This is a modern-English version of Worlds Within Worlds: The Story of Nuclear Energy, Volume 1 (of 3): Atomic Weights; Energy; Electricity, originally written by Asimov, Isaac. It has been thoroughly updated, including changes to sentence structure, words, spelling, and grammar—to ensure clarity for contemporary readers, while preserving the original spirit and nuance. If you click on a paragraph, you will see the original text that we modified, and you can toggle between the two versions.

Scroll to the bottom of this page and you will find a free ePUB download link for this book.

Worlds Within Worlds: The Story of Nuclear Energy, Volume 1; Atomic Weights; Energy; Electricity

Worlds Within Worlds:
The History of Nuclear Energy
Volume 1
Atomic Weights · Energy · Electricity

by Isaac Asimov

by Isaac Asimov

U. S. Energy Research and Development Administration
Office of Public Affairs
Washington, D.C. 20545

U.S. Energy Research and Development Administration
Public Affairs Office
Washington, D.C. 20545

Library of Congress Catalog Card Number: 75-189477
1972

Library of Congress Catalog Card Number: 75-189477
1972

Nothing in the history of mankind has opened our eyes to the possibilities of science as has the development of atomic power. In the last 200 years, people have seen the coming of the steam engine, the steamboat, the railroad locomotive, the automobile, the airplane, radio, motion pictures, television, the machine age in general. Yet none of it seemed quite so fantastic, quite so unbelievable, as what man has done since 1939 with the atom ... there seem to be almost no limits to what may lie ahead: inexhaustible energy, new worlds, ever-widening knowledge of the physical universe. Isaac Asimov

Nothing in human history has opened our eyes to the possibilities of science like the development of atomic power. In the last 200 years, we've witnessed the arrival of the steam engine, steamboats, locomotives, cars, airplanes, radio, movies, television, and the entire machine age. Yet nothing has felt as amazing or as unbelievable as what we've achieved with atomic energy since 1939 ... it feels like there are almost no limits to what the future might hold: endless energy, new worlds, and an ever-growing understanding of the physical universe. Isaac Asimov

Photograph of night sky

The U. S. Energy Research and Development Administration publishes a series of booklets for the general public.

The U.S. Energy Research and Development Administration publishes a series of booklets for the general public.

Please write to the following address for a title list or for information on a specific subject:

Please contact the following address for a list of titles or for information on a specific topic:

USERDA—Technical Information Center

USERDA—Tech Info Center

P. O. Box 62

P.O. Box 62

Oak Ridge, Tennessee 37830

Oak Ridge, TN 37830

Isaac Asimov

ISAAC ASIMOV received his academic degrees from Columbia University and is Associate Professor of Biochemistry at the Boston University School of Medicine. He is a prolific author who has written over 150 books in the past 20 years, including about 20 science fiction works, and books for children. His many excellent science books for the public cover subjects in mathematics, physics, astronomy, chemistry, and biology, such as The Genetic Code, Inside the Atom, Building Blocks of the Universe, Understanding Physics, The New Intelligent Man’s Guide to Science, and Asimov’s Biographical Encyclopedia of Science and Technology.

ISAAC ASIMOV earned his degrees from Columbia University and is currently an Associate Professor of Biochemistry at the Boston University School of Medicine. He is a prolific writer who has published over 150 books in the last 20 years, including around 20 science fiction novels, as well as books for kids. His many great science books for the general public address topics in mathematics, physics, astronomy, chemistry, and biology, including The Genetic Code, Inside the Atom, Building Blocks of the Universe, Understanding Physics, The New Intelligent Man’s Guide to Science, and Asimov’s Biographical Encyclopedia of Science and Technology.

In 1965 Dr. Asimov received the James T. Grady Award of the American Chemical Society for his major contribution in reporting science progress to the public.

In 1965, Dr. Asimov was awarded the James T. Grady Award by the American Chemical Society for his significant contributions in communicating scientific advancements to the public.

Photograph of night sky
VOLUME 1
Introduction 5
Atomic Weights 6
Electricity 11
Units of Electricity 11
Cathode Rays 13
Radioactivity 17
The Structure of the Atom 25
Atomic Numbers 30
Isotopes 35
Energy 47
The Law of Conservation of Energy 47
Chemical Energy 50
Electrons and Energy 54
The Energy of the Sun 55
The Energy of Radioactivity 57
VOLUME 2
Mass and Energy 69
The Structure of the Nucleus 75
The Proton 75
The Proton-Electron Theory 76
Protons in Nuclei 80
Nuclear Bombardment 82
Particle Accelerators 86
The Neutron 92
Nuclear Spin 92
Discovery of the Neutron 95
The Proton-Neutron Theory 98
The Nuclear Interaction 101
Neutron Bombardment 107
VOLUME 3
Nuclear Fission 117
New Elements 117
The Discovery of Fission 122
The Nuclear Chain Reaction 127
The Nuclear Bomb 131
Nuclear Reactors 141
Nuclear Fusion 147
The Energy of the Sun 147
Thermonuclear Bombs 149
Controlled Fusion 151
Beyond Fusion 159
Antimatter 159
The Unknown 164
Reading List 166
4

A total eclipse of the sun.

A total solar eclipse.

5

INTRODUCTION

In a way, nuclear energy has been serving man as long as he has existed. It has served all of life; it has flooded the earth for billions of years. The sun, you see, is a vast nuclear engine, and the warmth and light that the sun radiates is the product of nuclear energy.

In a sense, nuclear energy has been part of human existence since the beginning. It has supported all life; it has bathed the earth for billions of years. The sun, you see, is a massive nuclear engine, and the heat and light it emits result from nuclear energy.

In order for man to learn to produce and control nuclear energy himself, however (something that did not take place until this century), three lines of investigation—atoms, electricity, and energy—had to develop and meet.

In order for people to learn to produce and control nuclear energy themselves, however (something that didn’t happen until this century), three areas of research—atoms, electricity, and energy—had to evolve and come together.

We will begin with atoms.

We'll start with atoms.

6

ATOMIC WEIGHTS

As long ago as ancient Greek times, there were men who suspected that all matter consisted of tiny particles which were far too small to see. Under ordinary circumstances, they could not be divided into anything smaller, and they were called “atoms” from a Greek word meaning “indivisible”.

As far back as ancient Greece, some people believed that all matter was made up of tiny particles that were too small to see. Normally, these particles couldn't be split into anything smaller, and they were called "atoms," which comes from a Greek word meaning "indivisible."

It was not until 1808, however, that this “atomic theory” was really put on a firm foundation. In that year the English chemist John Dalton (1766-1844) published a book in which he discussed atoms in detail. Every element, he suggested, was made up of its own type of atoms. The atoms of one element were different from the atoms of every other element. The chief difference between the various atoms lay in their mass, or weight.[1]

It wasn't until 1808 that this "atomic theory" was truly established. That year, the English chemist John Dalton (1766-1844) published a book where he discussed atoms in detail. He suggested that every element was made up of its own specific type of atoms. The atoms of one element were different from the atoms of all other elements. The main difference between the various atoms was in their mass or weight.[1]

Dalton was the first to try to determine what these masses might be. He could not work out the actual masses in ounces or grams, for atoms were far too tiny to weigh with any of his instruments. He could, however, determine their relative weights; that is, how much more massive one kind of atom might be than another.

Dalton was the first to try to figure out what these masses could be. He couldn't measure the actual masses in ounces or grams because atoms were way too small for any of his instruments to weigh. However, he could determine their relative weights; that is, how much more massive one type of atom might be compared to another.

For instance, he found that a quantity of hydrogen gas invariably combined with eight times its own mass of oxygen gas to form water. He guessed that water consisted of combinations of 1 atom of hydrogen with 1 atom of oxygen. (A combination of atoms is called a “molecule” from a Greek word meaning “a small mass”, and so hydrogen and oxygen atoms can be said to combine to form a “water molecule”.)

For example, he discovered that a certain amount of hydrogen gas always combined with eight times its own weight of oxygen gas to create water. He theorized that water was made up of combinations of 1 atom of hydrogen and 1 atom of oxygen. (A combination of atoms is called a “molecule,” which comes from a Greek word meaning “a small mass,” so hydrogen and oxygen atoms can be said to combine to form a “water molecule.”)

7

John Dalton

John Dalton

8

To account for the difference in the masses of the combining gases, Dalton decided that the oxygen atom was eight times as massive as the hydrogen atom. If he set the mass of the hydrogen atom at 1 (just for convenience) then the mass of the oxygen atom ought to be set at 8. These comparative, or relative, numbers were said to be “atomic weights”, so that what Dalton was suggesting was that the atomic weight of hydrogen was 1 and the atomic weight of oxygen was 8. By noting the quantity of other elements that combined with a fixed mass of oxygen or of hydrogen, Dalton could work out the atomic weights of these elements as well.

To explain the difference in the masses of the gases that combined, Dalton concluded that the oxygen atom was eight times heavier than the hydrogen atom. If he assigned a mass of 1 to the hydrogen atom (just for simplicity), then the mass of the oxygen atom should be set at 8. These comparative, or relative, numbers were referred to as “atomic weights.” So, what Dalton was suggesting was that the atomic weight of hydrogen was 1 and the atomic weight of oxygen was 8. By observing how much of other elements combined with a fixed mass of oxygen or hydrogen, Dalton could also determine the atomic weights of those elements.

Dalton’s idea was right, but his details were wrong in some cases. For instance, on closer examination it turned out that the water molecule was composed of 1 oxygen atom and 2 hydrogen atoms. For this reason, the water molecule may be written H₂O, where H is the chemical symbol for a hydrogen atom, and O for an oxygen atom.

Dalton’s idea was correct, but some of his details were inaccurate. For example, upon closer inspection, it was found that a water molecule consists of 1 oxygen atom and 2 hydrogen atoms. Therefore, a water molecule can be represented as H₂O, where H is the chemical symbol for a hydrogen atom and O stands for an oxygen atom.

It is still a fact that a quantity of hydrogen combines with eight times its mass of oxygen, so the single oxygen atom must be eight times as massive as the 2 hydrogen atoms taken together. The oxygen atom must therefore be sixteen times as massive as a single hydrogen atom. If the atomic weight of hydrogen is 1, then the atomic weight of oxygen is 16.

It is still true that a certain amount of hydrogen combines with eight times its mass of oxygen, so the single oxygen atom must have eight times the mass of the two hydrogen atoms combined. Therefore, the oxygen atom must be sixteen times as heavy as a single hydrogen atom. If the atomic weight of hydrogen is 1, then the atomic weight of oxygen is 16.

At first it seemed that the atomic weights of the various elements were whole numbers and that hydrogen was the lightest one. It made particular sense, then, to consider the atomic weight of hydrogen as 1, because that made all the other atomic weights as small as possible and therefore easy to handle.

At first, it seemed that the atomic weights of different elements were whole numbers and that hydrogen was the lightest one. It made a lot of sense to consider the atomic weight of hydrogen as 1 because that made all the other atomic weights as small as possible and therefore easier to work with.

The Swedish chemist Jöns Jakob Berzelius (1779-1848) continued Dalton’s work and found that elements did not combine in quite such simple ratios. A given quantity of hydrogen actually combined with a little bit less than eight times its mass of oxygen. Therefore if the atomic weight of hydrogen were considered to be 1, the atomic weight of oxygen would have to be not 16, but 15.87.

The Swedish chemist Jöns Jakob Berzelius (1779-1848) continued Dalton’s work and discovered that elements didn't combine in such simple ratios. A specific amount of hydrogen actually combined with just under eight times its mass of oxygen. So, if we consider the atomic weight of hydrogen to be 1, the atomic weight of oxygen would need to be not 16, but 15.87.

9

Jöns Jakob Berzelius

Jöns Jakob Berzelius

As it happens, oxygen combines with more elements (and more easily) than hydrogen does. The ratio of its atomic weight to that of other elements is also more often a whole number. In working out the atomic weight of elements it was therefore more convenient to set the atomic weight of oxygen at a whole number than that of hydrogen. Berzelius did this, for instance, in the table of atomic weights he published in 1828. At first he called the atomic weight of oxygen 100. Then he decided to make the atomic weights as small as possible, without allowing any atomic weight to be less than 1. For that reason, he set the atomic weight of oxygen at exactly 16 and in that case, the atomic weight of 10 hydrogen had to be placed just a trifle higher than 1. The atomic weight of hydrogen became 1.008. This system was retained for nearly a century and a half.

As it turns out, oxygen bonds with more elements (and more easily) than hydrogen does. Its atomic weight ratio compared to other elements is also more frequently a whole number. When calculating the atomic weight of elements, it was therefore more convenient to set oxygen's atomic weight as a whole number instead of hydrogen's. Berzelius did this, for example, in the atomic weights table he published in 1828. Initially, he assigned the atomic weight of oxygen as 100. Then he decided to make the atomic weights as small as possible, without any atomic weight being less than 1. Because of this, he set oxygen's atomic weight at exactly 16, which meant the atomic weight of hydrogen had to be just slightly above 1. The atomic weight of hydrogen became 1.008. This system was maintained for nearly a century and a half.

Throughout the 19th century, chemists kept on working out atomic weights more and more carefully. By the start of the 20th century, most elements had their atomic weights worked out to two decimal places, sometimes three.

Throughout the 19th century, chemists continued to refine atomic weights with great precision. By the beginning of the 20th century, most elements had their atomic weights calculated to two decimal places, and sometimes even three.

A number of elements had atomic weights that were nearly whole numbers on the “oxygen = 16” standard. The atomic weight of aluminum was just about 27, that of calcium almost 40, that of carbon almost 12, that of gold almost 197, and so on.

A number of elements had atomic weights that were close to whole numbers based on the “oxygen = 16” standard. The atomic weight of aluminum was roughly 27, calcium's was nearly 40, carbon's was around 12, gold's was about 197, and so on.

On the other hand, some elements had atomic weights that were far removed from whole numbers. The atomic weight of chlorine was close to 35.5, that of copper to 63.5, that of iron to 55.8, that of silver to 107.9, and so on.

On the other hand, some elements had atomic weights that were far from whole numbers. The atomic weight of chlorine was around 35.5, copper was about 63.5, iron was around 55.8, silver was close to 107.9, and so on.

Throughout the 19th century, chemists did not know why so many atomic weights were whole numbers, while others weren’t. They simply made their measurements and recorded what they found. For an explanation, they had to wait for a line of investigation into electricity to come to fruition.

Throughout the 19th century, chemists didn’t understand why many atomic weights were whole numbers while others were not. They just took their measurements and noted their findings. For an explanation, they had to wait for research into electricity to bear fruit.

11

ELECTRICITY

Units of Electricity

Through the 18th century, scientists had been fascinated by the properties of electricity. Electricity seemed, at the time, to be a very fine fluid that could extend through ordinary matter without taking up any room.

Through the 18th century, scientists were intrigued by the properties of electricity. At the time, electricity appeared to be a fine fluid that could pass through ordinary matter without occupying any space.

Electricity did more than radiate through matter, however. It also produced important changes in matter. In the first years of the 19th century, it was found that a current of electricity could cause different atoms or different groups of atoms to move in opposite directions through a liquid in which they were dissolved.

Electricity did more than just flow through substances; it also caused significant changes in them. In the early 1800s, it was discovered that an electric current could make different atoms or groups of atoms move in opposite directions through a liquid in which they were dissolved.

The English scientist Michael Faraday (1791-1867) noted in 1832 that a given quantity of electricity seemed to liberate the same number of atoms of a variety of different elements. In some cases, though, it liberated just half the expected number of atoms; or even, in a few cases, just a third.

The English scientist Michael Faraday (1791-1867) observed in 1832 that a specific amount of electricity appeared to release the same number of atoms across various elements. However, in some instances, it only released half the anticipated number of atoms; or, in a few cases, just a third.

Scientists began to speculate that electricity, like matter, might consist of tiny units. When electricity broke up a molecule, perhaps a unit of electricity attached itself to each atom. In that case, the same quantity of electricity, containing the same number of units, would liberate the same number of atoms.

Scientists started to think that electricity, similar to matter, might be made up of tiny units. When electricity disrupted a molecule, a unit of electricity might connect itself to each atom. In that scenario, the same amount of electricity, containing the same number of units, would release the same number of atoms.

In the case of some elements, each atom could attach 2 units of electricity to itself, or perhaps even 3. When that happened a given quantity of electricity would liberate only one-half, or only one-third, the usual number of atoms. (Thus, 18 units of electricity would liberate 18 atoms if distributed 1 to an atom; only 9 atoms if distributed 2 to an atom; and only 6 atoms if distributed 3 to an atom.)

In some cases, each atom could attach 2 units of electricity to itself, or maybe even 3. When that happened, a specific amount of electricity would free only half, or a third, of the usual number of atoms. (So, 18 units of electricity would free 18 atoms if given 1 to each atom; only 9 atoms if given 2 to each atom; and only 6 atoms if given 3 to each atom.)

It was understood at the time that electricity existed in two varieties, which were called positive and negative. It appeared that if an atom attached a positive unit of electricity to itself it would be pulled in one direction through the solution by the voltage. If it attached a negative unit of electricity to itself it would be pulled in the other direction.

It was understood back then that electricity came in two types, known as positive and negative. It seemed that if an atom connected to a positive unit of electricity, it would be pulled in one direction through the solution by the voltage. If it connected to a negative unit of electricity, it would be pulled in the opposite direction.

12

Michael Faraday

Mike Faraday

13

The units of electricity were a great deal more difficult to study than the atomic units of matter, and throughout the 19th century they remained elusive. In 1891, though, the Irish physicist George Johnstone Stoney (1826-1911) suggested that the supposed unit of electricity be given a name at least. He called the unit an “electron”.

The units of electricity were much harder to study than the atomic units of matter, and they remained elusive throughout the 19th century. In 1891, however, the Irish physicist George Johnstone Stoney (1826-1911) proposed that the supposed unit of electricity should at least have a name. He named the unit an “electron.”

Cathode Rays

An electric current flows through a closed circuit of some conducting material, such as metal wires. It starts at one pole of a battery, or of some other electricity generating device, and ends at the other. The two poles are the positive pole or “anode” and the negative pole or “cathode”.

An electric current travels through a closed circuit made of conducting material, like metal wires. It begins at one terminal of a battery or another electricity-generating device and ends at the other. The two terminals are the positive terminal or "anode" and the negative terminal or "cathode."

If there is a break in the circuit, the current will usually not flow at all. If, however, the break is not a large one, and the current is under a high driving force (which is called the “voltage”), then the current may leap across the break. If two ends of a wire, making up part of a broken circuit, are brought close to each other with nothing but air between, a spark may leap across the narrowing gap before they actually meet and, while it persists, the current will flow despite the break.

If there's a gap in the circuit, the current typically won't flow at all. However, if the gap isn't too wide and the current has a strong driving force (known as "voltage"), the current might jump across the gap. If the two ends of a wire that are part of a broken circuit are brought close together with just air in between, a spark may jump across the small space before they actually touch, and as long as that spark is there, the current will flow despite the break.

The light of the spark, and the crackling sound it makes, are the results of the electric current interacting with molecules of air and heating them. Neither the light nor the sound is the electricity itself. In order to detect the electricity, the current ought to be forced across a gap containing nothing, not even air.

The light from the spark and the crackling sound it creates come from the electric current interacting with air molecules and heating them up. Neither the light nor the sound is the electricity itself. To actually detect the electricity, the current needs to be pushed across a space that has nothing in it, not even air.

In order to do that, wires would have to be sealed into a glass tube from which all (or almost all) the air was withdrawn. This was not easy to do and it was not until 1854 that Heinrich Geissler (1814-1879), a German glass-blower and inventor, accomplished this feat. The wires sealed 14 into such a “Geissler tube” could be attached to the poles of an electric generator, and if enough voltage was built up, the current would leap across the vacuum.

To achieve this, wires needed to be sealed inside a glass tube from which all (or nearly all) the air was removed. This wasn’t easy, and it wasn't until 1854 that Heinrich Geissler (1814-1879), a German glassblower and inventor, succeeded in doing it. The wires sealed 14 into this “Geissler tube” could be connected to the terminals of an electric generator, and if sufficient voltage was generated, the current would jump across the vacuum.

A Geissler tube.

A Geissler tube.

Such experiments were first performed by the German physicist Julius Plücker (1801-1868). In 1858 he noticed that when the current flowed across the vacuum there was a greenish glow about the wire that was attached to the cathode of the generator. Others studied this glow and finally the German physicist Eugen Goldstein (1850-1931) decided in 1876 that there were rays of some sort beginning at the wire attached to the negatively charged cathode and ending at the part of the tube opposite the cathode. He called them “cathode rays”.

Such experiments were first conducted by the German physicist Julius Plücker (1801-1868). In 1858, he observed that when the current passed through the vacuum, there was a greenish glow around the wire connected to the cathode of the generator. Others investigated this glow, and eventually, the German physicist Eugen Goldstein (1850-1931) concluded in 1876 that there were some kind of rays starting from the wire linked to the negatively charged cathode and reaching the section of the tube opposite the cathode. He named them "cathode rays."

These cathode rays, it seemed, might well be the electric current itself, freed from the metal wires that usually carried it. If so, determining the nature of the cathode rays might reveal a great deal about the nature of the electric current. Were cathode rays something like light and were they made up of tiny waves? Or were they a stream of particles possessing mass?

These cathode rays seemed like they could be the electric current itself, released from the metal wires that typically carried it. If that's the case, figuring out what the cathode rays actually are could tell us a lot about electric current. Were cathode rays similar to light and composed of tiny waves? Or were they a flow of particles that have mass?

There were physicists on each side of the question. By 1885, however, the English physicist William Crookes 15 (1832-1919) showed that cathode rays could be made to turn a small wheel when they struck that wheel on one side. This seemed to show that the cathode rays possessed mass and were a stream of atom-like particles, rather than a beam of mass-less light. Furthermore, Crookes showed that the cathode rays could be pushed sideways in the presence of a magnet. (This effect, when current flows in a wire, is what makes a motor work.) This meant that, unlike either light or ordinary atoms, the cathode rays carried an electric charge.

There were physicists on both sides of the debate. By 1885, though, the English physicist William Crookes 15 (1832-1919) demonstrated that cathode rays could make a small wheel spin when they hit it from one side. This seemed to indicate that cathode rays had mass and were streams of particles similar to atoms, rather than just a beam of massless light. Additionally, Crookes showed that the cathode rays could be pushed sideways in the presence of a magnet. (This effect, which occurs when current flows in a wire, is what powers a motor.) This meant that, unlike light or regular atoms, the cathode rays had an electric charge.

J. J. Thomson in his laboratory. On his right are early X-ray pictures.

J. J. Thomson in his lab. To his right are some of the first X-ray images.

This view of the cathode rays as consisting of a stream of electrically charged particles was confirmed by another English physicist, Joseph John Thomson (1856-1940). In 1897 he showed that the cathode rays could also be made to take a curved path in the presence of electrically charged 16 objects. The particles making up the cathode rays were charged with negative electricity, judging from the direction in which they were made to curve by electrically charged objects.

This idea that cathode rays are a stream of electrically charged particles was confirmed by another English physicist, Joseph John Thomson (1856-1940). In 1897, he demonstrated that cathode rays could also be made to follow a curved path when near electrically charged 16 objects. The particles that make up the cathode rays were negatively charged, based on the direction in which they curved when influenced by electrically charged objects.

Thomson had no hesitation in maintaining that these particles carried the units of electricity that Faraday’s work had hinted at. Eventually, Stoney’s name for the units of electricity was applied to the particles that carried those units. The cathode rays, in other words, were considered to be made up of streams of electrons and Thomson is usually given credit for having discovered the electron.

Thomson had no doubt in asserting that these particles carried the units of electricity that Faraday's work had suggested. Eventually, Stoney’s term for the units of electricity was assigned to the particles that carried those units. In other words, cathode rays were seen as streams of electrons, and Thomson is typically recognized for discovering the electron.

The extent to which cathode rays curved in the presence of a magnet or electrically charged objects depended on the size of the electric charge on the electrons and on the mass of the electrons. Ordinary atoms could be made to carry an electric charge and by comparing their behavior with those of electrons, some of the properties of electrons could be determined.

The degree to which cathode rays bent when exposed to a magnet or electrically charged objects depended on the amount of electric charge on the electrons and the mass of the electrons. Regular atoms could be given an electric charge, and by comparing their behavior to that of electrons, some properties of electrons could be figured out.

There were, for instance, good reasons to suppose that the electron carried a charge of the same size as one that a hydrogen atom could be made to carry. The electrons, however, were much easier to pull out of their straight-line path than the charged hydrogen atom was. The conclusion drawn from this was that the electron had much less mass than the hydrogen atom.

There were, for example, good reasons to believe that the electron had a charge the same size as the one that a hydrogen atom could have. However, it was much easier to remove electrons from their straight-line path than it was to move the charged hydrogen atom. The conclusion drawn from this was that the electron had much less mass than the hydrogen atom.

Thomson was able to show, indeed, that the electron was much lighter than the hydrogen atom, which was the lightest of all the atoms. Nowadays we know the relationship quite exactly. We know that it would take 1837.11 electrons to possess the mass of a single hydrogen atom. The electron is therefore a “subatomic particle”; the first of this sort to be discovered.

Thomson was able to demonstrate that the electron was significantly lighter than the hydrogen atom, which is the lightest of all atoms. Today, we understand this relationship very precisely. We know that it would take 1837.11 electrons to equal the mass of one hydrogen atom. Therefore, the electron is considered a "subatomic particle," the first of its kind to be discovered.

In 1897, then, two types of mass-containing particles were known. There were the atoms, which made up ordinary matter, and the electrons, which made up electric current.

In 1897, two types of mass-carrying particles were known. There were atoms, which constituted regular matter, and electrons, which formed electric current.

17

Radioactivity

Was there a connection between these two sets of particles—atoms and electrons? In 1897, when the electron was discovered, a line of research that was to tie the two kinds of particles together had already begun.

Was there a link between these two types of particles—atoms and electrons? In 1897, when the electron was discovered, research that would connect the two kinds of particles had already started.

In 1895 the German physicist Wilhelm Konrad Roentgen (1845-1923) was working with cathode rays. He found that if he made the cathode rays strike the glass at the other end of the tube, a kind of radiation was produced. This radiation was capable of penetrating glass and other matter. Roentgen had no idea as to the nature of the radiation, and so called it “X rays”. This name, containing “X” for “unknown”, was retained even after physicists worked out the nature of X rays and found them to be light-like radiation made up of waves much shorter than those of ordinary light.

In 1895, German physicist Wilhelm Konrad Roentgen (1845-1923) was researching cathode rays. He discovered that when these rays hit the glass at the end of the tube, they produced a type of radiation. This radiation could penetrate glass and other materials. Roentgen had no understanding of what the radiation was, so he named it “X rays.” The “X” stands for “unknown,” and the name stuck even after scientists figured out that X rays are a type of light-like radiation made up of waves much shorter than those of regular light.

Antoine Henri Becquerel.

Antoine Henri Becquerel.

At once, physicists became fascinated with X rays and began searching for them everywhere. One of those involved in the search was the French physicist Antoine Henri Becquerel (1852-1908). A certain compound, potassium uranyl sulfate, glowed after being exposed to sunlight and Becquerel wondered if this glow, like the glow on the glass in Roentgen’s X-ray tube, contained X rays.

At that moment, physicists became intrigued by X-rays and started looking for them everywhere. One of the researchers was the French physicist Antoine Henri Becquerel (1852-1908). A specific compound, potassium uranyl sulfate, glowed after being exposed to sunlight, and Becquerel speculated whether this glow, similar to the glow on the glass in Roentgen’s X-ray tube, might emit X-rays.

18
Roentgen’s laboratory
19

Wilhelm Roentgen and his laboratory at the University of Würzburg.

Wilhelm Roentgen and his lab at the University of Würzburg.

It did, but while investigating the problem in 1896, Becquerel found that the compound was giving off invisible penetrating X-ray-like radiation continually, whether it was exposed to sunlight or not. The radiation was detected because it would fog a photographic plate just as light would. What’s more, the radiation would fog the plate, even if the plate were wrapped in black paper, so that it could penetrate matter just as X rays could.

It did, but while looking into the issue in 1896, Becquerel discovered that the compound was continuously emitting invisible, penetrating radiation similar to X-rays, regardless of whether it was exposed to sunlight. The radiation was detected because it could fog a photographic plate just like light. Furthermore, the radiation would fog the plate even if it was wrapped in black paper, showing that it could penetrate matter just like X-rays.

Others, in addition to Becquerel, were soon investigating the new phenomenon. In 1898 the Polish (later French) 20 physicist Marie Sklodowska Curie (1867-1934) showed that it was the uranium atom that was the source of the radiation, and that any compound containing the uranium atom would give off these penetrating rays.

Others, along with Becquerel, quickly began looking into the new phenomenon. In 1898, the Polish (later French) 20 physicist Marie Sklodowska Curie (1867-1934) demonstrated that the uranium atom was the source of the radiation, and that any compound containing the uranium atom would emit these penetrating rays.

Until then, uranium had not been of much interest to chemists. It was a comparatively rare metal that was first discovered in 1789 by the German chemist Martin Heinrich Klaproth (1743-1817). It had no particular uses and remained an obscure element. As chemists learned to work out the atomic weights of the various elements, they found, however, that, of the elements then known, uranium had the highest atomic weight of all—238.

Until then, uranium hadn't been of much interest to chemists. It was a relatively rare metal first discovered in 1789 by the German chemist Martin Heinrich Klaproth (1743-1817). It didn't have any significant uses and remained an obscure element. However, as chemists began figuring out the atomic weights of the different elements, they discovered that, of all the known elements at the time, uranium had the highest atomic weight—238.

Once uranium was discovered to be an endless source of radiation, it gained interest that has risen ever since. Madame Curie gave the name “radioactivity” to this phenomenon of continuously giving off rays. Uranium was the first element found to be radioactive.

Once uranium was discovered to be an endless source of radiation, it piqued interest that has increased ever since. Madame Curie coined the term “radioactivity” for this phenomenon of continuously emitting rays. Uranium was the first element identified as radioactive.

It did not remain alone, however. It was soon shown that thorium was also radioactive. Thorium, which had been discovered in 1829 by Berzelius, was made up of atoms that were the second most massive known at the time. Thorium’s atomic weight is 232.

It didn't stay alone for long, though. It quickly became clear that thorium was also radioactive. Thorium, discovered in 1829 by Berzelius, consisted of atoms that were the second heaviest known at the time. Thorium’s atomic weight is 232.

But what was the mysterious radiation emitted by uranium and thorium?

But what was the mysterious radiation released by uranium and thorium?

Almost at once it was learned that whatever the radiation was, it was not uniform in properties. In 1899 Becquerel (and others) showed that, in the presence of a magnet, some of the radiation swerved in a particular direction. Later it was found that a portion of it swerved in the opposite direction. Still another part didn’t swerve at all but moved on in a straight line.

Almost immediately, it became clear that the radiation was not uniform in its properties. In 1899, Becquerel (and others) demonstrated that, when exposed to a magnet, some of the radiation deflected in a specific direction. Later, it was discovered that a portion of it deflected in the opposite direction. Additionally, another part didn’t deflect at all and continued moving in a straight line.

The conclusion was that uranium and thorium gave off three kinds of radiation. One carried a positive charge of electricity, one a negative charge, and one no charge at all. The New Zealand-born physicist Ernest Rutherford (1871-1937) called the first two kinds of radiation “alpha rays” and “beta rays”, after the first two letters of the Greek alphabet. The third was soon called “gamma rays” after the third letter.

The conclusion was that uranium and thorium emitted three types of radiation. One had a positive electrical charge, one had a negative charge, and one had no charge at all. The New Zealand-born physicist Ernest Rutherford (1871-1937) named the first two types of radiation “alpha rays” and “beta rays,” based on the first two letters of the Greek alphabet. The third type was soon called “gamma rays” after the third letter.

21

Ernest Rutherford

Ernest Rutherford

22

Marie Curie and her two daughters, Eve (left) and Irene, in 1908.

Marie Curie and her two daughters, Eve (left) and Irene, in 1908.

23

Pierre Curie during a class lecture in 1906, the year of his death.

Pierre Curie giving a lecture in 1906, the year he passed away.

24

The gamma rays eventually turned out to be another light-like form of radiation, with waves even shorter than those of X rays. The alpha rays and beta rays, which carried electric charges, seemed to be streams of charged particles (“alpha particles” and “beta particles”) just as the cathode rays had turned out to be.

The gamma rays turned out to be another type of light-like radiation, with waves even shorter than X-rays. The alpha and beta rays, which had electric charges, appeared to be streams of charged particles ("alpha particles" and "beta particles") just like the cathode rays were.

In 1900, indeed, Becquerel studied the beta particles and found them to be identical in mass and charge with electrons. They were electrons.

In 1900, Becquerel examined beta particles and discovered that they were identical in mass and charge to electrons. They were electrons.

By 1906 Rutherford had worked out the nature of the alpha particles. They carried a positive electric charge that was twice as great as the electron’s negative charge. If an electron carried a charge that could be symbolized as -, then the charge of the alpha particle was ++. Furthermore, the alpha particle was much more massive than the electron. It was, indeed, as massive as a helium atom (the second lightest known atom) and four times as massive as a hydrogen atom. Nevertheless, the alpha particle can penetrate matter in a way in which atoms cannot, so that it seems much smaller in diameter than atoms are. The alpha particle, despite its mass, is another subatomic particle.

By 1906, Rutherford had figured out what alpha particles were. They had a positive electric charge that was twice as strong as the negative charge of an electron. If an electron's charge is represented as -, then the alpha particle's charge is ++. Additionally, the alpha particle is much heavier than the electron. In fact, it’s as heavy as a helium atom (the second lightest known atom) and four times heavier than a hydrogen atom. However, the alpha particle can penetrate matter in a way that atoms cannot, making it seem much smaller in size than atoms. Despite its mass, the alpha particle is still a subatomic particle.

Here, then, is the meeting point of electrons and of atoms—the particles of electricity and of matter.

Here is where electrons and atoms meet— the particles of electricity and matter.

Ever since Dalton had first advanced the atomic theory over a century earlier, chemists had assumed that atoms were the fundamental units of matter. They had assumed atoms were as small as anything could be and that they could not possibly be broken up into anything smaller. The discovery of the electron, however, had shown that some particles, at least, might be far smaller than any atom. Then, the investigations into radioactivity had shown that atoms of uranium and thorium spontaneously broke up into smaller particles, including electrons and alpha particles.

Ever since Dalton first proposed the atomic theory over a hundred years ago, chemists have believed that atoms are the basic units of matter. They thought atoms were as small as anything could get and that they couldn't be broken down into anything smaller. However, the discovery of the electron revealed that some particles might actually be much smaller than any atom. Then, research into radioactivity showed that atoms of uranium and thorium could spontaneously break apart into smaller particles, including electrons and alpha particles.

25

It would seem, then, that atoms of these elements and, presumably, of all elements, were made up of still smaller particles and that among these particles were electrons. The atom had a structure and physicists became interested in discovering exactly what that structure was.

It seems, then, that atoms of these elements and, presumably, all elements, were made up of even smaller particles, and that among these particles were electrons. The atom had a structure, and physicists became interested in figuring out exactly what that structure was.

The Structure of the Atom

Since radioactive atoms gave off either positively charged particles or negatively charged particles, it seemed reasonable to assume that atoms generally were made up of both types of electricity. Furthermore, since the atoms in matter generally carried no charge at all, the normal “neutral atom” must be made up of equal quantities of positive charge and negative charge.

Since radioactive atoms emitted either positively charged particles or negatively charged particles, it made sense to assume that atoms were generally composed of both types of electricity. Additionally, since the atoms in matter typically had no charge at all, the standard “neutral atom” must consist of equal amounts of positive and negative charge.

It turned out that only radioactive atoms, such as those of uranium and thorium, gave off positively charged alpha particles. Many atoms, however, that were not radioactive, could be made to give off electrons. In 1899 Thomson showed that certain perfectly normal metals with no trace of radioactivity gave off electrons when exposed to ultraviolet light. (This is called the “photoelectric effect”.)

It turned out that only radioactive atoms, like uranium and thorium, emitted positively charged alpha particles. However, many non-radioactive atoms could be made to emit electrons. In 1899, Thomson demonstrated that certain completely normal metals with no signs of radioactivity would emit electrons when exposed to ultraviolet light. (This is known as the “photoelectric effect.”)

It was possible to suppose, then, that the main structure of the atom was positively charged and generally immovable, and that there were also present light electrons, which could easily be detached. Thomson had suggested, as early as 1898, that the atom was a ball of matter carrying a positive charge and that individual electrons were stuck throughout its substance, like raisins in pound cake.

It was reasonable to think that the main structure of the atom was positively charged and mostly stable, with light electrons that could be easily removed. Thomson had proposed as early as 1898 that the atom was like a ball of matter with a positive charge, and that individual electrons were scattered throughout it, similar to raisins in a pound cake.

If something like the Thomson view were correct then the number of electrons, each with one unit of negative electricity, would depend on the total size of the positive charge carried by the atom. If the charge were +5, there would have to be 5 electrons present to balance that. The total charge would then be 0 and the atom as a whole would be electrically neutral.

If the Thomson view were accurate, then the number of electrons, each carrying one unit of negative electricity, would depend on the total amount of positive charge in the atom. If the charge were +5, there would need to be 5 electrons to balance that out. The total charge would then be 0, meaning the atom as a whole would be electrically neutral.

26

If, in such a case, an electron were removed, the atomic charge of +5 would be balanced by only 4 electrons with a total charge of -4. In that case, the net charge of the atom as a whole would be +1. On the other hand, if an extra electron were forced onto the atom, the charge of +5 would be balanced by 6 electrons with a total charge of -6, and the net charge of the atom as a whole would be -1.

If an electron were removed in this situation, the atomic charge of +5 would only be balanced by 4 electrons, which have a total charge of -4. This means the net charge of the atom would be +1. Conversely, if an extra electron were added to the atom, the charge of +5 would be balanced by 6 electrons with a total charge of -6, resulting in a net charge of -1 for the atom.

Such electrically charged atoms were called “ions” and their existence had been suspected since Faraday’s day. Faraday had known that atoms had to travel through a solution under the influence of an electric field to account for the way in which metals and gases appeared at the cathode and anode. It was he who first used the term, ion, from a Greek word meaning “traveller”. The word had been suggested to him by the English scholar, William Whewell (1794-1866). In 1884 the Swedish chemist Svante August Arrhenius (1859-1927) had first worked out a detailed theory based on the suggestion that these ions were atoms or groups of atoms that carried an electric charge.

Such electrically charged atoms are called “ions,” and their existence had been suspected since Faraday's time. Faraday understood that atoms had to move through a solution under the influence of an electric field to explain how metals and gases appeared at the cathode and anode. He was the first to use the term "ion," derived from a Greek word meaning “traveller.” The word was suggested to him by the English scholar William Whewell (1794-1866). In 1884, the Swedish chemist Svante August Arrhenius (1859-1927) developed a detailed theory based on the idea that these ions were atoms or groups of atoms that carried an electric charge.

Svante A. Arrhenius

Svante Arrhenius

By the close of the 19th century, then, Arrhenius’s suggestion seemed correct. There were positive ions made up of atoms or groups of atoms, from which one or more of the electrons within the atoms had been removed. There were negative ions made up of single atoms or of groups of atoms, to which one or more extra electrons had been added.

By the end of the 19th century, Arrhenius’s suggestion appeared to be accurate. There were positive ions formed from atoms or groups of atoms, from which one or more electrons had been taken away. There were negative ions consisting of single atoms or groups of atoms, to which one or more extra electrons had been added.

27

Although Thomson’s model of the atom explained the existence of ions and the fact that atoms could give off electrons or absorb them, it was not satisfactory in all ways. Further investigations yielded results not compatible with the raisins-in-the-pound-cake notion.

Although Thomson’s model of the atom explained the existence of ions and how atoms could emit or absorb electrons, it wasn’t entirely satisfying. Further research produced results that didn’t align with the raisins-in-the-pound-cake idea.

In 1906 Rutherford began to study what happened when massive subatomic particles, such as alpha particles, passed through matter. When alpha particles passed through a thin film of gold, for instance, they raced through, for the most part, as though nothing were there. The alpha particles seemed to push the light electrons aside and to act as though the positively charged main body of the atom that Thomson had pictured was not solid, but was soft and spongy.

In 1906, Rutherford started investigating what occurred when large subatomic particles, like alpha particles, moved through matter. For example, when alpha particles went through a thin layer of gold, they mostly zipped through as if there was nothing there. The alpha particles appeared to push the light electrons aside and seemed to suggest that the positively charged core of the atom that Thomson had described was not solid but rather soft and sponge-like.

The only trouble was that every once in a while an alpha particle seemed to strike something in the gold film and bounce to one side. Sometimes it even bounced directly backward. It was as though somewhere in each atom there was something at least as massive as the alpha particle.

The only problem was that every now and then an alpha particle appeared to hit something in the gold film and bounce off to the side. Sometimes it even bounced straight back. It was as if there was something in each atom that was at least as massive as the alpha particle.

How large was this massive portion of the atom? It couldn’t be very large for if it were the alpha particles would hit it frequently. Instead, the alpha particles made very few hits. This meant the massive portion was very small and that most alpha particles tore through the atom without coming anywhere near it.

How big was this massive part of the atom? It couldn't be too big, because if it were, the alpha particles would collide with it often. Instead, the alpha particles hit it very rarely. This indicated that the massive part was quite small and that most alpha particles passed through the atom without coming close to it.

28

Rutherford’s alpha particle bombardment apparatus. A piece of radium in the lead box (B) emits alpha particles that go through the gold foil (F). These particles are scattered at different angles onto the fluorescent screen (S), where the flashes caused by each impact are seen through the microscope (M). Below, alpha particles are shown bouncing off a nucleus in the gold foil.

Rutherford’s alpha particle bombardment setup. A piece of radium in the lead box (B) emits alpha particles that pass through the gold foil (F). These particles get scattered at different angles onto the fluorescent screen (S), where the flashes from each impact can be seen through the microscope (M). Below, alpha particles are shown bouncing off a nucleus in the gold foil.

29

By 1911 Rutherford announced his results to the world. He suggested that just about all the mass of the atom was concentrated into a very tiny, positively charged “nucleus” at its center. The diameter of the nucleus was only about 1/10,000 the diameter of the atom. All the rest of the atom was filled with the very light electrons.

By 1911, Rutherford shared his findings with the world. He proposed that almost all of the atom's mass was concentrated in a tiny, positively charged "nucleus" at its center. The nucleus's diameter was just about 1/10,000 of the atom's diameter. The rest of the atom was occupied by very light electrons.

Hans Geiger (left) and Ernest Rutherford at Manchester University about 1910.

Hans Geiger (left) and Ernest Rutherford at Manchester University around 1910.

According to Rutherford’s notion, the atom consisted of a single tiny positively charged lead shot at the center of a foam of electrons. It was Thomson’s notion in reverse. Still, the nucleus carried a positive charge of a particular size and was balanced by negatively charged electrons. Rutherford’s 30 model of the atom explained the existence of ions just as easily as Thomson’s did and it explained more besides.

According to Rutherford's idea, the atom was made up of a tiny, positively charged core at the center, surrounded by a cloud of electrons. This was the opposite of Thomson's idea. The nucleus had a specific positive charge and was balanced by negatively charged electrons. Rutherford’s 30 model of the atom explained the existence of ions just as well as Thomson's did, and it offered even more insights.

For instance, if all the electrons are removed so that only the nucleus remains, this nucleus is as massive as an atom but is so tiny in size that it can penetrate matter. The alpha particle would be a bare atomic nucleus from this point of view.

For example, if all the electrons are taken away and only the nucleus is left, this nucleus has the same mass as an atom but is so small that it can pass through matter. From this perspective, the alpha particle would just be a bare atomic nucleus.

Rutherford’s model of the “nuclear atom” is still accepted today.

Rutherford's model of the "nuclear atom" is still accepted today.

Atomic Numbers

Since the atom consisted of a positively charged nucleus at the center, and a number of negatively charged electrons outside, the next step was to find the exact size of the nuclear charge and the exact number of electrons for the different varieties of atoms.

Since the atom had a positively charged nucleus in the center and a number of negatively charged electrons surrounding it, the next step was to determine the precise size of the nuclear charge and the exact number of electrons for the different types of atoms.

The answer came through a line of research that began with the English physicist Charles Glover Barkla (1877-1944). In 1911 he noted that when X rays passed through atoms, some were absorbed and some bounced back. Those that bounced back had a certain ability to penetrate other matter. When the X rays struck atoms of high atomic weight, the X rays that bounced back were particularly penetrating. In fact, each different type of atom seemed associated with reflected X rays of a particular penetrating power, so Barkla called these “characteristic X rays”.

The answer came from a line of research that started with the English physicist Charles Glover Barkla (1877-1944). In 1911, he observed that when X-rays passed through atoms, some were absorbed while others bounced back. The ones that bounced back had a specific ability to penetrate other materials. When the X-rays hit atoms with a high atomic weight, the X-rays that reflected were especially penetrating. In fact, each type of atom appeared to be linked to reflected X-rays with a distinct penetrating power, so Barkla named these “characteristic X-rays.”

In 1913 another English physicist, Henry Gwyn-Jeffreys Moseley (1887-1915), went into the matter more thoroughly. He measured the exact wavelength of the characteristic X rays by reflecting them from certain crystals. In crystals, atoms are arranged in regular order and at known distances from each other. X rays reflecting from (or more accurately, diffracting from) crystals are bent out of their path by the rows of atoms. The longer their waves, the more they are bent. From the degree of bending the wavelength of the waves can be determined.

In 1913, another English physicist, Henry Gwyn-Jeffreys Moseley (1887-1915), explored this topic in greater depth. He measured the precise wavelength of characteristic X-rays by reflecting them off specific crystals. In crystals, atoms are organized in a regular pattern and at known distances from one another. X-rays reflecting from (or more accurately, diffracting from) crystals are redirected from their original path by the rows of atoms. The longer the waves, the more they are bent. By measuring the degree of bending, the wavelength of the waves can be determined.

31

Charles Glover Barkla

Henry Gwyn-Jeffreys Moseley

Henry Gwyn-Jeffreys Moseley

32

Moseley found that the greater the atomic weight of an atom, the shorter the waves of the characteristic X rays associated with it and the more penetrating those X rays were. There was such a close connection, in fact, that Moseley could arrange the elements in order according to the wavelength of the characteristic X rays.

Moseley discovered that the higher the atomic weight of an atom, the shorter the wavelengths of the characteristic X-rays related to it, and the more penetrating those X-rays became. The connection was so strong that Moseley could organize the elements based on the wavelength of their characteristic X-rays.

For some 40 years prior to this, the elements had been listed in order of atomic weight. This was useful especially since the Russian chemist Dmitri I. Mendeléev (1834-1907) had arranged them in a “periodic table” based on the atomic weight order in such a way that elements of similar properties were grouped together. The elements in this table were sometimes numbered consecutively (“atomic number”) but this was inconvenient since, when new elements were discovered, the list of atomic numbers might have to be reorganized.

For about 40 years before this, the elements were listed by their atomic weight. This was helpful, especially because the Russian chemist Dmitri I. Mendeléev (1834-1907) had created a “periodic table” that organized them according to atomic weight, grouping elements with similar properties together. The elements in this table were sometimes numbered consecutively (“atomic number”), but this was inconvenient because, when new elements were discovered, the list of atomic numbers might need to be rearranged.

Dmitri Mendeléev and Bohuslav Brauner in Prague in 1900. Brauner was a professor of chemistry at the Bohemian University in Prague.

Dmitri Mendeléev and Bohuslav Brauner in Prague in 1900. Brauner was a chemistry professor at the Bohemian University in Prague.

33

The Danish physicist Niels Bohr (1885-1962) had just advanced a theory of atomic structure that made it reasonable to suppose that the wavelength of the characteristic X rays depended on the size of the nuclear charge of the atoms making up a particular element. Moseley therefore suggested that these X rays be used to determine the size of the positive charge on its nucleus. The atomic number could then be set equal to that charge and be made independent of new discoveries of elements.

The Danish physicist Niels Bohr (1885-1962) had just proposed a theory of atomic structure that made it logical to think that the wavelength of the characteristic X-rays depended on the size of the nuclear charge of the atoms in a specific element. Moseley then suggested using these X-rays to find out the size of the positive charge on its nucleus. This would allow the atomic number to be defined as equal to that charge, making it independent of any new discoveries of elements.

Hydrogen, for instance, has an atomic number of 1. Its nucleus carries a unit positive charge, +1, and the hydrogen atom possesses 1 electron to balance this. Helium, with an atomic number of 2, has a nuclear charge of +2 and 2 electrons, with a total charge of -2, to balance it. (The alpha particle released by radioactive atoms is identical with a helium nucleus.)

Hydrogen, for example, has an atomic number of 1. Its nucleus has a positive charge of +1, and the hydrogen atom has 1 electron to balance it out. Helium, which has an atomic number of 2, has a nuclear charge of +2 and 2 electrons, with a total charge of -2, to balance it. (The alpha particle released by radioactive atoms is the same as a helium nucleus.)

The atomic number increases as one goes up the line of atoms. Oxygen atoms, for instance, have an atomic number of 8 and iron atoms have one of 26. At the upper end, thorium is 90 and uranium is 92. Each uranium atom has a nucleus bearing a charge of +92 and contains 92 electrons to balance this.

The atomic number increases as you move up the list of atoms. For example, oxygen atoms have an atomic number of 8, while iron atoms have an atomic number of 26. At the top end, thorium has an atomic number of 90 and uranium has 92. Each uranium atom has a nucleus with a charge of +92 and contains 92 electrons to maintain balance.

Once the notion of the atomic number was worked out, it became possible to tell for certain whether any elements remained as yet undiscovered and, if so, where in the list they might be.

Once the idea of atomic number was figured out, it became possible to determine for sure whether any elements were still undiscovered and, if so, where they might fit in the list.

Thus, when Moseley first presented scientists with the atomic number it turned out that there were still 7 elements that were not discovered. At least elements with atomic numbers of 43, 61, 72, 75, 85, 87, and 91 were still not known. By 1945, all seven had been discovered.

Thus, when Moseley first introduced scientists to the atomic number, it became clear that there were still 7 elements that had not been discovered. Specifically, the elements with atomic numbers 43, 61, 72, 75, 85, 87, and 91 were still unknown. By 1945, all seven had been discovered.

It quickly turned out that the atomic number was more fundamental and more characteristic of a particular element than was the atomic weight.

It soon became clear that the atomic number was more essential and more defining of a specific element than the atomic weight.

34

Niels Bohr

Niels Bohr

Bohr’s study.

Bohr's research.

35

Since Dalton’s time it had been assumed that all the atoms of a particular element were of equal atomic weight and that atoms of two different elements were always of different atomic weight. The first inkling and the first proof that this might not be so came through the study of radioactivity.

Since Dalton’s time, it had been believed that all the atoms of a specific element had the same atomic weight and that atoms of two different elements always had different atomic weights. The first hint and the first evidence that this might not be true came from the study of radioactivity.

showing Helium atom, Hydrogen atom; Nucleus, Proton, Neutron, Electron labelled

Isotopes

In 1902 Rutherford and his co-worker Frederick Soddy (1877-1956) showed that when uranium atoms gave off alpha particles, a new kind of atom was formed that was not uranium at all. It was this new atom that was eventually found to give off a beta particle, and then another atom of still another element was formed. This work of Rutherford and Soddy began a line of investigation that by 1907 had shown that there was a whole radioactive chain of elements, each one breaking down to the next in line by giving off either an alpha particle or a beta particle, until finally a lead atom was formed that was not radioactive.

In 1902, Rutherford and his colleague Frederick Soddy (1877-1956) demonstrated that when uranium atoms emitted alpha particles, a new type of atom was created that wasn't uranium at all. This new atom was later found to emit a beta particle, leading to the formation of another atom of a different element. The research conducted by Rutherford and Soddy initiated a series of investigations that by 1907 had revealed an entire radioactive chain of elements, each breaking down into the next by releasing either an alpha particle or a beta particle, until a non-radioactive lead atom was formed.

36

Frederick Soddy

Frederick Soddy

37

There was, in short, a “radioactive series” beginning with uranium (atomic number 92) and ending with lead (atomic number 82). The same was true of thorium (atomic number 90), which began a series that also ended with lead. Still a third element, actinium (atomic number 89) was, at that time, the first known member of a series that also ended in lead.

There was, in short, a “radioactive series” starting with uranium (atomic number 92) and ending with lead (atomic number 82). The same was true for thorium (atomic number 90), which began a series that also ended with lead. A third element, actinium (atomic number 89), was at that time the first known member of a series that also ended in lead.

The various atoms formed in these three radioactive series were not all different in every way. When the uranium atom gives off an alpha particle, it forms an atom originally called “uranium X₁”. On close investigation, it turned out that this uranium X₁ had the chemical properties of thorium. Uranium X₁, had, however, radioactive properties different from ordinary thorium.

The different atoms created in these three radioactive series weren’t all completely unique. When the uranium atom emits an alpha particle, it becomes an atom originally named “uranium X₁.” Upon closer inspection, it was discovered that this uranium X₁ had the chemical properties of thorium. However, uranium X₁ had radioactive properties that were different from regular thorium.

Uranium X₁ broke down so rapidly, giving off beta particles as it did so, that half of any given quantity would have broken down in 24 days. Another way of saying this (which was introduced by Rutherford) was that the “half-life” of uranium X₁, is 24 days. Ordinary thorium, however, gives off alpha particles, not beta particles, and does so at such a slow rate, that its half-life is 14 billion years!

Uranium X₁ decayed so quickly, emitting beta particles in the process, that half of any amount would decay in 24 days. Another way to put this, which Rutherford introduced, is that the “half-life” of uranium X₁ is 24 days. In contrast, regular thorium emits alpha particles instead of beta particles and does so at such a slow rate that its half-life is 14 billion years!

Uranium X₁, and ordinary thorium were in the same place in the list of elements by chemical standards, and yet there was clearly something different about the two.

Uranium X₁ and regular thorium were listed together in the same spot on the periodic table, but it was obvious that there was something different about the two.

Here is another case. In 1913 the British chemist Alexander Fleck (1889- ) studied “radium B” and “radium D”, the names given to two different kinds of atoms in the uranium radioactive series. He also studied “thorium B” in the thorium radioactive series and “actinium B” in the actinium radioactive series. All four are chemically the same as ordinary lead; all four are in the same place in the list of elements. Yet each is different from the radioactive standpoint. Though all give off beta particles, radium B has a 38 half-life of 27 minutes, radium D one of 19 years, thorium B one of 11 hours, and actinium B one of 36 minutes.

Here is another case. In 1913, British chemist Alexander Fleck (1889-Sure! Please provide the text you'd like me to modernize. studied “radium B” and “radium D,” the names given to two different types of atoms in the uranium radioactive series. He also researched “thorium B” in the thorium radioactive series and “actinium B” in the actinium radioactive series. All four are chemically identical to ordinary lead; they all occupy the same spot on the periodic table. Yet each is different from a radioactive perspective. While all emit beta particles, radium B has a half-life of 27 minutes, radium D has one of 19 years, thorium B has one of 11 hours, and actinium B has one of 36 minutes.

In 1913 Soddy called atoms that were in the same place in the list of elements, but which had different radioactive properties, “isotopes”, from Greek words meaning “same place”.

In 1913, Soddy referred to atoms that occupied the same position on the periodic table but had different radioactive properties as “isotopes,” derived from Greek words meaning “same place.”

At first, it seemed that the only difference between isotopes might be in their radioactive properties and that only radioactive atoms were involved. Quickly that proved not to be so.

At first, it seemed that the only difference between isotopes might be their radioactive properties and that only radioactive atoms were involved. Quickly, that turned out not to be the case.

It proved that it was possible to have several forms of the same element that were all different even though none of them were radioactive. The uranium series, the thorium series, and the actinium series all ended in lead. In each case the lead formed was stable (not radioactive). Were the lead atoms identical in every case? Soddy had worked out the way in which atomic weights altered every time an alpha particle or a beta particle was given off by an atom. Working through the three radioactive series he decided that the lead atoms had different atomic weights in each case.

It was shown that it was possible to have multiple forms of the same element that were all different, even though none of them were radioactive. The uranium series, the thorium series, and the actinium series all ended in lead. In each case, the lead formed was stable (not radioactive). Were the lead atoms the same in each instance? Soddy figured out how atomic weights changed every time an alpha particle or a beta particle was emitted by an atom. By examining the three radioactive series, he concluded that the lead atoms had different atomic weights in each case.

The uranium series ought to end with lead atoms that had an atomic weight of 206. The thorium series ought to end in lead atoms with an atomic weight of 208 and the actinium series in lead atoms with an atomic weight of 207.

The uranium series should end with lead atoms that have an atomic weight of 206. The thorium series should end with lead atoms that have an atomic weight of 208, and the actinium series should end with lead atoms that have an atomic weight of 207.

If this were so, there would be 3 lead isotopes that would differ not in radioactive properties, but in atomic weight. The isotopes could be referred to as lead-206, lead-207, and lead-208. If we use the chemical symbol for lead (Pb), we could write the isotopes, ²⁰⁶Pb, ²⁰⁷Pb, and ²⁰⁸Pb. (We read the symbol ²⁰⁶Pb as lead-206.) Atomic weight measurements made in 1914 by Soddy and others supported that theory.

If this were the case, there would be 3 lead isotopes that would vary not in their radioactive properties but in their atomic weight. The isotopes could be called lead-206, lead-207, and lead-208. Using the chemical symbol for lead (Pb), we can write the isotopes as ²⁰⁶Pb, ²⁰⁷Pb, and ²⁰⁸Pb. (We read the symbol ²⁰⁶Pb as lead-206.) Atomic weight measurements taken in 1914 by Soddy and others backed up that theory.

All 3 lead isotopes had the same atomic number of 82. The atoms of all 3 isotopes had nuclei with an electric charge of +82 and all 3 had 82 electrons in the atom to balance that positive nuclear charge. The difference was in the mass of the nucleus only.

All 3 lead isotopes had the same atomic number of 82. The atoms of all 3 isotopes had nuclei with a +82 electric charge, and all 3 had 82 electrons in the atom to

39

Isotopes of two elements.

Isotopes of two elements.

40

But what of ordinary lead that existed in the rocks far removed from any radioactive substances and that had presumably been stable through all the history of earth? Its atomic weight was 207.2.

But what about the normal lead found in rocks that are far away from any radioactive materials and that has likely been stable throughout Earth's history? Its atomic weight was 207.2.

Was the stable lead that had no connection with radioactivity made up of atoms of still another isotope, one with a fractional atomic weight? Or could stable lead be made up of a mixture of isotopes, each of a different whole-number atomic weight and was the overall atomic weight a fraction only because it was an average?

Was the stable lead that had no connection with radioactivity made up of atoms of a different isotope, one with a fractional atomic weight? Or could stable lead be made up of a mixture of isotopes, each with a different whole-number atomic weight, and was the overall atomic weight a fraction just because it was an average?

It was at the moment difficult to tell in the case of lead, but an answer came in connection with another element, the rare gas neon (atomic symbol Ne), which has an atomic weight of 20.2.

It was hard to determine in the case of lead at that time, but an answer came up regarding another element, the rare gas neon (atomic symbol Ne), which has an atomic weight of 20.2.

Was that fractional atomic weight something that was possessed by all neon atoms without exception or was it the average of some lightweight atoms and some heavyweight ones? It would be a matter of crucial importance if isotopes of neon could be found, for neon had nothing to do with any of the radioactive series. If neon had isotopes then any element might have them.

Was that fractional atomic weight something that all neon atoms had in common, or was it just the average of some lighter atoms and some heavier ones? This would be really important if isotopes of neon could be discovered, since neon wasn't part of any radioactive series. If neon had isotopes, then any element could have them.

In 1912 Thomson was working on neon. He sent a stream of cathode-ray electrons through neon gas. The electrons smashed into the neon atoms and knocked an electron off some of them. That left a neon ion carrying a single positive charge—an ion that could be written Ne⁺.

In 1912, Thomson was studying neon. He sent a stream of cathode-ray electrons through neon gas. The electrons collided with the neon atoms and knocked an electron off some of them. This created a neon ion with a single positive charge—an ion that could be written as Ne⁺.

The neon ions move in the electric field as electrons do, but in the opposite direction since they have an opposite charge. In the combined presence of a magnet and of an electric field, the neon ions move in a curved path. If all the neon ions had the same mass, all would follow the same curve. If some were more massive than others, the more massive ones would curve less.

The neon ions move in the electric field like electrons, but in the opposite direction because they have an opposite charge. When both a magnet and an electric field are present, the neon ions follow a curved path. If all the neon ions had the same mass, they would all follow the same curve. If some were more massive than others, the heavier ones would curve less.

The neon ions ended on a photographic plate, which was darkened at the point of landing. There were two regions of 41 darkening, because there were neon ions of two different masses that curved in two different degrees and ended in two different places. Thomson showed, from the amount of curving, that there was a neon isotope with an atomic weight of 20 and one with an atomic weight of 22—²⁰Ne and ²²Ne.

The neon ions landed on a photographic plate, which darkened where they struck. There were two dark areas because the neon ions had two different masses, causing them to curve differently and land in different spots. Thomson demonstrated, based on the degree of curvature, that there was a neon isotope with an atomic weight of 20 and another with an atomic weight of 22—²⁰Ne and ²²Ne.

What’s more, from the intensity of darkening, it could be seen that ordinary neon was made up of atoms that were roughly 90% ²⁰Ne and 10% ²²Ne. The overall atomic weight of neon, 20.2, was the average atomic weight of these 2 isotopes.

What’s more, from the degree of darkening, it could be seen that regular neon was made up of atoms that were about 90% ²⁰Ne and 10% ²²Ne. The overall atomic weight of neon, 20.2, was the average atomic weight of these two isotopes.

Thomson’s instrument was the first one capable of separating isotopes and such instruments came to be called “mass spectrometers”. The first to use the name was the English physicist Francis William Aston (1877-1945), who built the first efficient instrument of this type in 1919.

Thomson's device was the first that could separate isotopes, and these devices became known as "mass spectrometers." The first person to use this name was the English physicist Francis William Aston (1877-1945), who created the first effective instrument of this kind in 1919.

He used it to study as many elements as he could. He and those who followed him located many isotopes and determined the frequency of their occurrence with considerable precision. It turned out, for instance, that neon is actually 90.9% ²⁰Ne, and 8.8% ²²Ne. Very small quantities of still a third isotope, ²¹Ne, are also present, making up 0.3%.

He used it to study as many elements as possible. He and those who followed him identified many isotopes and accurately measured their occurrence rates. For example, it turns out that neon is actually 90.9% ²⁰Ne and 8.8% ²²Ne. There are also very small amounts of a third isotope, ²¹Ne, which make up 0.3%.

As for ordinary lead in nonradioactive rocks, it is made up of 23.6% ²⁰⁶Pb, 22.6% ²⁰⁷Pb, and 52.3% ²⁰⁸Pb. There is still a fourth isotope, ²⁰⁴Pb, which makes up the remaining 1.5% and which is not the product of any radioactive series at all.

As for regular lead in non-radioactive rocks, it consists of 23.6% ²⁰⁶Pb, 22.6% ²⁰⁷Pb, and 52.3% ²⁰⁸Pb. There's also a fourth isotope, ²⁰⁴Pb, which accounts for the remaining 1.5% and isn't a result of any radioactive series.

The isotopes always have atomic weights that are close to, but not quite, whole numbers. Any atomic weight of an element that departs appreciably from an integer does so only because it is an average of different isotopes. For instance, the atomic weight of chlorine (chemical symbol Cl) is 35.5, but this is because it is made up of a mixture of 2 isotopes. About one quarter of chlorine’s atoms are ³⁷Cl and about three-quarters are ³⁵Cl.

The isotopes always have atomic weights that are close to, but not quite, whole numbers. Any atomic weight of an element that deviates significantly from an integer does so only because it’s an average of different isotopes. For example, the atomic weight of chlorine (chemical symbol Cl) is 35.5, but this is because it consists of a mixture of 2 isotopes. About one quarter of chlorine’s atoms are ³⁷Cl and about three-quarters are ³⁵Cl.

42

Francis W. Aston

Francis W. Aston

43

Mass spectrograph as used by Thomson and Aston to measure the atomic weight of neon.

Mass spectrometer used by Thomson and Aston to measure the atomic weight of neon.

To avoid confusion, the average mass of the isotopes that make up a particular element is still called the atomic weight of that element. The integer closest to the mass of the individual isotope is spoken of as the “mass number” of that isotope. Thus, chlorine is made up of isotopes with mass numbers 35 and 37, but the atomic weight of chlorine as it is found in nature is 35.5 (or, to be more accurate, 35.453).

To avoid confusion, the average mass of the isotopes that make up a specific element is still referred to as the atomic weight of that element. The whole number closest to the mass of an individual isotope is referred to as the "mass number" of that isotope. Therefore, chlorine consists of isotopes with mass numbers 35 and 37, but the atomic weight of chlorine as it occurs in nature is 35.5 (or, to be more precise, 35.453).

In the same way, ordinary lead is made up of isotopes with mass numbers 204, 206, 207, and 208, and its atomic weight is 207.19; neon is made up of isotopes with mass numbers 20, 21, and 22, and its atomic weight is 20.183, and so on.

In the same way, regular lead consists of isotopes with mass numbers 204, 206, 207, and 208, and its atomic weight is 207.19; neon consists of isotopes with mass numbers 20, 21, and 22, and its atomic weight is 20.183, and so on.

If the atomic weight of some element happens to be very close to a whole number to begin with, it may consist of a single kind of atom. For instance, the gas fluorine (chemical symbol F) has an atomic weight of nearly 19, while that of the metal sodium (chemical symbol Na) is nearly 23. As it turns out, all the atoms of fluorine are of the single variety ¹⁹F, while all the atoms of sodium are ²³Na.

If the atomic weight of an element is very close to a whole number, it might be made up of just one type of atom. For example, the gas fluorine (chemical symbol F) has an atomic weight of about 19, while the metal sodium (chemical symbol Na) has an atomic weight of about 23. In fact, all fluorine atoms are of the single type ¹⁹F, and all sodium atoms are ²³Na.

44

Sometimes the atomic weight of an element, as it occurs in nature, is nearly a whole number and yet it is made up of more than 1 isotope. In that case, one of the isotopes makes up very nearly all of it, while the others are present in such minor quantities that the average is hardly affected.

Sometimes the atomic weight of an element, as it appears in nature, is close to a whole number, even though it consists of more than one isotope. In this situation, one of the isotopes accounts for almost all of it, while the others are present in such small amounts that the average isn't significantly influenced.

Helium, for instance (atomic symbol He) has an atomic weight of just about 4 and, indeed, almost all the atoms making it up are ⁴He. However, 0.0001% of the atoms, or one out of a million, are ³He. Again, 99.6% of all the nitrogen atoms (atomic symbol N) are ¹⁴N, but 0.4% are ¹⁵N. Then, 98.9% of all carbon atoms (atomic symbol C) are ¹²C, but 1.1% are ¹³C. It is not surprising that the atomic weights of nitrogen and carbon are just about 14 and 12, respectively.

Helium, for example (atomic symbol He), has an atomic weight of about 4, and almost all the atoms that make it up are ⁴He. However, 0.0001% of the atoms, or one out of a million, are ³He. Similarly, 99.6% of all nitrogen atoms (atomic symbol N) are ¹⁴N, but 0.4% are ¹⁵N. Then, 98.9% of all carbon atoms (atomic symbol C) are ¹²C, but 1.1% are ¹³C. It’s not surprising that the atomic weights of nitrogen and carbon are approximately 14 and 12, respectively.

Harold Urey

Harold Urey

Even hydrogen does not escape. Its atomic weight is just about 1 and most of its atoms are ¹H. The American chemist Harold Clayton Urey (1893- ) detected the existence of a 45 more massive isotope, ²H. This isotope has almost twice the mass of the lighter one. No other isotopes of a particular atom differ in mass by so large a factor. For that reason ²H and ¹H differ in ordinary chemical properties more than isotopes usually do and Urey therefore gave ²H the special name of “deuterium” from a Greek word meaning “second”.

Even hydrogen doesn't escape. Its atomic weight is about 1, and most of its atoms are ¹H. The American chemist Harold Clayton Urey (1893-) discovered the existence of a more massive isotope, ²H. This isotope has nearly twice the mass of the lighter one. No other isotopes of a specific atom vary in mass by such a large factor. Because of this, ²H and ¹H have more distinct ordinary chemical properties than isotopes typically do, and Urey therefore gave ²H the special name “deuterium,” derived from a Greek word meaning “second.”

W. F. Giauque

W. F. Giauque

In 1929 the American chemist William Francis Giauque (1895- ) found that oxygen was composed of more than 1 isotope. Its atomic weight had been set arbitrarily at 16.0000 so it was a relief that 99.76% of its atoms were ¹⁶O. However, 0.20% were ¹⁸O, and 0.04% were ¹⁷O.

In 1929, American chemist William Francis Giauque (1895-) discovered that oxygen consists of more than one isotope. Its atomic weight had been set arbitrarily at 16.0000, so it was a relief to find that 99.76% of its atoms were ¹⁶O. However, 0.20% were ¹⁸O, and 0.04% were ¹⁷O.

As you see, ¹⁶O must have a mass number of slightly less than 16.0000 and it must be the more massive isotopes ¹⁷O and ¹⁸O that pull the average up to 16.0000. Disregarding this, chemists clung to a standard atomic weight of 16.000 for oxygen as it appeared in nature, preferring not to concern themselves with the separate isotopes.

As you can see, ¹⁶O has to have a mass number that's just under 16.0000, and it's the heavier isotopes ¹⁷O and ¹⁸O that raise the average to 16.0000. Even so, chemists stuck with a standard atomic weight of 16.000 for oxygen as it occurs in nature, choosing not to focus on the individual isotopes.

46

Physicists, however, felt uneasy at using an average as standard for they were more interested in working with individual isotopes. They preferred to set ¹⁶O at 16.0000 so that the average atomic weight of oxygen was 16.0044 and all other atomic weights rose in proportion. Atomic weights determined by this system were “physical atomic weights”.

Physicists, however, were uncomfortable using an average as a standard because they were more focused on working with individual isotopes. They preferred to set ¹⁶O at 16.0000 so that the average atomic weight of oxygen was 16.0044, and all other atomic weights increased proportionally. Atomic weights determined by this system were called “physical atomic weights.”

Finally, in 1961, a compromise was struck. Chemists and physicists alike decided to consider the atomic weight of ¹²C as exactly 12 and to use that as a standard. By this system, the atomic weight of oxygen became 15.9994, which is only very slightly less than 16.

Finally, in 1961, a compromise was reached. Chemists and physicists agreed to define the atomic weight of ¹²C as exactly 12 and use that as a standard. With this system, the atomic weight of oxygen became 15.9994, which is just slightly less than 16.

The radioactive elements did not escape this new view either. The atomic weight of uranium (chemical symbol U) is just about 238 and, indeed, most of its atoms are ²³⁸U. In 1935, however, the Canadian-American physicist, Arthur Jeffrey Dempster (1886-1950), found that 0.7% of its atoms were a lighter isotope, ²³⁵U.

The radioactive elements were also included in this new perspective. The atomic weight of uranium (chemical symbol U) is around 238, and most of its atoms are ²³⁸U. In 1935, however, Canadian-American physicist Arthur Jeffrey Dempster (1886-1950) discovered that 0.7% of its atoms were a lighter isotope, ²³⁵U.

These differed considerably in radioactive properties. The common uranium isotope, ²³⁸U, had a half-life of 4500 million years, while ²³⁵U had a half-life of only 700 million years. Furthermore ²³⁵U broke down in three stages to actinium. It was ²³⁵U, not actinium itself, that was the beginning of the actinium radioactive series.

These had significantly different radioactive properties. The common uranium isotope, ²³⁸U, had a half-life of 4,500 million years, while ²³⁵U had a half-life of only 700 million years. Additionally, ²³⁵U decayed in three stages to form actinium. It was ²³⁵U, not actinium itself, that marked the start of the actinium radioactive series.

As for thorium (atomic symbol Th) with an atomic weight of 232, it did indeed turn out that in the naturally occurring element virtually all the atoms were ²³²Th.

As for thorium (atomic symbol Th) with an atomic weight of 232, it turned out that in the naturally occurring element, almost all the atoms were ²³²Th.

47

ENERGY

The Law of Conservation of Energy

We have now gone as far as we conveniently can in considering the intertwining strands of the atom and of electricity. It is time to turn to the third strand—energy.

We have now gone as far as we can in looking at the interconnected aspects of atoms and electricity. It's time to focus on the third aspect—energy.

To physicists the concept of “work” is that of exerting a force on a body and making it move through some distance. To lift a weight against the pull of gravity is work. To drive a nail into wood against the friction of its fibers is work.

To physicists, the idea of "work" means applying a force to an object and causing it to move over a distance. Lifting a weight against gravity is considered work. Hammering a nail into wood, pushing against the friction of its fibers, is also work.

Anything capable of performing work is said to possess “energy” from Greek words meaning “work within”. There are various forms of energy. Any moving mass possesses energy by virtue of its motion. That is, a moving hammer will drive a nail into wood, while the same hammer held motionlessly against the nailhead will not do so. Heat is a form of energy, since it will expand steam that will force wheels into motion that can then do work. Electricity, magnetism, sound, and light can be made to perform work and are forms of energy.

Anything that can do work is said to have "energy," which comes from Greek words meaning "work within." There are different types of energy. Any object in motion has energy because of its movement. For example, a moving hammer can drive a nail into wood, but if the same hammer is held still against the nail, it won't do anything. Heat is also a form of energy, as it can expand steam to move wheels that do work. Electricity, magnetism, sound, and light can all be used to perform work, and they are types of energy.

The forms of energy are so many and so various that scientists were eager to find some rule that covered them all and would therefore serve as a unifying bond. It did not seem impossible that such a rule might exist, since one had been found in connection with matter that appeared in even greater variety than energy did.

The types of energy are so numerous and diverse that scientists were keen to discover a rule that encompassed them all and could serve as a unifying connection. It didn't seem unlikely that such a rule might exist, since one had been found regarding matter, which showed even greater variety than energy.

All matter, whatever its form and shape, possessed mass, and in the 1770s, the French chemist Antoine Laurent Lavoisier (1743-1794) discovered that the quantity of mass was constant. If a system of matter were isolated and made to undergo complicated chemical reactions, everything about it might change, but not its mass. A solid might turn into a gas; a single substance might change into two or three different substances, but whatever happened, the total mass at the end was exactly the same (as nearly as chemists could tell) as at the beginning. None was either created or destroyed, however, the nature of the matter might change. This was called the “law of conservation of mass”.

All matter, no matter its form or shape, has mass, and in the 1770s, the French chemist Antoine Laurent Lavoisier (1743-1794) found that the amount of mass was constant. If a system of matter was isolated and went through complex chemical reactions, everything about it could change, but not its mass. A solid could turn into a gas; a single substance could break down into two or three different substances, but no matter what happened, the total mass at the end was exactly the same (as closely as chemists could measure) as it was at the start. None was created or destroyed, regardless of how the matter itself changed. This was called the “law of conservation of mass.”

48

Lavoisier in his laboratory during his studies on respiration. From a sketch made by Madame Lavoisier.

Lavoisier in his lab while researching respiration. From a sketch by Madame Lavoisier.

49

Antoine Lavoisier and his wife.

Antoine Lavoisier and his spouse.

50

Naturally, it would occur to scientists to wonder if a similar law might hold for energy. The answer wasn’t easy to get. It wasn’t as simple to measure the quantity of energy as it was to measure the quantity of mass. Nor was it as simple to pen up a quantity of energy and keep it from escaping or from gaining additional quantity from outside, as it was in the case of mass.

Naturally, scientists would wonder if a similar rule applied to energy. Getting an answer wasn’t easy. Measuring the amount of energy was not as straightforward as measuring the amount of mass. It was also more complicated to contain a quantity of energy and prevent it from escaping or gaining extra energy from outside, unlike with mass.

Beginning in 1840, however, the English physicist James Prescott Joule (1818-1889) began a series of experiments in which he made use of every form of energy he could think of. In each case he turned it into heat and allowed the heat to raise the temperature of a given quantity of water. He used the rise in temperature as a measure of the energy. By 1847 he was convinced that any form of energy could be turned into fixed and predictable amounts of heat; that a certain amount of work was equivalent to a certain amount of heat.

Beginning in 1840, the English physicist James Prescott Joule (1818-1889) started a series of experiments using every type of energy he could think of. In each case, he converted it into heat and let the heat increase the temperature of a specific amount of water. He used the temperature rise as a measure of energy. By 1847, he was convinced that any type of energy could be transformed into fixed and predictable amounts of heat; that a certain amount of work was equal to a specific amount of heat.

In that same year, the German physicist Hermann Ludwig Ferdinand von Helmholtz (1821-1894) advanced the general notion that a fixed amount of energy in one form was equal to the same amount of energy in any other form. Energy might change its form over and over, but not change its amount. None could either be destroyed or created. This is the “law of conservation of energy”.

In that same year, the German physicist Hermann Ludwig Ferdinand von Helmholtz (1821-1894) proposed the general idea that a specific amount of energy in one form is equal to the same amount of energy in any other form. Energy can change its form repeatedly, but the total amount doesn’t change. It can neither be created nor destroyed. This is known as the “law of conservation of energy.”

Chemical Energy

There is energy in a piece of wood. Left quietly to itself, it seems completely incapable of bringing about any kind of work. Set it on fire, however, and the wood plus the oxygen in the air will give off heat and light that are clearly forms of energy. The heat could help boil water and run a steam engine.

There’s energy in a piece of wood. If you just leave it alone, it looks like it can’t do anything at all. But if you set it on fire, the wood and the oxygen in the air produce heat and light, which are clear forms of energy. The heat could boil water and power a steam engine.

51

The amount of energy in burning wood could be measured if it were mixed with air and allowed to burn in a closed container that was immersed in a known quantity of water. From the rise in temperature of the water, the quantity of energy produced could be measured in units called “calories” (from a Latin word for “heat”). The instrument was therefore called a “calorimeter”.

The energy released from burning wood can be measured by mixing it with air and letting it burn in a closed container submerged in a known amount of water. By measuring the increase in the water's temperature, we can calculate the energy produced in units known as "calories" (which comes from the Latin word for "heat"). This device is called a "calorimeter."

In the 1860s the French chemist Pierre Eugène Marcelin Berthelot (1827-1907) carried through hundreds of such determinations. His work and similar work by others made it clear that such “chemical energy”—the energy derived from chemical changes in matter—fit the law of conservation of energy.

In the 1860s, the French chemist Pierre Eugène Marcelin Berthelot (1827-1907) conducted hundreds of these measurements. His research and similar studies by others showed that this "chemical energy"—the energy obtained from chemical changes in matter—followed the law of conservation of energy.

Here’s how it looked in the last decades of the 19th century.

Here’s how it looked in the late 1800s.

Molecules are composed of combinations of atoms. Within the molecules, the atoms stick together more or less tightly. It takes a certain amount of energy to pull a molecule apart into separate atoms against the resistance of the forces holding them together.

Molecules are made up of combinations of atoms. Inside the molecules, the atoms bond together more or less tightly. It requires a specific amount of energy to break a molecule apart into individual atoms, working against the forces that keep them together.

If, after being pulled apart, the atoms are allowed to come together again, they give off energy. The amount of energy they give off in coming together is exactly equal to the amount of energy they had to gain before they could separate.

If, after being pulled apart, the atoms are allowed to come back together, they release energy. The amount of energy they release when they come together is exactly equal to the amount of energy they had to absorb before they could separate.

This is true of all substances. For instance, hydrogen gas, as it is found on earth, is made up of molecules containing 2 hydrogen atoms each (H₂). Add a certain amount of energy and you pull the atoms apart; allow the atoms to come back together into paired molecules, and the added energy is given back again. The same is true for the oxygen molecule, which is made up of 2 oxygen atoms (O₂) and of the water molecule (H₂O). Always the amount of energy absorbed in one change is given off in the opposite change. The amount absorbed and the amount given off are always exactly equal.

This applies to all substances. For example, hydrogen gas, as it exists on Earth, consists of molecules with 2 hydrogen atoms each (H₂). Add a certain amount of energy, and the atoms separate; when the atoms rejoin to form paired molecules, the energy that was added is released again. The same goes for the oxygen molecule, which is made up of 2 oxygen atoms (O₂), and for the water molecule (H₂O). The energy absorbed in one process is always released in the reverse process. The energy absorbed and the energy released are always perfectly equal.

52

However, the amount of energy involved differs from molecule to molecule. It is quite hard to pull hydrogen molecules apart, and it is even harder to pull oxygen molecules apart. You have to supply about 12% more energy to pull an oxygen molecule apart than to pull a hydrogen molecule apart. Naturally, if you let 2 oxygen atoms come together to form an oxygen molecule, you get back 12% more energy than if you allow 2 hydrogen atoms to come together to form a hydrogen molecule.

However, the amount of energy involved varies from molecule to molecule. It's quite difficult to separate hydrogen molecules, and it's even tougher to separate oxygen molecules. You need to provide about 12% more energy to break apart an oxygen molecule than to break apart a hydrogen molecule. Naturally, if you let 2 oxygen atoms combine to form an oxygen molecule, you get back 12% more energy than if you let 2 hydrogen atoms combine to form a hydrogen molecule.

It takes a considerably larger amount of energy to pull apart a water molecule into separate atoms than to pull apart either hydrogen or oxygen molecules. Naturally, that greater energy is also returned once the hydrogen and oxygen atoms are allowed to come back together into water molecules.

It requires a significantly larger amount of energy to separate a water molecule into individual atoms than to separate either hydrogen or oxygen molecules. Naturally, that extra energy is also released when the hydrogen and oxygen atoms are allowed to recombine into water molecules.

Next, imagine pulling apart hydrogen and oxygen molecules into hydrogen and oxygen atoms and then having those atoms come together to form water molecules. A certain amount of energy is put into the system to break up the hydrogen and oxygen molecules, but then a much greater amount of energy is given off when the water molecules form.

Next, picture separating hydrogen and oxygen molecules into hydrogen and oxygen atoms, and then having those atoms combine to create water molecules. Some energy is added to the system to split the hydrogen and oxygen molecules, but then a much larger amount of energy is released when the water molecules form.

It is for that reason that a great deal of energy (mostly in the form of heat) is given off if a jet of hydrogen gas and a jet of oxygen gas are allowed to mix in such a way as to form water.

It is for that reason that a lot of energy (mostly as heat) is released when a jet of hydrogen gas and a jet of oxygen gas mix together to form water.

Just mixing the hydrogen and oxygen isn’t enough. The molecules of hydrogen and oxygen must be separated and that takes a little energy. The energy in a match flame is enough to raise the temperature of the mixture and to make the hydrogen and oxygen molecules move about more rapidly and more energetically. This increases the chance that some molecules will be broken up into separate atoms (though the actual process is rather complicated). An oxygen atom might then strike a hydrogen molecule to form water (O + H₂ → H₂O) and more energy is given off than was 53 absorbed from the match flame. The temperature goes up still higher so that further breakup among the oxygen and hydrogen molecules is encouraged.

Just mixing hydrogen and oxygen isn’t enough. The molecules of hydrogen and oxygen need to be separated, and that requires some energy. The energy from a match flame is enough to heat up the mixture, causing the hydrogen and oxygen molecules to move around more quickly and energetically. This increases the chances of some molecules breaking apart into individual atoms (though the actual process is quite complex). An oxygen atom might then collide with a hydrogen molecule to form water (O + H₂ → H₂O), releasing more energy than what was absorbed from the match flame. The temperature rises even more, which encourages further breakup among the oxygen and hydrogen molecules.

The formation of a sodium chloride molecule.

The creation of a sodium chloride molecule.

This happens over and over again so that in very little time, the temperature is very high and the hydrogen and oxygen are combining to form water at an enormous rate. If a great deal of hydrogen and oxygen are well-mixed to begin with, the rate of reaction is so great that an explosion occurs.

This keeps happening repeatedly, so in no time at all, the temperature rises significantly, and hydrogen and oxygen are combining to create water at a huge rate. If a lot of hydrogen and oxygen are mixed together well from the start, the reaction rate is so high that an explosion takes place.

Such a situation, in which each reacting bit of the system adds energy to the system by its reaction and brings about more reactions like itself, is called a “chain reaction”. Thus, a match flame put to one corner of a large sheet of paper will set that corner burning. The heat of the burning will ignite a 54 neighboring portion of the sheet and so on till the entire sheet is burned. For that matter a single smoldering cigarette end can serve to burn down an entire forest in a vastly destructive chain reaction.

Such a situation, where each part of the system contributes energy through its reaction and triggers more reactions like itself, is known as a “chain reaction.” For example, if you light one corner of a large sheet of paper with a match, that corner will catch fire. The heat from the burning corner will ignite a nearby section of the paper and continue spreading until the whole sheet is burned. In fact, just one smoldering cigarette butt can ignite an entire forest in a highly destructive chain reaction.

Electrons and Energy

The discovery of the structure of the atom sharpened the understanding of chemical energy.

The discovery of the atom's structure enhanced the understanding of chemical energy.

In 1904 the German chemist Richard Abegg (1869-1910) first suggested that atoms were held together through the transfer of electrons from one atom to another.

In 1904, the German chemist Richard Abegg (1869-1910) was the first to suggest that atoms are held together by the transfer of electrons from one atom to another.

To see how this worked, one began by noting that electrons in an atom existed in a series of shells. The innermost shell could hold only 2 electrons, the next 8, the next 18 and so on. It turned out that some electron arrangements were more stable than others. If only the innermost shell contained electrons and it were filled with the 2 electrons that were all it could hold, then that was a stable arrangement. If an atom contained electrons in more than one shell and the outermost shell that held electrons held 8, that was a stable arrangement, too.

To understand how this worked, you started by noticing that electrons in an atom were arranged in layers. The innermost layer could hold only 2 electrons, the next one could hold 8, then 18, and so on. It turned out that some electron arrangements were more stable than others. If only the innermost layer had electrons and was filled with its maximum of 2 electrons, that was a stable arrangement. If an atom had electrons in multiple layers and the outermost layer that had electrons contained 8, that was also a stable arrangement.

Thus, the helium atom has 2 electrons only, filling the innermost shell, and that is so stable an arrangement that helium undergoes no chemical reactions at all. The neon atom has 10 electrons—2 in the innermost shell, and 8 in the next—and it does not react. The argon atom has 18 electrons—2, 8, and 8—and it too is very stable.

Thus, the helium atom has only 2 electrons, filling the innermost shell, and this arrangement is so stable that helium doesn’t participate in any chemical reactions. The neon atom has 10 electrons—2 in the innermost shell and 8 in the next one—and it also doesn’t react. The argon atom has 18 electrons—2, 8, and 8—and it is also very stable.

But what if an atom did not have its electron shell so neatly filled. The sodium atom has 11 electrons—2, 8, and 1—while the fluorine atom has 9 electrons—2 and 7. If the sodium atom passed one of its electrons to a fluorine atom, both would have the stable configuration of neon—2 and 8. This, therefore, ought to have a great tendency to happen.

But what if an atom didn't have its electron shell so neatly filled? The sodium atom has 11 electrons—2, 8, and 1—while the fluorine atom has 9 electrons—2 and 7. If the sodium atom gives one of its electrons to a fluorine atom, both would achieve the stable configuration of neon—2 and 8. So, this is likely to happen.

If it did happen, though, the sodium atom, minus 1 electron, would have a unit positive charge and would be Na⁺, 55 a positively charged ion. Fluorine with 1 electron in excess would become F⁻, a negatively charged ion. The 2 ions, with opposite charges, would cling together, since opposite charges attract, and thus the molecule of sodium fluoride (NaF) would be formed.

If it did happen, though, the sodium atom, missing 1 electron, would have a positive charge and would be Na⁺, 55 a positively charged ion. Fluorine with 1 extra electron would become F⁻, a negatively charged ion. The 2 ions, with opposite charges, would stick together because opposite charges attract, and so the molecule of sodium fluoride (NaF) would be formed.

In 1916 the American chemist Gilbert Newton Lewis (1875-1946) carried this notion farther. Atoms could cling together not only as a result of the outright transfer of 1 or more electrons, but through sharing pairs of electrons. This sharing could only take place if the atoms remained close neighbors, and it would take energy to pull them apart and break up the shared pool, just as it would take energy to pull 2 ions apart against the attraction of opposite charges.

In 1916, American chemist Gilbert Newton Lewis (1875-1946) took this idea further. Atoms could bond not just by completely transferring one or more electrons, but also by sharing pairs of electrons. This sharing could only happen if the atoms stayed close to each other, and it would require energy to separate them and break the shared electrons, just like it would need energy to pull two ions apart against the attraction of their opposite charges.

In this way the vague notions of atoms clinging together in molecules and being forced apart gave way to a much more precise picture of electrons being transferred or shared. The electron shifts could be dealt with mathematically by a system that came to be called “quantum mechanics” and chemistry was thus made a more exact science than it had ever been before.

In this way, the unclear ideas of atoms sticking together in molecules and being pulled apart were replaced by a much clearer understanding of electrons being transferred or shared. The movement of electrons could be explained mathematically through a system that became known as "quantum mechanics," making chemistry a more precise science than it had ever been before.

The Energy of the Sun

The most serious problem raised by the law of conservation of energy involved the sun. Until 1847, scientists did not question sunlight. The sun radiated vast quantities of energy but that apparently was its nature and was no more to be puzzled over than the fact that the earth rotated on its axis.

The biggest issue brought up by the law of conservation of energy was related to the sun. Until 1847, scientists didn’t really question sunlight. The sun emitted massive amounts of energy, and that seemed to be just part of its nature, just as unremarkable as the fact that the earth spins on its axis.

Once Helmholtz had stated that energy could neither be created nor destroyed, however, he was bound to ask where the sun’s energy came from. It had, to man’s best knowledge, been radiating heat and light, with no perceptible change, throughout the history of civilization and, from what biologists and geologists could deduce, for countless ages earlier. Where, then, did that energy come from?

Once Helmholtz declared that energy could neither be created nor destroyed, he had to question where the sun’s energy originated. It had, according to humanity's best understanding, been emitting heat and light without any noticeable change throughout the history of civilization and, based on what biologists and geologists could infer, for countless ages before that. So, where did that energy come from?

56

The sun gave the appearance of being a huge globe of fire. Could it actually be that—a large heap of burning fuel, turning chemical energy into heat and light?

The sun looked like a massive ball of fire. Could it really be that—a giant pile of burning fuel, converting chemical energy into heat and light?

The sun’s mass was known and its rate of energy production was known. Suppose the sun’s mass were a mixture of hydrogen and oxygen and it were burning at a rate sufficient to produce the energy at the rate it was giving it off. If that were so, all the hydrogen and oxygen in its mass would be consumed in 1500 years. No chemical reaction in the sun could account for its having given us heat and light since the days of the pyramids, let alone since the days of the dinosaurs.

The sun’s mass was understood, and its energy production rate was known. Imagine if the sun’s mass were made up of hydrogen and oxygen and it was burning at a rate that produced energy equal to what it emitted. If that were the case, all the hydrogen and oxygen in it would be used up in 1500 years. No chemical reaction in the sun could explain how it has provided us with heat and light since the days of the pyramids, not to mention since the time of the dinosaurs.

Was there some source of energy greater than chemical energy? What about the energy of motion? Helmholtz suggested that meteors might be falling into the sun at a steady rate. The energy of their collisions might then be converted into heat and light and this could keep the sun shining for as long as the supply of meteors held out—even millions of years.

Was there a source of energy greater than chemical energy? What about kinetic energy? Helmholtz proposed that meteors could be falling into the sun at a consistent rate. The energy from their collisions could then be transformed into heat and light, potentially allowing the sun to shine for as long as there was a supply of meteors—even for millions of years.

This, however, would mean that the sun’s mass would be increasing steadily, and so would the force of its gravitational pull. With the sun’s gravitational field increasing steadily, the length of earth’s year would be decreasing at a measurable rate—but it wasn’t.

This, however, would mean that the sun’s mass would be increasing steadily, and so would the force of its gravitational pull. With the sun’s gravitational field growing continuously, the length of Earth's year would be decreasing at a measurable rate—but it wasn’t.

In 1854 Helmholtz came up with something better. He suggested that the sun was contracting. Its outermost layers were falling inward, and the energy of this fall was converted into heat and light. What’s more, this energy would be obtained without any change in the mass of the sun whatever.

In 1854, Helmholtz proposed something better. He suggested that the sun was shrinking. Its outer layers were collapsing inward, and the energy from this collapse was transformed into heat and light. Additionally, this energy would be generated without any change in the sun's mass at all.

Helmholtz calculated that the sun’s contraction over the 6000 years of recorded history would have reduced its diameter only 560 miles—a change that would not have been noticeable to the unaided eye. Since the development of the telescope, two and a half centuries earlier, the decrease in 57 diameter would have been only 23 miles and that was not measurable by the best techniques of Helmholtz’s day.

Helmholtz calculated that the sun’s contraction over the 6,000 years of recorded history would have reduced its diameter by only 560 miles—a change that wouldn't have been noticeable to the naked eye. Since the invention of the telescope, two and a half centuries earlier, the decrease in diameter would have been just 23 miles, which wasn't measurable by the best techniques of Helmholtz’s time.

Working backward, however, it seemed that 25 million years ago, the sun must have been so large as to fill the earth’s orbit. Clearly the earth could not then have existed. In that case, the maximum age of the earth was only 25 million years.

Working backward, it appeared that 25 million years ago, the sun must have been so huge that it filled the earth’s orbit. Clearly, the earth couldn't have existed at that time. Therefore, the maximum age of the earth was only 25 million years.

Geologists and biologists found themselves disturbed by this. The slow changes in the earth’s crust and in the evolution of life made it seem very likely that the earth must have been in existence—with the sun delivering heat and light very much in the present fashion—for many hundreds of millions of years.

Geologists and biologists were unsettled by this. The gradual changes in the earth’s crust and the evolution of life suggested that the earth must have existed—with the sun providing heat and light much like it does today—for hundreds of millions of years.

Yet there seemed absolutely no other way of accounting for the sun’s energy supply. Either the law of conservation of energy was wrong (which seemed unlikely), or the painfully collected evidence of geologists and biologists was wrong (which seemed unlikely),—or there was some source of energy greater than any known in the 19th century, whose existence had somehow escaped mankind (which also seemed unlikely).

Yet there seemed to be no other way to explain the sun’s energy supply. Either the law of conservation of energy was incorrect (which seemed unlikely), or the meticulously gathered evidence from geologists and biologists was wrong (which also seemed unlikely),—or there was some source of energy greater than anything known in the 19th century, whose existence had somehow eluded humanity (which also seemed unlikely).

Yet one of those unlikely alternatives would have to be true. And then in 1896 came the discovery of radioactivity.

Yet one of those unexpected options had to be true. Then in 1896, the discovery of radioactivity happened.

The Energy of Radioactivity

It eventually became clear that radioactivity involved the giving off of energy. Uranium emitted gamma rays that we now know to be a hundred thousand times as energetic as ordinary light rays. What’s more, alpha particles were being emitted at velocities of perhaps 30,000 kilometers per second, while the lighter beta particles were being shot off at velocities of up to 250,000 kilometers per second (about 0.8 times the velocity of light).

It eventually became clear that radioactivity was about releasing energy. Uranium gave off gamma rays that we now know are a hundred thousand times more energetic than regular light rays. Additionally, alpha particles were emitted at speeds of around 30,000 kilometers per second, while the lighter beta particles were ejected at speeds of up to 250,000 kilometers per second (about 0.8 times the speed of light).

At first, the total energy given off by radioactive substances seemed so small that there was no use worrying 58 about it. The amount of energy liberated by a gram of uranium in 1 second of radioactivity was an insignificant fraction of the energy released by a burning candle.

At first, the total energy emitted by radioactive substances seemed so small that there was no point in worrying about it. The energy released by a gram of uranium in just one second of radioactivity was an inconsequential fraction of the energy produced by a burning candle.

In a few years, however, something became apparent. A lump of uranium might give off very little energy in a second, but it kept on for second after second, day after day, month after month, and year after year with no perceptible decrease. The energy released by the uranium over a very long time grew to be enormous. It eventually turned out that while the rate at which uranium delivered energy did decline, it did so with such unbelievable slowness that it took 4.5 billion years (!) for that rate to decrease to half what it was to begin with.

In a few years, however, it became clear that a lump of uranium might emit very little energy in a second, but it continued to do so second after second, day after day, month after month, and year after year with no noticeable decrease. The energy released by the uranium over a very long time accumulated to be enormous. It eventually turned out that while the rate at which uranium produced energy did decrease, it did so at such an incredibly slow pace that it took 4.5 billion years (!) for that rate to drop to half of what it originally was.

If all the energy delivered by a gram of uranium in the course of its radioactivity over many billions of years was totalled, it was enormously greater than the energy produced by the burning of a candle with a mass equal to that of uranium.

If all the energy from a gram of uranium during its radioactive decay over billions of years was added up, it would be far greater than the energy produced by burning a candle with the same mass as the uranium.

Let’s put it another way. We might think of a single uranium atom breaking down and shooting off an alpha particle. We might also think of a single carbon atom combining with 2 oxygen atoms to form carbon dioxide. The uranium atom would give off 2,000,000 times as much energy in breaking down, as the carbon atom would in combining.

Let’s rephrase that. We can picture a single uranium atom breaking apart and emitting an alpha particle. We can also imagine a single carbon atom bonding with 2 oxygen atoms to make carbon dioxide. The uranium atom releases 2,000,000 times more energy when it breaks down than the carbon atom does when it bonds.

The energy of radioactivity is millions of times as intense as the energy released by chemical reactions. The reason mankind had remained unaware of radioactivity and very aware of chemical reactions was, first, that the most common radioactive processes are so slow that their great energies were stretched over such enormous blocks of time as to be insignificant on a per second basis.

The energy from radioactivity is millions of times more intense than the energy released by chemical reactions. The reason people were unaware of radioactivity and very aware of chemical reactions is mainly that the most common radioactive processes are so slow that their enormous energy is spread out over such long periods of time that it seems insignificant on a per second basis.

Secondly, chemical reactions are easily controlled by changing quantities, concentrations, temperatures, pressures, states of mixtures, and so on, and this makes them easy to 59 take note of and to study. The rate of radioactive changes, however, could not apparently be altered. The early investigators quickly found that the breakdown of uranium-238, for instance, could not be hastened by heat, pressure, changes in chemical combination, or, indeed, anything else they could think of. It remained incredibly slow.

Secondly, chemical reactions can be easily controlled by adjusting quantities, concentrations, temperatures, pressures, mixtures, and so on, which makes them straightforward to observe and study. However, the rate of radioactive decay couldn't apparently be changed. Early researchers quickly discovered that the breakdown of uranium-238, for example, couldn't be sped up by heat, pressure, changes in chemical combinations, or anything else they could think of. It continued to be incredibly slow. 59

But despite all this, radioactivity had at last been discovered and the intensity of its energies was recognized and pointed out in 1902 by Marie Curie and her husband Pierre Curie (1859-1906).

But despite all this, radioactivity had finally been discovered, and the strength of its energies was acknowledged in 1902 by Marie Curie and her husband Pierre Curie (1859-1906).

Where, then, did the energy come from? Could it come from the outside? Could the radioactive atoms somehow collect energy from their surroundings, concentrate it several million-fold, and then let it out all at once?

Where did the energy come from? Could it come from outside? Could the radioactive atoms somehow gather energy from their surroundings, concentrate it millions of times, and then release it all at once?

To concentrate energy in this fashion would violate something called “the second law of thermodynamics”. This was first proposed in 1850 by the German physicist Rudolf Julius Emmanuel Clausius (1822-1888) and had proved so useful that physicists did not like to abandon it unless they absolutely had to.

To focus energy this way would go against something known as “the second law of thermodynamics.” This was first introduced in 1850 by the German physicist Rudolf Julius Emmanuel Clausius (1822-1888) and has been so valuable that physicists preferred to hold on to it unless they really had no choice.

Another possibility was that radioactive atoms were creating energy out of nothing. This, of course, violated the law of conservation of energy (also called “the first law of thermodynamics”) and physicists preferred not to do that either.

Another possibility was that radioactive atoms were generating energy from nothing. This, of course, went against the law of conservation of energy (also known as “the first law of thermodynamics”) and physicists were not keen on doing that either.

The only thing that seemed to remain was to suppose that somewhere within the atom was a source of energy that had never made itself evident to humanity until the discovery of radioactivity. Becquerel was one of the first to suggest this.

The only thing that seemed to be left was to assume that somewhere inside the atom was an energy source that had never shown itself to humanity until radioactivity was discovered. Becquerel was one of the first to suggest this.

It might have seemed at first that only radioactive elements had this supply of energy somewhere within the atom, but in 1903 Rutherford suggested that all atoms had a vast energy supply hidden within themselves. The supply in uranium and thorium leaked slightly, so to speak, and that was all that made them different.

It might have seemed at first that only radioactive elements had this energy source somewhere within the atom, but in 1903, Rutherford suggested that all atoms contained a huge energy supply hidden within them. The energy in uranium and thorium leaked a bit, so to speak, and that was all that set them apart.

60

The room in which the Curies discovered radium. Pierre Curie’s writing is on the blackboard.

The room where the Curies discovered radium. Pierre Curie's notes are on the blackboard.

61

But if a vast supply of energy existed in atoms, it was possible that the solution to the puzzle of the sun’s energy might rest there. As early as 1899 the American geologist Thomas Chrowder Chamberlin (1843-1928) was already speculating about a possible connection between radioactivity and the sun’s energy.

But if there was a huge amount of energy in atoms, it was possible that the answer to the mystery of the sun’s energy might be found there. As early as 1899, the American geologist Thomas Chrowder Chamberlin (1843-1928) was already considering a potential link between radioactivity and the sun’s energy.

If it were some variety of this newly discovered source of energy (not necessarily ordinary radioactivity, of course) that powered the sun—millions of times as intense as chemical energy—then the sun might be pouring out energy for hundreds of millions of years without perceptible physical change—just as uranium would show scarcely any change even in so mighty a time span. The sun would not have to be contracting; it would not have had to fill the earth’s orbit 25,000,000 years ago.

If this newly discovered energy source—maybe not just regular radioactivity—was what powered the sun, which is millions of times stronger than chemical energy, then the sun could be emitting energy for hundreds of millions of years without any noticeable physical change, similar to how uranium hardly changes over such a long time. The sun wouldn't need to be shrinking; it wouldn't have had to have filled the earth's orbit 25,000,000 years ago.

This was all exciting, but in 1900 the structure of the atom had not yet been worked out and this new energy was just a vague supposition. No one had any idea of what it actually might be or where in the atom it might be located. It could only be spoken of as existing “within the atom” and was therefore called “atomic energy”. Through long habit, it is still called that much of the time. And yet “atomic energy” is not a good name. In the first couple of decades of the 20th century, it became apparent that ordinary chemical energy involved electron shifts and those electrons were certainly components of atoms. This meant that a wood fire was a kind of atomic energy.

This was all exciting, but in 1900, the structure of the atom hadn’t been figured out yet, and this new energy was just a vague idea. No one knew what it actually was or where it could be found in the atom. It could only be referred to as existing “within the atom,” and so it became known as “atomic energy.” Out of habit, it’s still often called that. However, “atomic energy” isn’t a great name. In the first couple of decades of the 20th century, it became clear that regular chemical energy involved electron shifts, and those electrons were definitely parts of atoms. This meant that a wood fire was a type of atomic energy.

The electrons, however, existed only in the outer regions of the atom. Once Rutherford worked out the theory of the nuclear atom, it became apparent that the energy involved in radioactivity and in solar radiation had to involve components of the atom that were more massive and more energetic than the light electrons. The energy had to come, somehow, from the atomic nucleus.

The electrons existed only in the outer parts of the atom. Once Rutherford developed the theory of the nuclear atom, it became clear that the energy involved in radioactivity and solar radiation had to come from parts of the atom that were heavier and more energetic than the light electrons. The energy had to originate, in some way, from the atomic nucleus.

What is involved then in radioactivity and in the sun is “nuclear energy”. That is the proper name for it and in the 62 next section we will consider the subsequent history of the nuclear energy that broke upon the startled consciousness of scientists as the 20th century opened and which, less than half a century later, was to face mankind with untold consequences for good and for evil.

What’s involved in radioactivity and in the sun is "nuclear energy." That’s the correct term, and in the 62 next section, we will look at the history of the nuclear energy that surprised scientists as the 20th century began, and that, less than fifty years later, would present humanity with unknown consequences, both positive and negative.

FOOTNOTES

[1]“Mass” is the correct term, but “weight”, which is a somewhat different thing, is so commonly used instead that in this book I won’t try to make any distinction.
63

QUOTATION CREDIT

Inside front cover Copyright © by Abelard-Shuman, Ltd., New York. Reprinted by permission from Inside the Atom, Isaac Asimov, 1966.

PHOTO CREDITS

Cover The Metropolitan Museum of Art
Page facing inside cover The “Horsehead” Nebula in Orion. Hale Observatories.
Author’s Photo Jay K. Klein
Contents page & page 4 Lick Observatory
Page
7 New York Public Library
9 From Discovery of the Elements, Mary E. Weeks, Chemical Education Publishing Company, 1968.
12 Library of Congress
15 Sir George Thomson
18 Burndy Library
19 New York Public Library
21 Copyright © 1965 by Barbara Lovett Cline, reprinted from her volume The Questioners: Physicists and the Quantum Theory by permission of Thomas Y. Crowell Company, Inc., New York.
22 & 23 Curie Foundation, Institute of Radium
26 Academic Press, Inc.
29 Van Nostrand Reinhold Company
31 Top, Nobel Institute; bottom, from Discovery of the Elements, Mary E. Weeks, Chemical Education Publishing Company, 1968.
32 From Discovery of the Elements, Mary E. Weeks, Chemical Education Publishing Company, 1968.
34 Top, Nobel Institute; bottom, Niels Bohr Institute.
36, 42, 44, & 45 Nobel Institute
48 Academic Press, Inc.
49 From Discovery of the Elements, Mary E. Weeks, Chemical Education Publishing Company, 1968.
60 Curie Foundation, Institute of Radium

★ U.S. GOVERNMENT PRINTING OFFICE: 1975—640—285/13

★ U.S. GOVERNMENT PRINTING OFFICE: 1975—640—285/13

A word about ERDA....

The mission of the U. S. Energy Research & Development Administration (ERDA) is to develop all energy sources, to make the Nation basically self-sufficient in energy, and to protect public health and welfare and the environment. ERDA programs are divided into six major categories:

The mission of the U.S. Energy Research & Development Administration (ERDA) is to develop all energy sources, to make the nation largely self-sufficient in energy, and to protect public health, welfare, and the environment. ERDA programs are divided into six main categories:

· CONSERVATION OF ENERGY—More efficient use of existing energy sources, development of alternate fuels and engines for automobiles to reduce dependence on petroleum, and elimination of wasteful habits of energy consumption.

· CONSERVATION OF ENERGY—Using existing energy sources more efficiently, creating alternative fuels and engines for cars to lessen reliance on oil, and stopping wasteful energy consumption habits.

· FOSSIL ENERGY—Expansion of coal production and the development of technologies for converting coal to synthetic gas and liquid fuels, improvement of oil drilling methods and of techniques for converting shale deposits to usable oil.

· FOSSIL ENERGY—Growth in coal production and the advancement of technologies to turn coal into synthetic gas and liquid fuels, enhancements in oil drilling methods, and improvements in techniques for transforming shale deposits into usable oil.

· SOLAR, GEOTHERMAL, AND ADVANCED ENERGY SYSTEMS—Research on solar energy to heat, cool, and eventually electrify buildings, on conversion of underground heat sources to gas and electricity, and on fusion reactors for the generation of electricity.

· SOLAR, GEOTHERMAL, AND ADVANCED ENERGY SYSTEMS—Research on solar energy for heating, cooling, and eventually powering buildings, on converting underground heat sources to gas and electricity, and on fusion reactors for generating electricity.

· ENVIRONMENT AND SAFETY—Investigation of health, safety, and environmental effects of the development of energy technologies, and research on management of wastes from energy production.

· ENVIRONMENT AND SAFETY—Research into the health, safety, and environmental impacts of developing energy technologies, as well as studies on waste management from energy production.

· NUCLEAR ENERGY—Expanding medical, industrial and research applications and upgrading reactor technologies for the generation of electricity, particularly using the breeder concept.

· NUCLEAR ENERGY—Growing medical, industrial, and research applications while improving reactor technologies for electricity generation, especially through the breeder concept.

· NATIONAL SECURITY—Production and administration of nuclear materials serving both civilian and military needs.

· NATIONAL SECURITY—The production and management of nuclear materials for both civilian and military purposes.

ERDA programs are carried out by contract and cooperation with industry, university communities, and other government agencies. For more information, write to USERDA—Technical Information Center, P. O. Box 62, Oak Ridge, Tennessee 37830.

ERDA programs are conducted through contracts and collaborations with industry, university communities, and other government agencies. For more details, contact USERDA—Technical Information Center, P. O. Box 62, Oak Ridge, Tennessee 37830.

ENERGY RESEARCH & DEVELOPMENT ADMINISTRATION USA

United States
Energy Research and Development Administration
Office of Public Affairs
Washington, D.C. 20545

United States
Energy Research and Development Administration
Office of Public Affairs
Washington, D.C. 20545

Transcriber’s Notes

  • In the text version only, underlined or italicized text is delimited by _underscores_.
  • Where possible, UTF superscript and subscript numbers are used; some e-reader fonts may not support these characters.
  • In the text versions only, other superscript text is preceded by caret and delimited by ^{brackets}.
  • In the text versions only, other subscripted text is preceded by underscore and delimited by _{brackets}.

Special Note on Links between Gutenberg eBooks

The Table of Contents in each volume contains relative hyperlinks to pages in all three volumes of Worlds Within Worlds:

The Table of Contents in each volume includes relevant hyperlinks to pages in all three volumes of Worlds Within Worlds:

These links function correctly if the books are read online, and can be made to work for books installed on a local drive or a website. (EBook-reader formats like ePub or Mobi do not support links between eBooks.)

These links work properly when the books are read online and can also be set up for books stored on a local drive or a website. (EBook formats like ePub or Mobi do not support links between eBooks.)

localbooks/
40000/
40000-h/
40000-h.htm
images/
...
40001/
40001-h/
40001-h.htm
images/
...
...

HTML files are in a subdirectory named by the Gutenberg number followed by “-h”.

HTML files are in a subfolder named after the Gutenberg number followed by “-h”.

The HTML file itself has a name consisting of the Gutenberg number followed by “-h”, with a file extension of “.htm”.

The HTML file is named with the Gutenberg number followed by “-h” and has a file extension of “.htm”.

Associated media files (such as images, MIDI files, etc.) are contained in a further subdirectory “images”

Associated media files (like images, MIDI files, etc.) are located in an additional subdirectory called "images."

To view these files, open any of the “*-h.htm” files in a web browser.

To view these files, open any of the “*-h.htm” files in a web browser.


Download ePUB

If you like this ebook, consider a donation!