers with water until the distillate has almost lost all its fragrance. This typically occurs when 15 to 18 pounds have been collected. Next, add 2 lbs. of alcohol to the distillate and continue distilling until you have about 5 lbs. of liquid. This final product retains all the flower's scent. To create the ordinary water, mix 2 ounces of the concentrated water with 10 ounces of distilled water.—Buchner's Report.
PRACTICAL REMARKS ON SPIRIT OF WINE.
BY THOMAS ARNALL.
The strength of spirit of wine is, by law, regulated by proof spirit (sp. gr. .920) as a standard; and accordingly as it is either stronger or weaker than the above, it is called so much per cent. above or below proof. The term per cent. is used in this instance in a rather peculiar sense. Thus, spirit of wine at 56 per cent. overproof, signifies that 100 gallons of it are equal to 156 gallons of proof spirit; while a spirit at 20 per cent. underproof, signifies that 100 gallons are equal to 80 gallons at proof. The rectified spirit of the Pharmacopœia is 56 per cent. overproof, and may be reduced to proof by strictly adhering to the directions there given, viz., to mix five measures with three of water. The result, however, will not be eight measures of proof spirit; in consequence of the contraction which ensues, there will be a deficiency of about ℥iv in each gallon. This must be borne in mind in preparing tinctures.
The strength of distilled wine is legally defined by proof spirit (specific gravity .920), and so if it is either stronger or weaker than that standard, it is referred to as being a certain percentage above or below proof. The term percent is used in a somewhat unique way here. For example, a spirit of wine that is 56 percent overproof means that 100 gallons of it equals 156 gallons of proof spirit, while a spirit that is 20 percent underproof means that 100 gallons equals 80 gallons of proof. The rectified spirit in the Pharmacopœia is 56 percent overproof and can be brought down to proof by carefully following the instructions, which say to mix five measures with three measures of water. However, the result will not yield eight measures of proof spirit; due to the contraction that occurs, there will be a shortfall of about ℥iv in each gallon. This needs to be kept in mind when preparing tinctures.
During a long series of experiments on the preparation of ethers, it appeared a desideratum to find a ready method of ascertaining how much spirit of any density would be equal to one chemical equivalent of absolute alcohol. By a modification of a rule employed by the Excise, this question may be easily solved. The Excise rule is as follows:—
During a long series of experiments on making ethers, it became necessary to find an easy way to determine how much spirit of any density would be equivalent to one chemical equivalent of pure alcohol. By modifying a rule used by the Excise, this question can be easily answered. The Excise rule is as follows:—
To reduce from any given strength to any required strength, add the overproof per centage to 100, or subtract the underproof per centage from 100. Multiply the result by the quantity of spirit, and divide the product by the number obtained by adding the required per centage overproof, or subtracting the required per centage underproof, to or from 100, as the case may be. The result will give the measure of the spirit at the strength required.
To adjust a spirit from any given strength to the needed strength, add the overproof percentage to 100, or subtract the underproof percentage from 100. Multiply the result by the amount of spirit, and then divide that product by the number you get by adding the required overproof percentage or subtracting the required underproof percentage from 100, depending on the situation. The outcome will provide the measure of the spirit at the desired strength.
Thus, suppose you wished to reduce 10 gallons of spirit, at 54 overproof, down to proof, add 54 to 100 = 154; multiply by the quantity, 10 gallons (154 × 10) = 1540. The required strength being proof, of course there is nothing either to add to or take from 100; therefore, 1540 divided by 100 = 15.4 gallons at proof; showing that 10 gallons must be made to measure 15 gallons, 3 pints, 4 fl. oz., by the addition of water.
Thus, if you wanted to reduce 10 gallons of spirit at 54 overproof down to proof, you would add 54 to 100 to get 154. Then, multiply that by the quantity, which is 10 gallons (154 × 10 = 1540). The required strength being proof means there's nothing to add or subtract from 100; so, 1540 divided by 100 equals 15.4 gallons at proof. This shows that 10 gallons must be adjusted to measure 15 gallons, 3 pints, and 4 fluid ounces by adding water.
To ascertain what quantity of spirit of any given strength will contain one equivalent of absolute alcohol. Add the overproof per centage of the given spirit to 100, as before; and with the number thus obtained divide 4062.183. The result gives in gallons the quantity equal to four equivalents (46 × 4).
To determine how much of a spirit with a certain strength contains one equivalent of absolute alcohol, add the overproof percentage of the spirit to 100, as before. Then divide 4062.183 by that number. The result shows, in gallons, the quantity equal to four equivalents (46 × 4).
Example.—How much spirit at 54 per cent. overproof is equal to 1 equivalent of absolute alcohol?
Example.—How much liquor at 54 percent overproof is equal to 1 equivalent of pure alcohol?
Here,
Here,
54 + 100 = 154 and 4062.183 = 26.3778 galls., or 26 galls. 3 pts.
————
154
54 + 100 = 154 and 4062.183 = 26.3778 gallons, or 26 gallons 3 pints.
Understood! Please provide the text you'd like me to modernize.
154
which, divided by 4, gives 6 gallons, 4 pints, 15 oz.
which, divided by 4, gives 6 gallons, 4 pints, 15 oz.
Suppose the spirit to be 60 overproof,—
Suppose the spirit is 60 overproof,—
4062.183 {one-fourth of which is equal
then ————— = 25.388 gallons, {to 6 gallons, 2 pints,
(100 + 60) {15-1/2 oz.
4062.183 {one-fourth of which equals
then ————— = 25.388 gallons, {to 6 gallons, 2 pints,
(100 + 60) {15.5 oz.
This rule is founded on the following data. As a gallon of water weighs 10 lbs., it is obvious that the specific gravity of any liquid multiplied by 10 will give the weight of one gallon. The specific gravity of absolute alcohol is 0.793811; hence, the weight of one gallon will be 7.93811 lbs., and its strength is estimated at 75.25 overproof.
This rule is based on the following information. Since a gallon of water weighs 10 lbs., it’s clear that the specific gravity of any liquid multiplied by 10 will tell us the weight of one gallon. The specific gravity of pure alcohol is 0.793811; therefore, the weight of one gallon will be 7.93811 lbs., and its strength is estimated at 75.25 overproof.
4 equivalents of alcohol = 46 × 4 = 184,
and
23.17936 gallons × 7.93811 lbs. per gallon, also = 184.0003094.
4 equivalents of alcohol = 46 × 4 = 184,
and
23.17936 gallons × 7.93811 lbs. per gallon, also = 184.0003094.
The rule might have been calculated so as to show at once the equivalent, without dividing by 4; but it would have required several more places of decimals; it will give the required quantity to a fraction of a fluid drachm.
The rule might have been designed to show at once the equivalent without dividing by 4, but it would have needed several more decimal places; it will provide the required amount to a fraction of a fluid drachm.
PURIFICATION OF SPIRITS BY FILTRATION.
BY MR. W. SCHAEFFER.
Instead of resorting to repeated distillations for effecting the purification of spirits, Mr. Schaeffer proposes the use of a filter. In a suitable vessel, the form of which is not material, a filtering bed is constructed in the following manner:—On a false perforated bottom, covered with woollen or other fabric, a layer of about six inches of well-washed and very clean river sand is placed; next about twelve inches of granular charcoal, preferring that made from birch; on the charcoal is placed a layer of about one inch of wheat, boiled to such an extent as to cause it to swell as large as possible, and so that it will readily crush between the fingers. Above this is laid about ten inches of charcoal, then about one inch of broken oyster shells, and then about two inches more of charcoal, over which is placed a layer of woollen or other fabric, and over it a perforated partition, on to which the spirit to be filtered is poured; the filter is kept covered, and in order that the spirit may flow freely into the compartment of the filter below the filtering materials, a tube connects such lower compartment with the upper compartment of the filter, so that the air may pass freely between the lower and upper compartments of the filter. On each, of the several strata above described, it is desirable to place a layer of filtering paper.
Instead of repeatedly distilling to purify spirits, Mr. Schaeffer suggests using a filter. In a suitable vessel, which can take any form, a filtering bed is made as follows: On a false perforated bottom covered with wool or another fabric, place about six inches of well-washed and very clean river sand. Next, add about twelve inches of granular charcoal, preferably made from birch. On top of the charcoal, add a layer of about one inch of wheat, boiled until it swells as much as possible and can be easily crushed between fingers. Above this, lay about ten inches of charcoal, then about one inch of broken oyster shells, and then about two more inches of charcoal. Over that, place a layer of wool or another fabric, followed by a perforated partition where the spirit to be filtered is poured. The filter is kept covered, and to allow the spirit to flow freely into the compartment below the filtering materials, a tube connects the lower compartment with the upper one, so air can move freely between them. It's recommended to place a layer of filtering paper on each of the several layers described above.
The charcoal suitable for the above purpose is not such as is obtained in the ordinary mode of preparation. It is placed in a retort or oven, and heated to a red heat until the blue flame has passed off, and the flame become red. The charcoal is then cooled in water, in which carbonate of potash has previously been dissolved, in the proportion of two ounces of carbonate to fifty gallons of water. The charcoal being deprived of the water is then reduced to a granular state, in which condition it is ready for use.
The charcoal suitable for this purpose isn't made in the usual way. It's put in a retort or oven and heated until it glows red, after the blue flame has gone out and the flame turns red. After that, it's cooled in water that has had carbonate of potash dissolved in it, using two ounces of carbonate per fifty gallons of water. Once the charcoal is dry, it’s then crushed into granules, and at this stage, it’s ready to be used.
ON ESSENTIAL OIL OR OTTO OF LEMONS.
BY JOHN S. COBB.
(Read before the Chemical Discussion Society.)
(Read before the Chemical Discussion Society.)
I have recently made some experiments with oil of lemons, of which the following is a short account:—
I recently did some experiments with lemon oil, and here’s a brief summary of what I found:—
Being constantly annoyed by the deposit and alteration in my essence of lemons, I have tried various methods of remedying the inconvenience.
Being constantly irritated by the change in my lemon essence, I've tried different ways to fix the problem.
I first tried redistilling it, but besides the loss consequent on distilling small quantities, the flavor is thereby impaired. As the oil became brighter when heated, I anticipated that all its precipitable matter would be thrown down at a low temperature, and I applied a freezing mixture, keeping the oil at zero for some hours. No such change, however, took place.
I first tried redistilling it, but apart from the loss that happens when distilling small amounts, the flavor gets affected. As the oil got brighter when heated, I thought that all the solid particles would settle out at a low temperature, so I used a freezing mixture and kept the oil at zero degrees for several hours. However, no change occurred.
The plan which I ultimately decided upon as the best which I had arrived at, was to shake up the oil with a little boiling water, and to leave the water in the bottle; a mucilaginous preparation forms on the top of the water, and acquires a certain tenacity, so that the oil may be poured off to nearly the last, without disturbing the deposit. Perhaps cold water would answer equally well, were it carefully agitated with the oil and allowed some time to settle. A consideration of its origin and constitution, indeed, strengthens this opinion; for although lemon otto is obtained both by distillation and expression, that which is usually found in commerce is prepared by removing the "flavedo" of lemons with a rasp, and afterwards expressing it in a hair sack, allowing the filtrate to stand, that it may deposit some of its impurities, decanting and filtering. Thus obtained it still contains a certain amount of mucilaginous matter, which undergoes spontaneous decomposition, and thus (acting, in short, as a ferment) accelerates a similar change in the oil itself. If this view of its decomposition be a correct one, we evidently, in removing this matter by means of the water, get rid of a great source of alteration, and attain the same result as we should by distillation, without its waste or deterioration in flavor.
The plan I ultimately decided was the best was to mix the oil with some boiling water and leave the water in the bottle. A thick preparation forms on top of the water, which becomes sticky enough that the oil can be poured off almost completely without stirring up the sediment. Cold water might work just as well if it’s mixed carefully with the oil and allowed time to settle. Considering its origin and makeup supports this idea; while lemon otto can be produced through both distillation and expression, what you usually find in stores is made by scraping off the "flavedo" of lemons and then pressing it in a cloth sack, letting the liquid sit so it can settle out some impurities, and then decanting and filtering it. This method still contains a certain amount of thick substance that decomposes on its own and acts like a ferment, speeding up a similar change in the oil. If this explanation of its decomposition is correct, then by using water to remove this substance, we get rid of a significant source of change and achieve the same result as we would with distillation, but without wasting or ruining the flavor.
I am, however, aware that some consider the deposit to be modified resin.[H] Some curious experiments of Saussure have shown that volatile oils absorb oxygen immediately they have been drawn from the plant, and are partially converted into a resin, which remains dissolved in the remainder of the essence.
I know that some people think the deposit is altered resin.[H] Some interesting experiments by Saussure have demonstrated that volatile oils soak up oxygen as soon as they're extracted from the plant, and are partially transformed into a resin, which stays dissolved in the rest of the essence.
He remarked that this property of absorbing oxygen gradually increases, until a maximum is attained, and again diminishes after a certain lapse of time. In the oil of lavender this maximum remained only seven days, during each of which it absorbed seven times its volume of oxygen. In the oil of lemons the maximum was not attained until at the end of a month; it then lasted twenty-six days; during each of which it absorbed twice its volume of oxygen. The oil of turpentine did not attain the maximum for five months, it then remained for one month, during which time it absorbed daily its own volume of oxygen.
He noted that the ability to absorb oxygen gradually increases until it reaches a peak and then decreases after some time. In lavender oil, this peak lasted just seven days, during which it absorbed seven times its volume of oxygen. In lemon oil, the peak wasn't reached until the end of a month; it then lasted for twenty-six days, absorbing twice its volume of oxygen each day. Turpentine oil didn’t reach its peak for five months, but once it did, it lasted for one month, absorbing its own volume of oxygen daily.
It is the resin formed by the absorption of oxygen, and remaining dissolved in the essence, which destroys its original flavor. The oil of lemons presents a very great analogy with that of oil of turpentine, so far as regards its transformations, and its power of rotating a ray of polarized light. Authorities differ as regards this latter property. Pereira states that the oil of turpentine obtained by distillation with water, from American turpentine, has a molecular power of right-handed rotation, while the French oil of turpentine had a left-handed rotation. Oil of lemons rotates a ray of light to the right, but in France a distilled oil of lemons, sold as scouring drops for removing spots of grease, possesses quite the opposite power of rotation, and has lost all the original peculiar flavor of the oil. Oil of lemons combines with hydrochloric acid to form an artificial camphor, just in the same manner as does oil of turpentine, but its atom is only one half that of the oil of turpentine. The artificial camphor of oil of lemons is represented by the formula, C10H8HCl; the artificial camphor of oil of turpentine by C20H16HCl.
It’s the resin that forms when oxygen is absorbed and stays dissolved in the essence that ruins its original flavor. Lemon oil is very similar to turpentine oil in terms of how it changes and its ability to rotate polarized light. Experts have different opinions on this last property. Pereira mentions that turpentine oil distilled with water from American turpentine rotates light to the right, while French turpentine oil rotates it to the left. Lemon oil rotates light to the right, but in France, a distilled lemon oil sold as scouring drops for removing grease stains has the opposite rotation and has lost all its original distinct flavor. Lemon oil reacts with hydrochloric acid to create an artificial camphor, just like turpentine oil does, but its molecular size is only half that of turpentine oil. The artificial camphor from lemon oil is represented by the formula, C10H8HCl; the artificial camphor from turpentine oil is represented by C20H16HCl.
According to M. Biot, the camphor formed by the oil of lemons does not exercise any action on polarized light, whilst the oil of lemons itself rotates a ray to the right. The camphor from oil of turpentine, on the contrary, does exercise on the polarized ray the same power as the oil possessed while in its isolated state, of rotating to the left. These molecular properties establish an essential difference between the oils of turpentine and lemons, and may serve to detect adulteration and fraud. It is also a curious fact, that from the decomposition of these artificial camphors by lime, volatile oils may be obtained by distillation, isomeric with the original oils from which the camphors were formed; but in neither case has the new product any action on polarized light.
According to M. Biot, the camphor made from lemon oil doesn’t affect polarized light, while lemon oil itself rotates a ray to the right. In contrast, the camphor derived from turpentine oil does have the same ability to rotate the polarized ray to the left as the oil did in its pure form. These molecular properties highlight a key difference between turpentine and lemon oils, and they can be used to identify adulteration and fraud. Interestingly, when these synthetic camphors break down with lime, volatile oils can be obtained through distillation that are isomeric with the original oils used to create the camphors; however, in both cases, the new product has no effect on polarized light.
In conclusion, I would recommend that this oil, as well as all other essential oils, be kept in a cool, dark place, where no very great changes of temperature occur.
In conclusion, I recommend storing this oil, along with all other essential oils, in a cool, dark place where there aren’t any extreme temperature changes.
BENZOIC ACID, AND TESTS FOR ITS PURITY.
BY W. BASTICK.
Dr. Mohr's process for obtaining benzoic acid, which is adopted by the Prussian Pharmacopœia, unquestionably has the reputation of being the best. According to this process, coarsely-powdered gum benzoin is to be strewed on the flat bottom of a round iron pot which has a diameter of nine inches, and a height of about two inches. On the surface of the pot is spread a piece of filtering paper, which is fastened to its rim by starch paste. A cylinder of very thick paper is attached by means of a string to the top of the iron pot. Heat is then applied by placing the pot on a plate covered with sand, over the mouth of a furnace. It must remain exposed to a gentle fire from four to six hours. Mohr usually obtains about an ounce and a half of benzoic acid from twelve ounces of gum benzoin by the first sublimation. As the gum is not exhausted by the first operation, it may be bruised when cold and again submitted to the action of heat, when a fresh portion of benzoic acid will sublime from it. This acid thus obtained, is not perfectly pure and white, and Mohr states that it is a question, in a medicinal and perfumery point of view, whether it is so valuable when perfectly pure, as when it contains a small portion of a fragrant volatile oil, which rises with it from the gum in the process of sublimation.
Dr. Mohr's method for getting benzoic acid, which is recognized by the Prussian Pharmacopœia, is widely regarded as the best. In this method, coarsely powdered gum benzoin is spread on the flat bottom of a round iron pot that measures about nine inches in diameter and two inches in height. A piece of filtering paper is placed on the surface of the pot, secured to its rim with starch paste. A thick paper cylinder is attached to the top of the iron pot with a string. Heat is applied by setting the pot on a plate filled with sand, positioned over a furnace. The pot needs to be exposed to a gentle fire for four to six hours. Typically, Mohr gets about an ounce and a half of benzoic acid from twelve ounces of gum benzoin in the first sublimation. Since the gum isn’t fully used up after the first step, it can be crushed once it’s cool and then subjected to heat again, allowing more benzoic acid to sublime from it. The acid obtained this way isn’t completely pure and white, and Mohr mentions that, from a medicinal and fragrance perspective, it’s debatable whether it’s more valuable when it’s perfectly pure or when it contains a small amount of a fragrant volatile oil that rises with it during sublimation.
The London Pharmacopœia directs that it shall be prepared by sublimation, and does not prescribe that it shall be free from this oil, to which it principally owes its agreeable odor.
The London Pharmacopoeia states that it should be made by sublimation and does not require that it be free from this oil, which is mainly responsible for its pleasant scent.
By the second sublimation the whole of the benzoic acid is not volatilized. What remains in the resin may be separated by boiling it with caustic lime, and precipitating the acid from the resulting benzoate of lime with hydrochloric acid. Benzoic acid can be obtained also in the wet way, and the resin yields a greater product in this process than in the former; yet it has a less perfumery value, because it is free from the volatile oil which, as above stated, gives it its peculiar odor. The wet method devised by Scheele is as follows:—Make one ounce of freshly-burnt lime into a milk with from four to six ounces of hot water. To the milk of lime, four ounces of powdered benzoin and thirty ounces of water are to be added, and the mixture boiled for half an hour, and stirred during this operation, and afterwards strained through linen. The residue must be a second time boiled with twenty ounces of water and strained, and a third time with ten ounces; the fluid products must be mixed and evaporated to one-fourth of their volume, and sufficient hydrochloric acid added to render them slightly acid. When quite cold, the crystals are to be separated from the fluid by means of a linen strainer, upon which they are to be washed with cold water, and pressed, and then dissolved in hot distilled water, from which the crystals separate on cooling. When hydrochloric acid is added to a cold concentrated solution of the salts of benzoic acid, it is precipitated as a white powder. If the solution of the salts of this acid is too dilute and warm, none or only a portion of the benzoic acid will be separated. However, the weaker the solution is, and the more slowly it is cooled, the larger will be the crystals of this acid. In the preparation of this acid in the wet way, lime is to be preferred to every other base, because it forms insoluble combinations with the resinous constituents of the benzoin, and because it prevents the gum-resin from conglomerating into an adhesive mass, and also because an excess of this base is but slightly soluble.
By the second sublimation, not all of the benzoic acid is vaporized. The remaining substance in the resin can be separated by boiling it with caustic lime and then precipitating the acid from the resulting benzoate of lime using hydrochloric acid. Benzoic acid can also be produced using a wet method, which yields a larger amount from the resin than the previous method; however, it has less fragrance value because it lacks the volatile oil that gives it its distinctive smell. The wet method developed by Scheele is as follows: Make one ounce of freshly burned lime into a milk with four to six ounces of hot water. To this lime milk, add four ounces of powdered benzoin and thirty ounces of water, and boil the mixture for half an hour, stirring it during this time, then strain it through linen. The residue must be boiled a second time with twenty ounces of water and strained, and a third time with ten ounces; mix the liquid products and evaporate them to one-fourth of their volume, then add enough hydrochloric acid to make them slightly acidic. When completely cool, separate the crystals from the liquid using a linen strainer, wash them with cold water, press them, and then dissolve in hot distilled water, allowing the crystals to form again as it cools. When hydrochloric acid is added to a cold concentrated solution of the salts of benzoic acid, it precipitates as a white powder. If the solution of the salts of this acid is too diluted and warm, little or none of the benzoic acid will be separated. However, the weaker the solution is and the more slowly it cools, the larger the crystals of this acid will be. In preparing this acid using the wet method, lime is preferred over any other base because it forms insoluble compounds with the resinous components of benzoin, prevents the gum-resin from clumping together into a sticky mass, and because an excess of this base is only slightly soluble.
Stoltze has recommended a method by which all the acid can be removed from the benzoin:—The resin is to be dissolved in spirit, to which is to be added a watery solution of carbonate of soda, decomposed previously by alcohol. The spirit is to be removed by distillation, and the remaining watery solution, from which the resin has been separated by filtration, treated with dilute sulphuric acid, to precipitate the benzoic acid. This method gives the greatest quantity of acid, but is attended with a sacrifice of time and alcohol, which renders it in an economical point of view inferior to the above process of Scheele. It is so far valuable, that the total acid contents of the resin can be determined by it.
Stoltze has suggested a method to completely remove the acid from the benzoin: First, dissolve the resin in alcohol, then add a water solution of sodium carbonate, which has been previously decomposed with alcohol. Remove the alcohol by distillation, and treat the remaining water solution, from which the resin has been filtered out, with diluted sulfuric acid to precipitate the benzoic acid. This method yields the largest amount of acid but requires more time and alcohol, making it less economical compared to Scheele's method. However, it is valuable for determining the total acid content of the resin.
Dr. Gregory considers the following process for obtaining benzoic acid the most productive. Dissolve benzoin in strong alcohol, by the aid of heat, and add to the solution, whilst hot, hydrochloric acid, in sufficient quantity to precipitate the resin. When the mixture is distilled, the benzoic acid passes over in the form of benzoic ether. Distillation must be continued as long as any ether passes over. Water added towards the end of the operation will facilitate the expulsion of the ether from the retort. When the ether ceases to pass over, the hot water in the retort is filtered, which deposits benzoic acid on cooling. The benzoic ether and all the distilled liquids are now treated with caustic potash until the ether is decomposed, and the solution is heated to boiling, and super-saturated with hydrochloric acid, which afterwards, on cooling, deposits, in crystals, benzoic acid.
Dr. Gregory thinks the following process for getting benzoic acid is the most effective. Dissolve benzoin in strong alcohol with heat, and while the solution is hot, add enough hydrochloric acid to make the resin precipitate. When you distill the mixture, the benzoic acid comes out as benzoic ether. Keep distilling until no more ether comes over. Adding water towards the end will help get the ether out of the retort. Once the ether stops coming over, filter the hot water in the retort, which will leave behind benzoic acid when it cools. Now, treat the benzoic ether and all the distilled liquids with caustic potash until the ether breaks down, then heat the solution to boiling and super-saturate it with hydrochloric acid, which will later form crystals of benzoic acid when cooled.
Benzoic acid, as it exists in the resin, is the natural production of the plant from which the resin is derived. It may also be produced artificially. Abel found that when cumole (C18H12) was treated with nitric acid, so dilute that no red vapors were evolved for several days, this hydro-carbon was converted into benzoic acid. Guckelberger has, by the oxidation of casein with peroxide of manganese and sulphuric acid, obtained as one of the products benzoic acid. Albumen, fibrin, and gelatin yielded similar results when treated as above. Wöhler has detected benzoic acid in Canadian castor, along with salicin. It is also formed by the oxidation of the volatile oil of bitter almonds. Benzoate of potash results when chloride of benzoyle is treated with caustic potash. Benzoic acid in the animal economy is converted into hippuric acid, which may by the action of acids, be reconverted into benzoic acid.
Benzoic acid, found in resin, is a natural product of the plant from which the resin comes. It can also be produced artificially. Abel discovered that when cumole (C18H12) was treated with a very dilute nitric acid that did not release red vapors for several days, this hydrocarbon was turned into benzoic acid. Guckelberger obtained benzoic acid by oxidizing casein with manganese peroxide and sulfuric acid. Albumen, fibrin, and gelatin showed similar results when treated in the same way. Wöhler identified benzoic acid in Canadian castor along with salicin. It is also formed by oxidizing the volatile oil from bitter almonds. Benzoate of potash is produced when benzoyl chloride is treated with caustic potash. In the animal body, benzoic acid is transformed into hippuric acid, which can, through the action of acids, be turned back into benzoic acid.
Benzoic acid should be completely volatile, without leaving any ash or being carbonized when heated. When dissolved in warm water, to which a little nitric acid has been added, nitrate of silver and chloride of barium should produce no precipitates. Oxalate of potash should give no turbidity to an ammoniacal solution of this acid. When heated with an excess of caustic potash it should evolve no smell of ammonia, otherwise, it has been adulterated with sal ammoniac. In spirit, benzoic acid is easily soluble, and requires 200 parts of cold and 20 parts of boiling water to dissolve one part of it.
Benzoic acid should completely vaporize without leaving any residue or getting charred when heated. When mixed with warm water that has a bit of nitric acid added, neither silver nitrate nor barium chloride should create any precipitates. Potassium oxalate shouldn’t cause any cloudiness in an ammoniacal solution of this acid. When heated with excess caustic potash, it shouldn't emit any ammonia smell; if it does, that means it’s been mixed with ammonium chloride. In alcohol, benzoic acid is easily soluble, needing 200 parts of cold water and 20 parts of boiling water to dissolve one part of it.
ON THE COLORING-MATTERS OF FLOWERS.
BY FREMY AND CLOEZ.
Chemists possess only a very incomplete knowledge of the coloring matters of flowers. Their investigation involves difficulties which cannot be mistaken. The matters which color flowers are uncrystallized; they frequently change by the action of the reagents employed for their preparation; and, also, very brilliantly-colored flowers owe their color to very small quantities of coloring matter.
Chemists have only a limited understanding of the pigments found in flowers. Their research faces clear challenges. The substances that give flowers their color are uncrystallized; they often change when chemicals are used to prepare them; and highly colorful flowers get their brightness from very small amounts of pigment.
On the nature of the coloring matters of flowers several opinions have been expressed. Some observers have assumed that flowers owe their color to only two coloring matters, one of which is termed anthocyan, and the other anthoxanthine. Others will find a relation between the green coloring of leaves, the chlorophylle, and the coloring matters of flowers. They support their opinion generally on the results of the elementary analysis of those different bodies; but all chemists know that chlorophylle has not yet been prepared in a pure condition. Probably, it retains various quantities of fatty and albuminous bodies. Further, the coloring matters of flowers are scarcely known, so that it is impossible to establish relations supported by the necessarily uncertain composition of impure bodies.
People have expressed different opinions on what gives flowers their color. Some believe that there are only two colorants responsible: one called anthocyan and the other anthoxanthine. Others see a connection between the green pigment in leaves, chlorophyll, and the pigments in flowers. They generally base their views on the results of the elementary analysis of these different substances; however, all chemists understand that chlorophyll has yet to be isolated in a pure form. It probably contains various amounts of fatty and protein substances. Additionally, the pigments in flowers are not well understood, making it impossible to establish reliable connections based on the inevitably uncertain makeup of impure substances.
Some time since the blue color of flowers was ascribed to the presence of indigo; but Chevreul has shown, in a certain way, that the blue substance of flowers is always reddened by acids; and that with indigo it is quite different, which, as is known, retains its blue color even when the strongest acids are allowed to act on it.
Some time ago, the blue color of flowers was thought to come from indigo, but Chevreul has demonstrated that the blue pigment in flowers always turns red in the presence of acids. In contrast, indigo remains blue even when exposed to the strongest acids.
It is thus seen that the coloring matters of flowers have heretofore only in a superficial manner been examined, and that it is important to again undertake their complete examination, as these bodies are interesting to the chemist, because they are employed as reagents in the laboratory for the recognition of alkalies; and by an improved knowledge of them the florist might find the way by which he could give to cultivated flowers various colors.
It’s clear that the coloring substances in flowers have only been looked at superficially so far, and it's crucial to take a deeper look at them again. These substances are interesting to chemists because they are used as reagents in the lab to identify alkalis. A better understanding of them could help florists figure out how to produce different colors in cultivated flowers.
We have believed that before undertaking their elementary analysis, methods must be carefully sought for which can be followed for the obtainment of the coloring matters of flowers, and that it should be proved whether these substances are to be considered as independent bodies, or whether they proceed from one and the same matter, which is changed in various ways by the juices of the plant.
We believe that before starting their basic analysis, we need to carefully find methods that can be used to obtain the color compounds of flowers. We should also determine if these substances are independent entities or if they come from the same matter, which is altered in different ways by the plant's juices.
We now publish the results of our first investigations.
We are now sharing the results of our first investigations.
Blue Coloring Matter of Flowers (Cyanine).—The blue coloring matter of flowers we propose to call cyanine. To obtain this substance we treat the petals of Centauria cyanus, Viola odorata, or Iris pseudacorus, with boiling alcohol, by which the flowers are decolorized; and the liquid acquires immediately a fine blue color.
Blue Coloring Matter of Flowers (Cyanine).—The blue coloring matter of flowers will be referred to as cyanine. To obtain this substance, we treat the petals of Centauria cyanus, Viola odorata, or Iris pseudacorus with boiling alcohol, which decolorizes the flowers, and the liquid quickly takes on a beautiful blue color.
If the coloring matter is allowed to remain some time in contact with alcohol, it is perceived that the blue of the liquid gradually disappears, and soon a yellow brown coloration takes its place. The coloring matter has in this case suffered an actual reduction by the prolonged action of the alcohol, but it will again assume its original color when the alcohol is allowed to evaporate in the air. Nevertheless, the alcohol must not be allowed to remain in contact too long with the coloring matter, because the alcoholic extract will not then again assume its blue coloration by the action of oxygen.
If the dye is left in contact with alcohol for a while, you'll notice that the blue color of the liquid gradually fades, and soon it turns a yellow-brown color instead. In this case, the dye has actually been reduced due to the alcohol's prolonged effect, but it will regain its original color once the alcohol evaporates into the air. However, the alcohol shouldn't be left in contact with the dye for too long, because the alcoholic extract won't return to its blue color when exposed to oxygen.
The residue remaining from the evaporation of the alcohol is treated with water, which separates a fatty and resinous substance. The watery solution which contains the coloring matter is then precipitated by neutral acetate of lead. The precipitate, which possesses a beautiful green color, can be washed with plenty of water, and then decomposed with sulphuretted hydrogen; the coloring matter passes into the watery solution, which is carefully evaporated in a water-bath; the residue is again dissolved in absolute alcohol; and lastly, the alcoholic solution is mixed with ether, which precipitates the cyanine in the form of blue flocks.
The leftover substance from the evaporation of the alcohol is treated with water, which separates a fatty and resinous material. The watery solution containing the coloring matter is then precipitated with neutral lead acetate. The resulting precipitate, which has a beautiful green color, can be washed thoroughly with water and then broken down using hydrogen sulfide; the coloring matter moves into the watery solution, which is carefully evaporated in a water bath. The residue is then dissolved in pure alcohol, and finally, the alcoholic solution is mixed with ether, causing the cyanine to precipitate as blue flakes.
Cyanine is uncrystallizable, soluble in water and alcohol, insoluble in ether; acids, and acid salts color it immediately red; by alkalies it is, as known, colored green. Cyanine appears to behave as an acid, at least it forms with lime, baryta, strontia, oxide of lead, &c., green compounds insoluble in water.
Cyanine can't be crystallized, is soluble in water and alcohol, and is insoluble in ether; it immediately turns red when mixed with acids and acid salts, and as is known, it turns green when combined with alkalis. Cyanine seems to act like an acid, as it forms green compounds with lime, baryta, strontia, lead oxide, etc., that are insoluble in water.
Bodies absorbing oxygen, as sulphurous acid, phosphorous acid, and alcohols, decolorize it; under the influence of oxygen its color is restored.
Bodies absorbing oxygen, like sulfuric acid, phosphoric acid, and alcohols, cause it to lose color; when oxygen is present, its color returns.
We must here mention that Moroz has prepared a beautiful blue substance from Centauria cyanus by treatment with absolute alcohol.
We should mention that Moroz has created a beautiful blue substance from Centauria cyanus by treating it with pure alcohol.
Rose-red Coloring Matter.—We have employed alcohol to extract the substance which colors rose-red certain dahlias, roses, pœonias, &c. For the procuration of this coloring matter the method pursued is exactly as that for the preparation of cyanine.
Rose-red Coloring Matter.—We have used alcohol to extract the substance that gives certain dahlias, roses, peonies, etc. their rose-red color. The method used to obtain this coloring matter is exactly the same as the one used to prepare cyanine.
By an attentive comparison of the properties of this coloring matter with those of cyanine, we have found that the rose-red coloring matter is the same as the blue, or at least results from a modification of the same independent principle. It appears in the rose-red modification, when the juice of the plant, with which it exists in contact, possesses an acid reaction. We have always observed this acid reaction in the juices of plants with red or rose-red coloration, while the blue juices of plants have always exhibited an alkaline reaction.
By carefully comparing the properties of this dye with those of cyanine, we've discovered that the rose-red dye is the same as the blue one, or at least comes from a variation of the same independent principle. It shows up in the rose-red form when the plant juice it comes into contact with is acidic. We've consistently seen this acidic reaction in the juices of plants that are red or rose-red, while the blue juices of plants have always shown an alkaline reaction.
We have exposed most of the rose-red or red-colored flowers which are cultivated in the Paris Museum to the influence of alkalies, and have seen that they first become blue and then green by their action.
We have exposed most of the rose-red or red-colored flowers grown in the Paris Museum to the effects of alkalis, and we have observed that they first turn blue and then green as a result.
It is often perceived that certain rose-red flowers, as those of the Mallow, and in particular those of the Hibiscus Syriacus, acquire by fading a blue and then a green coloration, which change, as we have found, depends on the decomposition of an organic nitrogenous substance, which is found very frequently in the petals. This body generates as it decomposes ammonia, which communicates to the flowers the blue or green color. By action of weak acids, the petals can be restored to their rose-red color.
It's commonly believed that some rose-red flowers, like those of the Mallow and especially the Hibiscus Syriacus, fade to a blue and then a green color. This change, as we've discovered, is due to the breakdown of an organic nitrogenous substance that is often present in the petals. As this substance decomposes, it produces ammonia, which gives the flowers their blue or green tint. If weak acids are applied, the petals can be brought back to their original rose-red color.
The alteration of color of certain rose-red flowers can also be observed when the petals are very rapidly dried, for example, in vacuo, by which it cannot be easily assumed that a nitrogenous body has undergone decomposition to the evolution of ammonia. But, before all things, it must be mentioned that in this case the modification of color passes into violet, and never arrives at green; and, further, that it is always accompanied with the evolution of carbonic acid, which we have detected by a direct experiment. Petals which were before rose-red, and have become violet by slight drying, evolve carbonic acid, and on that account it may be assumed that the rose-red color is produced in the petals by this carbonic acid, and that by its expulsion the petals assume the blue color, by which the flowers with neutral juices are characterized.
The color change in some rose-red flowers can also be seen when the petals are dried quickly, for instance, in vacuo, which doesn't lead to the assumption that a nitrogenous compound has broken down to produce ammonia. However, it’s important to point out that in this case, the color change shifts to violet and never reaches green. Additionally, this process is always accompanied by the release of carbon dioxide, which we confirmed through a direct experiment. Petals that were originally rose-red and turned violet due to slight drying release carbon dioxide. Therefore, it can be assumed that the rose-red color in the petals is caused by this carbon dioxide, and with its removal, the petals shift to a blue color, which characterizes flowers with neutral juices.
We believe that we are able to speak with certainty that flowers with a rose-red, violet, or blue color, owe their coloration to one and the same substance, but which is modified in various ways by the influence of the juices of plants.
We believe we can confidently say that flowers with a rose-red, violet, or blue color get their color from the same substance, but it is altered in different ways by the influence of plant juices.
Scarlet-red flowers also contain cyanine reddened by an acid, but in such cases this substance is mixed with a yellow coloring matter which we will now describe.
Scarlet-red flowers also have cyanine that turns red when mixed with an acid, but in these instances, this substance is combined with a yellow coloring that we will describe next.
Yellow Coloring Matter.—The simplest experiments show that no analogy exists between the substance which colors flowers yellow and that of which we have already spoken. The agents which generate so easily with cyanine, the rose-red, violet, or green coloration, cannot in any case impart these colors to the yellow substance obtained from flowers.
Yellow Coloring Matter.—Basic experiments demonstrate that there’s no similarity between the substance that gives flowers their yellow color and the one we discussed earlier. The agents that easily produce cyanine, as well as rose-red, violet, or green colors, cannot, in any situation, transfer these colors to the yellow substance derived from flowers.
By the examination of the various yellow-colored flowers, we have ascertained that they owe their coloration to two substances, which differ from one another in their properties, and appear not to be derived from the same independent principle. One is completely insoluble in water, which we have termed xanthine, a name which Runge has given to a yellow matter from madder. As this name has not been accepted in science, we have employed it to denote one of the coloring matters of yellow flowers. The other substance is very soluble in water, and is by us termed xantheine.
By examining the different yellow flowers, we've determined that their color comes from two substances, which have distinct properties and don't seem to come from the same independent source. One is completely insoluble in water, which we've called xanthine, a name that Runge used for a yellow compound from madder. Since this name hasn't been widely accepted in science, we've used it to refer to one of the coloring agents in yellow flowers. The other substance is very soluble in water, and we call it xantheine.
Xanthine, or the Yellow Coloring Matter insoluble in water.—We have prepared this coloring matter from many yellow flowers, but chiefly from Helianthus annuus.
Xanthine, or the yellow pigment that doesn't dissolve in water.—We have made this pigment from various yellow flowers, but mainly from Helianthus annuus.
To obtain it we treat the flowers with boiling absolute alcohol, which dissolves the coloring matter in the heat, and by cooling almost completely allows it again to precipitate. The yellow deposit which is obtained in this way, is not pure xanthine, as it contains a rather considerable quantity of oil. To separate this oil we have recourse to a moderate saponification; thus, we heat the yellow precipitate with a small quantity of alkali to saponify the fatty body mixed with the xanthine, which even contains the xanthine dissolved. As the coloring matter is soluble in the soap solution, we do not treat the mass with water, but decompose it with an acid which isolates the xanthine and the fatty acids resulting from the saponification. This precipitate we treat with cold alcohol, which leaves behind the fatty acids, and dissolves the xanthine. This substance is a fine yellow color, insoluble in water, but soluble in alcohol and ether, which are thereby colored golden yellow. It appears to be uncrystallizable, and possesses the general properties of resins.
To get it, we soak the flowers in boiling absolute alcohol, which dissolves the color in the heat, and then, as it cools almost completely, it allows the color to settle again. The yellow deposit we get this way isn't pure xanthine, as it still contains a significant amount of oil. To separate the oil, we perform a mild saponification; we heat the yellow precipitate with a small amount of alkali to saponify the fatty substance mixed with the xanthine, which also includes the xanthine dissolved in it. Since the color is soluble in the soap solution, we don't wash the mass with water. Instead, we break it down with an acid that separates the xanthine from the fatty acids created by the saponification. We then treat this precipitate with cold alcohol, which leaves behind the fatty acids and dissolves the xanthine. This substance is a fine yellow color, insoluble in water but soluble in alcohol and ether, which turns a golden yellow. It seems to be uncrystallizable and has the general properties of resins.
Xanthine, in combination with cyanine, modified by the various juices of plants, communicates in variable proportions orange-yellow, scarlet-red, and red colors to flowers.
Xanthine, when mixed with cyanine and modified by different plant juices, gives flowers varying shades of orange-yellow, scarlet-red, and red.
Xantheine, or the Coloring Matter soluble in water.—By the preparation of the substance which colors yellow certain dahlias, it is at once perceived that it has no analogy to xanthine. The latter is as known insoluble in water, while the coloring matter under consideration is readily soluble in water.
To obtain the xanthine we treat the petals of yellow flowering dahlias with alcohol, which quickly dissolves the yellow coloring matter, besides the fat and resin. The solution is evaporated to dryness, and the residue treated with water, whereby the fat and resin are separated. The water is again evaporated to dryness, and the residue treated with absolute alcohol. The resulting solution diluted with water is mixed with neutral acetate of lead, which precipitates the coloring matters. The lead precipitate is then decomposed with sulphuric acid, upon which the xantheine which remains dissolved in the water is purified by alcohol.
To extract xanthine, we soak the petals of yellow flowering dahlias in alcohol, which quickly dissolves the yellow pigments, along with the fat and resin. The solution is then evaporated until dry, and the leftover material is treated with water to separate the fat and resin. The water is evaporated again until dry, and the residue is treated with pure alcohol. The resulting solution, when diluted with water and mixed with neutral lead acetate, causes the pigments to precipitate. The lead precipitate is then broken down with sulfuric acid, after which the xanthine that remains dissolved in the water is purified using alcohol.
Xantheine is soluble in water, alcohol, and ether, but crystallizes from none of these solutions. Alkalies color it intensely brown. Its power of coloration is considerable. It dyes various fabrics of a yellow tone, which is without brilliancy. Acids again destroy the brown coloration produced by alkalies. Xantheine combines with most metallic bases, and forms therewith yellow or brown insoluble lakes.
Xantheine dissolves in water, alcohol, and ether, but doesn’t crystallize from any of these solutions. Alkalies turn it a deep brown. Its coloring ability is significant. It dyes different fabrics a dull yellow. Acids then remove the brown color created by alkalies. Xantheine combines with most metallic bases to form yellow or brown insoluble compounds.
The facts here related agree with all which has been previously observed regarding the coloring matters of flowers. It is known that blue flowers can become red, and even white, where their coloring matter is destroyed, but never yellow—and vice versâ. These three coloring matters can generate the colors either alone or by admixture, which are seen in flowers; but whether they are the only matters which color flowers, we are at present unable to determine.—Journal de Pharmacie.
The facts here are consistent with everything that has been observed before about the coloring substances in flowers. It's known that blue flowers can turn red or even white when their coloring substance is destroyed, but they never turn yellow—and vice versa. These three coloring substances can produce the colors found in flowers either on their own or by mixing together, but we can't currently say if they are the only substances that color flowers.—Journal de Pharmacie.
IMPROVED PROCESS FOR BLEACHING BEES'-WAX AND THE FATTY ACIDS.
BY MR. G.F. WILSON.
This improved process consists of two parts:—1st, the application of highly-heated steam to heat the fatty matters under treatment, by which means the requisite heat for melting these substances is obtained, and at the same time the atmosphere is thereby excluded; the heated steam so applied in its passage off, carries with it the offensive smells given off by the fatty matters, and being made to traverse a pipe or passage up or along which gaseous chlorine is allowed to flow, a complete disinfection of the offensive products is thereby effected. 2dly, the treating of bees'-wax in a mixture of hard acid fat and bees'-wax, with compounds of chlorine and oxygen, preferring to employ that disengaged from chlorate of potash by treating it with sulphuric acid. For this purpose, Mr. Wilson takes at the rate, say, of a ton of yellow bees'-wax, and melts and boils it up with free steam for about half an hour. It is then allowed to stand a short time, and is then decanted into another vessel provided with a steam-pipe to emit free steam; about 20 lbs. of chlorate of potash is added, and the steam turned on; 80 lbs. of sulphuric acid, diluted with a like weight of water, is then gradually added. The matters are allowed to stand for a short time, and are then decanted into another vessel, and again boiled up with free steam, and treated with a like quantity of diluted sulphuric acid. The bees'-wax is then decanted into a receiver, and is ready for use. The bees'-wax may, before undergoing these processes, be combined and boiled up with a hard fatty acid, and then treated as above described.
This improved process has two parts: first, applying highly heated steam to heat the fatty substances we're working with. This method provides the necessary heat to melt these materials while also keeping out the surrounding air. As the heated steam is released, it carries away the unpleasant odors from the fatty substances, and as it moves through a pipe or passage where gaseous chlorine flows, it completely disinfects the unwanted byproducts. Second, we treat beeswax by mixing it with a blend of hard fatty acid and beeswax alongside chlorine and oxygen compounds, preferably using the chlorine released from potassium chlorate when it's treated with sulfuric acid. For this purpose, Mr. Wilson takes about a ton of yellow beeswax, melts it, and boils it with free steam for around half an hour. After letting it sit for a short time, he decants it into another vessel equipped with a steam pipe to emit free steam. Then, he adds about 20 lbs. of potassium chlorate and turns on the steam; he slowly adds 80 lbs. of sulfuric acid, diluted with an equal weight of water. The mixture is allowed to sit for a brief period and is then poured into another vessel, boiled again with free steam, and treated with the same amount of diluted sulfuric acid. Finally, the beeswax is poured into a container and is ready for use. Before going through these processes, the beeswax can be combined and boiled with a hard fatty acid, then treated as described above.
CHEMICAL EXAMINATION OF NAPLES SOAP.
A. Faiszt has submitted this celebrated shaving soap to analysis. He states that it is made by saponifying mutton fat with lime, and then separating the fatty acids from the soap thus formed, by means of a mineral acid. These fatty acids are afterwards combined with ordinary caustic potash to produce the Naples soap. He found that 100 parts of this soap contained
A. Faiszt has analyzed this well-known shaving soap. He says it's made by turning mutton fat into soap with lime, and then separating the fatty acids from the soap that’s formed using a mineral acid. These fatty acids are then mixed with regular caustic potash to create the Naples soap. He found that 100 parts of this soap contained
Parts. | |
Fatty acids, | 57.14 |
Potash combined with the fatty acids, | 10.39 |
Sulphate of potash, chloride of potassium, with a trace of carbonate of potash, | 4.22 |
Silica, &c., | 0.46 |
Water, | 27.68 |
——— | |
99.89 | |
Gewerbeblatt aus Wurttemberg. |
MANUFACTURE OF SOAP.
The removal of the duty from soap, and the consequent emancipation of this branch of industry from the tender mercies of the Excise, has given a fresh impetus to the manufacture of this important article of daily use, and enabled some processes to be practically carried out in England, which, previous to the removal of the duty, could not be adopted in this part of her Majesty's dominions.
The elimination of the tax on soap, and the resulting freedom of this industry from the strict control of the Excise, has reinvigorated the production of this essential everyday product. It has allowed certain processes to be effectively implemented in England that could not be used in this part of Her Majesty's territories before the tax was removed.
It will doubtless appear strange to those unacquainted with the circumstances, that owing to the mode of levying the duty by admeasurement, and not by actual weight, the maker of a particular kind of soap was debarred the privilege of manufacturing in this country. Fortunately for him, the manufacture of soap being free from all Excise restrictions in Ireland, he was enabled to carry out his process in the sister kingdom, whence it was exported to England, and admitted here on payment of the Customs' duty, which was the same as the Excise duty on its manufacture here. All this roundabout method of doing business is now done away with, and no restriction now exists to mar the peace of the soap manufacturer.
It might seem strange to those unfamiliar with the circumstances that, because the duty was charged based on measurements rather than actual weight, the producer of a specific type of soap was prevented from making it in this country. Fortunately for him, since soap production faced no Excise restrictions in Ireland, he was able to continue his process there, from where it was shipped to England, and allowed in here after paying the Customs duty, which was the same as the Excise duty for making it here. This complicated way of doing business has now been eliminated, and there are currently no restrictions to disrupt the soap manufacturer’s operations.
Amongst various new processes lately introduced is that of Mr. H.C. Jennings, which is practically carried out in the following manner:—
Among the various new processes recently introduced is that of Mr. H.C. Jennings, which is essentially carried out in the following way:—
Combine 1000 lbs. of stearic or margaric acid, as free from elaine or oleine as possible, or palmatine, or any vegetable or animal stearine or margarine, at the temperature of 212° Fahr., with a solution of bicarbonate of potash or soda, specific gravity 1500. Constantly stir or mix until an intimate combination is obtained, and that the elements will not part when tried upon glass or any other similar substance. When the mass is cooled down to about 60° Fahr. add one pound per cent. of liquor ammoniæ, specific gravity 880, and one pound per cent. of strongest solution of caustic potash; these are to be added gradually, and fully mixed or stirred until perfectly combined. Dissolve 15 to 18 pounds per cent. of common resin of commerce, by boiling it with a solution of subcarbonate of potash and common soda of commerce, in equal parts, as much as will give the solution a specific gravity of about 1800, when boiling hot. Mix these perfectly with the above-mentioned stearic or margaric acids, and carbonated alkali; then add a strong solution of caustic potash or soda, until a perfect saponification is produced. The dose of caustic alkali will much depend upon the purity of the stearine or margarine employed. The separation is now effected by using common salt, or sulphate of soda, &c., as is known and practised by soap manufacturers. If the soap intended to be produced is to be colorless, no resin must be employed, and a larger dose of liquor ammoniæ and caustic alkali must be used, according to the dryness of the stearine matters to be operated upon.
Combine 1000 lbs. of stearic or margaric acid, as free from elaine or oleine as possible, or palmatine, or any vegetable or animal stearine or margarine, at a temperature of 212°F, with a solution of bicarbonate of potash or soda, with a specific gravity of 1.500. Constantly stir or mix until a thorough combination is achieved, ensuring that the elements do not separate when tested on glass or any similar substance. When the mixture cools to about 60°F, add one pound per cent. of ammonia liquor, with a specific gravity of 0.880, and one pound per cent. of the strongest solution of caustic potash; these should be added gradually and mixed fully until perfectly combined. Dissolve 15 to 18 pounds per cent. of commercial common resin by boiling it with a solution of subcarbonate of potash and common soda in equal parts, enough to achieve a specific gravity of about 1.800 when boiling hot. Mix these thoroughly with the previously mentioned stearic or margaric acids and carbonated alkali; then add a strong solution of caustic potash or soda until a complete saponification occurs. The amount of caustic alkali needed will largely depend on the purity of the stearine or margarine used. The separation is now achieved by using common salt or sulfate of soda, etc., as is known and practiced by soap manufacturers. If the soap to be produced is meant to be colorless, no resin should be used, and a larger dose of ammonia liquor and caustic alkali must be employed, depending on the dryness of the stearine materials being processed.
A SIMPLE AND CERTAIN METHOD TO DETERMINE THE COMMERCIAL VALUE OF SOAP.
BY DR. ALEXANDER MÜLLER.
In consequence of the ceremonious process by which the fatty acids are determined in one portion of the soap, and the alkali by the incineration of another, I consider the following method is not unworthy of publication, because it appears to afford quicker and more correct results by reason of the greater simplicity of the manipulation. It is available principally for soda soaps, which are the most common; but it may be also employed with corresponding alterations for soaps which have other bases.
As a result of the formal process used to determine fatty acids in one part of the soap and the alkali through the burning of another part, I believe the following method is worth sharing because it offers faster and more accurate results due to the simpler handling. It is mainly suitable for soda soaps, which are the most common, but it can also be adapted with some changes for soaps with other bases.
A piece of soap weighing two or three grammes is dissolved in a tared beaker glass of about 160 cubic centimetres capacity with 80 to 100 cubic centimetres of water, by heat, in a water-bath, and then three or four times the quantity of diluted sulphuric acid or as much as is necessary to decompose the soap, added from a burette. When, after repeated agitation, the fatty acids have separated in a transparent clear stratum from the aqueous solution, it is allowed to cool, and then the contents of the beaker glass are placed in a moistened filter, which has been previously dried at 212° Fahr. and weighed. The contents of the filter are washed until their acid reaction disappears. In the meanwhile the beaker glass is placed in a steam-bath, so that, it being already dry, may support the washed and partly dry filter, which is laid on the mouth of the glass as if it were in the funnel. The fatty acids soon pass through the paper, and for the most part flow ultimately to the bottom of the beaker glass; the increase of weight of which, after cooling, and the subtraction of the weight of the filter, gives the quantity of fatty acids present in the soap. A second drying and weighing is not necessary, if on the cold sides of the interior of the glass no damp is to be observed, which is occasioned by a trace of water still present. If the quantity of oxide of iron added to marble the soap is considerable, it may be easily found by incinerating the filter and determining the weight of the residue.
A piece of soap weighing two or three grams is dissolved in a pre-weighed beaker with a capacity of about 160 milliliters, using 80 to 100 milliliters of water, by heating it in a water bath. Then, three or four times the amount of diluted sulfuric acid—or as much as needed to break down the soap—is added from a burette. After agitating several times, when the fatty acids have separated into a clear layer on top of the aqueous solution, it is allowed to cool. The contents of the beaker are then placed in a moistened filter that has been dried at 212°F and weighed. The filter contents are washed until they are no longer acidic. Meanwhile, the beaker is placed in a steam bath so that, being already dry, it can support the washed and partly dry filter, which is set on the mouth of the beaker as if it were in a funnel. The fatty acids quickly pass through the paper and mostly settle at the bottom of the beaker; the increase in weight of the beaker after cooling, minus the weight of the filter, provides the quantity of fatty acids present in the soap. A second drying and weighing are not necessary if no moisture is seen on the cold surfaces inside the glass, which could be due to residual water. If a significant amount of iron oxide was added to the soap, it can be easily measured by incinerating the filter and determining the weight of the residue.
The fluid runs from the fatty acids on the filter, which, with the washings, has been preserved in a sufficiently large beaker glass, is colored with tincture of litmus, and decomposed with a test alkaline solution until the blue color appears. The difference of the quantity of alkali required to neutralize the sulphuric acid, and the quantity of sulphuric acid used in the first instance, allows a calculation to be made as to the quantity of effective alkali in the soap, for example:—
The liquid from the fatty acids on the filter, which has been collected with the washings in a large beaker, is dyed with litmus dye and treated with a test alkaline solution until a blue color shows up. By comparing the amount of alkali needed to neutralize the sulfuric acid with the amount of sulfuric acid used initially, we can calculate the amount of effective alkali in the soap. For example:—
23.86 grms. of soap (partly cocoa-nut oil soap).
17.95 " fatty acids with filter.
04.44 " filter.
-----
13.51 grms. of hydrates of fatty acids = 56.62 per cent.
28.00 cub. cent. of the diluted sulphuric acid applied for the
decomposition of the soap, of which 100 cub. cent.
represent 2982 grms. of carbonate of soda.
17.55 cub. cent. of alkaline fluid, which were used for the
saturation of the above acid, and of which 100 cub.
cent. saturate an equal quantity of that acid.
----
10.45 cub. cent. of the sulphuric necessary for the alkali
contained in the soap, representing 0.1823 grms. of
soda = 7.64 per cent.
23.86 grams of soap (partly coconut oil soap).
17.95 " fatty acids with filter.
04.44 " filter.
-----
13.51 grams of hydrates of fatty acids = 56.62 percent.
28.00 cubic centimeters of the diluted sulfuric acid used for the
decomposition of the soap, which is 100 cubic centimeters
represent 2982 grams of sodium carbonate.
17.55 cubic centimeters of alkaline fluid, which were used for the
saturation of the above acid, and which 100 cubic
centimeters saturate the same amount of that acid.
----
10.45 cubic centimeters of the sulfuric needed for the alkali
contained in the soap, representing 0.1823 grams of
soda = 7.64%.
A determination of the alkali as a sulphate afforded in another portion of soap 9.57 per cent. of soda, because the sulphate of soda and chloride of sodium present in the soap gave up their alkali.
A measurement of the alkali as a sulfate showed that another part of the soap contained 9.57 percent sodium, because the sodium sulfate and sodium chloride present in the soap released their alkali.
The alkaline fluid applied by me was a saccharine solution of lime, which can be naturally replaced by a solution of soda, and must be if the chloride of sodium and sulphate of soda mixed with the soap shall be determined in the following way:—
The alkaline fluid I used was a sugary lime solution, which can naturally be substituted with a soda solution, and must be if the sodium chloride and sodium sulfate mixed with the soap are to be identified in the following way:—
The fluid again exactly neutralized with alkali is evaporated to dryness, and the residue gently heated to redness. As in the above manipulation, the fluid was not heated to the boiling point, the original chloride of sodium and sulphate of soda are contained in the weighed residue, besides the soda of the soap and that which has been added with the sulphuric acid, forming sulphate of soda. A second exposure to a red heat with sulphuric acid converts the whole residue into sulphate of soda, and from the increase of weight, by a comparison of the equivalents of NaCl and NaO, SO3 the quantity of the former may be decided. According to the equivalents which Kopp furnished in 1850, the increase of weight to the chloride of sodium is as 1:4.68. The original sulphate of soda must be, lastly, found by the subtraction of the same salt formed plus the calculated chloride of sodium from the first heated residue.
The fluid that was perfectly neutralized with alkali is evaporated until dry, and the leftover material is gently heated until it glows red. As in the previous step, the fluid wasn't heated to its boiling point. The original sodium chloride and sodium sulfate are in the measured residue, along with the soda from the soap and the soda added with the sulfuric acid, resulting in sodium sulfate. A second round of heating to high temperatures with sulfuric acid turns all the residue into sodium sulfate, and by comparing the weight increase, we can determine the amount of sodium chloride using the equivalents of NaCl and NaO, SO3. Based on the equivalents provided by Kopp in 1850, the weight increase for sodium chloride is in a ratio of 1:4.68. Finally, the original sodium sulfate is found by subtracting the amount of sodium sulfate produced plus the calculated sodium chloride from the first heated residue.
In practice, it is seldom necessary to proceed with the determination of the chloride of sodium and sulphate of soda, except with stirred and cocoa-nut oil soaps; certainly less of the truth is seen if, after the above determination of the fatty acids and the effective alkali, the absent per centage of water is introduced in the calculation, than if the water is reckoned, which is never completely evolved from soap, even technically prepared at 302° Fahr., and another determination made of the fatty acids or alkali en bloc the fatty acids, or even the alkaline contents.
In practice, it's rarely necessary to determine the sodium chloride and sodium sulfate content, except for stirred and coconut oil soaps. The results are less accurate if, after determining the fatty acids and the effective alkali, the percentage of water missing is included in the calculations, compared to counting the water, which is never completely removed from soap, even when processed at 302° Fahrenheit. Another determination can be done of the fatty acids or alkali as a whole, including the fatty acids, or even the alkaline content.
The method here given partakes of the usual imperfections, that the fatty acids as well as the unsaponified soap are equally estimated, and the mixed hydrate or carbonate of the alkali as well as the combined alkali. The presence of the carbonate can be easily recognized by the foaming of the soap solution, upon the addition of the sulphuric acid. These imperfections, however, are of little importance.
The method described here has its usual flaws, as both the fatty acids and the unsaponified soap are estimated equally, along with the mixed hydrate or carbonate of the alkali and the combined alkali. The presence of the carbonate can be easily detected by the foaming of the soap solution when sulfuric acid is added. However, these flaws are not very significant.
It must be granted that the minutely correct determination of the constitution of soap must be always yielded up to those who are technically conversant with this department of chemistry, the estimation of free alkali and unchanged fat excluded in, at least, by certain ages of the soap. Further, a considerable excess of one or another ingredient soon betrays itself by a corresponding departure in the soap of the characteristic properties of a good product, and a small excess can be judged sufficiently exact from the proportion of the alkali, which, supposing soda present, should not amount to more than 13 per cent. with a pure cocoa-nut oil soap, not less than 11.5 per cent. with a tallow soap; but with palm oil and mixed soaps the one or the other limit approximates.—Journal für Praktische Chemie.
It should be acknowledged that accurately determining the composition of soap should always be left to those who are skilled in this area of chemistry, excluding the measurement of free alkali and unchanged fat in, at least, certain ages of the soap. Additionally, a significant excess of any ingredient quickly shows itself by a noticeable change in the soap's typical properties of a high-quality product, and a small excess can be judged accurately based on the alkali content, which, assuming soda is present, should not exceed 13 percent for a pure coconut oil soap and should be no less than 11.5 percent for a tallow soap; however, with palm oil and mixed soaps, one limit or the other gets closer to being the same.—Journal für Praktische Chemie.
ON THE NATURAL FATS.
BY DR. CHARLES LÖWIG.
The fats which exist in nature can be divided into the general and the special; the former exist in almost all plants and parts of plants; the latter includes only some vegetable substances, as laurostearine, myristicine, and palmatine. The consistence of fats of the general kind depend upon the proportions of margarine, stearine, and oleine contained in them. The former preponderate in the solid fats (butter, lard, and tallow); and the latter in the fluid ones or oils. According as an oil contains oleic acid or olinic acid, it is termed a fatty or drying oil. To the class of fatty oils belong olive, almond, hazel-nut, beech, rape oils, &c.; to that of drying oils, linseed, nut, hemp, poppy, grape-seed, oils, &c.; which are used for varnishes.
The fats found in nature can be classified into general and special categories; the first type is found in almost all plants and their parts, while the second includes only certain plant substances like laurostearine, myristicine, and palmatine. The consistency of general fats depends on the amounts of margarine, stearine, and oleine present in them. Margarine tends to dominate in solid fats (like butter, lard, and tallow), whereas oleine is more prevalent in liquid fats or oils. Depending on whether an oil contains oleic acid or olinic acid, it is classified as a fatty oil or a drying oil. Fatty oils include olive, almond, hazelnut, beech, and rapeseed oils, while drying oils encompass linseed, nut, hemp, poppy, and grape seed oils, which are used for varnishes.
In the vegetable kingdom the fats are chiefly in the seeds and in their coverings, seldom in the perispemium (poppy), and in the fleshy substance surrounding the seed (olive). The fat in the seed is mostly enclosed in cells with a proteine compound. In the animal kingdom certain parts of the body are quite filled with fat-cells, particularly under the skin (Paniculus adiposus), in the cavities of the abdomen, in the so-called omentum, in the kidneys and the tubulated canals of the bones. Fat is also enclosed in cells (fatty globules) in milk.
In the plant kingdom, fats are mainly found in the seeds and their coverings, rarely in the outer layer (like in poppies), and in the fleshy part around the seed (like in olives). The fat in seeds is mostly contained within cells that have a protein compound. In the animal kingdom, certain body parts are largely filled with fat cells, especially under the skin (Paniculus adiposus), in the abdominal cavities, in what’s known as the omentum, in the kidneys, and in the tubular canals of the bones. Fat is also stored in cells (fatty globules) in milk.
It is established, without a doubt, that a greater portion of the fat which exists in the animal kingdom originates from the vegetable kingdom, for it is introduced into the body cotemporaneously with the proteine compounds of that kingdom. A portion of the fat as well as wax is formed in the animal organismus, as shown by a number of observations, and in most cases it is unquestionable that the non-nitrogenous nutriments, as starch, serve for the formation of fat by a process of deoxidation; nevertheless, the formation of fat in the animal body appears only to take place when the substances containing starch enter the body simultaneously with fat.
It’s clear that most of the fat found in animals comes from plants, as it enters the body at the same time as the protein from those plants. Some fat and wax are produced in the animal body, as shown by various studies, and it’s usually accepted that non-nitrogenous nutrients like starch help create fat through a process of deoxidation. However, it seems that fat in the animal body can only form when starch-rich foods are consumed alongside fat.
If the fat existing in the animal body is contained in cellular tissue, its separation may be simply effected by placing the incised tissue in hot water. The cells burst and the fat collects itself on the surface of the water. If vegetable substances contain fat in large quantity, as, for example, seeds, it may be obtained by expression. The dried seeds are bruised and expressed between either cold or hot metallic plates. Olives are laid in heaps before expression; when they begin to ferment, they can be completely expressed. If animal and vegetable substances contain only a little fat, it must be extracted by ether.
If the fat in an animal's body is stored in its cells, it can be easily separated by placing the cut tissue in hot water. The cells burst, and the fat rises to the surface of the water. If plant materials have a lot of fat, like seeds, it can be extracted by pressing. The dried seeds are crushed and pressed between either cold or hot metal plates. Olives are piled up before pressing; when they start to ferment, they can be fully pressed. If animal and plant materials contain only a small amount of fat, it needs to be extracted using ether.
In the pure condition the fats are mostly odorless and tasteless; when they possess an odor, it arises mostly from the presence of small quantities of volatile fatty acids, as butyric acid, capric acid, &c.; which becomes free through the decomposition of their oxide of glycyl combinations. This ensues by the presence of water and air through a kind of fermentation, and as it appears, by the presence of a nitrogenous substance. The fats are insoluble in water, and, with the exception of castor oil, are taken up by cold alcohol in very small quantities, however, more in proportion as they contain oleine. In boiling alcohol they are dissolved, but are, for the most part, again separated on cooling, particularly those rich in stearine. All fats are taken up by ether but those containing stearine in the smallest quantity.
In their pure form, fats are mostly odorless and tasteless. When they do have a smell, it usually comes from tiny amounts of volatile fatty acids, like butyric acid and capric acid. These acids are released when their glycyl oxide combinations break down. This breakdown happens in the presence of water and air through a type of fermentation, and it seems to also require a nitrogenous substance. Fats are not soluble in water and, except for castor oil, are only slightly soluble in cold alcohol, but this increases if they contain more oleine. In boiling alcohol, they dissolve, but mostly separate out again as they cool, especially those high in stearine. All fats dissolve in ether, except for those that contain very little stearine.
Their specific gravities fluctuate between .91 and .93. When heated, fats assume a dark color, and boil between 482° and 572° Fahr., but the boiling-point continuously rises, while an uninterrupted decomposition proceeds. From oxide of glycyl ensues acroline; oleic acid affords a fatty acid, and among the decomposition products of fats containing stearine and margarine are found pure margaric acid, and, at the same time, some hydro-carbons are formed. When exposed quickly to a high temperature, fats are completely decomposed. (Oil gas.) In closed vessels the pure fats undergo no change, but, placed in thin layers in the air, the fats containing oleine and oline rapidly absorb oxygen under the strong evolution of heat, which will inflame porous bodies, as cotton wool. The purer the fats are the more quickly their oxidation results. When the fats contain slimy materials, these latter can be destroyed with a little oxide of lead and water. (Preparation for the application of varnishes.) The action of nitric acid, nitrous acid, chlorine, sulphuric acid, &c., on fats is the same as that of these bodies on the fatty acids. The fatty oils dissolve sulphur in the heat which is again partly precipitated on cooling. When sulphur is heated with fatty oils, namely, with linseed oil, it dissolves by degrees, and a thick dark mass is formed, the so-called balsam of sulphur. By raising the heat, a violent reaction ensues under the evolution of sulphuretted hydrogen, and, at the same time, an oil resembling oil of garlic volatilizes. This oil begins to boil at 160° Fahr., but its boiling-point rises continually.
Their specific gravities range from 0.91 to 0.93. When heated, fats turn dark and boil between 482°F and 572°F, but the boiling point keeps increasing as they continuously decompose. From the oxide of glycyl arises acrolein; oleic acid produces a fatty acid, and among the breakdown products of fats containing stearine and margarine, pure margaric acid can be found, along with some hydrocarbons. When exposed quickly to high temperatures, fats completely decompose. (Oil gas.) In closed vessels, pure fats don't change, but when placed in thin layers in the air, fats containing olein and oline quickly absorb oxygen, generating a lot of heat, which can ignite porous materials like cotton wool. The purer the fats, the faster they oxidize. If the fats have slimy materials, these can be eliminated with a little lead oxide and water. (Preparation for applying varnishes.) The reaction of nitric acid, nitrous acid, chlorine, sulfuric acid, etc., on fats is similar to their effect on fatty acids. Fatty oils dissolve sulfur when heated, though some precipitates form when cooled. When sulfur is heated with fatty oils like linseed oil, it gradually dissolves, forming a thick dark substance known as balsam of sulfur. Increasing the heat causes a violent reaction that releases hydrogen sulfide, and an oil resembling garlic oil vaporizes at the same time. This oil starts boiling at 160°F, but its boiling point keeps rising.
PERFUMES AS PREVENTIVES OF MOULDINESS.
An interesting paper on this subject has been published by Dr. Macculloch. We presume our readers are aware that mouldiness is occasioned by the growth of minute vegetables. Ink, paste, leather, and seeds, are the substances that most frequently suffer from it. The effect of cloves in preserving ink is well known; any of the essential oils answer equally well. Leather may be kept free from mould by the same substances. Thus Russian leather, which is perfumed with the tar of birch, never becomes mouldy; indeed it prevents it from occurring in other bodies. A few drops of any essential oil are sufficient also to keep books entirely free from it. For harness, oil of turpentine is recommended. Bookbinders, in general, employ alum for preserving their paste; but mould frequently forms on it. Shoemakers' resin is sometimes also used for the same purpose; but it is less effectual than oil of turpentine. The best preventives, however, are the essential oils, even in small quantity, as those of peppermint, anise, or cassia, by which paste may be kept almost any length of time; indeed, it has, in this way, been preserved for years. The paste recommended by Dr. Macculloch is made in the usual way, with flour, some brown sugar, and a little corrosive sublimate; the sugar keeping it flexible when dry, and the sublimate preventing it from fermenting, and from being attacked by insects. After it is made, a few drops of any of the essential oils are added. Paste made in this way dries when exposed to the air, and may be used merely by wetting it. If required to be kept always ready for use, it ought to be put into covered pots. Seeds may also be preserved by the essential oils; and this is of great consequence, when they are to be sent to a distance. Of course moisture must be excluded as much as possible, as the oils or ottos prevent only the bad effects of mould.
An interesting paper on this topic has been published by Dr. Macculloch. We assume our readers know that moldiness is caused by the growth of tiny plants. Ink, paste, leather, and seeds are the substances that are most commonly affected by it. The effectiveness of cloves in preserving ink is well-known; any essential oils work just as well. Leather can be kept mold-free using the same substances. For example, Russian leather, which is scented with birch tar, never gets moldy; in fact, it prevents mold from occurring on other materials. Just a few drops of any essential oil are also enough to keep books completely free from mold. For harness, turpentine oil is recommended. Generally, bookbinders use alum to preserve their paste, but mold often forms on it. Shoemakers' resin is sometimes used for the same purpose, but it's less effective than turpentine oil. However, the best preventatives are essential oils, even in small amounts, such as peppermint, anise, or cassia, which can keep paste usable for a long time; in fact, it has been preserved this way for years. The paste recommended by Dr. Macculloch is made in the traditional way, with flour, some brown sugar, and a little corrosive sublimate; the sugar keeps it flexible when dry, and the sublimate prevents fermentation and insect attack. After it's made, a few drops of any essential oil are added. Paste made this way dries when exposed to air and can be used just by wetting it. If you need it to be always ready for use, it should be kept in covered containers. Seeds can also be preserved by essential oils, which is very important when they need to be sent far away. Obviously, moisture should be kept out as much as possible since the oils only counteract the harmful effects of mold.
FUSEL OIL.
BY W. BASTICK.
This organic compound was first discovered by Scheele, as one of the distillation products of the wort obtained from the fermentation of potatoes. It has been subsequently examined by Pelletier, Dumas, Cahours, and others. It is generally now termed the hydrate of the oxide of amyl, from amyl being supposed to be its base or radical, as cyanogen is regarded to be the radical of another series of compounds.
This organic compound was first discovered by Scheele as one of the distillation products from the wort produced during potato fermentation. It has since been studied by Pelletier, Dumas, Cahours, and others. It is now commonly referred to as the hydrate of amyl oxide, with amyl thought to be its base or radical, similar to how cyanogen is considered the radical of another group of compounds.
It passes over towards the termination of the distillation process in a white turbid fluid, which consists of a watery and alcoholic solution of the fusel oil. The crude oil, consisting of about one-half of its weight of alcohol and water, may be purified, being shaken with water and redistilled, with the previous addition of chloride of calcium. When the temperature of the contents of retort reaches 296° Fahr., pure fusel oil distils over.
It moves toward the end of the distillation process in a cloudy white liquid, which is a mixture of water and alcohol from the fusel oil. The crude oil, which is roughly half its weight in alcohol and water, can be purified by shaking it with water and redistilling it after adding calcium chloride. When the temperature in the retort reaches 296° F, pure fusel oil distills over.
Fusel oil is a colorless oily fluid, which possesses at first not an unagreeable odor, but at last is very disgusting, producing oppression at the chest and exciting cough. It has a sharp hot taste, and burns with a white blue flame. It boils at 296° Fahr., and at temperature of -4° Fahr. it becomes solid, and forms crystals. Its specific gravity at 59° Fahr. is 0.8124, and its formula C10H12O2. On paper it produces a greasy stain, which disappears by heat, and when exposed to the action of the air it acquires an acid reaction. Fusel oil is slightly soluble in water, to which it imparts its odor; and soluble in all proportions in alcohol, ether, volatile and fixed oils, and acetic acid. It dissolves phosphorus, sulphur, and iodine without any noticeable change, and also mixes with caustic soda and potash. It rapidly absorbs hydrochloric acid, with the disengagement of heat. When mixed with concentrated sulphuric acid, the mixture becomes of a violet-red color, and bisulphate of amyloxide is formed. Nitric acid and chlorine decompose it. By its distillation with anhydrous phosphoric acid, a fluid, oily combination of hydrogen and carbon results. By oxidation with bichromate of potash and sulphuric acid, fusel oil yields valerianic acid, which is used in medicine, and apple-oil, employed as a flavoring ingredient in confectionery.
Fusel oil is a colorless oily liquid that initially has a somewhat pleasant smell but eventually becomes very unpleasant, causing chest tightness and provoking coughing. It has a sharp, hot taste and burns with a bluish-white flame. It boils at 296°F, and at -4°F, it solidifies and forms crystals. Its specific gravity at 59°F is 0.8124, and its chemical formula is C10H12O2. On paper, it leaves a greasy stain that disappears when heated, and when exposed to air, it turns acidic. Fusel oil has low solubility in water, which it affects by imparting its smell; however, it is completely soluble in alcohol, ether, both volatile and fixed oils, and acetic acid. It dissolves phosphorus, sulfur, and iodine without noticeable changes, and it also mixes with caustic soda and potash. It quickly absorbs hydrochloric acid, releasing heat in the process. When mixed with concentrated sulfuric acid, the mixture turns a violet-red color and forms bisulphate of amyloxide. Nitric acid and chlorine can break it down. When distilled with anhydrous phosphoric acid, it produces a fluid, oily combination of hydrogen and carbon. Through oxidation with bichromate of potash and sulfuric acid, fusel oil produces valeric acid, which is used in medicine, and apple oil, which is used as a flavoring agent in candy.
ESSENCE OF PINE-APPLE.
BY W. BASTICK.
The above essence is, as already known, butyric ether more or less diluted with alcohol; to obtain which pure, on the large scale and economically, the following process is recommended:—
The essence mentioned above is, as already known, butyric ether diluted with alcohol to some extent; to obtain it pure, on a large scale and economically, the following process is suggested:—
Dissolve 6 lbs. of sugar and half an ounce of tartaric acid, in 26 lbs. of boiling water. Let the solution stand for several days; then add 8 ounces of putrid cheese broken up with 3 lbs. of skimmed and curdled sour milk and 3 lbs. of levigated chalk. The mixture should be kept and stirred daily in a warm place, at the temperature of about 92° Fahr., as long as gas is evolved, which is generally the case for five or six weeks.
Dissolve 6 lbs. of sugar and half an ounce of tartaric acid in 26 lbs. of boiling water. Let the solution sit for several days, then add 8 ounces of spoiled cheese broken up with 3 lbs. of skimmed and sour curdled milk and 3 lbs. of ground chalk. The mixture should be kept and stirred daily in a warm place, at a temperature of about 92° F, for as long as gas is being produced, which typically lasts for five or six weeks.
The liquid thus obtained, is mixed with an equal volume of cold water, and 8 lbs. of crystallized carbonate of soda, previously dissolved in water, added. It is then filtered from the precipitated carbonate of lime; the filtrate is to be evaporated down to 10 lbs., when 5-1/2 lbs. of sulphuric acid, previously diluted with an equal weight of water, are to be carefully added. The butyric acid, which separates on the surface of the liquid as a dark-colored oil, is to be removed, and the rest of the liquid distilled; the distillate is now neutralized with carbonate of soda, and the butyric acid separated as before, with sulphuric acid.
The resulting liquid is mixed with an equal volume of cold water, and 8 lbs. of crystallized sodium carbonate, which has been dissolved in water, is added. It is then filtered to remove the precipitated calcium carbonate; the filtered liquid should be evaporated down to 10 lbs. After that, 5-1/2 lbs. of sulfuric acid, previously diluted with an equal weight of water, should be added carefully. The butyric acid, which forms a dark-colored oil on the surface of the liquid, should be removed, and the remaining liquid should be distilled; the distillate is now neutralized with sodium carbonate, and the butyric acid is separated as before, using sulfuric acid.
The whole of the crude acid is to be rectified with the addition of an ounce of sulphuric acid to every pound. The distillate is then saturated with fused chloride of calcium, and redistilled. The product will be about 28 ounces of pure butyric acid. To prepare the butyric acid or essence of pine-apple, from this acid proceed as follows:—Mix, by weight, three parts of butyric acid with six parts of alcohol, and two parts of sulphuric acid in a retort, and submit the whole, with a sufficient heat, to a gentle distillation, until the fluid which passes over ceases to emit a fruity odor. By treating the distillate with chloride of calcium, and by its redistillation, the pure ether may be obtained.
The entire crude acid should be purified by adding one ounce of sulfuric acid for every pound. Then, the distillate should be saturated with fused calcium chloride and redistilled. This process will yield about 28 ounces of pure butyric acid. To create butyric acid or pineapple essence from this acid, follow these steps: Mix three parts of butyric acid, six parts of alcohol, and two parts of sulfuric acid in a retort. Apply sufficient heat for a gentle distillation until the liquid that comes out stops giving off a fruity smell. By treating the distillate with calcium chloride and redistilling it, you can obtain the pure ether.
The boiling-point of butyric ether is 238° Fahr. Its specific gravity, 0.904, and its formula,
The boiling point of butyric ether is 238° F. Its specific gravity is 0.904, and its formula is,
C12H12O4, or C4H5O + C8H7O3.
C12H12O4, or C4H5O + C8H7O3.
Bensch's process, above described, for the production of butyric acid, affords a remarkable exemplification of the extraordinary transformations that organic bodies undergo in contact with ferment, or by catalytic action. When cane sugar is treated with tartaric acid, especially under the influence of heat, it is converted into grape sugar. This grape sugar, in the presence of decomposing nitrogenous substances, such as cheese, is transformed in the first instance into lactic acid, which combines with the lime of the chalk. The acid of the lactate of lime, thus produced, is by the further influence of the ferment changed into butyric acid. Hence, butyrate of lime is the final result of the catalytic action in the process we have here recommended.
Bensch's method for producing butyric acid, as described above, is a striking example of the amazing changes that organic substances go through when they come into contact with ferment or through catalytic action. When cane sugar is treated with tartaric acid, especially when heated, it turns into grape sugar. This grape sugar, in the presence of decomposing nitrogen-rich substances like cheese, first transforms into lactic acid, which then combines with the lime from chalk. The lactic acid produced is further altered by the ferment into butyric acid. Therefore, butyrate of lime is the final result of the catalytic action in the process we've described here.
PREPARATION OF CRUDE PELARGONATE OF ETHYL-OXIDE (ESSENCE OF QUINCE.)
BY DR. R. WAGNER.
It has been believed, until the most recent period, that the peel of quinces contains œnanthylate of ethyl-oxide. New researches, however, have led to the supposition that the odorous principle of quinces is derived from the ether of pelargonic acid. In my last research on the action of nitric acid on oil of rue, I found that besides the fatty acids, which Gerhardt had already discovered, pelargonic acid is formed. This process may be advantageously employed for the preparation of crude pelargonate of ethyl-oxide, which, on account of its extremely agreeable odor, may be applied as a fruit essence equally with those prepared by Dobereiner, Hofmann, and Fehling. For the preparation of the liquid, which can be named the essence of quince, oil of rue is treated with double its quantity of very diluted nitric acid, and the mixture heated until it begins to boil. After some time two layers are to be observed in the liquid: the upper one is brownish, and the lower one consists of the products of the oxidation of oil of rue and the excess of nitric acid. The lower layer is freed from the greater part of its nitric acid by evaporation in a chloride of zinc bath. The white flocks frequently found in the acid liquid, which are probably fatty acids, are separated by filtration. The filtrate is mixed with spirit, and long digested in a gentle heat, by which a fluid is formed, which has the agreeable odor of quince in the highest degree, and may be purified by distillation. The spirituous solution of pelargonic ether may also be profitably prepared from oleic acid, according to Gottlieb's method.—Journal für Praktische Chemie.
It has been believed, until recently, that the peel of quinces contains ethyl-oxide œnanthylate. However, new research suggests that the fragrant component of quinces comes from pelargonic acid ether. In my last study on the effect of nitric acid on oil of rue, I discovered that, in addition to the fatty acids already identified by Gerhardt, pelargonic acid is also produced. This method can be effectively used to prepare crude ethyl-oxide pelargonate, which, due to its very pleasant scent, can be used as a fruit essence just like those made by Dobereiner, Hofmann, and Fehling. To make the liquid, which can be called quince essence, oil of rue is treated with double its volume of diluted nitric acid, and the mixture is heated until it starts to boil. After a while, two layers can be seen in the liquid: the upper one is brownish, and the lower one contains the products of the oxidation of oil of rue and any excess nitric acid. The lower layer is mostly freed of its nitric acid through evaporation in a zinc chloride bath. The white flakes often found in the acidic liquid, which are likely fatty acids, are removed by filtration. The filtrate is mixed with alcohol and gently heated for a long time, resulting in a liquid that has an extremely pleasant quince scent, which can then be purified by distillation. The alcoholic solution of pelargonic ether can also be efficiently prepared from oleic acid, following Gottlieb's method.—Journal für Praktische Chemie.
PREPARATION OF RUM-ETHER.
Take of black oxide of manganese, of sulphuric acid, each twelve pounds; of alcohol, twenty-six pounds; of strong acetic acid, ten pounds. Mix, and distil twelve pints. The ether, as above prepared, is an article of commerce in Austria, being the body to which rum owes its peculiar flavor.—Austrian Journal of Pharmacy.
Take 12 pounds of manganese black oxide and 12 pounds of sulfuric acid; 26 pounds of alcohol; and 10 pounds of strong acetic acid. Mix them together and distill 12 pints. The ether prepared this way is a commercial product in Austria, giving rum its distinctive flavor.—Austrian Journal of Pharmacy.
ARTIFICIAL FRUIT ESSENCES.
BY FEHLING.
Pine-apple Oil is a solution of one part of butyric ether, in eight or ten parts of alcohol. For the preparation of this ether, pure butyric acid must be first obtained by the fermentation of sugar, according to the method of Bensch. One pound of this acid is dissolved in one pound of strong alcohol, and mixed with from a quarter to half an ounce of sulphuric acid; the mixture is heated for some minutes, whereby the butyric ether separates as a light stratum. The whole is mixed with half its volume of water, and the upper stratum then removed; the heavy fluid is distilled, by which more butyric ether is obtained. The distillate and the removed oily liquid are shaken with a little water, the lighter portion of the liquid removed, which at last, by being shaken with water and a little soda, is freed from adhering acid.
Pineapple Oil is a mixture of one part butyric ether in eight or ten parts alcohol. To prepare this ether, you need to first obtain pure butyric acid through the fermentation of sugar, following Bensch’s method. Dissolve one pound of this acid in one pound of strong alcohol, then mix in a quarter to half an ounce of sulfuric acid. Heat the mixture for a few minutes, during which time butyric ether will separate as a light layer. Combine this with half its volume of water, then remove the upper layer; the heavier liquid is distilled, yielding more butyric ether. Shake the distillate and the extracted oily liquid with a little water, and discard the lighter portion. Finally, shake the remaining mixture with water and a bit of soda to remove any leftover acid.
For the preparation of the essence of pine-apple, one pound of this ether is dissolved in 8 or 10 pounds of alcohol. 20 or 25 drops of this solution is sufficient to give to one pound of sugar a strong taste of pine-apple, if a little citric or tartaric acid has been added.
To make pineapple essence, dissolve one pound of this ether in 8 or 10 pounds of alcohol. Just 20 or 25 drops of this solution will give one pound of sugar a strong pineapple flavor, especially if a bit of citric or tartaric acid is added.
Pear-oil.—This is an alcoholic solution of acetate of amyloxide, and acetate of ethyloxide. For its preparation, one pound of glacial acetic acid is added to an equal weight of fusel-oil (which has been prepared by being washed with soda and water, and then distilled at a temperature between 254° and 284° Fahr.), and mixed with half a pound of sulphuric acid. The mixture is digested for some hours at a temperature of 254°, by which means acetate of amyloxide separates, particularly on the addition of some water. The crude acetate of amyloxide obtained by separation, and by the distillation of the liquid to which the water has been added, is finally purified by being washed with soda and water. Fifteen parts of acetate of amyloxide are dissolved with half a part of acetic ether in 100 or 120 parts of alcohol; this is the essence of pear, which, when employed to flavor sugar or syrup, to which a little citric or tartaric acid has been added, affords the flavor of bergamot pears, and a fruity, refreshing taste.
Pear oil.—This is an alcoholic solution of amyloxide acetate and ethyloxide acetate. To make it, one pound of glacial acetic acid is combined with an equal amount of fusel oil (which has been cleaned with soda and water and then distilled at a temperature between 254° and 284° F), along with half a pound of sulfuric acid. The mixture is heated for a few hours at 254°, causing amyloxide acetate to form, especially when some water is added. The crude amyloxide acetate obtained from separation and by distilling the liquid after adding water is then purified by washing it with soda and water. Fifteen parts of amyloxide acetate are dissolved with half a part of acetic ether in 100 or 120 parts of alcohol; this is the essence of pear, which, when used to flavor sugar or syrup with a little added citric or tartaric acid, provides the flavor of bergamot pears and a fruity, refreshing taste.
Apple-oil is an alcoholic solution of valerianate of amyloxide. It is obtained impure, as a by product, when for the preparation of valerianic acid, fusel-oil is distilled with bichromate of potash and sulphuric acid. It is better prepared in the following manner:—For the preparation of valerianic acid, 1 part of fusel-oil is mixed gradually with 3 parts of sulphuric acid, and 2 parts of water added. A solution of 2-1/4 parts of bichromate of potash, with 4-1/2 parts of water, is heated in a tubulated retort, and into this fluid the former mixture is gradually poured, so that the ebullition is not too rapid. The distillate is saturated with carbonate of soda, and warmed, when a solution of 3 parts of crystallized carbonate of soda, 2 parts of strong sulphuric acid, diluted with an equal quantity of water, are added. The valerianic acid separates as an oily stratum.
Apple-oil is an alcoholic solution of valerianate of amyloxide. It is usually obtained impure as a byproduct when fusel oil is distilled with potassium bichromate and sulfuric acid to prepare valerianic acid. A better method is as follows: To make valerianic acid, mix 1 part of fusel oil gradually with 3 parts of sulfuric acid, then add 2 parts of water. Heat a solution of 2-1/4 parts of potassium bichromate mixed with 4-1/2 parts of water in a tubulated retort, and gradually pour in the previous mixture, ensuring that the boiling isn’t too vigorous. The distillate is saturated with sodium carbonate and warmed, after which a solution of 3 parts of crystallized sodium carbonate and 2 parts of strong sulfuric acid, diluted with an equal amount of water, is added. The valerianic acid will separate as an oily layer.
One part, by weight, of pure fusel-oil is carefully mixed with an equal weight of sulphuric acid. The cold solution is added to 1-1/4 parts of the above valerianic acid; the mixture is warmed for some minutes (not too long or too much) in a water-bath, and then mixed with a little water, by which means the impure valerianate of amyloxide separates, which is washed with water and carbonate of soda. For use as an essence of apples, one part of this valerianate of amyloxide is dissolved in 6 or 8 parts of alcohol.
One part, by weight, of pure fusel oil is carefully mixed with an equal weight of sulfuric acid. The cold solution is added to 1 and 1/4 parts of the valerianic acid mentioned above; the mixture is warmed for a few minutes (not too long or too much) in a water bath, and then mixed with a little water, which causes the impure valerianate of amyloxide to separate. This is washed with water and sodium carbonate. To use it as an essence of apples, one part of this valerianate of amyloxide is dissolved in 6 or 8 parts of alcohol.
VOLATILE OIL OF GAULTHERIA PROCUMBENS.
BY W. BASTICK.
This volatile oil is obtained from the winter-green, an American shrub of the heath family, by distillation. When this plant is distilled, at first an oil passes over which consists of C10H8, but when the temperature reaches 464° Fahr., a pure oil distils into the receiver. Therefore the essential oil of this plant, like many others, consists of two portions—one a hydro-carbon, and the other an oxygenated compound; this latter is the chief constituent of the oil, and that which is of so much chemical interest, from the fact that it has been artificially prepared.
This volatile oil is extracted from the wintergreen, an American shrub from the heath family, through distillation. During the distillation process, an oil first comes out that consists of C10H8, but once the temperature hits 464° Fahrenheit, a pure oil distills into the receiver. Therefore, the essential oil of this plant, like many others, has two parts—one is a hydrocarbon, and the other is an oxygenated compound; the latter is the main component of the oil and is of significant chemical interest because it has been artificially created.
It is termed, when thus prepared, the spiroylate of the oxide of methyl, and is obtained when two parts of wood spirit, one and a half parts of spiroylic acid, and one part of sulphuric acid are distilled together. It is a colorless liquid, of an agreeable aromatic odor and taste; it dissolves slightly in water, but in all proportions in ether and alcohol; it boils between 411° and 435° Fahr., and has a specific gravity of 1.173. This compound expels carbonic acid from its combinations, and forms a series of salts, which contain one atom of base and one atom of spiroylate of the oxide of methyl. It behaves therefore as a conjugate acid. Its formula is C14H5O5 + C2H3O.
It’s called the spiroylate of the oxide of methyl when prepared this way, and it’s made by distilling two parts of wood spirit, one and a half parts of spiroylic acid, and one part of sulfuric acid together. It’s a colorless liquid with a pleasant aromatic smell and taste; it dissolves a bit in water, but fully in ether and alcohol; it boils between 411° and 435° Fahrenheit, and has a specific gravity of 1.173. This compound releases carbonic acid from its combinations and creates a series of salts, which contain one atom of base and one atom of spiroylate of the oxide of methyl. Therefore, it acts as a conjugate acid. Its formula is C14H5O5 + C2H3O.
The spiroylic acid may be separated from the natural oil by treating it with a concentrated solution of caustic potash at a temperature of 113° Fahr., when wood spirit is formed and evaporates, and the solution contains the spiroylate of potash, from which, when decomposed with sulphuric acid, the spiroylic acid separates and subsides in the fluid.
The spiroylic acid can be extracted from the natural oil by treating it with a concentrated solution of caustic potash at a temperature of 113°F. During this process, wood spirit is produced and evaporates, leaving a solution that contains spiroylate of potash. When this solution is decomposed with sulfuric acid, the spiroylic acid separates and sinks to the bottom of the liquid.
Spiroylic acid is also formed by the oxidation of spiroyligenic acid, and when saligenin, salicin, courmacin, or indigo, is heated with caustic potash.
Spiroylic acid is also produced by the oxidation of spiroyligenic acid, and when saligenin, salicin, courmacin, or indigo is heated with caustic potash.
ON THE APPLICATION OF ORGANIC CHEMISTRY TO PERFUMERY.
BY DR. A.W. HOFMANN,
Professor to the Royal College of Chemistry, London.
Professor at the Royal College of Chemistry, London.
Cahours' excellent researches concerning the essential oil of Gaultheria procumbens (a North American plant of the natural order of the Ericinæ of Jussieu), which admits of so many applications in perfumery,[I] have opened a new field in this branch of industry. The introduction of this oil among compound ethers must necessarily direct the attention of perfumers[J] towards this important branch of compounds, the number of which is daily increasing by the labors of those who apply themselves to organic chemistry. The striking similarity of the smell of these ethers to that of fruit had not escaped the observation of chemistry; however, it was reserved to practical men to discover by which choice and combinations it might be possible to imitate the scent of peculiar fruits to such a nicety, that makes it probable that the scent of the fruit is owing to a natural combination identical to that produced by art; so much so, as to enable the chemist to produce from fruits the said combinations, provided he could have at his disposal a sufficient quantity to operate upon. The manufacture of artificial aromatic oils for the purpose of perfumery[K] is, of course, a recent branch of industry; nevertheless, it has already fallen into the hands of several distillers, who produce sufficient quantity to supply the trade; a fact, which has not escaped the observation of the Jury at the London Exhibition. In visiting the stalls of English and French perfumers at the Crystal Palace, we found a great variety of these chemical perfumes, the applications of which were at the same time practically illustrated by confectionery flavored by them. However, as most of the samples of the oils sent to the Exhibition were but small, I was prevented, in many cases, from making an accurate analysis of them. The largest samples were those of a compound labelled "pear-oil," which, by analysis, I discovered to be an alcoholic solution of pure acetate of amyloxide. Not having sufficient quantity to purify it for combustion, I dissolved it with potash, by which free fusel-oil was separated, and determined the acetic acid in the form of a silver salt.
Cahours' impressive research on the essential oil of Gaultheria procumbens (a North American plant from the Ericinæ family of Jussieu), which has so many uses in perfumery,[I] has opened up a new area in this industry. The introduction of this oil among compound ethers will definitely draw the attention of perfumers[J] to this important category of compounds, which continues to grow thanks to the efforts of those engaged in organic chemistry. The remarkable similarity of the scent of these ethers to that of fruit hasn’t gone unnoticed in the field of chemistry; however, it has been left to practical experts to figure out the right selections and combinations needed to replicate the scents of specific fruits so accurately that it suggests the fragrance of the fruit is due to a natural combination identical to that created by artificial means. This allows chemists to recreate these combinations from fruits, assuming they have enough material to work with. The production of artificial aromatic oils for perfumery[K] is, of course, a relatively new industry; nevertheless, it has already gained traction with several distillers producing enough to meet market demand, a fact that has not gone unnoticed by the Jury at the London Exhibition. During my visit to the stalls of English and French perfumers at the Crystal Palace, I encountered a wide variety of these chemical perfumes, which were also practically demonstrated through flavored confectioneries. However, since most of the samples of oils sent to the Exhibition were quite small, I was often unable to conduct a thorough analysis. The largest samples were labeled "pear-oil," which, upon analysis, I found to be an alcoholic solution of pure acetate of amyloxide. Lacking enough quantity to purify it for combustion, I dissolved it in potash, which separated free fusel-oil, and determined the acetic acid in the form of a silver salt.
0.3080 gram. of silver salt = 0.1997 gram. of silver.
0.3080 grams of silver salt equals 0.1997 grams of silver.
The per centage of silver in acetate of silver is, according to
The percentage of silver in silver acetate is, according to
Theory, 64.68
Experiment, 64.55
Theory, 64.68
Experiment, 64.55
The acetate of amyloxide, which, according to the usual way of preparing it, represents one part sulphuric acid, one part fusel-oil, and two parts of acetate of potash, had a striking smell of fruit, but it acquired the pleasant flavor of the jargonelle pear only after having been diluted with six times its volume of spirit of wine.
The acetate of amyloxide, typically made from one part sulfuric acid, one part fusel oil, and two parts potassium acetate, had a strong fruity smell, but it only took on the nice flavor of the jargonelle pear after being diluted with six times its volume of wine spirit.
Upon further inquiry I learned that considerable quantities of this oil are manufactured by some distillers,—from fifteen to twenty pounds weekly,—and sold to confectioners, who employ it chiefly in flavoring pear-drops, which are nothing else but barley-sugar, flavored with this oil.
After looking into it more, I found out that a significant amount of this oil is produced by some distillers — between fifteen to twenty pounds a week — and sold to candy makers, who primarily use it to flavor pear drops, which are really just barley sugar flavored with this oil.
I found, besides the pear-oil, also an apple-oil, which, according to my analysis, is nothing but valerianate of amyloxide. Every one must recollect the insupportable smell of rotten apples which fills the laboratory whilst making valerianic acid. By operating upon this raw distillate produced with diluted potash, valerianic acid is removed, and an ether remains behind, which, diluted in five or six times its volume of spirits of wine, is possessed of the most pleasant flavor of apples.
I discovered, in addition to the pear oil, an apple oil, which, based on my analysis, is basically valerianate of amyloxide. Everyone must remember the unbearable smell of rotten apples that fills the lab while making valerianic acid. By processing this raw distillate created with diluted potash, valerianic acid is extracted, and what’s left is an ether that, when diluted in five or six times its volume of spirits of wine, has a delightful apple flavor.
The essential oil[L] most abundant in the Exhibition was the pine-apple oil, which, as you well know, is nothing else but the butyrate of ethyloxide. Even in this combination, like in the former, the pleasant flavor or scent is only attained by diluting the ether with alcohol. The butyric ether which is employed in Germany to flavor bad rum, is employed in England to flavor an acidulated drink called pine-apple ale. For this purpose they generally do not employ pure butyric acid, but a product obtained by saponification of butter, and subsequent distillation of the soap with concentrated sulphuric acid and alcohol; which product contains, besides the butyric ether, other ethers, but nevertheless can be used for flavoring spirits. The sample I analyzed was purer, and appeared to have been made with pure butyric ether.
The main essential oil[L] featured at the Exhibition was pineapple oil, which, as you know, is actually butyrate of ethyloxide. Even in this form, similar to the previous one, the nice flavor or scent is only achieved by mixing the ether with alcohol. The butyric ether used in Germany to enhance bad rum is also used in England for a fizzy drink called pineapple ale. For this, they usually don’t use pure butyric acid, but rather a product created by breaking down butter, then distilling the soap with concentrated sulfuric acid and alcohol; this product contains, in addition to butyric ether, other ethers, but can still be used to flavor spirits. The sample I tested was purer and seemed to have been made with pure butyric ether.
Decomposed with potash and changed into silver salt, it gave
Decomposed with potash and turned into silver salt, it gave
0.4404 gram. of silver salt = 0.2437 gram. of silver.
0.4404 grams of silver salt = 0.2437 grams of silver.
The per centage of silver in the butyrate of silver is according to
The percentage of silver in the butyrate of silver is according to
Theory, 55.38
Experiment, 55.33
Theory, 55.38
Experiment, 55.33
Both English and French exhibitors have also sent samples of cognac-oil and grape-oil, which are employed to flavor the common sorts of brandy. As these samples were very small, I was prevented from making an accurate analysis. However, I am certain that the grape-oil is a combination of amyl, diluted with much alcohol; since, when acted upon with concentrated sulphuric acid, and the oil freed from alcohol by washing it with water, it gave amylsulphuric acid, which was identified by the analysis of the salt of barytes.
Both English and French exhibitors have sent samples of cognac oil and grape oil, which are used to flavor ordinary types of brandy. Since these samples were very small, I wasn't able to do an accurate analysis. However, I'm confident that the grape oil is a mix of amyl diluted with a lot of alcohol; because when it was treated with concentrated sulfuric acid and the oil was washed with water to remove the alcohol, it produced amylsulfuric acid, which was confirmed by analyzing the barium salt.
1.2690 gram. of amylsulphate of barytes gave 0.5825 gram. of sulphate of barytes. This corresponds to 45.82 per cent. of sulphate of barytes.
1.2690 grams of amylsulphate of barytes produced 0.5825 grams of sulphate of barytes. This corresponds to 45.82 percent of sulphate of barytes.
Amylsulphate of barytes, crystallized with two equivalents of water, contains, according to the analysis of Cahours and Kekule, 45.95 per cent. of sulphate of barytes. It is curious to find here a body, which, on account of its noxious smell, is removed with great care from spirituous liquors, to be applied under a different form for the purpose of imparting to them a pleasant flavor.
Amyl sulfate of baryta, crystallized with two equivalents of water, contains, according to the analysis by Cahours and Kekule, 45.95 percent sulfate of baryta. It's interesting to see this substance, which has a toxic smell and is carefully removed from alcoholic drinks, being used in a different form to give them a pleasant flavor.
I must needs here also mention the artificial oil of bitter almonds. When Mitscherlich, in the year 1834, discovered the nitrobenzol, he would not have dreamed that this product would be manufactured for the purpose of perfumery, and, after twenty years, appear in fine labelled samples at the London Exhibition. It is true that, even at the time of the discovery of nitrobenzol, he pointed out the striking similarity of its smell to that of the oil of bitter almonds. However, at that time, the only known sources for obtaining this body were the compressed gases and the distillation of benzoic acid, consequently the enormity of its price banished any idea of employing benzol as a substitute for oil of bitter almonds. However, in the year 1845, I succeeded by means of the anilin-reaction in ascertaining the existence of benzol in common coal-tar oil; and, in the year 1849, C.B. Mansfield proved, by careful experiments, that benzol can be won without difficulty in great quantity from coal-tar oil. In his essay, which contains many interesting details about the practical use of benzol, he speaks likewise of the possibility of soon obtaining the sweet-scented nitrobenzol in great quantity. The Exhibition has proved that his observation has not been left unnoticed by the perfumers. Among French perfumeries we have found, under the name of artificial oil of bitter almonds, and under the still more poetical name of "essence de mirbane," several samples of essential oils, which are no more nor less than nitrobenzol. I was not able to obtain accurate details about the extent of this branch of manufacture, which seems to be of some importance. In London, this article is manufactured with success. The apparatus employed is that of Mansfield, which is very simple. It consists of a large glass worm, the upper extremity of which divides in two branches or tubes, which are provided with funnels. Through one of these funnels passes a stream of concentrated nitric acid; the other is destined as a receiver of benzol, which, for this purpose, requires not to be quite pure; at the angle from where the two tubes branch out, the two bodies meet together, and instantly the chemical combination takes place, which cools sufficiently by passing through the glass worm. The product is afterwards washed with water, and some diluted solution of carbonate of soda; it is then ready for use. Notwithstanding the great physical similarity between nitrobenzol and oil of bitter almonds, there is yet a slight difference in smell which can be detected by an experienced nose.[M] However, nitrobenzol is very useful in scenting soap, and might be employed with great advantage by confectioners and cooks, particularly on account of its safety, being entirely free from prussic acid.
I also need to mention the synthetic oil of bitter almonds. When Mitscherlich discovered nitrobenzol in 1834, he could never have imagined that this product would be made for perfumery and, twenty years later, showcased as fine labeled samples at the London Exhibition. It's true that even at the time of the nitrobenzol discovery, he noted its striking similarity in smell to the oil of bitter almonds. However, back then, the only known sources for obtaining this compound were compressed gases and the distillation of benzoic acid, so the high cost made it impractical to use benzol as a substitute for oil of bitter almonds. In 1845, I successfully identified benzol in common coal-tar oil using the anilin-reaction; by 1849, C.B. Mansfield demonstrated through careful experiments that benzol could be easily obtained in large quantities from coal-tar oil. In his essay, which includes many interesting details about the practical use of benzol, he also mentioned the potential to soon produce fragrant nitrobenzol in large amounts. The Exhibition showed that perfumers took notice of his findings. Among French perfumeries, we found samples labeled as artificial oil of bitter almonds and the more poetic name "essence de mirbane," which are essentially nitrobenzol. I couldn't get precise details about the scale of this manufacturing branch, which seems significant. In London, this product is successfully made using Mansfield's very simple apparatus. It consists of a large glass worm, which splits at the top into two branches or tubes, each equipped with funnels. One funnel carries a stream of concentrated nitric acid; the other collects benzol, which doesn't need to be entirely pure for this purpose. At the junction where the two tubes branch out, the two substances combine, and the chemical reaction cools sufficiently as it passes through the glass worm. The final product is washed with water and some diluted sodium carbonate solution, making it ready for use. Despite the strong physical resemblance between nitrobenzol and oil of bitter almonds, there's a slight smell difference that an experienced nose can detect.[M] However, nitrobenzol is very useful for scenting soap and could be highly beneficial for confectioners and cooks, especially because it is completely free from prussic acid, making it safe to use.
The application of organic chemistry to perfumery is quite new; it is probable that the study of all the ethers or ethereal combinations already known, and of those which the ingenuity of the chemist is daily discovering, will enlarge the sphere of their practical applications. The capryl-ethers lately discovered by Bouis are remarkable for their aromatic smells (the acetate of capryloxide is possessed of the most intense and pleasant smell), and they promise a large harvest to the manufacturers of perfumes.—Annalen der Chemie.
The use of organic chemistry in making perfumes is relatively recent. It's likely that studying all the ethers or ether-like combinations currently known, along with those that chemists are discovering every day, will broaden their practical uses. The capryl-ethers recently discovered by Bouis are notable for their strong, pleasant aromas (the acetate of capryloxide has an incredibly intense and delightful scent), and they hold great potential for perfume manufacturers.—Annalen der Chemie.
CORRESPONDENCE FROM THE "JOURNAL OF THE SOCIETY OF ARTS."[N]
Chemistry and Fragrance.
Sir,
Hey,
When such periodicals as "Household Words" and the "Family Herald" contain scientific matters, treated in a manner to popularize science, all real lovers of philosophy must feel gratified; a little fiction, a little metaphor, is expected, and is accepted with the good intention with which it is given, in such popular prints; but when the "Journal of the Society of Arts" reprints quotations from such sources, without modifying or correcting their expressions, it conveys to its readers a tissue of fiction rather too flimsy to bear a truthful analysis.[O]
When magazines like "Household Words" and the "Family Herald" include scientific topics presented in an accessible way, true enthusiasts of philosophy should feel pleased. A bit of fiction and metaphor is anticipated and accepted with the good intentions behind it in these popular publications. However, when the "Journal of the Society of Arts" reprints quotes from these sources without adjusting or correcting their wording, it gives its readers a mix of fiction that is too thin to withstand a genuine analysis.[O]
In the article on Chemistry and Perfumery, in No. 47, you quote that "some of the most delicate perfumes are now made by chemical artifice, and not, as of old, by distilling them from flowers." Now, sir, this statement conveys to the public a very erroneous idea; because the substances afterwards spoken of are named essences of fruit, and not essences of flowers, and the essences of fruits named in your article never are, and never can be, used in perfumery. This assertion is based on practical experience. The artificial essences of fruits are ethers: when poured upon a handkerchief, and held up to the nose, they act, as is well known, like chloroform. Dare a perfumer sell a bottle of such a preparation to an "unprotected female?"
In the article on Chemistry and Perfumery, in No. 47, you quoted that "some of the most delicate perfumes are now made by chemical artifice, and not, as of old, by distilling them from flowers." Now, sir, this statement gives the public a very misleading idea; because the substances you're referring to are called fruit essences, not flower essences, and the fruit essences mentioned in your article can never be used in perfumery. This claim is based on practical experience. The artificial fruit essences are ethers: when applied to a handkerchief and held up to the nose, they act, as is well known, like chloroform. Would a perfumer really sell a bottle of such a product to an "unprotected female?"
Again, you quote that "the drainings of cow-houses are the main source to which the manufacturer applies for the production of his most delicate and admired perfumes."
Again, you quote that "the runoff from cow barns is the primary source that manufacturers use to create their most delicate and sought-after perfumes."
Shade of Munchausen! must I refute this by calling your attention to the fact that in the south of France more than 80,000 persons are employed, directly and indirectly, in the cultivation of flowers, and in the extraction of their odors for the use of perfumers? that Italy cultivates flowers for the same purpose to an extent employing land as extensive as the whole of some English counties? that tracts of flower-farms exist in the Balkan, in Turkey, more extensive than the whole of Yorkshire? Our own flower-farms at Mitcham, in Surrey, need not be mentioned in comparison, although important. These, sir, are the main sources of perfumes. There are other sources at Thibet, Tonquin, and in the West Indies; but enough has been said, I hope, to refute the cow-house story. This story is founded on the fact that Benzoic acid can be obtained from the draining of stables, and that Benzoic acid has rather a pleasant odor. Some of the largest wholesale perfumers use five or six pounds of gum benzoin per annum, but none use the benzoic acid. The lozenge-makers consume the most of this article when prepared for commercial purposes; as also the fruit essences. Those of your readers interested in what really is used in perfumery, are referred to the last six numbers of the "Annals of Pharmacy and Practical Chemistry," article "Perfumery."
Shade of Munchausen! Do I really need to point out that in the south of France, over 80,000 people work, directly and indirectly, in growing flowers and extracting their scents for perfumers? That Italy grows flowers for the same purpose on land as large as some English counties? That there are flower-farms in the Balkans and Turkey that are bigger than all of Yorkshire? Our own flower-farms in Mitcham, Surrey, while significant, don't need to be mentioned in comparison. These, sir, are the main sources of perfumes. There are additional sources in Tibet, Tonquin, and the West Indies; but I hope I've said enough to debunk the cow-stable story. This story is based on the fact that benzoic acid can be obtained from stable drainage and has a fairly pleasant smell. Some of the largest wholesale perfumers use five or six pounds of gum benzoin each year, but none use the benzoic acid. The lozenge manufacturers consume most of this substance when it’s prepared for commercial use, as do those who produce fruit essences. Readers interested in what is truly used in perfumery should check the last six issues of the "Annals of Pharmacy and Practical Chemistry," article "Perfumery."
Septimus Piesse.
Chemistry and Perfumery.[P]
Chemistry and Fragrance. __A_TAG_PLACEHOLDER_0__
Sir,
Sir,
The discussion about chemistry and perfumery, in reality amounts to this: Mr. Septimus Piesse confines the term "perfumery" to such things as Eau de Cologne, &c.; perfumed soaps, groceries, &c., he does not appear to class as "perfumery." Now the artificial scents are as yet chiefly used for the latter substances, which in common language, and, I should say, in a perfumer's nomenclature also, would be included in perfumery. The authority for cows' urine being used for perfumery is to be found in a little French work called, I believe, "La Chimie de l'Odorat" in which a full description is given of the collection of fresh urine and its application to this purpose. I need scarcely say, that it is the benzoic acid of the urine which is the odoriferous principle.
The conversation about chemistry and perfumery really comes down to this: Mr. Septimus Piesse limits the term "perfumery" to things like Eau de Cologne, etc.; he doesn't seem to consider perfumed soaps, groceries, etc., as part of "perfumery." However, artificial scents are mostly used for those latter products, which, in everyday language and, I would argue, in a perfumer's terminology too, would fall under the category of perfumery. The information about cows' urine being used in perfumery can be found in a little French book called, I believe, "La Chimie de l'Odorat," which gives a detailed description of how to collect fresh urine and its use for this purpose. I barely need to mention, that it's the benzoic acid in the urine that is the fragrant component.
A Fragrance Maker.
[When benzoic acid is prepared by any of the wet processes, it is free from the fragrant volatile oil which accompanies it when prepared by sublimation from the resin, and to which oil the acid of commerce owes its peculiar odor. This fact completely nullifies the above assertion.—Septimus Piesse.]
[When benzoic acid is made using any of the wet processes, it is free from the fragrant volatile oil that comes with it when it is obtained through sublimation from the resin, and that oil is what gives the commercial acid its distinctive smell. This reality completely disproves the previous statement.—Septimus Piesse.]
Sir,
Dude,
If the author of the Letter on Chemistry and Perfumery, published in No. 50 of your Journal, and intended as a reply to mine—though none was needed—which appeared in No. 49, really be a perfumer, as his signature implies, he would know that I could not, though ever so inclined, "confine the term perfumery" to various odoriferous substances, and exclude scented soaps; because he would be aware that one-third of the returns of every manufacturing perfumer is derived from perfumed soap. I do however emphatically exclude from the term perfumery, "groceries, &c.," the et cætera meaning, I presume, "confectionery," because perfumery has to do with one of the senses, smelling, while groceries, &c., are distinguishable by another, taste; and had not our physical faculties clearly made the distinction, commerce and manufactures would have defined them: I therefore repeat, that the artificial essences of fruits are not used in perfumery, as stated in No. 47, from the quoted authorities. If any man can deny this assertion, let him now do so, "or forever after hold his peace," at least upon this subject. The "Journal of the Society of Arts" is not a medium of mere controversy. If a statement be made in error, let truth correct it, which, if gain-sayed, it should be done, not under the veil of an anonymous correspondent, but with a name to support the assertion. Science has to deal with tangible facts and figures, to the political alone belongs the anonymous ink-spiller.
If the author of the Letter on Chemistry and Perfumery, published in No. 50 of your Journal, and meant as a response to mine—though none was needed—which appeared in No. 49, is truly a perfumer, as his signature suggests, he should know that I could not, no matter how much I wanted to, "limit the term perfumery" to just various fragrant substances and leave out scented soaps; because he would understand that one-third of the revenue from every manufacturing perfumer comes from perfumed soap. However, I do clearly exclude from the term perfumery, "groceries, etc.," the et cætera meaning, I assume, "confectionery," because perfumery relates to one of the senses, odor detection, while groceries, etc., are recognized by another, flavor; and if our physical senses hadn't clearly made this distinction, commerce and manufacturing would have defined them as such: I therefore repeat that artificial fruit essences are not used in perfumery, as stated in No. 47, according to the quoted authorities. If anyone can refute this claim, let them do so now, "or forever after hold their peace," at least on this topic. The "Journal of the Society of Arts" is not a platform for mere arguments. If a statement is wrong, let the truth correct it, and if it's challenged, it should be done with a name backing the claim, not through an anonymous correspondent. Science deals with concrete facts and figures; only politics engages in anonymous writing.
Septimus Piesse. 42 Chapel St, Edgware Rd.
[If the word flavor had been used by the various authors who have written upon this subject, in place of the word perfume, the dissemination of an erroneous idea would have been prevented: the word perfume, applied to pear-oil, pine-apple oil, &c., implies, and the general tenor of the remarks of the writers leads the reader to infer, that these substances are used by perfumers, who not only do not, but cannot use them in their trade.
[If the word flavor had been used by the various authors who have written about this topic instead of the word perfume, it would have prevented the spread of a misunderstanding: the word perfume, when referring to pear oil, pineapple oil, etc., suggests, and the overall tone of the authors' statements leads the reader to believe, that these substances are utilized by perfumers, who actually do not, and cannot, use them in their work.]
But for flavoring nectar, lozenges, sweetmeats, &c., these ethers, or oils as the writers term them, are extensively used, and quite in accordance with assertions of Hoffman, Playfair, Fehling, and Bastick. However, the glorious achievements of modern chemistry have not lost anything by this misapplication of a trade term.—Septimus Piesse.]
But for flavoring nectar, lozenges, sweets, etc., these ethers, or oils as the writers call them, are widely used, and completely in line with the claims of Hoffman, Playfair, Fehling, and Bastick. However, the remarkable advancements of modern chemistry have not been diminished by this misuse of a trade term.—Septimus Piesse.
OTTOS FROM PLANTS.
Amounts of Ottos, also known as essential oils, produced by different plants.
Pounds | Of otto. | |
Orange-peel, | 10 yield about | 1 oz. |
Dry marjoram herb, | 20 " | 3 oz. |
Fresh " " | 100 " | 3 oz. |
" Peppermint, | 100 " | 3 to 4 oz. |
Dry " | 25 " | 3 to 4 oz. |
" Origanum, | 25 " | 2 to 3 oz. |
" Thyme, | 20 " | 1 to 1-1/2 oz. |
" Calamus, | 25 " | 3 to 4 oz. |
Anise-seed, | 25 " | 9 to 12 oz. |
Caraway, | 25 " | 16 oz. |
Cloves, | 1 " | 2-1/2 oz. |
Cinnamon, | 25 " | 3 oz. |
Cassia, | 25 " | 3 oz. |
Cedar-wood, | 28 " | 4 oz. |
Mace, | 2 " | 3 oz. |
Nutmegs, | 2 " | 3 to 4 oz. |
Fresh balm herb, | 60 " | 1 to 1-1/2 oz. |
Cake of bitter almond, | 14 " | 1 oz. |
Sweet flag root, | 112 " | 16 oz. |
Geranium leaves, | 112 " | 2 oz. |
Lavender flowers, | 112 " | 30 to 32 oz. |
Myrtle leaves, | 112 " | 5 oz. |
Patchouly herb, | 112 " | 28 oz. |
Province rose blossom, | 112 " | 1-1/2 to 2 drachms. |
Rhodium-wood, | 112 " | 3 to 4 oz. |
Santal-wood, | 112 " | 30 oz. |
Vitivert or kus-kus-root, | 112 " | 15 oz. |
WEIGHTS AND MEASURES.
French Weights and Measures Compared to English.
Imperial | Troy | Kilo- | Lbs. | ||
Litres. | Gallons. | Grammes. | Grains. | grammes. | Avoird. |
1, | 0.22010 | 1, | 15.434 | 1, | 2.20486 |
2, | 0.44019 | 2, | 30.868 | 2, | 4.40971 |
3, | 0.66029 | 3, | 46.302 | 3, | 6.61457 |
4, | 0.88039 | 4, | 61.736 | 4, | 8.81943 |
5, | 1.10048 | 5, | 77.170 | 5, | 11.02429 |
6, | 1.32058 | 6, | 92.604 | 6, | 13.22914 |
7, | 1.54068 | 7, | 108.038 | 7, | 15.43400 |
8, | 1.76077 | 8, | 123.472 | 8, | 17.63886 |
9, | 1.98087 | 9, | 138.906 | 9, | 19.84371 |
English Weights and Measures Compared to French.
Imp. | Troy | Lbs. | Kilo- | ||
Gallons. | Litres. | Grains. | Grammes. | Avoird. | grammes. |
1, | 4.54346 | 1, | 0.06479 | 1, | 0.45354 |
2, | 9.08692 | 2, | 0.12958 | 2, | 0.90709 |
3, | 13.63038 | 3, | 0.19438 | 3, | 1.36063 |
4, | 18.17384 | 4, | 0.25917 | 4, | 1.81418 |
5, | 22.71730 | 5, | 0.32396 | 5, | 2.26772 |
6, | 27.26076 | 6, | 0.38875 | 6, | 2.72126 |
7, | 31.80422 | 7, | 0.45354 | 7, | 3.17481 |
8, | 36.34768 | 8, | 0.51834 | 8, | 3.62835 |
9, | 40.89114 | 9, | 0.58313 | 9, | 4.08190 |
FOOTNOTES:
[A] Brother of the Author.
__A_TAG_PLACEHOLDER_0__ Author's Brother.
[B] See Appendix, "Benzoic Acid."
[C] See "Incense."
[H] The deposit is nearly insoluble in water, is acid and astringent to the taste, gives an acid reaction with litmus. Spirit of wine dissolves out a small portion, which, on evaporation, leaves a thick oleo-resinous substance, having a rancid smell. Ether leaves a pleasant-smelling resin, somewhat resembling camphor. The remainder is nearly insoluble in liq. ammoniæ, liq. potassæ, more soluble in nitric acid, and well deserves to be further examined.
[H] The deposit is almost insoluble in water, has an acidic and astringent taste, and shows an acidic reaction with litmus. Alcohol extracts a small amount, which, when evaporated, leaves a thick, oily resin with a rancid smell. Ether produces a pleasant-smelling resin that's somewhat similar to camphor. The rest is nearly insoluble in ammonia and potassium solutions, but more soluble in nitric acid, and definitely warrants further investigation.
[I] Qy. Confectionery?
__A_TAG_PLACEHOLDER_0__ Qy. Sweets?
[J] Qy. Confectioners?
__A_TAG_PLACEHOLDER_0__ Qy. Candy makers?
[K] Confectionery.
__A_TAG_PLACEHOLDER_0__ Candy.
[L] The writer means ether!
The writer means either!
[M] See "Almond."
__A_TAG_PLACEHOLDER_0__ See "Almond."
[N] No. 49.
[O] If our Correspondent had carefully read the article he so fiercely attacks, he would have seen that the authorities were Dr. Lyon Playfair's Lecture, and Professsor Fehling, in the "Wurtemberg Journal of Industry."—Ed.
[O] If our correspondent had taken the time to read the article he is criticizing so passionately, he would have noticed that the sources were Dr. Lyon Playfair's lecture and Professor Fehling, in the "Wurtemberg Journal of Industry."—Ed.
[P] No. 50.
__A_TAG_PLACEHOLDER_0__ No. 50.
[Q] No. 52.
Download ePUB
If you like this ebook, consider a donation!